Boundary-layer Growth and Shock Attenuation in a Shock Tube with Roughness
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The main focus was the development, implementation, and calibration of methods for performing molecular electronic structure calculations to high accuracy. These various methods were then applied to a number of chemical reactions and species of interest to NASA, notably in the area of combustion chemistry. Among the development work undertaken was a collaborative effort to develop a program to efficiently predict molecular structures and vibrational frequencies using energy derivatives. Another major development effort involved the design of new atomic basis sets for use in chemical studies: these sets were considerably more accurate than those previously in use. Much effort was also devoted to calibrating methods for computing accurate molecular wave functions, including the first reliable calibrations for realistic molecules using full CI results. A wide variety of application calculations were undertaken. One area of interest was the spectroscopy and thermochemistry of small molecules, including establishing small molecule binding energies to an accuracy rivaling, or even on occasion surpassing, the experiment. Such binding energies are essential input to modeling chemical reaction processes, such as combustion. Studies of large molecules and processes important in both hydrogen and hydrocarbon combustion chemistry were also carried out. Finally, some effort was devoted to the structure and spectroscopy of small metal clusters, with applications to materials science problems.
When a simple model for the relationship between the density-temperature fluctuation correlation and mean values is used, we determine that the rate of change of turbulent intensity can influence directly the accretion rate of droplets. We find, experimentally, that the droplet particle size is both temperature and Reynolds number dependent. We also find that the rate of droplet growth has an important dependence on Reynolds number, in a manner stronger than its simple temperature dependence, thereby suggesting a previously unsuspected role for turbulence in the control of condensate accretion.
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The EAST facility has been widely used in the past to provide experimental data aiming to validate radiative heating models. However, all the past studies involved measurements of compressing flows. In order to study recombining flows, an expansion cone has been installed in the EAST facility. Four spectrometers are mounted at different axial positions of the cone to measure the evolution of the radiation during expansion. Quantitative data from optical emission spectroscopy will be used to get the densities of radiative species. These data are intended to be compared with simulations in order to improve the current models used by the entry community.
The EAST facility has been widely used in the past to provide experimental data aiming to validate radiative heating models. However, all the past studies involved measurements of compressing flows. In order to study recombining flows, an expansion cone has been installed in the EAST facility. Four spectrometers are mounted at different axial positions of the cone to measure the evolution of the radiation during expansion. Quantitative data from optical emission spectroscopy will be used to get the densities of radiative species. These data are intended to be compared with simulations in order to improve the current models used by the entry community.
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Abstract not provided.