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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

The Density Matrix of H20 - N2 In the Coordinate Representation: A Monte Carlo Calculation of the Far-Wing Line Shape

The far-wing line shape theory within the binary collision and quasistatic framework has been developed using the coordinate representation. Within this formalism, the main computational task is the evaluation of multidimensional integrals whose variables are the orientational angles needed to specify the initial and final positions of the system during transition processes. Using standard methods, one is able to evaluate the 7-dimensional integrations required for linear molecular systems, or the 7-dimensional integrations for more complicated asymmetric-top (or symmetric-top) molecular systems whose interaction potential contains cyclic coordinates. In order to obviate this latter restriction on the form of the interaction potential, a Monte Carlo method is used to evaluate the 9-dimensional integrations required for systems consisting of one asymmetric-top (or symmetric-top) and one linear molecule, such as H20-N2. Combined with techniques developed previously to deal with sophisticated potential models, one is able to implement realistic potentials for these systems and derive accurate, converged results for the far-wing line shapes and the corresponding absorption coefficients. Conversely, comparison of the far-wing absorption with experimental data can serve as a sensitive diagnostic tool in order to obtain detailed information on the short-range anisotropic dependence of interaction potentials.

Ma, Q.↗
NASA NTRS2008

Absorption and Attenuation Coefficients Using the WET Labs ac-s in the Mid-Atlantic Bight: Field Measurements and Data Analysis

Ocean color algorithms are based on the parameterization of apparent optical properties as a function of inherent optical properties. WET Labs underwater absorption and attenuation meters (ac-9 and ac-s) measure both the spectral beam attenuation [c (lambda)] and absorption coefficient [a (lambda)]. The ac-s reports in a continuous range of 390-750 nm with a band pass of 4 nm, totaling approximately 83 distinct wavelengths, while the ac-9 reports at 9 wavelengths. We performed the ac-s field measurements at nine stations in the Mid-Atlantic Bight from water calibrations to data analysis. Onboard the ship, the ac-s was calibrated daily using Milli Q-water. Corrections for the in situ temperature and salinity effects on optical properties of water were applied. Corrections for incomplete recovery of the scattered light in the ac-s absorption tube were performed. The fine scale of spectral and vertical distributions of c (lambda) and a (lambda) were described from the ac-s. The significant relationships between a (674) and that of spectrophotometric analysis and chlorophyll a concentration of discrete water samples were observed.

Ohi, Nobuaki↗
NASA NTRS1966

A Congeries of Absorption Cross Sections for Wavelengths Less Than 3000 degrees Angstrom

The absorption of ultraviolet solar radiation is of prime importance for the study of planetary atmospheres.The absorption coefficients of most of the atmospheric gases have been measured by a number of investigators, but the results are scattered throughout the literature. This report contains a detailed collection of absorption cross sections of the gases listed in Table 1 for wavelengths less than 3000 degrees angstroms. The data on each gas are given together with a historical sketch of the study of the gas and a list of the pertinent references. Also included is a study of the absorption and photoionization coefficients of the major atmospheric gases at intense solar emission lines.

Sullivan, J. O.↗
DOE OSTI2024

EPCAPE-PT-LANL Measurements: Photoacoustic Extinctometer

Coastal cities offer a unique environment for studying aerosol-cloud interactions and the effects of urban emissions on cloud properties. As part of the Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE), the Partitioning Thrust by Los Alamos National Laboratory (EPCAPE-PT-LANL) was conducted. Our campaign focused on measuring the optical and chemical properties of aerosols and their interactions within marine stratocumulus clouds in La Jolla, California. EPCAPE-PT-LANL enhances the primary goals of EPCAPE through innovative observations of vapor-phase transitions between aerosols and cloud droplets, the impact of black carbon on aerosol-cloud dynamics, and the effects of cloud processing on aerosol optical properties. Instrument: Photoacoustic Extinctiometer at 870 nm (Droplet Measurement Technology) Header: - AbsorptionNoise_870nm[1/Mm]: Noise level associated with the absorption measurement at 870 nm, expressed in inverse megameters (Mm⁻¹). - Absorption_870nm[1/Mm]: Absorption coefficient of aerosols measured at 870 nm, expressed in inverse megameters (Mm⁻¹). - Extinction_870nm[1/Mm]: Extinction coefficient of aerosols measured at 870 nm, expressing the sum of scattering and absorption by aerosols, in inverse megameters (Mm⁻¹). - Scattering_870nm[1/Mm]: Scattering coefficient of aerosols measured at 870 nm, expressed in inverse megameters (Mm⁻¹). - BackgroundAbsorption_870nm[1/Mm]: Background absorption measurement at 870 nm, used to correct the primary absorption data, expressed in inverse megameters (Mm⁻¹). - BackgroundScattering_870nm[1/Mm]: Background scattering measurement at 870 nm, used to correct the primary scattering data, expressed in inverse megameters (Mm⁻¹). - Temperature[C]: The ambient temperature at the time of the measurement, expressed in degrees Celsius. - RelativeHumidity[%]: The relative humidity at the time of the measurement, expressed as a percentage. - CVI_Flag[bool]: A boolean flag indicating whether the Counterflow Virtual Impactor (CVI) was active (true) or inactive (false) during the measurement

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

Electrical properties of tin-doped zinc oxide nanostructures doped at different dopant concentrations

This project has been focused on the electrical and optical properties respectively on the effect of Tin doped zinc oxide (ZnO) thin films at different dopant concentrations. These thin films were doped with different Sn dopant concentrations at 1 at%, 2 at%, 3 at%, 4 at% and 5 at% was selected as the parameter to optimize the thin films quality while the annealing temperature is fixed 500 °C. Sn doped ZnO solutions were deposited onto the glass substrates using sol-gel spin coating method. This project was involved with three phases, which are thin films preparation, deposition and characterization. The thin films were characterized using Current Voltage (I-V) measurement and ultraviolet-visible-near-infrared (UV-vis-NIR) spectrophotometer (Perkin Elmer Lambda 750) for electrical properties and optical properties. The electrical properties show that the resistivity is the lowest at 4 at% Sn doping concentration with the value 3.08 × 10{sup 3} Ωcm{sup −1}. The absorption coefficient spectrum obtained shows all films exhibit very low absorption in the visible (400-800 nm) and near infrared (NIR) (>800 nm) range but exhibit high absorption in the UV range.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
NASA NTRS1977

A theoretical/experimental program to develop active optical pollution sensors

Light detection and ranging (LIDAR) technology was applied to the assessment of air quality, and its usefulness was evaluated by actual field tests. Necessary hardware was successfully constructed and operated in the field. Measurements of necessary physical parameters, such as SO2 absorption coefficients were successfully completed and theoretical predictions of differential absorption performance were reported. Plume modeling improvements were proposed. A full scale field test of equipment, data analysis and auxiliary data support was conducted in Maryland during September 1976.

Mills, F. S.↗
NASA NTRS1980

Spectral scattering properties of turbid waters

River water samples have been examined for optical scattering properties at wavelengths between 400 and 800 nm. Scattering coefficients were calculated from measurements of beam attenuation and absorption coefficients and are observed to vary with wavelength. At a fixed wavelength, the scattering coefficient is influenced by both phytoplankton concentration (as indicated by chlorophyll a) and suspended solids concentration. Measurements of small angle volume-scattering function indicate that the phase function at an angle of 1.5 deg is not constant for turbid waters and varies with both wavelength and beam attenuation coefficient. These data differ from previously published results for relatively clear oceanic and coastal waters. Caution is required when attempting to estimate scattering coefficient values from single-angle measurements of volume-scattering function.

Whitlock, C. H.↗
NASA NTRS1983

A parameterization of the absorption in the 15 micron CO2 spectral region with application to climate sensitivity studies

A technique for quantifying the absorption that takes place in the 15 micron CO2 band in the atmosphere is developed as a function of the scaled CO2 content. A spectrally averaged transmission function is defined and a scaling approximation for the absorption coefficient is calculated, as is the width of the absorption band. An assessment is made of the accuracies of the parameterized atmospheric transmittance and cooling rate. The resulting radiation parameterization is applied in a climate sensitivity study. The model is concluded useful in examining atmospheres with a variable CO2 content, with the highest accuracies being available in the troposphere and the lower stratosphere. CO2 doubling the earth's atmosphere is projected to cause a 20 percent warming in the surface temperatures and a 30 percent warming for the tripling of the CO2 content, provided the spectral range for CO2 absorption is extended from 580-760 to 540-800/cm.

Chou, M.-D.↗
NASA NTRS2012

On Spectral Invariance of Single Scattering Albedo for Water Droplets and Ice Crystals at Weakly Absorbing Wavelengths

The single scattering albedo omega(sub O lambda) in atmospheric radiative transfer is the ratio of the scattering coefficient to the extinction coefficient. For cloud water droplets both the scattering and absorption coefficients, thus the single scattering albedo, are functions of wavelength lambda and droplet size r. This note shows that for water droplets at weakly absorbing wavelengths, the ratio omega(sub O lambda)(r)/omega(sub O lambda)(r (sub O)) of two single scattering albedo spectra is a linear function of omega(sub O lambda)(r). The slope and intercept of the linear function are wavelength independent and sum to unity. This relationship allows for a representation of any single scattering albedo spectrum omega(sub O lambda)(r) via one known spectrum omega(sub O lambda)(r (sub O)). We provide a simple physical explanation of the discovered relationship. Similar linear relationships were found for the single scattering albedo spectra of non-spherical ice crystals.

single scattering albedo↗
DOE OSTI2018

Simulation of the optical properties of surface nanostructures for photoacoustic converters

A computer model has been developed and a theoretical study has been performed for nanostructures in the form of a two-dimensional monolayer of nanoparticles of noble metals on an optical fibre end face. The parameters of nanostructure-based photoacoustic converters are chosen for different environments in order to provide a high light absorption coefficient, which, in turn, provides a maximally high conversion efficiency for ultrasound generation. It is established that efficient photoacoustic conversion can be implemented in a surface nanostructure composed of spherical gold nanoparticles, located on an optical fibre end face in water, in wide ranges of the nanostructure microscopic parameters. It is shown that the backscattering coefficient also turns out large in the case of resonance absorption; for this reason, one must provide optical isolation of a laser in use when designing photoacoustic generators. (nanostructures)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2017

Experimental realization of a terahertz all-dielectric metasurface absorber

Metamaterial absorbers consisting of metal, metal-dielectric, or dielectric materials have been realized across much of the electromagnetic spectrum and have demonstrated novel properties and applications. However, most absorbers utilize metals and thus are limited in applicability due to their low melting point, high Ohmic loss and high thermal conductivity. Other approaches rely on large dielectric structures and / or a supporting dielectric substrate as a loss mechanism, thereby realizing large absorption volumes. Here we present a terahertz (THz) all dielectric metasurface absorber based on hybrid dielectric waveguide resonances. We tune the metasurface geometry in order to overlap electric and magnetic dipole resonances at the same frequency, thus achieving an experimental absorption of 97.5%. A simulated dielectric metasurface achieves a total absorption coefficient enhancement factor of F T =140, with a small absorption volume. Our experimental results are well described by theory and simulations and not limited to the THz range, but may be extended to microwave, infrared and optical frequencies. In conclusion, the concept of an all-dielectric metasurface absorber offers a new route for control of the emission and absorption of electromagnetic radiation from surfaces with potential applications in energy harvesting, imaging, and sensing.

36 MATERIALS SCIENCE↗
NASA NTRS1971

Basic characteristics of high-frequency Stark-effect modulation of CO2 lasers.

The molecular Stark effect and its application to the modulation of infrared laser radiation have been investigated both theoretically and experimentally. Using a density matrix approach, a quantum mechanical description of the effect of a time-varying electric field on the absorption coefficient and refractive index of a molecular gas near an absorption line has been formulated. For modulation applications a quantity known as the ?modulation depth' is of prime importance. Theoretical expressions for the frequency dependence of the modulation depth show that the response to the frequency of a time-varying Stark field is separated into a nondispersive and a dispersive region, depending on whether the modulating frequency is less than or greater than the homogeneous absorption linewidth. Experimental results showing nondispersive modulation at frequencies to 30 MHz are presented. In addition it is shown that the response of modulation depth to Stark field amplitude is separated into linear and nonlinear regions, the field at which nonlinearities begin being determined by the absorption spectrum of the molecule being used.

Claspy, P. C.↗
NASA NTRS1973

On the emission coefficient of uranium plasmas.

The emission coefficient for uranium plasmas (temperature: 8000 K) was measured for the wavelength range from 1200 to 6000 A. The results were compared to theoretical calculations and other measurements. Reasonable agreement between theoretical predictions and our measurements was found in the region from 1200 to 2000 A. Although it was difficult to make absolute comparisons among the different reported measurements, considerable disagreement was found for the higher wavelength region. A short discussion regarding the overall comparisons is given, and final suggestions are made as to the most appropriate emission coefficient values to be used in future design calculations. The absorption coefficient for the same wavelength interval is also reported.

Schneider, R. T.↗
NASA NTRS1979

Application of a microprocessor controlled lidar to tropospheric ozone measurements

A microprocessor controlled lidar system under construction at the NASA Goddard Space Flight Center is described and the problems in making space-based measurements of tropospheric ozone are considered. The differential absorption lidar using a dual wavelength, pulsed CO2 laser and direct detection receiver can significantly improve the existing global data base on tropospheric ozone burden. Sensitivity to tropospheric ozone can be obtained in the spaceborne version of lidar by selecting laser lines located in the wings of the target zone lines. Simulation studies using various laser line pairs in the P-branch of the CO2 9.4 micron band show that the ozone burden retrieval may be weighted to particular altitude regions. These simulation studies are based on numerical integration of differences in absorption coefficient at the two selected laser wavelengths using the AFGL absorption line parameter compilations, U.S. Standard Atmosphere ozone profile, and laser software. Simulation, data collection and reduction are performed by a microprocessor subsystem of the CO2 lidar.

Stewart, R. W.↗
NASA NTRS1984

Satellite observation of SO2 from El Chichon - Identification and measurement

Absorption bands between 300 nm and 315 nm were observed in spectral scans of the atmospheric albedo made by the solar backscattered ultraviolet instrument (SBUV) on Nimbus 7 following the eruption of El Chichon. It is shown that these bands coincide with peaks in the absorption coefficient spectrum of SO2 and use the magnitude of the absorption to estimate the column content of SO2 present. A maximum concentration of 15 matm-cm of SO2 was observed west of Hawaii on April 15; the minimum detectable amount of SO2 in a single scan is about 1 matm-cm. The disappearance of the band structure at wavelengths below 300 nm indicates that the SO2 was between 20 km and 30 km altitude. An excess albedo was also observed near 300 nm which was attributed to increased scattering from volcanic aerosols; the wavelength of the scattering feature indicates that the aerosols also were near 25 km altitude.

Mcpeters, R. D.↗
NASA NTRS1987

Analysis of SO2 signals in SBUV/TOMS data

Absorption bands between 300 nm and 315 nm were observed in spectral scans of the atmospheric albedo made by the Solar Backscatter Ultraviolet (SBUV) spectrometer following the eruption of El Chichon. It is shown that those bands coincide with peaks in the absorption coefficient spectrum of SO sub 2. The magnitude of the absorption is used to the column content of present SO sub 2. These observations confirm that the differential absorption between 312.5 nm and 317.5 nm in Total Ozone Mapping Spectrometer (TOMS) data can be used to measure SO sub 2 with high spatial resolution. A maximum concentration of SO sub 2 of 15 matm-cm was observed by SBUV on April 15, 1982. The measurement based on direct measurement of band intensity can be used to calibrate the TOMS algorithm for deriving SO sub 2 amounts.

Mcpeters, Richard↗
NASA NTRS2001

Determining CDOM Absorption Spectra in Diverse Aquatic Environments Using a Multiple Pathlength, Liquid Core Waveguide System

We evaluated the accuracy, sensitivity and precision of a multiple pathlength, liquid core waveguide (MPLCW) system for measuring colored dissolved organic matter (CDOM) absorption in the UV-visible spectral range (370-700 nm). The MPLCW has four optical paths (2.0, 9.8, 49.3, and 204 cm) coupled to a single Teflon AF sample cell. Water samples were obtained from inland, coastal and ocean waters ranging in salinity from 0 to 36 PSU. Reference solutions for the MPLCW were made having a refractive index of the sample. CDOM absorption coefficients, aCDOM, and the slope of the log-linearized absorption spectra, S, were compared with values obtained using a dual-beam spectrophotometer. Absorption of phenol red secondary standards measured by the MPLCW at 558 nm were highly correlated with spectrophotometer values and showed a linear response across all four pathlengths. Values of aCDOM measured using the MPLCW were virtually identical to spectrophotometer values over a wide range of concentrations. The dynamic range of aCDOM for MPLCW measurements was 0.002 - 231.5 m-1. At low CDOM concentrations spectrophotometric aCDOM were slightly greater than MPLCW values and showed larger fluctuations at longer wavelengths due to limitations in instrument precision. In contrast, MPLCW spectra followed an exponential to 600 nm for all samples.

Miller, Richard L.↗
NASA NTRS2001

A Multi-Band Analytical Algorithm for Deriving Absorption and Backscattering Coefficients from Remote-Sensing Reflectance of Optically Deep Waters

A multi-band analytical (MBA) algorithm is developed to retrieve absorption and backscattering coefficients for optically deep waters, which can be applied to data from past and current satellite sensors, as well as data from hyperspectral sensors. This MBA algorithm applies a remote-sensing reflectance model derived from the Radiative Transfer Equation, and values of absorption and backscattering coefficients are analytically calculated from values of remote-sensing reflectance. There are only limited empirical relationships involved in the algorithm, which implies that this MBA algorithm could be applied to a wide dynamic range of waters. Applying the algorithm to a simulated non-"Case 1" data set, which has no relation to the development of the algorithm, the percentage error for the total absorption coefficient at 440 nm a (sub 440) is approximately 12% for a range of 0.012 - 2.1 per meter (approximately 6% for a (sub 440) less than approximately 0.3 per meter), while a traditional band-ratio approach returns a percentage error of approximately 30%. Applying it to a field data set ranging from 0.025 to 2.0 per meter, the result for a (sub 440) is very close to that using a full spectrum optimization technique (9.6% difference). Compared to the optimization approach, the MBA algorithm cuts the computation time dramatically with only a small sacrifice in accuracy, making it suitable for processing large data sets such as satellite images. Significant improvements over empirical algorithms have also been achieved in retrieving the optical properties of optically deep waters.

Lee, Zhong-Ping↗