Search NASA⌕ Search

SEARCH · Search NASA

Results for “Range expansion”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS1961

The Effect on Thrust Minus Base Drag of Exchanging Base Area for Nozzle Expansion in Supersonic Nozzles at Transonic Mach Numbers

A wind-tunnel investigation to determine the effect on thrust minus base drag of exchanging base area for nozzle overexpansion on a cylindrical afterbody with a single supersonic nozzle has been conducted a t Mach numbers from 0.9 t o 1.4. The throat-to-base diameter ratio has been varied from 0.320 to 0.550; the jet-to-base diameter ratio has been varied from 0.320 to 1, resulting in a jet Mach number variation of 1.0 to 3.897. The jet total-pressure ratio ranged from 2 to approximately 22. The results indicated that a proper balance between nozzle over-expansion and base area exists, which will produce the maximum afterbody net-thrust factor over a given operating range. For a given Mach number and throat-to-base diameter ratio, the optimum values of jet-to-base diameter ratio corresponding to the peak values of the net-thrust factor are, in general, larger than the values at the jet design pressure ratio and tend to increase with increasing j e t total-pressure ratio in a manner similar to the design values. Also, for given values of throat-to-base diameter ratio and jet total-pressure ratio, the optimum value of jet-to-base diameter ratio changed as the free-stream Mach number was varied from transonic to low supersonic speeds. The magnitude of the changes varied with jet total-pressure ratio and throat-to-base diameter ratio.

Slocumb, Travis H.↗
DOE OSTI2021

Effect of polycarboxylate ether on the expansion of ye'elimite hydration in the presence of anhydrite

Polycarboxylate ether (PCE), a commonly used superplasticizer, is known to influence the morphology of ettringite during the early hydration of C{sub 3}A- and ye'elimite-containing cements. According to existing theories, such morphological changes may be crucial to the expansive behavior of these cements. This paper studied the expansion of ye'elimite-anhydrite pastes and found the use of PCE to reduce expansion after 4 days of curing. Hydration studies were conducted by calorimetry, X-ray diffractometry, scanning electron microscopy, mercury intrusion porosimetry, inductively coupled plasma–optical emission spectrometry, and X-ray microtomography. The results show that the influences of PCE on the morphology of ettringite and the hydration of ye'elimite were quite small after 2 days. Based on the crystal growth theory, the range of pores in which ettringite can grow was calculated to explain the observed expansive behaviors. The presence of ettringite nano-crystals in aluminum hydroxide was also revealed and considered as a possible expansion mechanism.

36 MATERIALS SCIENCE↗
NASA NTRS2001

Isolated Performance at Mach Numbers From 0.60 to 2.86 of Several Expendable Nozzle Concepts for Supersonic Applications

Investigations have been conducted in the Langley 16-Foot Transonic Tunnel (at Mach numbers from 0.60 to 1.25) and in the Langley Unitary Plan Wind Tunnel (at Mach numbers from 2.16 to 2.86) at an angle of attack of 0 deg to determine the isolated performance of several expendable nozzle concepts for supersonic nonaugmented turbojet applications. The effects of centerbody base shape, shroud length, shroud ventilation, cruciform shroud expansion ratio, and cruciform shroud flap vectoring were investigated. The nozzle pressure ratio range, which was a function of Mach number, was between 1.9 and 11.8 in the 16-Foot Transonic Tunnel and between 7.9 and 54.9 in the Unitary Plan Wind Tunnel. Discharge coefficient, thrust-minus-drag, and the forces and moments generated by vectoring the divergent shroud flaps (for Mach numbers of 0.60 to 1.25 only) of a cruciform nozzle configuration were measured. The shortest nozzle had the best thrust-minus-drag performance at Mach numbers up to 0.95 but was approached in performance by other configurations at Mach numbers of 1.15 and 1.25. At Mach numbers above 1.25, the cruciform nozzle configuration having the same expansion ratio (2.64) as the fixed geometry nozzles had the best thrust-minus-drag performance. Ventilation of the fixed geometry divergent shrouds to the nozzle external boattail flow generally improved thrust-minus-drag performance at Mach numbers from 0.60 to 1.25, but decreased performance above a Mach number of 1.25.

Re, Richard J.↗
DOE OSTI2021

Predicting the Pseudocapacitive Windows for MXene Electrodes with Voltage-Dependent Cluster Expansion Models

MXene transition-metal carbides and nitrides are of growing interest for energy storage applications. These compounds are especially promising for use as pseudocapacitive electrodes due to their ability to convert energy electrochemically at fast rates. Using voltage-dependent cluster expansion models, we predict the charge storage performance of MXene pseudocapacitors for a range of electrode compositions. M 3 C 2 O 2 electrodes based on group-VI transition metals have up to 80% larger areal energy densities than prototypical titanium-based (e.g., Ti 3 C 2 O 2 ) MXene electrodes. We attribute this high pseudocapacitance to the Faradaic voltage windows of group-VI MXene electrodes, which are predicted to be 1.2 to 1.8 times larger than those of titanium-based MXenes. The size of the pseudocapacitive voltage window increases with the range of oxidation states that are accessible to the MXene transition metals. Here, by similar mechanisms, the presence of multiple ions in the solvent (Li + and H + ) leads to sharp changes in the transition-metal oxidation states and can significantly increase the charge capacity of MXene pseudocapacitors.

36 MATERIALS SCIENCE↗
NASA NTRS1984

Thermal expansion uniformity of materials for large telescope mirrors

Uniformity of thermal expansion has been measured for fused quartz and borosilicate glass. The variation of expansion coefficient for three melts of TO8E was 5 x 10 to the -9th/K over a temperature range of 300 to 100 K and was found to vary linearly with position in the melt. This spatial gradient averaged 3.5 x 10 to the -11th/K-cm. The room-temperature thermal expansivity variation of Duran (Tempax) glass was about 27 x 10 to the -9th/K, while that of E6 glass was about 52 x 10 to the -9th/K.

Jacobs, S. F.↗
DOE OSTI2022

Towards new zero-thermal-expansion materials: Li-free quartz solid solutions stuffed with transition metal cations

Stuffed aluminosilicate quartz solid solutions (Qss) represent the main functional component of state-of-the-art zero-thermal-expansion glass-ceramics. For the first time, we present the synthesis of Li-, Mg- and Zn-free Qss solely stuffed with transition metal cations (Fe 2+ , Ni 2+ , Co 2+ ); partial Li + co-doping enables also significant Mn 2+ incorporation. Further, they were obtained by glass powder crystallization; Qss crystals exhibit compositionally tunable coefficients of thermal expansion (CTEs), from - 2 × 10 -6 K -1 to ~10 × 10 -6 K -1 in the range 30–300 °C. Co 2+ -bearing crystals exhibit the closest-to-zero CTE value (0.2 ×10 -6 K -1 ) and the most isotropic behavior in the whole Qss family, opening up new perspectives for the development of Li-free low-expansion materials. From a structural point of view, we identified the unit cell volume (and not the pseudo-hexagonality of the aluminosilicate framework) as the key structural parameter leading to low or negative CTEs in Qss, with a linear correlation extending to non-stuffed non-silicate quartz-like phases.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Effect of lot microstructure variations on detonation performance of the triaminotrinitrobenzene (TATB)-Based insensitive high explosive PBX 9502

PBX 9502 is an important insensitive high explosive due to its combination of safety properties and detonation performance. It is a polymer-bonded formulation consisting of 95 wt.% 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) as the high explosive crystal, bound with Kel F-800 (FK-800), a co-polymer of chlorotrifluoroethylene and vinylidene-fluoride. Two different types are used, one known as virgin that uses only pristine manufactured TATB, and a second known as recycled that has 50 wt.% of its TATB reclaimed from machining scraps of previously pressed virgin PBX 9502. Recycled lots have a higher percentage of fine particles compared to virgin lots, due to the fracturing and damage sustained by TATB crystals during pressing. We examine the influence that this TATB microstructure difference between virgin and recycled PBX 9502 has on detonation performance properties. New rate-stick geometry diameter effect, detonation front shape and cylinder expansion test data are obtained for two previously uncharacterized virgin lots and one recycled lot of PBX 9502. This is combined with previously published data for one virgin and one recycled lot for evaluation purposes. Detonation shock dynamics model calibrations are conducted on each of the five lots to provide an assessment of the detonation timing characteristics of virgin versus recycled PBX 9502 lots. For two of the virgin lots, detonations propagate slower in the rate-stick geometry than those in the two recycled lots. However, the other virgin lot tested has propagation rates comparable to that of the recycled lots for larger diameter rate-sticks. The latter result, though, is shown to be geometry dependent and depends on the range of detonation curvatures accessed in different geometries. New copper-confined, cylinder expansion tests are conducted on each of the three virgin and two recycled lots to obtain detonation product Jones-Wilkins-Lee equations of state, enabling an assessment of the metal push capabilities for each of the five lots. We find that the metal push capabilities, characterized by the evolution of the heat of detonation with volume, are similar between the virgin and recycled lots. Thus, changes in microstructure between different PBX 9502 lots seemingly affect the rate of reaction, but not the overall energy content.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1973

A technique for measuring hypersonic flow velocity profiles

A technique for measuring hypersonic flow velocity profiles is described. This technique utilizes an arc-discharge-electron-beam system to produce a luminous disturbance in the flow. The time of flight of this disturbance was measured. Experimental tests were conducted in the Langley pilot model expansion tube. The measured velocities were of the order of 6000 m/sec over a free-stream density range from 0.000196 to 0.00186 kg/cu m. The fractional error in the velocity measurements was less than 5 percent. Long arc discharge columns (0.356 m) were generated under hypersonic flow conditions in the expansion-tube modified to operate as an expansion tunnel.

Gartrell, L. R.↗
NASA NTRS1961

Aerodynamic Loading Characteristics at Mach Numbers from 0.80 to 1.20 of a 1/10-Scale Three-Stage Scout Model

Aerodynamic loads results have been obtained in the Langley 8-foot transonic pressure tunnel at Mach numbers from 0.80 to 1.20 for a 1/10-scale model of the upper three stages of the Scout vehicle. Tests were conducted through an angle-of-attack range from -8 deg to 8 deg at an average test Reynolds number per foot of about 4.0 x 10(exp 6). Results indicated that the peak negative pressures associated with expansion corners at the nose and transition flare exhibit sizeable variations which occur over a relatively small Mach number range. The magnitude of the variations may cause the critical local loading condition for the full-scale vehicle to occur at a Mach number considerably lower than that at which the maximum dynamic pressure occurs in flight. The addition of protuberances simulating antennas and wiring conduits had slight, localized effects. The lift carryover from the nose and transition flare on the cylindrical portions of the model generally increased with an increase in Mach number.

Kelly, Thomas C.↗
DOE OSTI2022

Breaking covalent bonds in the context of the many-body expansion (MBE). I. The purported “first row anomaly” in XH n (X = C, Si, Ge, Sn; n = 1–4)

We present a new, novel implementation of the Many-Body Expansion (MBE) to account for the breaking of covalent bonds, thus extending the range of applications from its previous popular usage in the breaking of hydrogen bonds in clusters to molecules. A central concept of the new implementation is the in situ atomic electronic state of an atom in a molecule that casts the one-body term as the energy required to promote it to that state from its ground state. The rest of the terms correspond to the individual diatomic, triatomic, etc., fragments. Its application to the atomization energies of the XH n series, X = C, Si, Ge, Sn and n = 1–4, suggests that the (negative, stabilizing) 2-B is by far the largest term in the MBE with the higher order terms oscillating between positive and negative values and decreasing dramatically in size with increasing rank of the expansion. The analysis offers an alternative explanation for the purported “first row anomaly” in the incremental H n–1 X–H bond energies seen when these energies are evaluated with respect to the lowest energy among the states of the XH n molecules. Due to the “flipping” of the ground/first excited state between CH 2 ( 3 B 1 ground state, 1 A 1 first excited state) and XH 2 , X = Si, Ge, Sn ( 1 A 1 ground state, 3 B 1 first excited state), the overall picture does not exhibit a “first row anomaly” when the incremental bond energies are evaluated with respect to the molecular states having the same in situ atomic states.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1981

Helicopter rotor loads using a matched asymptotic expansion technique

The theoretical basis and computational feasibility of the Van Holten method, and its performance and range of validity by comparison with experiment and other approximate methods was examined. It is found that within the restrictions of incompressible, potential flow and the assumption of small disturbances, the method does lead to a valid description of the flow. However, the method begins to break down under conditions favoring nonlinear effects such as wake distortion and blade/rotor interaction.

Pierce, G. A.↗
DOE OSTI2022

Interaction-expansion inchworm Monte Carlo solver for lattice and impurity models

Multiorbital quantum impurity models with general interaction and hybridization terms appear in a wide range of applications, including embedding, quantum transport, and nanoscience. However, most quantum impurity solvers are restricted to a few impurity orbitals, discretized baths, diagonal hybridizations, or density-density interactions. We generalize the inchworm quantum Monte Carlo method to the interaction expansion, and we explore its application to typical single- and multiorbital problems encountered in investigations of impurity and lattice models. Our implementation generically outperforms bare and bold-line quantum Monte Carlo algorithms in the interaction expansion. For the systems studied here, our implementation remains inferior to the more specialized hybridization expansion and auxiliary field algorithms. So, the problem of convergence to unphysical fixed points, which hampers so-called bold-line methods, is not encountered in inchworm Monte Carlo.

36 MATERIALS SCIENCE↗
DOE OSTI2025

First-principles thermodynamics of Al 10 ⁢V: An analytical treatment of localized anharmonic modes

Many complex intermetallic structures possess cagelike environments that can host additional guest atoms. In Al 10 ⁢V, these atoms give rise to low-frequency, localized vibrations (Einstein modes) that dominate the thermodynamic response at low temperature. They become imaginary under volume expansion as temperature rises, invalidating the harmonic approximation. Here, we develop a framework to incorporate these strongly anharmonic vibrational modes into first-principles thermodynamic calculations. By explicitly modeling the cage potential and solving the associated Schrödinger equation numerically, we compute the full anharmonic free energy contribution and demonstrate its impact on the thermodynamic behavior of Al 10⁢ V. This allows us to examine structures with different cage fillings and construct the Al-V phase diagram in the relevant composition range. Our results reproduce key experimental signatures, including the anomalous rise in the thermal expansion coefficient and heat capacity at low temperatures, and reveal that the presence and the extent of cage filling by guest atoms is essential to stabilizing the Al 10 ⁢V phase at elevated temperatures.

anharmonic lattice dynamics↗
DOE OSTI2025

Periodic GFN1-xTB Tight Binding: A Generalized Ewald Partitioning Scheme for the Klopman–Ohno Function

A novel formulation is presented for the treatment of electrostatics in the periodic GFN1-xTB tight-binding model. Periodic GFN1-xTB is hindered by the functional form of the second-order electrostatics, which only recovers Coulombic behavior at large interatomic distances and lacks a closed-form solution for its Fourier transform. We address this by introducing a binomial expansion of the Klopman–Ohno function to partition short- and long-range interactions, enabling the use of a generalized Ewald summation for the solution of the electrostatic energy. This approach is general and is applicable to any damped potential of the form |R n + c| –m . Benchmarks on the X23 molecular crystal dataset and a range of prototypical bulk semiconductors demonstrate that this systematic treatment of the electrostatics eliminates unphysical behavior in the equation of state curves. In the bulk systems studied, we observe a mean absolute error in total energy of 35 meV/atom, comparable to the machine-learned universal force field, M3GNet, and sufficiently precise for structure relaxation. These results highlight the promising potential of GFN1-xTB as a universal tight-binding parametrization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Advanced thermal/environmental barrier coatings of high-entropy rare earth disilicates tuned by strong anharmonicity of Eu 2 Si 2 O 7

Advancing thermal/environmental barrier coating (TEBC) materials with integrated thermal-mechanical functions is paramount for safeguarding SiC-based ceramic matrix composites (CMCs) in high-efficiency gas turbines. Herein, we employ a synergistic approach, combining density functional theory (DFT) methods and combinatorial chemistry techniques, to design high-performance and low-cost RE 2 Si 2 O 7 (RE = rare earth elements) TEBC materials tailored for enhanced compatibility with SiC-based CMCs. Expanding on phase stability of alloying pure RE 2 Si 2 O 7 , the investigation extends to the mechanical and thermal properties of solid solution systems, including Er 1/2 Y 3/4 Yb 3/4 Si 2 O 7 , Gd 1/4 Er 1/4 Y 3/4 Yb 3/4 Si 2 O 7 , and Eu 1/4 Er 1/4 Y 3/4 Yb 3/4 Si 2 O 7 . The solid solution systems exhibit a major reduction in lattice thermal conductivity relative to their pure counterparts, achieving ultralow values of 0.25 to 0.39 W m −1 K −1 at 1500 K. Furthermore, the coefficients of thermal expansion (CTE) of these solid solutions are precisely tuned within the desired range for SiC (4.4 to 5.5 × 10 −6 K −1 ), while maintaining good mechanical properties. Here, in particular, the addition of Eu 2 Si 2 O 7 demonstrates to be an important variable to the tuning of CTE and lattice thermal conductivity by leveraging its strong anharmonicity, presenting a pioneering avenue for fine-tuning material properties. In summary, this research not only identifies promising TEBC materials with superior thermal properties, but also introduces a valuable computational material design methodology for the rapid discovery of complex materials for harsh environments.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Plans for Expanded Data Testing at ORNL [Slides]

VALID expansion is on-going and should provide coverage over a wider range of systems in the future. Adding additional application types beyond critical experiments can also be used in expanded data testing. Two other test suites have been developed at ORNL for other purposes, but never waste a good test suite. These suites are more likely to be relevant to testing differences in data as compared to assessing accuracy of evaluations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2024

The Thermophysical Properties of TcO2

Technetium-99 is a highly radioactive isotope with a long half-life that is common in nuclear waste. It volatizes at a low temperature, which poses a significant challenge to the clean-up and containment processes. Due to difficulties in purifying technetium compounds, their thermophysical properties have not been measured or calculated. Here, first principle methods are used along with the quasi quasi-harmonic harmonic approximation to compute the Debye temperature, volumetric thermal expansion coefficient, bulk modulus, and heat capacity of rutile TcO2 for temperatures ranging from 0 to 1500 K and applied pressures ranging from 0 to 255 GPa. The computed atomic structures agree well with the results from diffraction measurements. The computed thermophysical properties are in the neighborhood of other rutile metal oxides and, in particular, are within approximately 10–13% of rutile ReO2, which is frequently used as a substitute for TcO2 in experimental studies.

Zhong, Hong↗
NASA NTRS1974

Flight-test investigation of the aerodynamic characteristics and flow interference effects about the aft fuselage of the F-111A airplane

Static pressure measurements were made on the aft fuselage of an F-111A airplane to determine local flow characteristics and engine/airframe interaction effects. Data were obtained over the Mach number range from 0.5 to 2.0. Aspiration effects associated with low ejector nozzle expansion ratios reduced the local pressure coefficients particularly on the interfairing but also extending to the trailing edge of the nacelle. The presence of afterbodies also affected the behavior of the air flowing into and about the ejector nozzle. Pressures about the aft fuselage were improved by an increase in primary nozzle area at a supersonic speed. A comparison of wind-tunnel and flight-test results showed generally good agreement, although there was a large disparity in pressure level about the ejector nozzle. However, the shape of the data curves and the local flow behavior were basically similar.

Taillon, N. V.↗