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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Multiwavelength Afterglow Analysis of GRB 221009A: Unveiling the Evolution of a Cooling Break in a Wind-like Medium

Gamma-ray bursts (GRBs) are the most energetic explosions in the Universe, and their afterglow emission provides an opportunity to probe the physics of relativistic shock waves in an extreme environment. Several key pieces for completing the picture of GRB afterglow physics are still missing, including jet properties, the emission mechanism, and particle acceleration. Here, we present a study of the afterglow emission of GRB 221009A, the most energetic GRB ever observed. Using optical, X-ray, and gamma-ray data up to approximately 2 days after the trigger, we trace the evolution of the multiwavelength spectrum and the physical parameters behind the emission process. The broadband spectrum is consistent with the synchrotron emission emitted by relativistic electrons with its index of p = 2.29 ± 0.02. We identify a break energy at keV and an exponential cutoff at GeV in the observed multiwavelength spectrum. The break energy increases in time from $16.0^{+7.1}_{-4.9}$ keV at 0.65 days to $46.8^{+25.0}_{-15.5}$ keV at 1.68 days, favoring a stellar-wind-like profile of the circumburst medium with k = 2.4 ± 0.1 as in ρ(r) ∝ r -k . The high-energy attenuation at around 0.4 to 4 GeV is attributed to the maximum of the particle acceleration in the relativistic shock wave. This study confirms that the synchrotron process can explain the multiwavelength afterglow emission and its evolution.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Fossil Corals With Various Degrees of Preservation Can Retain Information About Biomineralization-Related Organic Material

Scleractinian corals typically form a robust calcium carbonate skeleton beneath their living tissue. This skeleton, through its trace element composition and isotope ratios, may record environmental conditions of water surrounding the coral animal. While bulk unrecrystallized aragonite coral skeletons can be used to reconstruct past ocean conditions, corals that have undergone significant diagenesis have altered geochemical signatures and are typically assumed to retain insufficient meaningful information for bulk or macrostructural analysis. However, partially recrystallized skeletons may retain organic molecular components of the skeletal organic matrix (SOM), which is secreted by the animal and directs aspects of the biomineralization process. Some SOM proteins can be retained in fossil corals and can potentially provide past oceanographic, ecological, and indirect genetic information. Here, we describe a dataset of scleractinian coral skeletons, aged from modern to Cretaceous plus a Carboniferous rugosan, characterized for their crystallography, trace element composition, and amino acid compositions. We show that some specimens that are partially recrystallized to calcite yield potentially useful biochemical information whereas complete recrystalization or silicification leads to significant alteration or loss of the SOM fraction. Our analysis is informative to biochemical-paleoceanographers as it suggests that previously discounted partially recrystallized coral skeletons may indeed still be useful at the microstructural level.

58 GEOSCIENCES↗
DOE OSTI2025

Imaging a light-induced molecular elimination reaction with an X-ray free-electron laser

Tracking the motion of individual atoms during chemical reactions represents a severe experimental challenge, especially if several competing reaction pathways exist or if the reaction is governed by the correlated motion of more than two molecular constituents. Here we demonstrate how ultrashort X-ray pulses combined with coincident ion imaging can be used to trace molecular iodine elimination from laser-irradiated diiodomethane (CH 2 I 2 ), a reaction channel of fundamental importance but small relative yield that involves the breaking of two molecular bonds and the formation of a new one. We map bending vibrations of the bound molecule, disentangle different dissociation pathways, image the correlated motion of the iodine atoms and the methylene group leading to molecular iodine ejection, and trace the vibrational motion of the formed product. Our results provide a quantitative mechanistic picture behind previously suggested reaction mechanisms and prove that a variety of geometries are involved in the molecular bond formation.

Atomic and molecular interactions with photons↗
DOE OSTI2020

Characterization of groove density variation of VLS gratings with ALS XROL LTP-II in different operation modes

The long trace profiler, LTP-II, available at the Advanced Light Source (ALS) X-ray Optics Laboratory (XROL), was recently upgraded by replacing a multimode diode laser light source with a single-mode, wavelength-stabilized, fibercoupled diode laser system. The upgrade enables us to reliably characterize the lateral variation of groove density of variable-line-spacing (VLS) x-ray diffraction gratings. Here, we discuss the LTP-II performance with an example of measurements with a VLS grating with the groove density at the grating center of 300 lines/mm. For the measurements, we use the LTP-II in two different operation arrangements, the single Gaussian beam and the pencil beam interferometer arrangements. For each operation arrangement, we apply two data processing algorithms: with calculating the centroid position and with determining the position of a characteristic features of the detected beam intensity distributions. Additionally, we discuss the observed strong correlation between the LTP-II modes of operation and the resulted (extracted) groove density variations. We also speculate on possible origin of the correlation.

42 ENGINEERING↗
DOE OSTI2021

Unraveling the advances of trace doping engineering for potassium ion battery anodes via tomography

Doping have been considered as a prominent strategy to stabilize crystal structure of battery materials during the insertion and removal of alkali ions. The instructive knowledge and experience acquired from doping strategies predominate in cathode materials, but doping principle in anodes remains unclear. Here, we demonstrate that trace element doping enables stable conversion-reaction and ensures structural integrity for potassium ion battery (PIB) anodes. With a synergistic combination of X-ray tomography, structural probes, and charge reconfiguration, we encode the physical origins and structural evolution of electro-chemo-mechanical degradation in PIB anodes. By the multiple ion transport pathways created by the orderly hierarchical pores from “surface to bulk” and the homogeneous charge distribution governed in doped nanodomains, the anisotropic expansion can be significantly relieved with trace isoelectronic element doping into the host lattice, maintaining particle mechanical integrity. Our work presents a close relationship between doping chemistry and mechanical reliability, projecting a new pathway to reengineering electrode materials for next-generation energy storage.

25 ENERGY STORAGE↗
DOE OSTI2025

Discovery of a z ∼ 0.8 ultra steep spectrum radio halo in the MeerKAT-South Pole Telescope Survey

Radio haloes are diffuse synchrotron sources that trace the turbulent intracluster medium (ICM) of galaxy clusters. However, their origin remains unknown. Two main formation models have been proposed: the hadronic model, in which relativistic electrons are continuously injected by cosmic-ray protons; and the leptonic turbulent re-acceleration model, where cluster mergers re-energize electrons in situ. A key discriminant between the two models would be the existence of ultra-steep spectrum radio haloes (USSRHs), which can only be produced through turbulent re-acceleration. Here, we report the discovery of an USSRH in the galaxy cluster SPT-CLJ2337–5942 at redshift $z = 0.78$ in the MeerKAT-South Pole Telescope 100 deg$^2$ UHF (0.58–1.09 GHz) survey. This discovery is noteworthy for two primary reasons: it is the highest redshift USSRH system to date; and the close correspondence of the radio emission with the thermal ICM as traced by Chandra X-ray observations, further supporting the leptonic re-acceleration model. The halo is underluminous for its mass, consistent with a minor merger origin, which produces steep-spectrum, lower luminosity haloes. This result demonstrates the power of wide-field, high-fidelity, low-frequency ($\lesssim 1$ GHz) surveys like the MeerKAT-SPT 100 deg$^2$ programme to probe the origin and evolution of radio haloes over cosmic time, ahead of the Square Kilometre Array.

X-rays: galaxies↗
DOE OSTI2020

Simultaneous observations of the blazar PKS 2155-304 from ultra-violet to TeV energies

Here we report the results of the first ever contemporaneous multi-wavelength observation campaign on the BL Lac object PKS 2155−304 involving Swift , NuSTAR , Fermi -LAT, and H.E.S.S. The use of these instruments allows us to cover a broad energy range, which is important for disentangling the different radiative mechanisms. The source, observed from June 2013 to October 2013, was found in a low flux state with respect to previous observations but exhibited highly significant flux variability in the X-rays. The high-energy end of the synchrotron spectrum can be traced up to 40 keV without significant contamination by high-energy emission. A one-zone synchrotron self-Compton model was used to reproduce the broadband flux of the source for all the observations presented here but failed for previous observations made in April 2013. A lepto-hadronic solution was then explored to explain these earlier observational results.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

In situ X-ray spatial profiling reveals uneven compression of electrode assemblies and steep lateral gradients in lithium-ion coin cells

Coin cells are used extensively as test devices in battery research for evaluation of new materials and optimization of cycling protocols. Here, in situ X-ray diffraction profilometry is used to characterize spatial distribution of the active materials, lithiation, and phase distribution in electrodes of NCM523/graphite coin cells. The X-ray data indicate uneven areal compression of the electrode assembly in such cells, which we trace to a specific design feature that leads to elastic deformation of a metal spacer. Steep lithiation gradients observed in the electrodes imply radially-dependent resistivity, for which uneven compression of the separator is a likely cause. Electrochemical model calculations suggest that variable porosity of the polymer separator would account for the salient features of spatial profiles observed in these coin cells.

25 ENERGY STORAGE↗
DOE OSTI2022

Upgrades to the gamma ray imager on DIII-D enabling access to high flux hard x-ray measurements during the runaway electron plateau phase (invited)

The Gamma Ray Imager (GRI) is a pinhole camera providing 2D imaging of MeV hard x-ray (HXR) bremsstrahlung emission from runaway electrons (REs) over the poloidal cross section of the DIII-D tokamak. We report a series of upgrades to the GRI expanding the access to RE scenarios from the diagnosis of a trace amount of REs to high flux HXR measurements during the RE plateau phase. We present the implementation of novel gamma ray detectors based on LYSO and YAP crystals coupled to multi-pixel photon counters, enabling a count rate in excess of 1 MHz. Finally, we highlight new insights into the RE physics discovered during the current quench and RE plateau phase experiments as the result of these upgrades.

Lvovskiy, A. (ORCID:0000000236491169)↗
DOE OSTI2023

The status of the galactic center gamma-ray excess

The Galactic Center Gamma-Ray Excess has a spectrum, angular distribution, and overall intensity that agree remarkably well with that expected from annihilating dark matter particles in the form of a m_X \sim m X ∼ 50 GeV thermal relic. Previous claims that these photons are clustered on small angular scales or trace the distribution of known stellar populations once appeared to favor interpretations in which this signal originates from a large population of unresolved millisecond pulsars. More recent work, however, has overturned these conclusions, finding that the observed gamma-ray excess does not contain discernible small scale power, and is distributed with approximate spherical symmetry, not tracing any known stellar populations. In light of these results, it now appears significantly more likely that the Galactic Center Gamma-Ray Excess is produced by annihilating dark matter.

Hooper, Dan↗
DOE OSTI2025

Probing the Surface Chemistry of Lithium Nitridation

Chemical synthesis of Li 3 N through lithium nitridation has potential to advance rechargeable battery and nitrogen fixation technology. However, studies of the conditions for forming Li 3 N on the lithium surface via nitrogen gas exposure report contradictory findings, such as the spontaneous reaction of Li with pure N 2 , the impossibility of forming Li 3 N through pure Li and N 2 interaction, the requirement of trace H 2 O to catalyze the reaction, and evidence to the contrary. In this study, ambient pressure X-ray photoelectron spectroscopy (APXPS) was applied to evaluate the in situ chemical evolution of the lithium metal surface under nitrogen gas up to 800 mTorr. At pressures ≤10 mTorr, no Li 3 N was detected. At higher pressures, surface Li 3 N rapidly reacts with trace CO 2 . Additionally, because metallic lithium is readily oxidized by trace gases, the atomic nitrogen concentration of the lithium surface remains below 2%. When nitridation follows oxidation by O 2 gas, CO 2 gas, or H 2 O vapor, surface Li 3 N formation is inhibited. These results suggest that nitrogen gas can diffuse through the oxidized lithium metal surface to react with subsurface metallic lithium.

Binding energy↗
DOE OSTI2022

The Status of the Galactic Center Gamma-Ray Excess

The Galactic Center Gamma-Ray Excess has a spectrum, angular distribution, and overall intensity that agree remarkably well with that expected from annihilating dark matter particles in the form of a $m_X \sim 50 \, {\rm GeV}$ thermal relic. Previous claims that these photons are clustered on small angular scales or trace the distribution of known stellar populations once appeared to favor interpretations in which this signal originates from a large population of unresolved millisecond pulsars. More recent work, however, has overturned these conclusions, finding that the observed gamma-ray excess does {\it not} contain discernible small scale power, and is distributed with approximate spherical symmetry, not tracing any known stellar populations. In light of these results, it now appears significantly more likely that the Galactic Center Gamma-Ray Excess is produced by annihilating dark matter.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

The Status of the Galactic Center Gamma-Ray Excess

The Galactic Center Gamma-Ray Excess has a spectrum, angular distribution, and overall intensity that agree remarkably well with that expected from annihilating dark matter particles in the form of a $m_X \sim 50 \, {\rm GeV}$ thermal relic. Previous claims that these photons are clustered on small angular scales or trace the distribution of known stellar populations once appeared to favor interpretations in which this signal originates from a large population of unresolved millisecond pulsars. More recent work, however, has overturned these conclusions, finding that the observed gamma-ray excess does {\it not} contain discernible small scale power, and is distributed with approximate spherical symmetry, not tracing any known stellar populations. In light of these results, it now appears significantly more likely that the Galactic Center Gamma-Ray Excess is produced by annihilating dark matter.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2020

Fermi and Swift Observations of GRB 190114C: Tracing the Evolution of High-energy Emission from Prompt to Afterglow

We report on the observations of gamma-ray burst (GRB) 190114C by the Fermi Gamma-ray Space Telescope and the Neil Gehrels Swift Observatory . The prompt gamma-ray emission was detected by the Fermi GRB Monitor (GBM), the Fermi Large Area Telescope (LAT), and the Swift Burst Alert Telescope (BAT) and the long-lived afterglow emission was subsequently observed by the GBM, LAT, Swift X-ray Telescope (XRT), and Swift UV Optical Telescope. The early-time observations reveal multiple emission components that evolve independently, with a delayed power-law component that exhibits significant spectral attenuation above 40 MeV in the first few seconds of the burst. This power-law component transitions to a harder spectrum that is consistent with the afterglow emission observed by the XRT at later times. This afterglow component is clearly identifiable in the GBM and BAT light curves as a slowly fading emission component on which the rest of the prompt emission is superimposed. As a result, we are able to observe the transition from internal-shock- to external-shock-dominated emission. We find that the temporal and spectral evolution of the broadband afterglow emission can be well modeled as synchrotron emission from a forward shock propagating into a wind-like circumstellar environment. We estimate the initial bulk Lorentz factor using the observed high-energy spectral cutoff. Considering the onset of the afterglow component, we constrain the deceleration radius at which this forward shock begins to radiate in order to estimate the maximum synchrotron energy as a function of time. We find that even in the LAT energy range, there exist high-energy photons that are in tension with the theoretical maximum energy that can be achieved through synchrotron emission from a shock. These violations of the maximum synchrotron energy are further compounded by the detection of very high-energy (VHE) emission above 300 GeV by MAGIC concurrent with our observations. We conclude that the observations of VHE photons from GRB 190114C necessitates either an additional emission mechanism at very high energies that is hidden in the synchrotron component in the LAT energy range, an acceleration mechanism that imparts energy to the particles at a rate that is faster than the electron synchrotron energy-loss rate, or revisions of the fundamental assumptions used in estimating the maximum photon energy attainable through the synchrotron process.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Hot Spot Evolution Measured by High-Resolution X-Ray Spectroscopy at the National Ignition Facility

Evolution of the hot spot plasma conditions was measured using high-resolution x-ray spectroscopy at the National Ignition Facility. The capsules were filled with DD gas with trace levels of Kr and had either a high-density-carbon (HDC) ablator or a tungsten (W)-doped HDC ablator. Time-resolved measurement of the Kr He β spectra, absolutely calibrated by a simultaneous time-integrated measurement, allows inference of the electron density and temperature through observing Stark broadening and the relative intensities of dielectronic satellites. By matching the calculated hot spot emission using a collisional-radiative code to experimental observations, the hot spot size and areal density are determined. Here these advanced spectroscopy techniques further reveal the effect of W dopant in the ablator on the hot spot parameters for their improved implosion performance.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Synchrotron-based X-ray fluorescence microscopy mapping the ionome of a toxic freshwater cyanobacterium

Harmful algal blooms (HABs) pose a major environmental concern across the globe. In abundance, cyanobacteria, or so-called green-blue algae can produce extremely dangerous cyanotoxins that harm humans and animals. This study focused on the mapping and distribution of intracellular macro-and micronutrients of the widespread freshwater cyanobacteria Microcystis aeruginosa (M. aeruginosa). Towards a better understanding of trace metal uptake and homeostasis throughout the cell cycle, we quantitatively mapped the spatial distribution of the elements P, K, Fe, Ca, Zn, Mn, and Cu across the ultrastructure of frozen-hydrated single cells using state-of-theart X-ray nanofluorescence imaging at the Advanced Photon Source (APS) at Argonne National Laboratory. Further, bulk cellular nutrient and trace metal content correlated well with the total intracellular elemental content in individual cells obtained by quantitative synchrotron X-ray fluorescence measurements. Multi-dimensional mappings showed P and K atoms colocalized as discrete semicircular hotspots that were analyzed with respect to their stoichiometry. Elevated Cu and Ca concentrations were detected along division plane of cells. P and K were found to have similar spatial elemental distribution with about 65% and 69% of the total cellular P and K, respectively, located at the hotspots. The P and K colocalization were refined further using nanotomography, showing a K envelope surrounding the P core. Inorganic P and organic P compounds were specified using solution-state 31 P nuclear magnetic resonance (NMR) spectroscopy from M. aeruginosa. Of the total extracted P determined by 31 P NMR spectroscopy, 47% were found to be nucleotides while only 11% were polyphosphates. Multimodal X-ray imaging provides a better understanding of intracellular biochemical processes in cyanobacteria, helping us monitor and combat an emerging environmental threat.

31P NMR spectroscopy↗