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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS2015

On the Sensitivity of the Diurnal Cycle in the Amazon to Convective Intensity

This presentation uses publicly available CERES and radiosonde data to investigate the sensitivity of thetropical convective diurnal cycle to atmosphere state. Averaging surface observations into regimes of convective intensitydefined by satellite shows great promise for physical understandingof convection.• Convective processes in the Amazon are highly variable seasonallyand locally.• Buoyancy/CIN more important JJA– Mesoscale/synoptic features easier to separate– Length/depth of buoyancy layer very important in DJF (EL).• Moisture more important DJF, esp. UTH– Humidity of lower atmosphere significantly impacts LTS, LCL and abilityfor parcels to reach LFC.• Lower level jet strength/direction important• Convective initiation correlated with LTS, LR, LTH, EL• Duration/Phase better correlated with humidity variables• Surface Flux amplitude well correlated with convection

Itterly, Kyle↗
NASA NTRS2019

Disentangling the Drivers of the Summertime Ozone‐Temperature Relationship Over the United States

Summertime surface-level ozone (O3 ) is known to vary with temperature, but the relative roles of different processes responsible for causing the O3 -temperature relationship are not well quantified. In this study we use simulations of NASA's Global Modeling Initiative (GMI) chemical transport model (CTM) to isolate and assess the relative impact of atmospheric transport, chemistry, and emissions on O3 variability, events, and its correlation with temperature. Using observations from CASTNet in the contiguous United States, we show that the GMI CTM reproduces the spatiotemporal variability of O3 and the O3 -temperature relationship during the summer. We primarily focus on the total change in O3 due to a change in temperature (d O3 /d T). In regions with strong positive correlations between temperature and O3 such as the Northeast, Great Lakes, and Great Plains, temperature's association with transport primarily drives d O3 /d T with smaller contributions from temperature-dependent chemistry and anthropogenic emissions. There are regions, however, with near-zero correlation between temperature and O3 , and our findings suggest that transport is still an important driver of O3 variability in these regions, albeit not correlated with temperature. Transport is not directly dependent on temperature but rather is linked through an indirect association, and it is therefore important to understand the exact mechanisms that link transport to O3 and how these mechanisms will change in a warming world.

ozone, temperature, CTM↗
NASA NTRS1999

The Variability and Predictability of Precipitation over Southeast Asian

The large scale atmospheric moisture budget, including precipitation, moisture flux convergence, and evaporation is described over southeast Asian. ne results are from the Goddard Earth Observing System (GEOS-1) data assimilation system for the period March 1981 - February 1995. On average, in the late spring and early summer season, precipitation is largely balanced by the atmospheric moisture flux convergence over southeast Asian; evaporation is also an important contributor. The seasonal variability of precipitation is best related to variations in the moisture flux convergence. On the monthly time scales, both the precipitable water and precipitation anomalies are most closely related to moisture flux convergence anomalies and less closely related to evaporation anomalies. The impact of the low-level jet (LLJ) on the strong low-level moisture flux convergence will be discussed. An ensemble of GEOS-2 atmospheric General Circulation Model (GCM) seasonal forecasts and long-term simulation are analyzed to assess the controlling influences of boundary forcing and memory of initial conditions. We also assess the variability and potential predictability from these experiments.

Chang, Yehui↗
NASA NTRS1974

Variable-beamwidth monopulse antennas

The merits of nine methods for zooming microwave amplitude-sensing monopulse antenna patterns are discussed. Of these, six are directly related to the TDRSS (Tracking Data Relay Satellite System) and are compatible with a deployable-mesh pseudo-paraboloidal main reflector. The remaining three methods utilize radically different geometrical configurations that depart considerably from the TDRSS parameters existing at this time. Preservation of the monopulse postulates is considered to be of prime importance for any variable-beamwidth candidate, however, it is allowed that approximate satisfaction of the postulates should be accepted for practical reasons. All of the methods discussed admit free choice of the polarization state, and the zooming function is never predicated on polarization. Exploration of the zooming techniques was carried out almost entirely by means of the Kirchhoff-Kottler vector diffraction program. The program generates electric and magnetic field intensity, associated phase, and time-average Poynting vector power flow in the intermediate near-field and far-field zones in both receive and transmit modes of operation. A few of the concepts have been verified experimentally with excellent agreement between theory and practice.

Schmidt, R. F.↗
NASA NTRS1978

Synthetic aperture radar operator tactical target acquisition research

A radar target acquisition research study was conducted to access the effects of two levels of 13 radar sensor, display, and mission parameters on operator tactical target acquisition. A saturated fractional-factorial screening design was employed to examine these parameters. Data analysis computed ETA squared values for main and second-order effects for the variables tested. Ranking of the research parameters in terms of importance to system design revealed four variables (radar coverage, radar resolution/multiple looks, display resolution, and display size) accounted for 50 percent of the target acquisition probability variance.

Hershberger, M. L.↗
NASA NTRS2024

Critical Load Exceedances for North America and Europe using an Ensemble of Models and an Investigation of Causes for Environmental Impact Estimate Variability: An AQMEII4 Study

Exceedances of critical loads for deposition of sulphur (S) and nitrogen (N) to different ecosystems were estimated using European and North American ensembles of air quality models, under Phase 4 of the Air Quality Model Evaluation International Initiative (AQMEII4), to identify where risk of ecosystem harm is expected to occur based on model deposition estimates. The ensembles were driven by common emissions and lateral boundary condition inputs. Model output was regridded to common North American and Europe 0.125° resolution domains, which were then used to calculate critical load exceedances. New, targeted deposition diagnostics implemented in AQMEII4 allowed an unprecedented level of post-simulation analysis to be carried out and facilitated the identification of specific causes of model-to-model variability in critical load exceedance estimates. New datasets for North American critical loads for acidity for forest soil water and aquatic ecosystems were combined with the ensemble deposition predictions to show a substantial decrease in the area and number of locations in exceedance between 2010 and 2016 (forest soils: 13.2 % to 6.1 %; aquatic ecosystems: 21.2 % to 11.4 %). All models agreed in the direction of the ensemble exceedance change between 2010 and 2016. The North American ensemble also predicted a decrease in both severity and total area in exceedance between the years 2010 and 2016 for eutrophication-impacted ecosystems in the USA (sensitive epiphytic lichen: 81.5 % to 75.8 %). The exceedances for herbaceous community richness also decreased between 2010 and 2016, from 13.9 % to 3.9 %. The uncertainty associated with the North American eutrophication results is high; there were sharp differences between the models in both predictions of total N deposition and the change in N deposition, and hence in the predicted eutrophication exceedances between the two years. The European ensemble was used to predict relatively static exceedances of critical loads with respect to acidification (4.48 % to 4.32 % from 2009 to 2010) while eutrophication exceedance increased slightly (60.2 % to 62.2 %). While most models showed the same changes in critical load exceedances as the ensemble between the two years, the spatial extent and magnitude of exceedances varied significantly between the models. The reasons for this variation were examined in detail by first ranking the relative contribution of different sources of sulphur and nitrogen deposition in terms of deposited mass and model-to-model variability in that deposited mass, followed by their analysis using AQMEII4 diagnostics, along with evaluation of the most recent literature. All models in both the North American and European ensembles had net annual negative biases with respect to observed wet deposition of sulphate, nitrate and ammonium. Diagnostics and recent literature suggest that this bias may stem from insufficient cloud scavenging of aerosols and gases, and may be improved through the incorporation of multiphase hydrometeor scavenging within the modelling frameworks. The inability of North American models to predict the timing of the seasonal peak in wet ammonium ion deposition (observed maximum was in April, while all models predicted a June maximum) may also relate to the need for multiphase hydrometeor scavenging (absence of snow scavenging in all models employed here). High variability in the relative importance of particulate sulphate, nitrate and ammonium deposition fluxes between models was linked to the use of updated particle dry deposition parameterizations in some models. However, recent literature and further development of some of the models within the ensemble suggests these particulate biases may also be ameliorated via the incorporation of multiphase hydrometeor scavenging. Annual sulphur and nitrogen deposition prediction variability was linked to SO 2 and HNO 3 dry deposition parameterizations, and diagnostic analysis showed that the cuticle and soil deposition pathways dominate the deposition mass flux of these species. Further work improving parameterizations for these deposition pathways should reduce variability in model acidifying gas deposition estimates. The absence of base cation chemistry in some models was shown to be a major factor in positive biases in fine mode particulate ammonium and particle nitrate concentrations. Models employing ammonia bidirectional fluxes had both the largest and the smallest magnitude biases, depending on the model and bidirectional flux algorithm employed. A careful analysis of bidirectional flux models suggests that those with poor NH 3 performance may underestimate the extent of NH 3 emissions fluxes from forested areas. Based on these results, an increased process-research focus is therefore recommended for the following model processes and on observations which may assist in model evaluation and improvement: multiphase hydrometeor scavenging combined with updated particle dry deposition, cuticle and soil deposition pathway algorithms for acidifying gases, base cation chemistry and emissions, and NH 3 bidirectional fluxes. Comparisons with satellite observations suggest that oceanic NH 3 emissions sources should be included in regional chemical transport models. The choice of land use database employed within any given model was shown to significantly influence deposition totals in several instances, and employing a common land use database across chemical transport models and critical load calculations is recommended for future work.

critical loads↗
NASA NTRS1998

Variability of Arctic Sea Ice as Viewed from Space

Over the past 20 years, satellite passive-microwave radiometry has provided a marvelous means for obtaining information about the variability of the Arctic sea ice cover and particularly about sea ice concentrations (% areal coverages) and from them ice extents and the lengths of the sea ice season. This ability derives from the sharp contrast between the microwave emissions of sea ice versus liquid water and allows routine monitoring of the vast Arctic sea ice cover, which typically varies in extent from a minimum of about 8,000,000 sq km in September to a maximum of about 15,000,000 sq km in March, the latter value being over 1.5 times the area of either the United States or Canada. The vast Arctic ice cover has many impacts, including hindering heat, mass, and y momentum exchanges between the oceans and the atmosphere, reducing the amount of solar radiation absorbed at the Earth's surface, affecting freshwater transports and ocean circulation, and serving as a vital surface for many species of polar animals. These direct impacts also lead to indirect impacts, including effects on local and perhaps global atmospheric temperatures, effects that are being examined in general circulation modeling studies, where preliminary results indicate that changes on the order of a few percent sea ice concentration can lead to temperature changes of 1 K or greater even in local areas outside of the sea ice region. Satellite passive-microwave data for November 1978 through December 1996 reveal marked regional and interannual variabilities in both the ice extents and the lengths of the sea ice season, as well as some statistically significant trends. For the north polar ice cover as a whole, maximum ice extents varied over a range of 14,700,000 - 15,900,000 km(2), while individual regions showed much greater percentage variations, e.g., with the Greenland Sea experiencing a range of 740,000 - 1,1110,000 km(2) in its yearly maximum ice coverage. Although variations from year to year and region to region are large, overall the Arctic ice extents did show a statistically significant, 2.8%/ decade negative trend over the 18.2-year period. Ice season lengths, which vary from only a few weeks near the ice margins to the full year in the large region of perennial ice coverage, also experienced interannual variability, and mapping their trends allows detailed geographic information on exactly where the ice season lengthened and where it shortened. Over the 18 years, ice season lengthening occurred predominantly in the western hemisphere and was strongest in the western Labrador Sea, while ice season shortening occurred predominantly in the eastern hemisphere and was strongest in the eastern Barents Sea. Much information about other important Arctic sea ice variables has also been obtained from satellite data, including information about melt ponding, temperature, snow cover, and ice velocities. For instance, maps of ice velocities have now been made from satellite scatterometry data, including information about melt ponding, temperature, snow cover, and ice velocities.

Parkinson, Claire L.↗
NASA NTRS2018

Su Lyn: Diagnosing the Boundary Layer with UV and Hard X-Ray Data

Symbiotic stars in which the symbiotic phenomenon is powered solely by accretion, often at an average rate that is higher than in cataclysmic variable stars, provide an important opportunity to diagnose boundary layers around disk-accreting white dwarfs. Here, we investigate SU Lyncis (SU Lyn), a recently discovered example of a purely accretion-powered symbiotic star, using the first reliable X-ray spectroscopy, obtained with NuSTAR, and ultraviolet (UV) photometry obtained with Swift. SU Lyn has hard, thermal, X-ray emission that is strongly affected by a variable local absorber that has little impact on the UV emission. Its X-ray spectrum is described well using a plasma cooling from kT ≈ 21 keV, with a 3-30 keV luminosity of approximately 4.9 × 10(exp 32) erg s(exp -1). The spectrum is also consistent with the presence of reflection with an amplitude of 1.0, although in that case, the bestfit plasma temperature is 20%-25% lower. The UV to X-ray luminosity ratio of SU Lyn changed significantly between 2015 and 2016. We interpret this as a consequence of a drop by almost 90% in the accretion rate. Whereas the UV luminosity of the disk responded linearly, the luminosity of the optically thin (hard X-ray) emission from the boundary layer remained roughly constant because the boundary layer changed from partially optically thick to almost completely optically thin. Under this interpretation, we place a lower limit on the white dwarf mass of 0.7 solar mass (0.8 solar mass if we neglect reflection).

NuSTAR↗
DOE OSTI2025

Optimization of direct air capture processes using reactive transport models of adsorption-desorption cycles

In this study, we develop and implement a reactive transport model in COMSOL Multiphysics® to address the challenges of direct air carbon capture. The model is validated against experimental data and used to simulate the cyclic steady state of the adsorption-desorption process. The optimization of this model is achieved through advanced trust-region methods integrated with Gaussian Processes. Key decision variables, including adsorption and desorption times, desorption temperature and pressure, input velocity, bed porosity, column length, and radius were optimized to minimize the capture cost. After optimization, a sensitivity analysis revealed the complex interplay between the decision variables and their effect on the specific energy and cost of removing the CO 2 . We optimized the capture cost while taking into account the trade-off between energy consumption and productivity. The resulting minimum capture cost was determined to be 265.2 $/t-CO 2 , which aligns with expected values reported in the literature. Numerical results suggest the effectiveness of the optimization strategies applied, and underscore the importance of simultaneous decision variable selection in improving the performance in direct air capture processes. We also extend the modeling approach to a 2D axisymmetric model to better visualize CO₂ uptake and temperature profiles, revealing significant radial gradients during the regeneration step. As a main drawback, this enhanced model comes with a computational cost approximately 40 times higher than that of the 1D model.

Adsorption-desorption process↗
NASA NTRS2001

Evidence-Based Approach to the Analysis of Serious Decompression Sickness with Application to EVA Astronauts

It is important to understand the risk of serious hypobaric decompression sickness (DCS) in order to develop procedures and treatment responses to mitigate the risk. Since it is not ethical to conduct prospective tests about serious DCS with humans, the necessary information was gathered from 73 published reports. We hypothesize that a 4-hr 100% oxygen (O2) prebreathe results in a very low risk of serious DCS, and test this through analysis. We evaluated 258 tests containing information from 79,366 exposures in attitude chambers. Serious DCS was documented in 918 men during the tests. Serious DCS are signs and symptoms broadly classified as Type II DCS. A risk function analysis with maximum likelihood optimization was performed to identify significant explanatory variables, and to create a predictive model for the probability of serious DCS [P(serious DCS)]. Useful variables were Tissue Ratio, the planned time spent at altitude (T(sub alt)), and whether or not repetitive exercise was performed at altitude. Tissue Ratio is P1N2/P2, where P1N2 is calculated nitrogen (N2) pressure in a compartment with a 180-min half-time for N2 pressure just before ascent, and P2 is ambient pressure after ascent. A prebreathe and decompression profile Shuttle astronauts use for extravehicular activity (EVA) includes a 4-hr prebreathe with 100% O2, an ascent to P2 = 4.3 lb per sq. in. absolute, and a T(sub alt) = 6 hr. The P(serious DCS) is: 0.0014 (0.00096 - 0.00196, 95% confidence interval) with exercise and 0.00025 (0.00016 - 0.00035) without exercise. Given 100 Shuttle EVAs to date and no report of serious DCS, the true risk is less than 0.03 with 95% confidence (Binomial Theorem). It is problematic to estimate the risk of serious DCS since it appears infrequently, even if the estimate is based on thousands of altitude chamber exposures. The true risk to astronauts may lie between the extremes of the confidence intervals (0.00016 - 0.00196) since the contribution of other factors, particularly exercise, to the risk of serious DCS during EVA is unknown. A simple model that only accounts for four important variables in retrospective data is still helpful to increase our understanding about the risk of serious DCS.

Conkin, Johnny↗
NASA NTRS2022

Mid-Pliocene El Niño/Southern Oscillation Suppressed By Pacific Intertropical Convergence Zone Shift

The El Niño/Southern Oscillation (ENSO), the dominant driver of year-to-year climate variability in the equatorial Pacific Ocean, impacts climate pattern across the globe. However, the response of the ENSO system to past and potential future temperature increases is not fully understood. Here we investigate ENSO variability in the warmer climate of the mid-Pliocene (~3.0–3.3 Ma), when surface temperatures were ~2–3 °C above modern values, in a large ensemble of climate models—the Pliocene Model Intercomparison Project. We show that the ensemble consistently suggests a weakening of ENSO variability, with a mean reduction of 25% (±16%). We further show that shifts in the equatorial Pacific mean state cannot fully explain these changes. Instead, ENSO was suppressed by a series of off-equatorial processes triggered by a northward displacement of the Pacific intertropical convergence zone: weakened convective feedback and intensified Southern Hemisphere circulation, which inhibit various processes that initiate ENSO. The connection between the climatological intertropical convergence zone position and ENSO we find in the past is expected to operate in our warming world with important ramifications for ENSO variability.

Atmospheric dynamics↗
NASA NTRS1988

Atmospheric effects on earth rotation and polar motion

The variability in the earth's rotation rate not due to known solid body tides is dominated on time scales of about four years and less by variations in global atmospheric angular momentum (M) as derived from the zonal wind distribution. Among features seen in the length of day record produced by atmospheric forcing are the strong seasonal cycle, quasi-periodic fluctuations around 40-50 days, and an interannual signal forced by a strong Pacific warming event known as the El Nino. Momentum variations associated with these time scales arise in different latitudinal regions. Furthermore, winds in the stratosphere make a particularly important contribution to seasonal variability. Other related topics discussed here are: (1) comparisons of the M series from wind fields produced at different weather centers; (2) the torques that dynamically link the atmosphere and earth; and (3) longer-term nonatmospheric effects that can be seen upon removal of the atmospheric signal.an interestigapplication for climatological purposes is the use of the historical earth rotation series as a proxy for atmospheric wind variability prior to the era of upper-air data. Lastly, results pertaining to the role of atmospheric pressure systems in exciting rapid polar motion are presented.

Salstein, David A.↗
NASA NTRS1979

The search for, and study of black holes in the galaxy

The study of the short-term (less than 10 s) time variability of Cygnus X-1 is reviewed, with attention given to measurements of the autocorrelation function and of the cross-correlation between different energy bandwidths, as well as to a simple shot noise model for describing all such short-term variations. Observational questions with regard to Cygnus X-1 are discussed, relating to the average shape of the randomly occurring flares, energy dependence in the cross-correlation and the dependence on energy of the X-ray polarization. Concerning the study of the Cyg X-1-like aperiodic X-ray sources, an estimate is made of what can be accomplished at the limits of sensitivity where Poisson fluctuations are at least as important as the intrinsic variability of the source, considering the third moment due to the source fluctuations.

Weisskopf, M. C.↗
NASA NTRS1991

Spatial and temporal variability of the extent of chemically processed stratospheric air

Simulations of the spatial and temporal variability of the extent of chemically processed air in the Arctic stratosphere have been carried out using a three-dimensional chemistry-transport model for the winters of 1979 and 1989. Chemically processed air is identified in the model as that in which the amounts of hydrogen chloride (HCl) calculated with parameterized loss for conditions appropriate to polar stratospheric cloud (PSC) formation are substantially smaller than those calculated in a model with gas phase chemistry only. It is seen that chemically processed air may be identified over much of the Arctic lower stratosphere from early January to late February, with HCl depletions being larger in 1989 than in 1979. Near the latitude of the Arctic circle, there is important spatial and temporal variability in the extent of chemically processed air. There is some evidence for transport to midlatitudes of processed air during these winters, but the HCl reductions are much smaller and more sporadic than those near the pole. At 62 and 42N, processed air is calculated to occur preferentially over the longitude regions from 60-120E and 270-330E.

Kaye, Jack A.↗
DOE OSTI2025

Impact of a dynamic grid mix and climate on operational carbon emissions modeling for different building typologies and climate zones

Calculating operational carbon emissions through a building’s lifecycle is complex due to the dynamic nature of influencing factors such as climate and energy grid mix. This paper introduces a novel methodology for modeling 30-year operational carbon impacts of buildings and applies this method to mid-rise office and residential typologies across various US climate zones. The method accounts for these temporal variabilities using new and scarcely cited data sources. Key findings indicate that future changes in the climate, while impactful, play a relatively modest role in operational carbon emissions compared to significant reductions with modeling scenarios using the projected decarbonization of the electricity grid. Here, the study also finds that using annual, month-hourly, or hourly grid emission factors have a minimal impact on carbon accounting, except in certain climates and program types where emission patterns do not align with a building’s energy consumption. Warmer climates like Miami, Florida and Tucson, Arizona, which rely heavily on cooling, demonstrate larger variations in carbon emissions when using higher temporal resolution emission factors. Ultimately, this study underscores the critical role of grid decarbonization in reducing long-term emissions and the importance of incorporating this variable in life cycle assessment (LCA) modeling.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS2018

Reconstruction of Snow on Arctic Sea Ice

Snow on Arctic sea ice is a poorly observed variable that plays an important role in the Arctic climate system and impacts the remote sensing systems that monitor Arctic sea ice. We present and validate a reconstruction of Arctic snow depth based on observed sea ice motion and snowfall derived from reanalysis data. Overall, the reconstruction is in good agreement with direct measurements of snow depth from Operation IceBridge, slightly underestimating mean IceBridge snow depth. At the local scale (10 km), the reconstruction is more skilled than a weighted climatology over first year ice, but underestimates deeper snow over multiyear ice. Reconstructions of single buoy snow depths are unskilled, but the reconstruction shows skill in simulating the mean snow depth across all buoys. Spring snow depths show a lowtohigh crossArctic gradient and tend to be greatest in the Atlantic sector of the eastern Arctic. The relationship between ice type (multiyear or firstyear ice) and snow depth previously documented in the western Arctic is not evident in the eastern Arctic. Using ice type to weight snow depths for satellite ice thickness retrievals may not be justifiable in the eastern Arctic. Reconstructed snow depth across the Arctic shows significant interannual variability, suggesting that use of a fixed snow depth climatology may lead to biases in retrieved ice thickness and its variability. However, interannual variability in panArctic mean snow depth is comparable or smaller than the uncertainty in both the reconstruction and IceBridge, highlighting the need for high accuracy snow depth products and reconstructions.

sea ice↗
DOE OSTI2024

Subdecadal Holocene Warm-Season Temperature Variability in Central Europe Recorded by Biochemical Varves

Paleoclimate data provide important information about the character of natural climate variability. However, records with sufficient length and resolution to resolve high-frequency (decadal-scale) variability across the Holocene are scarce. We present a 10,800-year reconstruction of spring and summer temperature at three-year resolution based on biochemical varves from Lake $\dot{Z}abi$$\acute{n}skie$, Poland. The reconstruction is based on Ca/Ti ratio, which are significantly correlated with instrumental spring and summer temperature spanning 240 years. Major climate events of the Holocene period are represented in the reconstruction, including the Holocene Thermal Maximum, 8.2 ka Event, Medieval Climate Anomaly, and Little Ice Age. A low-frequency 8,000-year decreasing trend in warm-season temperatures is driven by declining summer insolation. Temperature variability is highest during the early Holocene, likely related to warmer and drier conditions. The rate of warming during the past 90 years is extremely unusual, if not unprecedented for the Holocene, based on our reconstruction.

58 GEOSCIENCES↗
DOE OSTI2025

The Freundlich isotherm equation best represents phosphate sorption across soil orders and land use types in tropical soils of Puerto Rico

Biomass production in the lowland wet tropical forest is greater than in any other biome, and it is typically limited by soil phosphorus (P) availability. However, the mechanisms involved in the P cycle remain poorly represented in Earth System Models (ESMs). Soil P sorption processes are key in the P cycle and for understanding the extent of P limitation for plant productivity. Currently, a few ESMs include isotherm equations to model these processes. Although the Langmuir equation is widely cited, other isotherm equations may better describe sorption in tropical soils. Here, we use a diverse range of soil samples from Puerto Rico to test the validity of the Langmuir, Freundlich, and Temkin equation. We found that across four soil orders (Inceptisols, Mollisols, Oxisols, Ultisols), and forested and cultivated land use types, the Freundlich equation best represented soil P sorption. Furthermore, the Langmuir and the Temkin equations poorly represent soil P adsorption, especially at low P concentrations. Specifically, the Langmuir equation underestimated soil P adsorption by 40% and the Temkin equation overestimated adsorption by 76%. We also found, as expected, that soil clay content and pH were the most important parameters explaining the variability of the Freundlich (K f ) constant. Greater clay content and lower pH, common in highly weathered Ultisols and Oxisols which are abundant in the tropics, led to greater K f values. Overall, our results suggest that a diversity of soils can prompt underestimation of P sorption when using the Langmuir isotherm, which leads to an overestimation of available P that can have repercussions on ESM predictions of the P cycle and tropical forest productivity.

Earth system models↗