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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Progress Towards an Investigation of the MiniBooNE Low Energy Excess Using Neutral-Current Delta-Like Single Photons in MicroBooNE with Wire-Cell 3D Reconstruction Algorithms

This note presents progress towards a Neutral-Current (NC) Delta-like single photon search in MicroBooNE using Wire-Cell 3D reconstruction and pattern recognition algorithms. This analysis will help address the question of the MiniBooNE Low Energy Excess (LEE) [1]. The selections are similar to the previously published Pandora-based single photon selections [2] in many ways, but here we use independent reconstruction and selection tools and examine a larger phase space (including charged pions and multiple protons). In the future, we will significantly reduce systematic uncertainties via the use of constraining sideband observations in order to statistically test specific models of the MiniBooNE LEE.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Progress towards an investigation of the MiniBooNE Low Energy Excess using neutral-current Delta-like single photons in MicroBooNE with Wire-Cell 3D reconstruction algorithms

This note presents progress towards a Neutral-Current (NC) Delta-like single photon search in MicroBooNE using Wire-Cell 3D reconstruction and pattern recognition algorithms. This analysis will help address the question of the MiniBooNE Low Energy Excess (LEE). The selections are similar to the previously published Pandora-based single photon selections in many ways, but here we use independent reconstruction and selection tools and examine a larger phase space (including charged pions and multiple protons). In the future, we will significantly reduce systematic uncertainties via the use of constraining sideband observations in order to statistically test specific models of the MiniBooNE LEE.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Final Technical Report: Transport of Complex Mixtures in Ion-Containing Polymer Membranes

Permselective ion-containing membranes are an integral component for many applications from water treatment, fuel cells, and solar fuels devices where the selective transport of molecules and ions is desired. In solar fuels devices, ion-containing polymer membranes are responsible for permitting selective transport of ions between electrodes to maintain overall charge neutrality yet limit transport of reaction products produced at the electrodes. While the transport of single solutes through such membranes has been fairly well described, binary and multicomponent transport is poorly understood due to the myriad of interactions that occur in these systems (i.e. between co-permeants and between permeants and the membrane). Solar fuels devices are just one example of an application where understanding the transport of multiple simultaneous species is critically important to improving device performance as product crossover leads to reductions in overall device performance. The objectives of this research was to improve our understanding of the complex array of factors that influence transport behavior of multiple solutes within ion-containing polymer membranes. This experimental project addressed the lack of fundamental understanding of multicomponent transport behavior by synthesizing ion exchange membranes with varied incorporation of comonomers (ionic and neutral moieties) to investigate fundamental relationships between membrane structure, membrane physiochemical properties, and transport behavior of solutes and complex solute mixtures through dense, hydrated membranes.

25 ENERGY STORAGE↗
DOE OSTI2026

Measurements of $\textrm{t}\overline{\textrm{t}}\textrm{W}$ differential cross sections and the leptonic charge asymmetry at $\sqrt{s}=13$ TeV

Measurements of properties of top quark-antiquark pair production in association with a W boson in proton-proton collisions at a center-of-mass energy of 13 TeV are presented, using a data sample corresponding to an integrated luminosity of 138 fb −1 , recorded by the CMS experiment at the CERN LHC. Events are selected based on the presence of either two leptons with the same electric charge or three leptons, and multiple jets and b-tagged jets. We present measurements of differential production cross sections as a function of kinematic variables sensitive to different aspects of the process modeling, using a multivariate discriminator in the two-lepton selection region and a simple selection-based method in the three-lepton region. The normalized cross section measurements are generally consistent with the standard model expectations, while we observe larger values compared to the expectations in the absolute cross section measurements, consistent with previous inclusive cross section measurements. In addition, we measure the leptonic charge asymmetry of this process, obtaining an observed value of ${A}_c^{\ell }=-{0.19}_{-0.18}^{+0.16}$, consistent with the expectation of −0.085 ± 0.006 predicted by next-to-leading order simulations.

Hadron-Hadron Scattering↗
DOE OSTI2021

Size-Dependent Onset of Nitric Acid Dissociation in Cs + ·(HNO 3 )(H 2 O) n =0–11 Clusters at 20 K

We report the water-mediated charge separation of nitric acid upon incorporation into size-selected Cs + ∙(HNO 3 )(H 2 O) n=0-11 clusters at 20 K. Dramatic spectral changes are observed in the range n=7-9 that are traced to the formation of many isomeric structures associated with intermediate transfer of the acidic proton to the water network. This transfer is complete by n=10, which exhibits much simpler vibrational band patterns consistent with those expected for a tri-coordinated hydronium ion (the Eigen motif) along with the NO stretching bands predicted for a hydrated NO 3 – anion that is directly complexed to the Cs + cation. Theoretical analysis of the n=10 spectrum indicates that the dissociated ions adopt a solvent-separated ion-pair configuration such that the Cs + and H 3 O + cations flank the NO 3 – anion in a microhydrated salt bridge. In conclusion, this charge separation motif is evidently assisted by the electrostatic stabilization of the product NO 3 – /H 3 O + ion pair by the proximal metal ion.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Ultrafast Spectroscopy in Chemistry

Ultrafast spectroscopy has become an indispensable investigation tool in numerous areas of chemical research encompassing purely synthetic to semiconductor material domains. Harnessing light on its femtosecond time scales offers a glimpse into submolecular processes that direct reaction pathways, energy transfer, charge separation, and many other fundamental chemical phenomena. In this Perspective, we highlight select examples that introduce how ultrafast spectroscopy became a pillar for modern chemical science. We emphasize the achievements of conventional pump–probe spectroscopy by showing its contribution to disentangling peculiar mechanisms of carrier relaxation in semiconductor nanocrystals, charge separation in organic photovoltaic devices, and photoredox catalyst activation. Our examples show that even traditional pump–probe experiments can provide extensive insights that go beyond the resolution of ultrafast time scales if combined with a thorough preliminary assessment of the target system. We conclude with suggestions for how ultrafast spectroscopy in tandem with chemical science can embark on advancing practical quantum information research.

Excitons↗
DOE OSTI2023

Selective heterogeneous capture and release of actinides using carborane-functionalized electrodes

Here we report the heterogenization of molecular, electrochemically switchable ortho-substituted carboranes ( PO Cb, PO Cb-Pyr) for selective metal capture. Films of PO Cb and PO Cb-Pyr on glassy carbon and carbon fiber (CF) electrodes demonstrated heterogeneous electrochemical behaviour that was enhanced by the inclusion of single-walled carbon nanotubes (CNTs). Galvanostatically charged CF|CNT| PO Cb and CF|CNT| PO Cb-Pyr electrodes selectively captured and released actinides (Th 4+ , UO 2 2+ ) from mixed solutions containing alkali (Cs + ), lanthanide (Nd 3+ , Sm 3+ ) and actinide (Th 4+ , UO 2 2+ ) metal ions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Transmission mounted electrical charging system and dual driveline load coupling

A system includes a PTO device that selectively couples to a driveline of a vehicle at each of two driveline coupling positions, and a motor/generator electrically coupled to an electrical power storage system. The system further includes a shared load selectively powered by the driveline or the motor/generator. The PTO device further includes a coupling actuator that couples the shared load to the motor/generator in a first position, and couples the shared load to the driveline in a second position.

Fortune, Glenn Clark↗
DOE OSTI2024

Measurement of inclusive and differential cross sections for W + W − production in proton-proton collisions at $\sqrt{s} = 13$ TeV

Measurements at $\sqrt{s} = 13$ TeV of the opposite-sign W boson pair production cross section in proton-proton collisions are presented. The data used in this study were collected with the CMS detector at the CERN LHC in 2022, and correspond to an integrated luminosity of 34.8 fb -1 . Events are selected by requiring one electron and one muon of opposite charge. A maximum likelihood fit is performed on signal- and background-enriched data categories defined by the flavor and charge of the leptons, the number of jets, and number of jets originating from b quarks. The overall sensitivity is significantly better than that of previous results with a similar integrated luminosity. The improvement comes from a more refined control of experimental uncertainties and an improved fit strategy. An inclusive W + W - production cross section of 125.7 ± 5.6 pb is measured, in agreement with standard model predictions. Cross sections are also reported in a fiducial region close to that of the detector acceptance, both inclusively and differentially, as a function of the jet multiplicity in the event. For the first time in proton-proton collisions, WW events with zero, one, and at least two jets are studied simultaneously and compared with recent theoretical predictions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Grand Challenges and Opportunities in Stimulated Dynamic and Resonant Catalysis

Traditional heterogeneous catalysis is constrained by kinetic and thermodynamic limits, such as the Sabatier principle and reaction equilibrium. Dynamic and resonant catalysts hold promise to overcome these limitations by actively oscillating a catalyst’s physical or electronic structure at the time scale of the catalytic cycle, allowing programmable control over reaction pathways, and leading to improved rate and selectivity. External stimuli such as temperature swing, mechanical strain, electric charge, and light can perturb catalyst surfaces in different ways, altering adsorbate coverage, binding energies, and transition states beyond what steady-state catalysis allows. This work surveys the current state of dynamic catalysis, introduces the concept of “ stimulando ” characterization for observing transient dynamics, and outlines key modeling, mechanistic, and benchmarking strategies to advance the field toward improved chemical transformation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Out-of-equilibrium charge redistribution in a copper-oxide based superconductor by time-resolved X-ray photoelectron spectroscopy

Charge-transfer excitations are of paramount importance for understanding the electronic structure of copper-oxide based high-temperature superconductors. In this study, we investigate the response of a Bi 2 Sr 2 CaCu 2 O 8+δ crystal to the charge redistribution induced by an infrared ultrashort pulse. Element-selective time-resolved core-level photoelectron spectroscopy with a high energy resolution allows disentangling the dynamics of oxygen ions with different coordination and bonds thanks to their different chemical shifts. Our experiment shows that the O 1s component arising from the Cu–O planes is significantly perturbed by the infrared light pulse. Conversely, the apical oxygen, also coordinated with Sr ions in the Sr-O planes, remains unaffected. This result highlights the peculiar behavior of the electronic structure of the Cu–O planes. It also unlocks the way to study the out-of-equilibrium electronic structure of copper-oxide-based high-temperature superconductors by identifying the O 1s core-level emission originating from the oxygen ions in the Cu–O planes. This ability could be critical to gain information about the strongly-correlated electron ultrafast dynamical mechanisms in the Cu–O plane in the normal and superconducting phases.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Observation of quantum entanglement in top quark pair production in proton–proton collisions at $\sqrt{s}$ = 13 TeV

Entanglement is an intrinsic property of quantum mechanics and is predicted to be exhibited in the particles produced at the Large Hadron Collider. A measurement of the extent of entanglement in top quark-antiquark ($t\bar{t}$) events produced in proton–proton collisions at a center-of-mass energy of 13 TeV is performed with the data recorded by the CMS experiment at the CERN LHC in 2016, and corresponding to an integrated luminosity of 36.3 fb −1 . The events are selected based on the presence of two leptons with opposite charges and high transverse momentum. An entanglement-sensitive observable D is derived from the top quark spin-dependent parts of the $t\bar{t}$ production density matrix and measured in the region of the $t\bar{t}$ production threshold. Values of $D \lt -1/3$ are evidence of entanglement and D is observed (expected) to be $-0.480^{+0.026}_{-0.029}$ ($-0.467^{+0.026}_{-0.029}$) at the parton level. With an observed significance of 5.1 standard deviations with respect to the non-entangled hypothesis, this provides observation of quantum mechanical entanglement within $t\bar{t}$ pairs in this phase space. This measurement provides a new probe of quantum mechanics at the highest energies ever produced.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Measurement of 𝑊⁢𝑊⁢𝑍 and 𝑍⁢𝐻 Production Cross Sections at $\sqrt{𝑠}$ = 13 and 13.6 TeV

A measurement is presented of the cross section in proton-proton collisions for the production of two 𝑊 bosons and one 𝑍 boson. It is based on data recorded by the CMS experiment at the CERN LHC at center-of-mass energies $\sqrt{𝑠}$ = 13 and 13.6 TeV, corresponding to an integrated luminosity of 200 fb −1 . Events with four charged leptons (electrons or muons) in the final state are selected. Both nonresonant 𝑊⁢𝑊⁢𝑍 production and 𝑍⁢𝐻 production, with the Higgs boson decaying into two 𝑊 bosons, are reported. For the first time, the two processes are measured separately in a simultaneous fit. Combining the two modes, signal strengths relative to the standard model (SM) predictions of 0.75$^{+0.34}_{−0.29}$ and 1.74$^{+0.71}_{−0.60}$ are measured for $\sqrt{𝑠}$ = 13 and 13.6 TeV, respectively. The observed (expected) significance for the triboson signal is 3.8 (2.5) standard deviations for $\sqrt{𝑠}$ = 13.6 TeV, thus providing the first evidence for triboson production at this center-of-mass energy. Combining the two modes and the two center-of-mass energies, the inclusive signal strength relative to the SM prediction is measured to be 1.03$^{+0.31}_{−0.28}$, with an observed (expected) significance of 4.5 (5.0) standard deviations.

Gauge bosons↗
DOE OSTI2023

Observation of four-top-quark production in the multilepton final state with the ATLAS detector

This paper presents the observation of four-top-quark ($t$$\overline{t}$$t$$\overline{t}$) production in proton-proton collisions at the LHC. The analysis is performed using an integrated luminosity of 140 fb -1 at a centre-of-mass energy of 13 TeV collected using the ATLAS detector. Events containing two leptons with the same electric charge or at least three leptons (electrons or muons) are selected. Event kinematics are used to separate signal from background through a multivariate discriminant, and dedicated control regions are used to constrain the dominant backgrounds. The observed (expected) significance of the measured $t$$\overline{t}$$t$$\overline{t}$ signal with respect to the standard model (SM) background-only hypothesis is 6.1 (4.3) standard deviations. The $t$$\overline{t}$$t$$\overline{t}$ production cross section is measured to be ${22.5}^{+6.6}_{-5.5}$, consistent with the SM prediction of 12.0 ± 2.4 fb within 1.8 standard deviations. Data are also used to set limits on the three-top-quark production cross section, being an irreducible background not measured previously, and to constrain the top-Higgs Yukawa coupling and effective field theory operator coefficients that affect $t$$\overline{t}$$t$$\overline{t}$ production.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Inclusive Charged-Current Electron Neutrino Interactions in SBND

The Short-Baseline Near Detector (SBND), a 112 ton liquid argon time projection chamber (LArTPC), is the near detector of the Short- Baseline Neutrino Program at Fermilab. Due to its proximity to the Booster Neutrino Beam target, SBND has already seen a record-breaking number of electron neutrino interactions on argon. We present preliminary results from SBND’s differential inclusive electron neutrino charged-current analysis from our first year of beam data, selecting over 2,000 interactions. This analysis will present the largest sample of electron neutrinos on argon to date, as well as the first differential cross section measurement of electron neutrinos. This poster will give an overview of the selection, cross-section extraction, and demonstrate SBND’s detector and electromagnetic shower reconstruction performance through data/MC comparisons.

Tung, Lynn [Chicago U.]↗
DOE OSTI2026

Pandora-based muon neutrino disappearance search in the SBN program with 1muonNp quasi-elastic like channel

The Short-Baseline Neutrino (SBN) program at Fermilab aims to perform a definitive search for light sterile neutrinos using multiple liquid argon time projection chamber detectors. We present the status of an analysis of muon neutrino charged-current interactions in two SBN detectors (SBND and ICARUS), selecting fully contained events with one muon and at least one proton in the final state, inspired by the recent ICARUS standalone results. This topology-driven selection reduces dependence on neutrino interaction cross-section modeling while preserving high statistics and good neutrino energy resolution, enabled by robust reconstruction and particle identification. Fully contained events enable precise kinematic reconstruction and support relative measurements between detectors, directly addressing the core goals of the SBN program. A detailed evaluation of systematic uncertainties is currently underway, with the objective of reducing the dominant systematics to the percent level. The current status of this analysis, with a particular focus on the event selection performance, will be presented in this poster.

Artero Pons, Maria [Padua U.; INFN, Padua]↗
DOE OSTI2024

Excited State Bond Homolysis of Vanadium(V) Photocatalysts for Alkoxy Radical Generation

Advancements in photocatalysis have transformed synthetic organic chemistry, using light as a powerful tool to drive selective chemical transformations. Recent approaches have focused on metal-halide ligand-to-metal charge transfer (LMCT) photoactivated bond homolysis reactions leveraged by earth-abundant elements to generate valuable synthons for radical-mediated cross-coupling reactions. Of recent utility, oxovanadium(V) LMCT photocatalysts exhibit selective alkoxy radical generation from aliphatic alcohols upon blue light (UVA) irradiation under mild conditions. The selective photochemical liberation of alkoxy radicals is valuable for applying late-stage fragmentation approaches in organic synthesis and depolymerization strategies for nonbiodegradable polymers. Steady-state and time-resolved spectroscopy were used to assign the electronic structure of three well-defined V(V) photocatalysts in their ground and excited states. We assign the excited state for this transformation at earth-abundant vanadium(V), interrogating the electronic structure using static UV–visible absorption, ultrafast transient absorption, and electron paramagnetic resonance spectroscopy coupled to computational approaches. Furthermore, these findings afford assignments of the short-lived excited state intermediates that dictate selective homolytic bond cleavage in metal alkoxides, illustrating the valuable insight gleaned from fundamental investigations of the molecular photochemistry responsible for light-escalated chemical transformations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗