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At least 361 records · Page 20

Deep Space Habitat Primary Structure - A Comparison between Metallic, Inflatable, and Composite Materials

This paper presents a comprehensive trade study comparing metallic, inflatable, and composite primary structure materials for a Mars Transit Habitat module. The study evaluates the impact of these materials on the overall mass, outfitting, and mission complexity of the habitat. The results show that the composite module outperforms the other options in terms of minimum mass, being 33% lighter than the metallic configurations and 41% lighter than the inflatable option. The study highlights the potential of composite habitats for future space missions and emphasizes the need for further development and testing to increase the Technology Readiness Level.

Matthew T. Ziglar↗

Decomposition of Electron Ionization Mass Spectra for Space Application Using a Monte-Carlo approach

Rationale: Quadrupole mass spectrometers equipped with an electron ionization (EI) sources have been widely used in space exploration to investigate the composition of planetary surfaces and atmospheres. However, the complexity of the samples and the minimal calibration for the fragmentation of molecules in the ionization chambers have prevented the deconvolution of the majority of the mass spectra obtained at different targets, thus limiting the determination of the exact composition of the samples analyzed. We propose a Monte‐Carlo approach to solve this issue mathematically. Methods: We decomposed simulated mass spectra of mixtures acquired with unit resolving power mass spectrometers and EI sources into the sum of the single components fragmentation patterns weighted by their relative concentration using interior‐point least‐square fitting. To fit compounds with poorly known fragmentation patterns, we used a Monte‐Carlo method to vary the intensity of individual fragment ions. We then decomposed the spectrum thousands of times to obtain a statistical distribution. Results: By performing the deconvolution on a mixture of seven different molecules with interfering fragmentation patterns (H2O, O2, CH4, Ar, N2, C2H4, and C2H6) we show that this approach retrieves the mixing ratio of the individual components more accurately than regular mass spectra decomposition methods that rely on fragmentation patterns from general databases. It also provides the probability density function for each species's mixing ratio. Conclusions: By removing the solution degeneracy in the decomposition of mass spectra, the method described herein could significantly increase the scientific retrieval from archived space flight mass spectrometry data, where calibration of the ionization source is no longer an option.

Thomas Gautier↗

High Resolution Imaging and Analysis of Terrestrial Impact Glass: Amorphous Materials, Phyllosilicates and Everything in Between

Introduction: Impact cratering is one of the most ubiquitous geologic processes shaping the surface of all solid bodies in our solar system. Impacts are also a major source of clay minerals, poorly crystalline clay-like phases and amorphous (i.e., lacking long-range atomic order) materials on Earth and Mars. Phyllosilicates and amorphous materials have consistently formed a major component (~20-70 wt%) of every single drilled rock and soil sample in Gale Crater on Mars, as determined by the CheMin instrument on Curiosity. The origin of the amorphous component is speculative, but could be primary impact or volcanic-produced glass(es) deposited via aeolian or fluvial processes, secondary aqueous alteration products or chemical precipitates; it is likely to be a combination of all three possibilities. Efforts to determine the composition of these materials across the rover’s traverse through Gale Crater are ongoing. Naturally occurring amorphous phases are found in a variety of environments on Earth, and terrestrial analogue studies may help shed light on how they may have formed on Mars. Primary and altered impact glass are likely widespread on Mars and may have contributed to the amorphous component found throughout Gale Crater. In its pristine, unaltered state, impact glass (i.e., melt glass) is considered amorphous. However, truly unaltered glass is rarely preserved in crater fill impactites as it quickly alters in the post-impact environ-ment, commonly forming a mixture of hydrated aluminosilicate phases whose structures are not always discernable at the microscale (i.e., they may be amorphous or contain short-range order). These phases are part of an incredibly complex group of materials; differences in their composition and crystalline structure (or lack thereof) and genetic relationship to the more well-crystalline clay minerals are often only discernable at the nanoscale, beyond the resolution of traditional X-ray diffractometers (XRD) and scanning electron microscopes/microprobes (SEM/EPMA) alone. In this contribution, we summarize recent results from ongoing characterization of clay minerals, poorly crystalline clay-like phases, and amorphous materials preserved in altered terrestrial impact glass from the Chicxulub (~66 Ma) and Ries (~15 Ma) impact structures. This work has been performed using a combination of high-resolution transmission electron microscopy (HR-TEM), SEM, microprobe/EPMA, Raman spectroscopy and XRD.

Impact crater↗

Tooling Foam for Structural Composite Applications

Tooling technology applications for composite structures fabrication have been expanded at MSFC's Productivity Enhancement Complex (PEC). Engineers from NASA/MSFC and Lockheed Martin Corporation have developed a tooling foam for use in composite materials processing and manufacturing that exhibits superior thermal and mechanical properties in comparison with other tooling foam materials. This tooling foam is also compatible with most preimpregnated composite resins such as epoxy, bismaleimide, phenolic and their associated cure cycles. MARCORE tooling foam has excellent processability for applications requiring either integral or removable tooling. It can also be tailored to meet the requirements for composite processing of parts with unlimited cross sectional area. A shelf life of at least six months is easily maintained when components are stored between 50F - 70F. The MARCORE tooling foam system is a two component urethane-modified polyisocyanurate, high density rigid foam with zero ozone depletion potential. This readily machineable, lightweight tooling foam is ideal for composite structures fabrication and is dimensionally stable at temperatures up to 350F and pressures of 100 psi.

DeLay, Tom↗

From Astrochemistry to Astrobiology ...... and Back Again

Tremendous strides have been made in our understanding of interstellar material over the past twenty five years thanks to significant developments in observational infrared astronomy and laboratory astrophysics. Twenty five years ago the composition of interstellar dust was largely guessed at, the concept of ices in dense molecular clouds generally ignored, and the notion of large, abundant, gas phase, carbon-rich molecules widespread throughout the interstellar medium (ISM) considered impossible. Today the composition of interstellar dust is reasonably well understood. In molecular clouds, the birthplace of stars and planets, these cold dust particles are coated with mixed molecular ices whose composition is reasonably well constrained. Lastly, the signature of carbon-rich polycyclic aromatic hydrocarbons (PAHs), shockingly large molecules by early interstellar chemistry standards, is widespread throughout the Universe. The first part of this talk will describe how infrared spectroscopic studies of interstellar space, combined with laboratory simulations and theoretical studies of PAHs and interstellar ices, have revealed the widespread presence of interstellar PAHs and the composition of interstellar precometary ices. The remainder of the presentation will focus on the photochemical evolution of these icy materials. Within a molecular cloud, and especially the presolar nebula, materials frozen into the ices are photoprocessed by ultraviolet light and more complex molecules are produced. As these materials are the building blocks of comets and related to carbonaceous micrometeorites, they are likely to be important sources of complex materials delivered to habitable planets and their composition may be related to the origin of life.

Allamandola, L. J.↗

Detection of Micro-Leaks Through Complex Geometries Under Mechanical Load and at Cryogenic Temperature

Polymer Matrix Composite (PMC) hydrogen tanks have been proposed as an enabling technology for reducing the weight of Single-Stage-to-Orbit reusable launch vehicles where structural mass has a large impact on vehicle performance. A key development issue of these lightweight structures is the leakage of hydrogen through the composite material. The rate of hydrogen leakage can be a function of the material used, method of 6 fabrication used to manufacture the tank, mechanical load the tank must react, internal damage-state of the material, and the temperatures at which the tank must operate. A method for measuring leakage through a geometrically complex structure at cryogenic temperature and under mechanical load was developed, calibrated and used to measure hydrogen leakage through complex X-33 liquid-hydrogen tank structure sections.

Rivers, H. Kevin↗

Approaches for Tensile Testing of Braided Composites

For angleply composites, lamina tension and compression strengths are commonly determined by applying classical lamination theory to test data obtained from testing of angleply composite specimens. For textile composites such as 2D triaxial braids, analysis is more complex and standard test methods do not always yield reliable strength measurements. This paper describes recent research focused on development of more reliable tensile test methods for braided composites and presents preliminary data for various approaches. The materials investigated in this work have 0deg+/-60 2D triaxial braid architecture with nearly equal fiber volume fraction in each of the three fiber directions. Flat composite panels are fabricated by resin transfer molding (RTM) using six layers of the braided preform aligned along the 0deg fiber direction. Various epoxy resins are used as matrix materials. Single layer panels are also fabricated in order to examine local variations in deformation related to the braid architecture. Specimens are cut from these panels in the shape of standard straight-sided coupons, an alternative bowtie geometry, and an alternative notched geometry. Axial tensile properties are measured using specimens loaded along the 0deg fiber direction. Transverse tensile properties are measured using specimens loaded perpendicular to the 0deg fibers. Composite tubes are also fabricated by RTM. These tubes are tested by internal pressurization using a soft rubbery material sealed between the inside diameter of the tube and the load fixtures. The ends of the tube are unconstrained, so the primary load is in the hoop direction. Tubes are fabricated with the 0deg fibers aligned along the tube axis by overbraiding the preform on a mandrel. Since the loading is in the hoop direction, testing of the overbraided tube provides a measure of transverse tensile strength. Previous work has indicated that straight-sided coupons yield a transverse tensile strength that is much lower than the expected material strength because of premature edge-initiated failure. Full-field strain measured during transverse tensile tests clearly showed accumulation of edge damage prior to failure. In the current work, high speed video and testing of single layer specimens are used to investigate potential failure mechanisms in more detail. High speed video clearly shows the edge initiation in six layer transverse tensile test coupons. Specimens with the bowtie geometry and the notched geometry minimize this edge effect and yield significantly higher transverse tensile strength values compared to the straight-sided coupons. However, bowtie and notched specimens geometries are not ideal because of the non-uniform stress and strain fields in the region of failure. Testing of tubes using internal pressurization eliminates edge-initiated failure and provides a more uniform state of stress and strain. Preliminary results indicate that bowtie, notched, and tube specimens yield comparable values for transverse tensile strength and that these values are much higher than the strength measured using a straight-sided coupon.

Roberts, Gary D.↗

Laboratory investigations of impact-generated plasma

The characteristics of plasma that was produced in laboratory by hypervelocity impacts were investigated to demonstrate the feasibility of generation of magnetic fields by meteoritic impacts and to explain the presence of paleomagnetic fields on the lunar surface. The impact-generated magnetic fields were found to exhibit spatial and temporal complexity that depended on the impact angle, the velocity, and the projectile/target composition. The results suggest that crater-related paleomagnetism associated with this mechanism should exhibit similar complexity with spatial wavelengths on the order of a fraction of the crater radius.

Crawford, David A.↗

An analysis of delamination in angle-ply fiber-reinforced composites

A study of the mechanics and failure modes of delamination initiated from a surface flaw in angle-ply fiber-reinforced composites is presented. The analysis employs a hybrid-stress finite-element method including a crack-tip singular element with its field variables expressed by Muskhelishvili's complex stress functions. Solutions are obtained for the delaminated composites with various laminate parameters. The results elucidate unique and important characteristics of delamination crack-tip response and interlaminar stress transfer mechanisms. Of particular interest are the mixed-mode stress-intensity factors associated with the delamination crack. The influence of ply orientation on KI and KII and their effects on subsequent crack extension are discussed.

Wang, S. S.↗

Automated Fiber Placement of Composite Wind Tunnel Blades: Process Planning and Manufacturing

The ability to accurately manufacture large complex shapes in a consistent and repeatable manner has led to Automated Fiber Placement (AFP) being the predominant mode of manufacturing for large composite aerospace structures today. Currently, AFP is being considered for medium- and small-scale parts. Composite wind tunnel blades have traditionally been fabricated by hand layup for pre-impregnated or dry fabrics with resin infusion. Though well proven, the traditional fabrication method is laborious and tedious, and hence expensive. The project described in this paper used the Integral Structural Assembly of Advanced Composites (ISAAC) facility at the NASA Langley Research Center to build a manufacturing demonstration unit (MDU) with a shape representative of a wind tunnel blade. This MDU is used to discuss tooling, process planning, and fabrication. Additionally, details of the generic manufacturing workflow are presented.

Harik, Ramy↗

One Step Closer to Mars with Aquaponics: Cultivating Citizen Science in K12 Schools

The Microbial Ecology and Biogeochemistry Research Laboratory at NASA Ames Research Center focuses primarily on the nutrient cycling and diversity of complex microbial communities. NASA is interested in the composition and functioning of microbial mat communities as these processes fundamentally shape the form and function of these analogs for the earliest forms of life on Earth (3.6 billion years ago), and likely will on other planets as well. Aquaponics systems are supported by microbial communities who perform many complex ecosystem services, including cycling nitrogen. Microbes are integral to the stability and productivity of aquaponics systems, which are analogous to microbial communities in food production systems that are essential for building efficient life support systems for long-distance space travel. Students at Meadow Park Middle School created 10 parallel aquaponics systems and took temporal microbial samples to characterize whether any macro-ecology variables impacted or changed the microbial diversity of these systems. Students additionally created a website so that other classrooms can pursue similar projects in their own schools (https://go.nasa.gov/2uJhxmF). Our lab at NASA Ames has sequenced water samples from each of the 10 tanks at 3 timepoints using a MinION sequencer. MPMS students will be involved in the analysis of the bioinformatics data generated through this collaboration. Our ongoing collaboration aims to collect and analyze data in the classroom setting that has utility for research scientists, while involving students as collaborators in the research process.

Kolattukudy, Maria↗

The Equilibrium Response of Climate and Composition to Lightning

Climate change can affect atmospheric composition through perturbation of natural processes, leading to complex feedbacks. The primary atmospheric oxidants OH and ozone are very sensitive to emissions of nitrogen oxides (NO x ) from lightning, and therefore so are the subsequent chemical perturbations to long-lived greenhouse gases (e.g., methane) and aerosol chemistry and physics. Meanwhile, cloud electrification responds to both meteorology and composition (aerosol particles). Key to understanding the ultimate impact of lightning on air quality and climate is the long-term methane feedback. Here, we present simulations from the GISS ModelE2.1 chemistry-climate model in which we isolate the response of Earth’s radiative budget and composition to lightning NO x in the present day and at the end of this century by allowing the model to re-equilibrate following removal of the source. Whereas lightning initially contributes to surface ozone enhancements, longer-term responses amplified by the methane lifetime feedback reduce surface ozone on multi-decadal time scales in the northern midlatitudes. Lightning consequently contributes a strong negative radiative effect in the present day (-0.5 W m -2 ), stronger than that estimated for the anthropogenic NOx source. In addition to influencing tropospheric composition, we find significant changes in stratospheric dynamics and composition. We test the sensitivity of our results to multiple parameterizations for global lightning activity.

Lightning↗

Studies of Lubricating Materials in Vacuum

Lubricating materials for use in a vacuum environment have been the subject of a series of experimental investigations. Evaporation properties were evaluated for solid polymeric compositions. Friction and wear studies explored the behavior during sliding contact for series of polymeric compositions, binary alloys containing soft film-forming phases, complex alloys with film-forming materials, and a burnished MoS2 film. Friction and wear experiments were conducted at 10(exp-9)mm Hg with a 3/16-inch-radius-hemisphere rider specimen sliding on the flat surface of a rotating 2-1/2-inch-diameter disk specimen with materials that had low rates of evaporation. The influence of fillers in polytetrafluoroethylene (PTFE) on decomposition during vacuum friction studies was determined with a mass spectrometer. A real advantage in reducing decomposition and improving friction wear properties is gained by adding fillers (e.g., copper) that improve thermal conductivity through the composite materials. A polyimide and an epoxy-MoS2 composition material were found to have better friction and wear properties than PTFE compositions. A series of alloys (cast binary as well as more complex alloys) that contained microinclusions of potential film-forming material was studied. These materials replaced the normal surface oxides as they were worn away on sliding contact. Iron sulfide, nickel oxide, and tin are typical film-forming materials employed and were demonstrated to be effective in inhibiting surface welding and reducing friction. A burnished MoS2 film applied to type 440-C stainless steel in argon with a rotating soft wire brush had good endurance properties but somewhat higher friction than commercially available bonded films. An oil film applied to the burnished MoS2 markedly reduced its endurance life.

WEAR↗

The magnetic field of Mercury, part 1

An updated analysis and interpretation is presented of the magnetic field observations obtained during the Mariner 10 encounter with the planet Mercury. The combination of data relating to position of the detached bow shock wave and magnetopause, and the geometry and magnitude of the magnetic field within the magnetosphere-like region surrounding Mercury, lead to the conclusion that an internal planetary field exists with dipole moment approximately 5.1 x 10 the 22nd power Gauss sq cm. The dipole axis has a polarity sense similar to earth's and is tilted 7 deg from the normal to Mercury's orbital plane. The magnetic field observations reveal a significant distortion of the modest Hermean field (350 Gamma at the equator) by the solar wind flow and the formation of a magnetic tail and neutral sheet which begins close to the planet on the night side. The composite data is not consistent with a complex induction process driven by the solar wind flow.

Ness, N. F.↗

Symbolic generation of constitutive equations

The use of the symbolic manipulation program MACSYMA for the automatic generation of constitutive equations describing the thermomechanical behavior of complex materials such as metal-matrix composites is demonstrated. Problem-specific algorithms are developed; e.g., for partial differentiation by the chain rule, automatic generation of tree structures, special tensor analysis, and the simplification of expressions. The resulting subprogram package, SDICE, is shown to be fully applicable to both isotropic and anisotropic materials; its potential usefulness as a basis for FEM analyses is indicated.

Tan, H. Q.↗

The composition and origin of the C, P, and D asteroids - Water as a tracer of thermal evolution in the outer belt

A telescopic and laboratory investigation of water distribution among low albedo asteroids in the outer belt, using the 3-micron reflectance absorption of molecular H2O and structural OH ions (coincident with the 3-micron spectral signature of meteorite and asteroid hydrated silicates) shows that 66 percent of the C-class asteroids in the sample have hydrated silicate surfaces. In conjunction with the apparently anhydrous P and D surfaces, this pronounced hydration difference between C-class asteroids and the more distant P and D classes points to an original outer belt asteroid composition of anhydrous silicates, water ice, and complex organic material. Early solar-wind induction heating of protoasteroids, declining in intensity with distance from the sun, is conjectured to have produced the observed diminution of hydrated silicate abundance.

Jones, Thomas D.↗

Innovative fabrication processing of advanced composite materials concepts for primary aircraft structures

The autoclave based THERM-X(sub R) process was evaluated by cocuring complex curved panels with frames and stiffeners. The process was shown to result in composite parts of high quality with good compaction at sharp radius regions and corners of intersecting parts. The structural properties of the postbuckled panels fabricated were found to be equivalent to those of conventionally tooled hand laid-up parts. Significant savings in bagging time over conventional tooling were documented. Structural details such as cocured shear ties and embedded stiffener flanges in the skin were found to suppress failure modes such as failure at corners of intersecting members and skin stiffeners separation.

Kassapoglou, Christos↗

Validating spatial structure in canopy water content using geostatistics

Heterogeneity in ecological phenomena are scale dependent and affect the hierarchical structure of image data. AVIRIS pixels average reflectance produced by complex absorption and scattering interactions between biogeochemical composition, canopy architecture, view and illumination angles, species distributions, and plant cover as well as other factors. These scales affect validation of pixel reflectance, typically performed by relating pixel spectra to ground measurements acquired at scales of 1m(exp 2) or less (e.g., field spectra, foilage and soil samples, etc.). As image analysis becomes more sophisticated, such as those for detection of canopy chemistry, better validation becomes a critical problem. This paper presents a methodology for bridging between point measurements and pixels using geostatistics. Geostatistics have been extensively used in geological or hydrogeolocial studies but have received little application in ecological studies. The key criteria for kriging estimation is that the phenomena varies in space and that an underlying controlling process produces spatial correlation between the measured data points. Ecological variation meets this requirement because communities vary along environmental gradients like soil moisture, nutrient availability, or topography.

Sanderson, E. W.↗