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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20

Degree of Weathering of H-Chondrites From Frontier Mountain, Antarctica

One of the factors that determines the survival time of meteorites on the Earth's surface is the rate of weathering. For meteorites from hot deserts, a clear correlation is found between the degree of weathering, and the terrestrial age, but for Antarctic meteorites this correlation is weak or even lacking. The lack of a clear correlation can partly be attributed to the two-stage history of many Antarctic meteorites, which spend part of their terrestrial residence time in the ice before they are exposed on the ice. Recently, it was found that for Lewis Cliff (LEW) meteorites local conditions on the ice play an important role in the weathering process. This work focuses on weathering effects in ordinary chondrites from Frontier Mountain (FRO), North Victoria Land. Although most FRO meteorites were classified as weathering category A or B, many are contaminated with terrestrial uranium, deposited from meltwater. This suggests that weathering plays a more significant role than the qualitative A-B-C weathering index indicates. We therefore determined the degree of weathering more quantitatively, by deriving the amount of oxidized metal from the concentrations of Fe and Ni in the nonmagnetic fraction of 23 H-chondrites and 1 L-chondrite The results will be compared with those of LEW meteorites and will be discussed in terms of terrestrial age and location of find on the ice.

Welten, K. C.↗

Comparison of Fuel Cycles for Lead-Lithium and Pure Lithium Liquid Metal Walls in a Magnetized Target Fusion Power Plant

General Fusion (GF) is developing an adaptable, commercial fusion power plant based on magnetized target fusion (MTF). The GF approach involves forming a spherical torus of deuterium-tritium plasma in a large (~4 m diameter) cavity formed in liquid metal, and then collapsing that cavity with an array of pneumatic piston drivers. The liquid metal is constantly flowing through the fusion chamber and out to processing systems where tritium and heat will be extracted using tritium extraction technologies and heat exchangers, respectively. Here, this study focuses on two candidate designs for the liquid metal blanket and first wall material for the General Fusion Magnetized Target Fusion (GF MTF) power plant and assesses their impact on the tritium fuel cycle. The first candidate is the lead lithium eutectic (LLE) and the second candidate is pure lithium (Li). It was found that the main differences between LLE and Li designs are the extraction technologies required to remove tritium from the blanket and the amount of tritium and its distribution within the facility. More than 80% of the in-process tritium inventory for the LLE design is contained in the isotope separation system, while for the Li design, over 60% of the in-process tritium inventory is contained within the blanket material. This is due to significant tritium retention by Li. For the Li blanket, the burden of tritium processing rests on the blanket extraction technology rather than the traditional exhaust processing route. Thus, the blanket extraction technology is a main driver of tritium inventory in the Li system and determines the subsequent interface with the tritium processing plant.

General Fusion↗

Heavy Element Spectroscopy in the Gas Phase

Actinides are inherently unstable and undergo nuclear decay processes with a concurrent release of energy. Consequently, they are used for nuclear power generation, nuclear weapons, and nuclear medicine. However, the radioactive decay processes also pose significant technological problems for the safe treatment and storage of spent nuclear materials. Cost-effective extraction of the actinides is the key first step in the remediation of nuclear waste, but the appropriate chemical means have yet to be determined. Our present understanding of the chemistry of actinides is limited, with the role of the 5f electrons posing a set of particularly challenging questions. The work reported here is focused on the use of electronic spectroscopy to probe the bonding of small molecules in the gas phase that contains thorium or uranium. Analyses of these data, carried out within the framework of ligand field theory, reveal clear evidence that the 5f electrons are spectators that retain their atomic metal ion character.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Report-reading patterns of technical managers and nonmanagers

A survey to determine the review and reading processes used by technical managers and nonmanagers indicates that the summary, abstract, conclusion, title page, and introduction are the components used most frequently by both groups to decide whether to read a NASA technical report. In the review process, significantly more managers than nonmanagers use the summary and conclusion, whereas significantly more nonmanagers use the abstract and title page. The most common sequence of review consists of the title page, abstract, and summary, in that order, for both groups. In the reading process, the conclusion, results and discussion, and summary are the components read by the highest percentage of both groups.

Pinelli, T. E.↗

Reduction of blade-vortex interaction noise using higher harmonic pitch control

An acoustics test using an aeroelastically scaled rotor was conducted to examine the effectiveness of higher harmonic blade pitch control for the reduction of impulsive blade-vortex interaction (BVI) noise. A four-bladed, 110 in. diameter, articulated rotor model was tested in a heavy gas (Freon-12) medium in Langley's Transonic Dynamics Tunnel. Noise and vibration measurements were made for a range of matched flight conditions, where prescribed (open-loop) higher harmonic pitch was superimposed on the normal (baseline) collective and cyclic trim pitch. For the inflow-microphone noise measurements, advantage was taken of the reverberance in the hard walled tunnel by using a sound power determination approach. Initial findings from on-line data processing for three of the test microphones are reported for a 4/rev (4P) collective pitch control for a range of input amplitudes and phases. By comparing these results to corresponding baseline (no control) conditions, significant noise reductions (4 to 5 dB) were found for low-speed descent conditions, where helicopter BVI noise is most intense. For other rotor flight conditions, the overall noise was found to increase. All cases show increased vibration levels.

Brooks, Thomas F.↗

Reduction of blade-vortex interaction noise through higher harmonic pitch control

An acoustics test using an aeroelastically scaled rotor was conducted to examine the effectiveness of higher harmonic blade pitch control for the reduction of impulsive blade-vortex interaction (BVI) noise. A four-bladed, 110 in. diameter, articulated rotor model was tested in a heavy gas (Freon-12) medium in Langley's Transonic Dynamics Tunnel. Noise and vibration measurements were made for a range of matched flight conditions, where prescribed (open-loop) higher harmonic pitch was superimposed on the normal (baseline) collective and cyclic trim pitch. For the inflow-microphone noise measurements, advantage was taken of the reverberance in the hard walled tunnel by using a sound power determination approach. Initial findings from on-line data processing for three of the test microphones are reported for a 4/rev (4P) collective pitch control for a range of input amplitudes and phases. By comparing these results to corresponding baseline (no control) conditions, significant noise reductions (4 to 5 dB) were found for low-speed descent conditions, where helicopter BVI noise is most intense. For other rotor flight conditions, the overall noise was found to increase. All cases show increased vibration levels.

Brooks, Thomas F.↗

Flux estimation of the FIFE planetary boundary layer (PBL) with 10.6 micron Doppler lidar

A method is devised for calculating wind, momentum, and other flux parameters that characterize the planetary boundary layer (PBL) and thereby facilitate the calibration of spaceborne vs. in situ flux estimates. Single Doppler lidar data are used to estimate the variance of the mean wind and the covariance related to the vertically pointing fluxes of horizontal momentum. The skewness of the vertical velocity and the range of kinetic energy dissipation are also estimated, and the surface heat flux is determined by means of a statistical Navier-Stokes equation. The conclusion shows that the PBL structure combines both 'bottom-up' and 'top-down' processes suggesting that the relevant parameters for the atmospheric boundary layer be revised. The conclusions are of significant interest to the modeling techniques used in General Circulation Models as well as to flux estimation.

Gal-Chen, Tzvi↗

Thermophysical Property Measurements of Silicon-Transition Metal Alloys

Metals and metallic alloys often have high melting temperatures and highly reactive liquids. Processing reactive liquids in containers can result in significant contamination and limited undercooling. This is particularly true for molten silicon and it alloys. Silicon is commonly termed "the universal solvent". The viscosity, surface tension, and density of several silicon‐transition metal alloys were determined using the Electrostatic Levitator system at the Marshall Space Flight Center. The temperature dependence of the viscosity followed an Arrhenius dependence, and the surface tension followed a linear temperature dependence. The density of the melts, including the undercooled region, showed a linear behavior as well. Viscosity and surface tension values were obtain for several of the alloys in the undercooled region.

Banish, R. Michael↗

Oil Dispersant Corexit 9500 Is Weakly Estrogenic, but Does Not Skew the Sex Ratio in Alligator Mississippiensis

During the Deepwater Horizon oil spill, vast quantities of the chemical dispersant Corexit 9500 were applied in remediation efforts. In addition to the acute toxicity and obesogenicity of Corexit, it is important to further evaluate Corexit with long-term sublethal endocrine endpoints. The American alligator (Alligator mississippiensis) exhibits temperature-dependent sex determination, in which egg incubation temperatures during a thermosensitive period (TSP) in embryonic development determine sex of the embryos. Estrogen signals also play critical roles in this process. For example, a single exposure to exogenous estrogen during the TSP overrides the effects of temperature and leads to skewed sex ratios. At a dose of 100 ppm, Corexit significantly induced transcriptional activity of both alligator nuclear estrogen receptors 1 and 2 in vitro using the reporter gene assays. To investigate the estrogenic effects on gonadal development in ovo, alligator eggs were exposed to Corexit at environmentally relevant concentrations (0.25, 2.5, and 25 ppm) prior to the TSP. Significant delays in the hatching and growth were observed in 0.25 and 25 ppm Corexit exposed groups. At one week of age, no significant effects on sex ratios or testicular mRNA abundance were observed as a result of exposure to Corexit at the tested exposure levels, suggesting Corexit does not have strong estrogenic activity in ovo. Further investigations are required using individual components of Corexit to better understand their estrogenic effects on the development and reproductive health of alligators and other coastal aquatic wildlife.

Nicole Mcnabb↗

Real-time determination of geophysical parameters from a multibeam altimeter

Satellite radar altimeters flown aboard Skylab, GEOS-3 and Seasat-1 have provided a wealth of information on oceanic processes, ice dynamics and geodesy. This paper describes satellite altimetry in its present state and forecasts its future. A brief review of present capability to measure altitude, significant wave height, wind, and current is given. Near term and long range applications are used to indicate desirable technical improvements and an evolutionary plan is presented to develop a sensor to meet future needs. The plan shows a progression from the presently available single-beam terrain profiler to a multibeamed profiling system in the near future which could measure large scale surface slopes without knowing the precise satellite orbit. Ultimately a system would be developed that provides images of height, reflectivity, and target motion. Some of this future system is vividly illustrated by data obtained with the WFC airborne Surface Contour Radar.

Mcgoggan, J. T.↗

Investigation of use of space data in watershed hydrology

The author has identified the following significant results. Ground truth data have been compiled and 256 rainfall runoff events have been used to detemine coefficients for two storm runoff equations that apply to the 20 study watersheds. Two scenes have been processed using CCT data. Data pertinent to each of the study watersheds have been excerpted from the tapes. A computer program and display technique has been developed to retrieve the data from irregular shaped areas and store it in a format that allows future display of only the area desired. Means, standard deviations, and distributions have been determined for extreme dry and extreme wet conditions in the dormant season. Mean digital values show some variation between watersheds when dry, but no significant differences when wet. Standard deviations of digital values diminish drastically under wet dormant conditions. Thus the standard deviations may be a good indicator of influence of moisture. Distributions of seven bit values show that odd numbers are prevalent and irregular distribution may influence some classification schemes now in use.

Blanchard, B.↗

Moonrise: Sampling the South Pole-Aitken Basin to Address Problems of Solar System Significance

A mission to land in the giant South Pole-Aitken (SPA) Basin on the Moon's southern farside and return a sample to Earth for analysis is a high priority for Solar System Science. Such a sample would be used to determine the age of the SPA impact; the chronology of the basin, including the ages of basins and large impacts within SPA, with implications for early Solar System dynamics and the magmatic history of the Moon; the age and composition of volcanic rocks within SPA; the origin of the thorium signature of SPA with implications for the origin of exposed materials and thermal evolution of the Moon; and possibly the magnetization that forms a strong anomaly especially evident in the northern parts of the SPA basin. It is well known from studies of the Apollo regolith that rock fragments found in the regolith form a representative collection of many different rock types delivered to the site by the impact process (Fig. 1). Such samples are well documented to contain a broad suite of materials that reflect both the local major rock formations, as well as some exotic materials from far distant sources. Within the SPA basin, modeling of the impact ejection process indicates that regolith would be dominated by SPA substrate, formed at the time of the SPA basin-forming impact and for the most part moved around by subsequent impacts. Consistent with GRAIL data, the SPA impact likely formed a vast melt body tens of km thick that took perhaps several million years to cool, but that nonetheless represents barely an instant in geologic time that should be readily apparent through integrated geochronologic studies involving multiple chronometers. It is anticipated that a statistically significant number of age determinations would yield not only the age of SPA but also the age of several prominent nearby basins and large craters within SPA. This chronology would provide a contrast to the Imbrium-dominated chronology of the nearside Apollo samples and an independent test of the timing of the lunar cataclysm.

Zeigler, R. A.↗

Shining a Light on Some Fundamental Research Opportunities in Semiconductor Photoelectrochemistry

Decades of research in semiconductor photoelectrochemistry have yielded a deep understanding of charge transfer, energetics, and stability at solid−liquid interfaces. Theoretical frameworks developed by Gerischer and contemporaries, together with extensive experimental validation, have clarified the key principles affecting the interfacial kinetics and energetics of semiconductor photoelectrodes. Nevertheless, significant opportunities remain for advances in fundamental understanding of semiconductor photoelectrochemistry. Exciting opportunities include exploiting advances in theory, synthesis, and instrumentation to determine the chemical identity and reactivity of surface states; exerting control of band-edge energetics through molecular-level surface modification processes; and systematically improving emerging photoelectrode protection strategies to enable long-term photoelectrode operation under both oxidative and reductive conditions. Advanced morphologies, such as nanowire and microwire arrays, present new pathways to combine efficient light absorption with effective charge collection and catalyst integration. Unique light−matter interactions during photoelectrochemical deposition of p-type semiconductors readily allow preparation at scale of complex 3D morphologies that are difficult, if not impossible, to access by other methods. Continued exploration of these avenues will expand the fundamental understanding of semiconductor−liquid interfaces and could additionally advance the realization of efficient, stable, and scalable systems for solar fuel generation and other emerging photoelectrochemical applications.

Bean, Paul J. L. [California Institute of Technolo↗

Grain size analysis and high frequency electrical properties of Apollo 15 and 16 samples

The particle size distribution of eleven surface fines samples collected by Apollo 15 and 16 was determined by the method of measuring the sedimentation rate in a column of water. The fact that the grain size distribution in the core samples shows significant differences within a few centimeters variation of depth is important for the understanding of the surface transportation processes which are responsible for the deposition of thin layers of different physical and/or chemical origin. The variation with density of the absorption length is plotted, and results would indicate that for the case of meter wavelength radar waves, reflections from depths of more than 100 meters generally contribute significantly to the radar echoes obtained.

Gold, T.↗

Dielectronic recombination rates, ionization equilibrium, and radiative emission rates for calcium and nickel ions in low-density high-temperature plasmas

The total dielectronic recombination rates for Ca and Ni ions were calculated taking into account autoionization to excited states of the recombining ion and stabilizing radiative transitions of the recombining electron. Radiative transitions of the recombining ion are found to be the dominant stabilizing processes, and the relative importance of Delta n = 0 and Delta n not equal to 0 transitions in the relevant temperature region is determined for each ion. The relative importance of the Delta n = 0 and Delta n not equal to 0 contributions is significantly altered for some ions by the inclusion of autoionization to excited levels. The relative abundance of the various ionization stages has been determined by using a corona equilibrium model in which collisional ionization and inner-shell excitation followed by autoionization are balanced by direct radiative and dielectronic recombination.

Jacobs, V. L.↗

A sensitivity/intrusion comparison of mental workload estimation techniques using a flight task emphasizing perceptual piloting activities

In a literature review it was found that little research effort has been directly applied to the problem of specifying a viable workload estimation technique for a given pilot/aircrew problem. Furthermore, the relative sensitivity and intrusion of most techniques has not been studied. The present investigation is concerned with a comparative evaluation of eight workload estimation techniques under identical experimental conditions in a flight simulator. The objective of this comparison was to determine the relative sensitivity and intrusion of each estimation technique in applications to a piloting situation which emphasizes the use of perceptual processes. No differential intrusion could be observed, but six of the eight techniques did show sensitivity to changes in perceptual load. All significant techniques displayed monotonic increases in measured values across the three loading levels considered.

Casali, J. G.↗

Re-Os Systematics and HSE Distribution in Metal from Ochansk (H4) Chondrite

Previous studies of the Re-Os systematics of chondrites have documented considerable variation in the Re/Os ratios of whole rock samples. For some whole rock chondrites, Re-Os systematics display large deviations from the primitive isochron that are considerably larger than deviations in other isotope systems. Possible interpretation of these facts is that the Re-Os system in chondrites is particularly sensitive to post-formation alteration processes, thus providing a useful tool to examine such processes. Significant variations that have been detected in highly siderophile element (HSE) patterns for ordinary chondrites support this conclusion. We report Re-Os isotope data for metal separates from the Ochansk H4 chondrite coupled with abundance data for Ru, Pd, Ir, and Pt, determined in the same samples by isotope dilution. We chose this meteorite mainly because it is an observed fall with minimal signs of weathering, and its low metamorphic grade (H4) and shock stage (S3).

Smoliar, M. I.↗

Standardization of Rocket Engine Pulse Time Parameters

Plumes of bipropellant thrusters are a source of contamination. Small bipropellant thrusters are often used for spacecraft attitude control and orbit correction. Such thrusters typically operate in a pulse mode, at various pulse lengths. Quantifying their contamination effects onto spacecraft external surfaces is especially important for long-term complex-geometry vehicles, e.g. International Space Station. Plume contamination tests indicated the presence of liquid phase contaminant in the form of droplets. Their origin is attributed to incomplete combustion. Most of liquid-phase contaminant is generated during the startup and shutdown (unsteady) periods of thruster pulse. These periods are relatively short (typically 10-50 ms), and the amount of contaminant is determined by the thruster design (propellant valve response, combustion chamber size, thruster mass flow rate, film cooling percentage, dribble volume, etc.) and combustion process organization. Steady-state period of pulse is characterized by much lower contamination rates, but may be lengthy enough to significantly conh'ibute to the overall contamination effect. Because there was no standard methodology for thruster pulse time division, plume contamination tests were conducted at various pulse durations, and their results do not allow quantifying contaminant amounts from each portion of the pulse. At present, the ISS plume contamination model uses an assumption that all thrusters operate in a pulse mode with the pulse length being 100 ms. This assumption may lead to a large difference between the actual amounts of contaminant produced by the thruster and the model predictions. This paper suggests a way to standardize thruster startup and shutdown period definitions, and shows the usefulness of this approach to better quantify thruster plume contamination. Use of the suggested thruster pulse time-division technique will ensure methodological consistency of future thruster plume contamination test programs, and allow accounting for thruster pulse length when modeling plume contamination and erosion effects.

Larin, Max E.↗