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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20

Cosmic Ray Hysteresis as Evidence for Time-dependent Diffusive Processes in the Long Term Solar Modulation

A simple one-dimensional time-dependent diffusion-convection model for the modulation of cosmic rays is presented. This model predicts that the observed intensity at a given time is approximately equal to the intensity given by the time independent diffusion convection solution under interplanetary conditions which existed a time iota in the past, (U(t sub o) = U sub s(t sub o - tau)) where iota is the average time spent by a particle inside the modulating cavity. Delay times in excess of several hundred days are possible with reasonable modulation parameters. Interpretation of phase lags observed during the 1969 to 1970 solar maximum in terms of this model suggests that the modulating region is probably not less than 10 a.u. and maybe as much as 35 a.u. in extent.

Ogallagher, J. J.↗

The SMART Ground-based Remote Sensing for Terra/MODIS Validation

A ground-based remote sensing system - SMART (Surface Measurements for Atmospheric Radiative Transfer) - was deployed during both the SAFARI-2000 and the ARREX-1999 dry season campaigns. The measurement site is the Skukuza airport. The operation period for 1999 is from August 16 to September 10. The main instruments include shortwave (approximately 0.28-2.8 micrometers) and longwave (approximately 4-50 micrometers) broadband radiometers, a shadow-band radiometer, a micro-pulse lidar, and a microwave radiometer. We also did some measurements of solar spectral flux by using an ASD spectrometer. The operation period for 2000 is from August 15 to September 22. This time we added a few new features to the SMART system: a solar tracker for direct and diffuse components of solar fluxes; the scanning capability to the microwave radiometer; a whole sky camera for documenting the sky conditions every minute; and a mini-weather station for atmospheric pressure, temperature, humidity, wind speed/direction. A surface SSFR (Solar Spectral Flux Radiometer) from NASA Ames also joined us for the measurements. This is a unique data set with reasonably long observational period and high accuracy. The data show good correlation with the local weather patterns. We also see diurnal change and some special events, such as fierce fires nearby. To quantify the surface radiative forcing of biomass burning aerosols, many pyranometers, pyrgeometers, and pyrheliometers measure the global, direct, and diffuse irradiance at the surface. These fluxes combining with the collocated optical thickness retrievals from sun photometer (or shadow-band radiometer), the solar radiative forcing, proportional to delta F/delta tau, can be investigated. Integrated with measurements of other instruments at the site, these data sets will serve as "ground truth" for the satellite measurements and modeling.

Tsay, Si-Chee↗

Evaluation of the minority carrier diffusion length and surface-recombination velocity in GaAs p/n solar cells

The minority carrier diffusion length (Lp) and the surface recombination velocity (Vs) were measured as a function of distance (x) from the p-n junction in GaAs p/n concentrator solar cells. The measured Vs values were used in a theoretical expression for the normalized electron-beam-induced current. A fitting procedure was then used to fit this expression with experimental values to obtain Lp. The results show that both Vs and Lp vary with x. Lp measured in irradiated cells showed a marked reduction. These values were compared to those measured previously which did not account for Vs.

Hakimzadeh, Roshanak↗

Highlights of theoretical progress related to the International Magnetospheric Study

U.S. theoretical research efforts have addressed three areas within the International Magnetospheric Study. The first, solar wind/magnetosphere interaction, is presently concerned with the suggestion that magnetic merging may predominantly occur near the polar cusps rather than near the subsolar point. Mechanisms have been proposed for noncollisional diffusion of solar wind plasma across the closed magnetopause entailed by such a phenomenon. The second area considers the importance to magnetotail dynamics of a continuous source of solar wind plasma, and of sporadic plasma loss associated with an unsteady convection cycle. In the third area, the electrodynamic magnetosphere/ionosphere interaction, an advanced state has been reached in the understanding of the relevant physics, with respect both to coupling in the subauroral region and the large scale structure of auroral zone electric fields parallel, and perpendicular to, the magnetic field.

Hill, T. W.↗

Effect of forest canopy closure on incoming solar radiance

In order to better understand the physical processes involved in defoliation assessment from remotely sensed data, a field study was designed to investigate the effect of forest canopy closure and other environmental variables on incoming solar radiation. Diffuse radiation measurements were recorded in red, infrared, and middle infrared wavelengths using the Mark 2 three band field radiometer. Results to date indicate that the percent canopy closure is the single most important variable affecting incoming solar radiation. In the visible and near infrared regions, interaction between time of day and date (defined later as solar zenith angle) also affect radiometric response. Aspect has only limited influence on radiance response. These same variables do not influence middle infrared response, however. Uniformity of the forest canopy appears to be more important. These results are compared to LANDSAT MSS classification results of gypsy moth defoliation.

Dottavio, C. L.↗

Performance evaluation of the solar backscatter ultraviolet radiometer, model 2 (SBUV/2) inflight calibration system

The Solar Backscatter Ultraviolet Radiometer, Model 2 (SBUV/2) instruments, as part of their regular operation, deploy ground aluminum reflective diffusers to deflect solar irradiance into the instrument's field-of-view. Previous SBUV instrument diffusers have shown a tendency to degrade in their reflective efficiencies. This degradation will add a trend to the ozone measurements if left uncorrected. An extensive in-flight calibration system was designed into the SBUV/2 instruments to effectively measure the degradation of the solar diffuser (Ball Aerospace Systems Division 1981). Soon after launch, the NOAA-9 SBUV/2 calibration system was unable to track the diffuser's reflectivity changes due, in part, to design flows (Frederick et al. 1986). Subsequently, the NOAA-11 SBUV/2 calibration system was redesigned and an analysis of the first 2 years of data (Weiss et al. 1991) indicated the NOAA-11 SBUV/2 onboard calibration system's performance to be exceeding preflight expectations. This paper will describe the analysis of the first three years NOAA-11 SBUV/2 calibration system data.

Weiss, H.↗

Reducing Thermal Degradation of Perovskite Solar Cells during Vacuum Lamination by Internal Diffusion Barriers

Current photovoltaic (PV) panels typically contain interconnected solar cells that are vacuum laminated with a polymer encapsulant between two pieces of glass or glass with a polymer backsheet. This packaging approach is ubiquitous in conventional photovoltaic technologies such as silicon and thinfilm solar modules, contributing to thermal management, mechanical reinforcement, and environmental protection to enable the long lifetimes necessary to become financially acceptable. Commercial vacuum lamination processes typically occur at 150 °C to ensure cross-linking and/or glass bonding of the encapsulant to the glass and PV cells. Perovskite solar cells (PSCs) have emerged as a promising next-generation PV technology that is known to degrade under thermal stresses, especially at temperatures above 100 °C. In this study, we determine degradation modes during lamination and engineer internal diffusion barriers within the PSC to withstand the harsh thermal conditions of vacuum lamination. PSCs with self-assembled monolayers at the ITO interface and SnO X layers deposited by atomic layer deposition at the electron extraction side of the device endured vacuum lamination at conditions typical of commercial PV processes (150 °C) without degradation. This work demonstrates that perovskite PV can be integrated into the existing module lamination process, enabling future single- and multijunction modules utilizing perovskite absorbers.

14 SOLAR ENERGY↗

UV‐induced degradation of high‐efficiency silicon PV modules with different cell architectures

Abstract Degradation from ultraviolet (UV) radiation has become prevalent in the front of solar cells due to the introduction of UV‐transmitting encapsulants in photovoltaic (PV) module construction. Here, we examine UV‐induced degradation (UVID) in various commercial, unencapsulated crystalline silicon cell technologies, including bifacial silicon heterojunction (HJ), interdigitated back contact (IBC), passivated emitter and rear contact (PERC), and passivated emitter rear totally diffused (PERT) solar cells. We performed UV exposure tests using UVA‐340 fluorescent lamps at 1.24 W·m −2 (at 340 nm) and 45°C through 4.02 MJ·m −2 (2000 h). Our results showed that modern cell architectures are more vulnerable to UVID, leading to a significant power decrease (−3.6% on average; −11.8% maximum) compared with the conventional aluminum back surface field (Al‐BSF) cells (<−1% on average). The power degradation is largely caused by the decrease in short‐circuit current and open‐circuit voltage. A greater power decrease is observed in bifacial cells with rear‐side exposure compared with those with front‐side exposure, indicating that the rear side is more susceptible to UV damage. Secondary ion mass spectroscopy (SIMS) confirmed an increase in hydrogen concentration near the Si/passivation interface in HJ and IBC cells after UV exposure; the excess of hydrogen could result in hydrogen‐induced degradation and subsequently cause higher recombination losses. Additionally, surface oxidation and hot‐carrier damage were identified in PERT cells. Using a spectral‐based analysis, we obtained an acceleration factor of 5× between unpackaged cells (containing a silicon nitride antireflective coating on the front) in the UV test and an encapsulated module (with the front glass and encapsulant blocking 90% of the UV at 294 nm and 353 nm, respectively) in outdoor conditions. From the analytical calculations, we show that a UV‐blocking encapsulant can reduce UV transmission in the module by an additional factor of ~50.

14 SOLAR ENERGY↗

Quantitative assessment of selenium diffusion and passivation in CdSeTe solar cells probed by spatially resolved cathodoluminescence

The introduction of selenium in CdSeTe/CdTe solar cells has led to improved device performances attributed to the passivation of bulk defects. In this work, high-resolution cathodoluminescence experiments are performed on a series of CdSeTe/CdTe thin films with different Se concentrations to quantify the mechanisms and the passivation role of Se. We demonstrate a universal dependence between the Se concentration and the radiative efficiency and a ten-fold enhancement of the luminescence between CdTe and CdSe 0.4 Te 0.6 . Raw luminescence maps are converted into maps of the Se concentration, revealing its graded profile within the stack. We demonstrate the diffusion of Se along CdTe grain boundaries induced by the cadmium chloride annealing treatment and determine the diffusion coefficients, which are more than eight times higher at grain boundaries than in grain interiors. These results provide microscopic insights into the distribution of Se and its impact on the passivation of CdSeTe/CdTe solar cells.

14 SOLAR ENERGY↗

Energetic solar particles in the interplanetary medium.

Models which describe the diffusion of energetic solar particles in the interplanetary medium are reviewed. Most attention is paid to the case of impulsive emission from solar flares, taking into account the effects of the interplanetary magnetic field, diffusion near the sun, convection, and energy losses associated with the expansion of the solar wind. The case of continuous emission is also considered briefly.

Axford, W. I.↗

Probing elemental diffusion and radiation tolerance of perovskite solar cells via non-destructive Rutherford backscattering spectrometry

Mixed organic–inorganic halide perovskite-based solar cells have attracted interest in recent years due to their potential for both terrestrial and space applications. Analysis of interfaces is critical to predicting device behavior and optimizing device architectures. Most advanced tools to study buried interfaces are destructive in nature and can induce further degradation. Ion beam techniques, such as Rutherford backscattering spectrometry (RBS), is a useful non-destructive method to probe an elemental depth profile of multilayered perovskite solar cells (PSCs) as well as to study the inter-diffusion of various elemental species across interfaces. Additionally, PSCs are becoming viable candidates for space photovoltaic applications, and it is critical to investigate their radiation-induced degradation. RBS can be simultaneously utilized to analyze the radiation effects induced by He+ beam on the device, given their presence in space orbits. In the present work, a 2 MeV He+ beam was used to probe the evidence of elemental diffusion across PSC interfaces with architecture glass/ITO/SnO2/Cs0.05(MA0.17FA0.83)0.95Pb(I0.83Br0.17)3/spiro-OMeTAD/MoO3/Au. During the analysis, the device active area was exposed to an irradiation equivalent of up to 1.62 × 1015 He+/cm2, and yet, no measurable evidence (with a depth resolution ∼1 nm) of beam-induced ion migration was observed, implying high radiation tolerance of PSCs. On the other hand, aged PSCs exhibited indications of the movement of diverse elemental species, such as Au, Pb, In, Sn, Br, and I, in the active area of the device, which was quantified with the help of RBS.

14 SOLAR ENERGY↗

Corrosion of novel reactive silver ink and commercial silver-based metallizations in diluted acetic acid

Silver-based metallizations in photovoltaic modules are susceptible to corrosion by acetic acid generated in ethylene vinyl acetate encapsulated modules, resulting in power losses over time. Here, three silver-based metallizations are exposed to diluted acetic acid, in concentrations representative of that found in field-exposed modules. Compositional, morphological, and structural changes of the metallizations are studied over 3000 h of exposure to diluted acetic acid using Raman spectroscopy mapping, X-ray diffraction, and scanning electron microscopy. The three metallizations studied are: 1) a commercial high-temperature fire-through Ag paste, commonly used for Si diffused junction solar cells; 2) a commercial low-temperature paste normally used for silicon heterojunction cells; and 3) a novel low-temperature reactive silver ink shown to be suitable for photovoltaic applications. We find distinct corrosion rates for the high-temperature silver paste and reactive silver ink in the presence of diluted acetic acid. However, the low-temperature silver paste appears to be more corrosion resistant, likely due to a polymer layer that protects the silver particles.

36 MATERIALS SCIENCE↗

The solar wind near the sun - The solar envelope.

Recent observational data and models for the structure of the solar envelope are discussed, with emphasis on those physical processes in the envelope which are decisive in determining solar wind states at 1 AU. Diffusion of relativistic solar flare protons, collisionless damping of a variable flux of hydromagnetic waves, heat transfer from electrons to protons, acceleration by Alfven waves, and magnetic field effects are examined from the viewpoint of possible contributions to solar wind behavior.

Burlaga, L. F.↗

Io-accelerated electrons - Predictions for Pioneer 10 and Pioneer 11

Based on a model in which electrons are accelerated to energies of 100 kiloelectron volts through sheaths associated with Io, predictions are made about energetic electrons to be observed by Pioneer 10 and Pioneer 11 in the Jovian magnetosphere. This energetic electron source may be distinguishable from the solar wind diffusion source by the radial flux profile and by the characteristic electron energies.

Shawhan, S. D.↗