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At least 361 records · Page 20

Active Flow Effectors for Noise and Separation Control

New flow effector technology for separation control and enhanced mixing is based upon shape memory alloy hybrid composite (SMAHC) technology. The technology allows for variable shape control of aircraft structures through actively deformable surfaces. The flow effectors are made by embedding shape memory alloy actuator material in a composite structure. When thermally actuated, the flow effector def1ects into or out of the flow in a prescribed manner to enhance mixing or induce separation for a variety of applications, including aeroacoustic noise reduction, drag reduction, and f1ight control. The active flow effectors were developed for noise reduction as an alternative to fixed-configuration effectors, such as static chevrons, that cannot be optimized for airframe installation effects or variable operating conditions and cannot be retracted for off-design or fail-safe conditions. Benefits include: Increased vehicle control, overall efficiency, and reduced noise throughout all f1ight regimes, Reduced flow noise, Reduced drag, Simplicity of design and fabrication, Simplicity of control through direct current stimulation, autonomous re sponse to environmental heating, fast re sponse, and a high degree of geometric stability. The concept involves embedding prestrained SMA actuators on one side of the chevron neutral axis in order to generate a thermal moment and def1ect the structure out of plane when heated. The force developed in the host structure during def1ection and the aerodynamic load is used for returning the structure to the retracted position. The chevron design is highly scalable and versatile, and easily affords active and/or autonomous (environmental) control. The technology offers wide-ranging market applications, including aerospace, automotive, and any application that requires flow separation or noise control.

Turner, Travis L.↗

Spin Frustration and Unconventional Surface Spin Canting State in Van der Waals Ferromagnet/Antiferromagnet Heterostructures

Atomically flat surfaces of van der Waals (vdW) materials pave an avenue for addressing a long-standing fundamental issue of how a compensated antiferromagnet (AFM) surface frustrates a ferromagnetic (FM) overlayer in FM/AFM heterostructures. We investigate Fe5GeTe2/NiPS3 vdW heterostructures by characterizing AFM and FM spins separately. We find that in-plane zig-zag AFM NiPS3 develops three equivalent AFM domains, which are robust against external magnetic field and magnetic coupling with Fe5GeTe2. Moreover, evidence is provided of in-plane-AFM-induced perpendicular magnetic anisotropy (PMA) in adjacent Fe5GeTe2, and an unconventional out-of-plane surface spin canting state with the Fe5GeTe2 spins spatially turn from out-of-plane direction near the interface to in-plane direction away from the interface in Fe5GeTe2/NiPS3. The out-of-plane surface spin canting is a unique property of spin frustration in vdW magnetic heterostructures.

Wang, Tianye↗

Intensified charge coupled devices for use as a spaceborne spectrographic image-plane detector system

An instrument that has been developed for studies of atmospheric emissions from the Space Shuttle comprises an array of imaging spectrometers to observe features over the 300-12,000-A wavelength range. Each spectrometer has a 2-D image-plane detector system on which spectral information is dispersed in one direction and spatial information is resolved in the other. The detectors consist of CCD arrays which are coupled to proximity focused image intensifiers. The intensifier in each case is selected for the wavelength range covered by the particular spectrometer. The result is a compact low-power spectrographic detector system. In the course of building the five flight detector systems, there was occasion to evaluate a larger number of the charge coupled devices and the proximity focused image intensifiers. Various characteristics, advantages, and shortcomings of these devices and the overall intensified CCD system are reported.

Torr, M. R.↗

Probing the Contribution of Lateral Pathways to Out–of–Plane Charge Transport in Organic Bulk Heterojunctions

The nanoscale interpenetrating electron donor–acceptor network in organic bulk heterojunction (BHJ) solar cells results in efficient charge photogeneration but creates complex 3D pathways for charge transport. At present, little is known about the extent to which out-of-plane charge flow relies on lateral electrical connectivity. In this work, a procedure, based on conductive atomic force microscopy, is introduced to quantify lateral current spreading during out-of-plane charge transport. Using the developed approach, the dependence of lateral spreading on BHJ phase separation, composition, and molecule type (small molecule vs polymer) is studied. In the small-molecule BHJ, 7,7'-(4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b']dithiophene-2,6-diyl)bis(6-fluoro-4-(5'-hexyl-[2,2'-bithiophen]-5-yl)benzo[c]-[1,2,5]thiadiazole):(6,6)-Phenyl-C 71 -butyric acid methyl ester (p-DTS(FBTTh 2 ) 2 :PC 71 BM), an increase is observed in lateral hole current spreading as the population of donor crystallites, bearing an edge-on molecular orientation, is increased. When integrated into BHJs, the polymer donor poly(3-hexylthiophene-2,5-diyl) (P3HT) leads to greater lateral hole current spreading and more spatially uniform charge transport than the small-molecule donor, owing to in-plane charge transport along the polymer backbone. Finally, through the newly introduced electrical characterization scheme, these experiments bring to light the role of lateral electrical connectivity in assisting charge navigation across BHJs.

14 SOLAR ENERGY↗

Direct simulation of compressible wall-bounded turbulence

When analyzing many turbulent flows, the effects of compressibility can be neglected. Even some relatively high-speed flows, such as boundary layers generated by a supersonic aircraft, produce turbulent statistics that are similar to those found for the incompressible case. There are other situations, however, in which the non-zero divergence of the turbulence leads to behavior that is fundamentally different from that found at constant density. Examples include flows created by internal combustion engines, hypersonic flight, and supersonic combustion. It is with instances such as these that this project is concerned. In particular, we are interested in the effects of compressibility on turbulence near a smooth solid constant temperature surface; our primary objective is an increased physical understanding that can be used to improve turbulence models of wall-bounded compressible flows. With this in mind, we have begun a direct numerical simulation (DNS) study of turbulence in a plane channel. Because all of the relevant spatial and temporal scales are to be resolved, the simulations require no subgrid scale parameterization. The DNS code developed by Buell to study compressible plane Couette flow was modified to solve the compressible Navier-Stokes equations in the plane channel. The channel was chosen over the Couette flow for two reasons: (1) to avoid using the very large streamwise domains needed to adequately capture the large Couette vortical structures; and (2) to make use of previous experience by considering the compressible version of a well established case and isolate finite Mach number effects by comparing to the incompressible channel.

Coleman, Gary N.↗

Three-dimensional vortical structures of transition in plane channel flow

Three-dimensional visualization of flwo field structures in transitional plane channel flow obtained from a numerical simulation are presented at two Reynolds numbers. It is revealed that at the one-spike stage, independent of Reynolds number, the flow is characterized by a multi-layer vortex system. In the upper layer, total vorticity vector plots indicate a high-shear layer dominated by spanwise vorticity, whereas the middle layer (corresponding approximately to the critical layer) forms a vortex loop (alpha-vortex) consisting of strong streamwise and spanwise vorticity components. At the three-spike stage, the breakdown of the vortical structure proceeds in a manner similar to frontal relaminarization of turbulent spots. This process is accompanied by intense vortex lift-up activity near the wall which seems to originate at the legs of the vortex loop trailing the high-shear layer. Finally, at the five-spike stage, it is shown that high-vorticity regions (vortical structures) develop into horseshow eddies in planes inclined to the main flow direction.

Biringen, S.↗

Quasi-three-dimensional flow solution by meridional plane analysis

A computer program has been developed to obtain subsonic or shockfree transonic, nonviscous flow analysis on the hub-shroud mid-channel flow surface of a turbomachine. The analysis may be for any annular passage, with or without blades. The blades may be fixed or rotating and may be twisted and leaned. The flow may be axial, radial or mixed. Blade surface velocities over the entire blade are approximated based on the rate of change of angular momentum. This gives a 3-D flow picture based on a 2-D analysis. The paper discusses the method used for the program and shows examples of the type of passages and blade rows which can be analyzed. Also, some numerical examples are given to show how the program can be used for practical assistance in design of blading, annular passages, and annular diffusers.

Katsanis, T.↗

Quasi-three-dimensional flow solution by meridional plane analysis

A computer program has been developed to obtain subsonic or shock-free transonic, nonviscous flow analysis on the hub-shroud midchannel flow surface of a turbomachine. The analysis may be for any annular passage, with or without blades. The blades may be fixed or rotating and may be twisted and leaned. The flow may be axial, radial, or mixed. Blade surface velocities over the entire blade are approximated, based on the rate of change of angular momentum. This gives a three-dimensional flow picture based on a two-dimensional analysis. This paper discusses the method used for the program and shows examples of the type of passages and blade rows which can be analyzed. Also, some numerical examples are given to show how the program can be used for practical assistance in design of blading, annular passages, and annular diffusers.

Katsanis, T.↗

Unsteady laminar boundary-layer calculations on oscillating configurations including backflow. Part 1: Flat plate, oscillating in its own plane

A finite difference method has been developed to calculate the unsteady boundary layer over an oscillating flat plate. Low- and high frequency approximations were used for comparison with numerical results. Special emphasis was placed on the behavior of the flow and on the numerical calculation procedure as soon as reversed flow has occurred over part of the oscillation cycle. The numerical method displayed neither problems nor singular behavior at the beginning of or within the reversed flow region. Calculations, however, came to a limit where the back-flow region reached the plate's leading edge in the case of high oscillation amplitudes. It is assumed that this limit is caused by the special behavior of the flow at the plate's leading edge where the boundary layer equations are not valid.

Geissler, W.↗

A High-Energy Focal-Plane Gas Scintillation Proportional Counter

We have developed a high-pressure Gas Scintillation Proportional Counter (GSPC) for the focus of a hard-x-ray telescope. It features an absorption region 50 mm in diameter and 50 mm deep, filled with Xenon + 4% He at 10(exp 6) Pa total pressure, which gives useful response (greater than 75% efficiency) up to the mirror cut-off of 70 keV. Tests with a prototype unit show an energy resolution of 3.5% at 60 keV and a spatial resolution of 0.35 mm from 30-50 keV. Two flight units are currently under construction for a balloon flight in September 1999. Full details of their design and performance will be presented together with available quick-look background data from the flight.

Ramsey, B. D.↗

Pulsed laser Rayleigh scattering diagnostic for hydrogen/oxygen rocket exit plane flowfield velocimetry

A Doppler-resolved, pulsed laser Rayleigh scattering diagnostic has been developed to obtain local flowfield velocity measurements at the exit plane of a low thrust hydrogen/oxygen rocket engine operating in a high-altitude test facility. Fiberoptic signal collection was employed to obtain the forescatter and backscatter Doppler shifts necessary to resolve the axial and radial velocity components. A radial profile was obtained by traversing the collection probes along the beam path at the nozzle exit. The results are compared with theoretical predictions from a full Navier-Stokes model (RK/RPLUS). Significant discrepancies between the measured and predicted axial velocity profiles are observed, in terms of both magnitude and character. Radial velocity measurements exhibit excellent agreement with predictions near the centerline but show some departure off-axis. The discrepancies between theory and experiment are potentially the result of enhanced mixing between the core and fuel-film region beyond that predicted, and/or flow stratification between the hydrogen and oxygen injected into the central core region.

Zupanc, Frank J.↗

Development of programs for computing characteristics of ultraviolet radiation

Efficient programs were developed for computing all four characteristics of the radiation scattered by a plane-parallel, turbid, terrestrial atmospheric model. They were developed (FORTRAN 4) and tested on the IBM /360 computers with 2314 direct access storage facility. The storage requirement varies between 200K and 750K bytes depending upon the task. The scattering phase matrix (or function) is expanded in a Fourier series whose number of terms depend upon the zenith angles of the incident and scattered radiations, as well as on the nature of aerosols. A Gauss-Seidel procedure is used for obtaining the numerical solution of the transfer equation.

Dave, J. V.↗

Range Safety Flight Elevation Limit Calculation Software

This program was developed to fill a need within the Wallops Flight Facility workflow for automation of the development of vertical plan limit lines used by flight safety officers during the conduct of expendable launch vehicle missions. Vertical plane present-position-based destruct lines have been used by range safety organizations at numerous launch ranges to mitigate launch vehicle risks during the early phase of flight. Various ranges have implemented data submittal and processing workflows to develop these destruct lines. As such, there is significant prior art in this field. The ElLimits program was developed at NASA's Wallops Flight Facility to automate the process for developing vertical plane limit lines using current computing technologies. The ElLimits program is used to configure launch-phase range safety flight control lines for guided missiles. The name of the program derives itself from the fundamental quantity that is computed - flight elevation limits. The user specifies the extent and resolution of a grid in the vertical plane oriented along the launch azimuth. At each grid point, the program computes the maximum velocity vector flight elevation that can be permitted without endangering a specified back-range location. Vertical plane x-y limit lines that can be utilized on a present position display are derived from the flight elevation limit data by numerically propagating 'streamlines' through the grid. The failure turn and debris propagation simulation technique used by the application is common to all of its analysis options. A simulation is initialized at a vertical plane grid point chosen by the program. A powered flight failure turn is then propagated in the plane for the duration of the so-called RSO reaction time. At the end of the turn, a delta-velocity is imparted, and a ballistic trajectory is propagated to impact. While the program possesses capability for powered flight failure turn modeling, it does not require extensive user inputs of vehicle characteristics (e.g., thrust and aerodynamic data), nor does it require reams of turn data after the traditional fashion of the Air Force ranges. The program requires a nominal trajectory table (time, altitude, range, velocity, and flight elevation) and makes heavy use of it to initialize and model a failure turn.

Lanzi, Raymond J↗

Prediction of Half-Metallic Properties in Non-transition Metal-based Binary Compounds X Bi (X = Ba, Sr and Ca) with Zinc-Blende and Wurtzite Structures

In this study, structural, electronic and magnetic properties of non-transition metal-based binary compounds X Bi (X = Ba, Sr and Ca) in five different phases: rock salt, NiAs, wurtzite, zinc blende and CsCl, are investigated in order to find new sp magnetic materials used for real spintronic and other related applications. The calculations are performed by a developed full-potential augmented plane wave plus local orbitals (FP-L/APW + lo) method within the spin density functional theory. As exchange-correlation potential, we used the generalized gradient approximation of Perdew, Burke, and Ernzerhof (GGA-PBE) and the modified Becke-Johnson potential mBJ-GGA-PBE form. It is found that the magnetic moment in these compounds is mainly contributed by the spin-polarized p orbitals of Bi atoms. The WZ XBi are true half-metallic ferromagnet with opposite spin direction at Fermi energy having a magnetic moment of 2.00 μ B per formula unit.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Effects of Zn and Ca on the deformation texture evolution of Mg–Zn–Ca alloys at elevated temperatures

This work utilized crystal plasticity simulations and experimental thermo-mechanical processing to examine how Zn and Ca content affects texture evolution in Mg–Zn–Ca alloys during simulated hot rolling. Four different compositions were studied: unalloyed Mg and three Mg alloys of ZX0p50 (Mg- 0.5 wt% Zn- 0.1 wt% Ca), ZX30 (Mg-3 wt% Zn- 0.1 wt% Ca), and ZX31 (Mg-3 wt% Zn- 0.3 wt% Ca). Multi-pass Gleeble experiments simulated hot rolling using plane strain conditions. Unalloyed Mg developed a strong basal texture, while the addition of Zn and Ca significantly weakened the texture in ZX30 and ZX31; this reduction was not seen in ZX0p50. Notably, ZX31 exhibited a split basal texture aligned with the rolling direction. Crystal plasticity simulations revealed that the weaker basal texture in ZX30 and ZX31 resulted from reduced activation of basal and twinning modes compared to unalloyed Mg and Zx0p50. Increased Zn and Ca content raised the ratios of basal to pyramidal critical resolved sheer stress (CRSS) and twin to pyramidal CRSS, enhancing pyramidal slip activity and weakening the basal texture. Extension twinning played a critical role in texture development during the first deformation pass. In unalloyed Mg and ZX0p50, twinning led to a strong basal texture, while ZX30 and ZX31 had weak basal textures that increased only slightly with further deformation. The split basal poles simulated in ZX31 were consistent with the experimental findings, highlighting the interplay between alloy composition and texture evolution.

Crystal plasticity finite element↗

Radiation-Induced Solid-State Transformations of Uranyl Peroxides

Single-crystal X-ray diffraction studies of pristine and γ-irradiated Ca 2 [UO 2 (O 2 ) 3 ]·9H 2 O reveal site-specific atomic-scale changes during the solid-state progression from a crystalline to X-ray amorphous state with increasing dose. Following γ-irradiation to 1, 1.5, and 2 MGy, the peroxide group not bonded to Ca 2+ is progressively replaced by two hydroxyl groups separated by 2.7 Å (with minor changes in the unit cell), whereas the peroxide groups bonded to Ca 2+ cations are largely unaffected by irradiation prior to amorphization, which occurs by a dose of 3 MGy. The conversion of peroxide to hydroxyl occurs through interaction of neighboring lattice H 2 O molecules and ionization of the peroxide O–O bond, which produces two hydroxyls, and allows isolation of the important monomer building block, UO 2 (O 2 ) 2 (OH) 2 4– , that is ubiquitous in uranyl capsule polyoxometalates. Steric crowding in the equatorial plane of the uranyl ion develops and promotes transformation to an amorphous phase. In contrast, γ-irradiation of solid Li 4 [(UO 2 )(O 2 ) 3 ]·10H 2 O results in a solid-state transformation to a well-crystallized peroxide-free uranyl oxyhydrate containing sheets of equatorial edge and vertex-sharing uranyl pentagonal bipyramids with likely Li and H 2 O in interlayer positions. The irradiation products of these two uranyl triperoxide monomers are compared via X-ray diffraction (single-crystal and powder) and Raman spectroscopy, with a focus on the influence of the Li + and Ca 2+ countercations. Highly hydratable and mobile Li+ yields to uranyl hydrolysis reactions, while Ca 2+ provides lattice rigidity, allowing observation of the first steps of radiation-promoted transformation of uranyl triperoxide.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Signatures of chiral superconductivity in rhombohedral graphene

Chiral superconductors are unconventional superconducting states that break time-reversal symmetry spontaneously and typically feature Cooper pairing at non-zero angular momentum. Such states may host Majorana fermions and provide an important platform for topological physics research and fault-tolerant quantum computing. Despite intensive search and prolonged studies of several candidate systems, chiral superconductivity has remained elusive so far. Here we report the discovery of robust unconventional superconductivity in rhombohedral tetralayer and pentalayer graphene without moiré superlattice effects. We observed two superconducting states in the gate-induced flat conduction bands with T c up to 300 mK and charge density n e down to 2.4 ×10 11 cm −2 in five devices. Spontaneous time-reversal-symmetry breaking (TRSB) owing to orbital motion of the electron is found and several observations indicate the chiral nature of these superconducting states, including: (1) in the superconducting state, R xx shows magnetic hysteresis in varying out-of-plane magnetic field B ⊥ —absent from all other superconductors; (2) the superconducting states are robust against in-plane magnetic field and are developed within a spin-polarized and valley-polarized quarter-metal (QM) phase; (3) the normal states show anomalous Hall signals at zero magnetic field and magnetic hysteresis. Here, we also observed a critical B ⊥ of 1.4 T, higher than any graphene superconductivity, which indicates a strong-coupling superconductivity close to the Bardeen–Cooper–Schrieffer (BCS)–Bose–Einstein condensate (BEC) crossover. Our observations establish a pure carbon material for the study of topological superconductivity, with the promise to explore Majorana modes and topological quantum computing.

36 MATERIALS SCIENCE↗