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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS2001

Ground-Based Correlates of Solar Irradiance Variation

Ground-based instruments cannot directly measure solar irradiance variability at the 0.1% level at which it occurs because of the earth's atmosphere. However, many forms of ground-based solar observations correlate well with solar irradiance variations, and this fact has been used to construct facular-sunspot models which can explain about 90% of the variance of total solar irradiance as observed by spacecraft radiometers. It is not yet clear whether remaining discrepancies are observational or require additional sources in the model. This paper is a selective review of the current status of the use of ground-based data to understand spacecraft observations of solar irradiance and to apply this understanding to periods before space-based measurements were available. New results from the extension of the histogram analysis of NASA/NSO spectromagnetograph observations (Jones et al., 2000, ApJ529, 1070) to the period from Nov. 1992 to Sep. 2000 are reported which confirm that strong mixed polarity magnetic regions (quiet network) are not significantly correlated with total solar irradiance and which show an unexplained linear trend in the residuals of a multiple regression.

Jones, Harrison P.↗
DOE OSTI2024

p K a of alcohols dictates their reactivity with reduced uranium-substituted thiomolybdate clusters

The uranium-substituted thiomolybdate cluster, (Cp* 3 Mo 3 S 4 )UCp*, has been demonstrated as a model for water reduction by single uranium atoms supported on a molybdenum sulfide surface (U@MoS 2 ). In this study, the scope of O–H bond activation is expanded through the investigation of the reactivity of various alcohols with differing pKa values for the –OH proton. The reaction of (Cp* 3 Mo 3 S 4 )UCp* with stoichiometric amounts of methanol, phenol, 2,6-dichlorophenol, and nonafluoro-tert-butyl alcohol affords the corresponding mono-alkoxide species, (Cp* 3 Mo 3 S 4 )Cp*U(OR), via a uranium-metalloligand cooperative activation of the O–H bond. This observed reactivity is analogous to the O–H bond activation reported by (Cp* 3 Mo 3 S 4 )UCp* in the presence of water. However, addition of tert-butanol induces protonolysis of the Cp* ligand on uranium, resulting in the formation of a uranium tris-tert-butoxide cluster, (Cp* 3 Mo 3 S 4 )U(O t Bu) 3 . Independent synthesis of (Cp* 3 Mo 3 S 4 )Cp*U(O t Bu) was possible via an alternative pathway, eliminating sterics as a justification for the observed discrepancy in reactivity. Furthermore, these results offer insight into the role the –OH proton pKa plays in dictating the mechanism of O–H bond activation of alcohols by the uranium-substituted thiomolybdate cluster.

Patra, Kamaless↗
NASA NTRS1986

Review and analysis of high temperature chemical reactions and the effect of non-equilibrium conditions

Chemical reactions at high temperatures have been considered extensively because of their importance to the heating effects on re-entry of space vehicles. Data on these reactions however, are not abundant and even when found there are discrepancies in data collected by various investigators. In particular, data for recombination reactions are calculated from the dissociation reactions or vice versa through the equilibrium constant. This involves the use of the principle of detailed balancing. This principle is discussed in reference to conditions where it is valid as well as to those where it is not valid. Related topics that merit further study or for which applicable information was available are briefly mentioned in an appendix to this report.

Johnson, R. E.↗
NASA NTRS1987

Polarized fluorescence spectroscopy of O2(+)

Polarized fluorescence measurements involving the A 2Pi(u) - X 2Pi(g) and b 4Sigma(g)(-) - a 4Pi(u) transitions in O2(+) following narrow-band photoexcitation of O2/X 3Sigma(g)(-)/ are reported. The analysis, based on the conventional high-J limit, involves deducing the quadrupole alignment factor from which the relative strengths of degenerate photoexcitation channels responsible for the population distribution in the A 2Pi(u) and b 4Sigma(g)(-) states of O2(+) can be estimated. The measured A-channel polarization exhibits pronounced structure which correlates well with the known positions of Rydberg states, whereas the polarization signal in the b channel has broad and less prominent features. Discrepancies between theoretical and measured results can largely be accounted for by additional configuration mixing and autoionization considerations.

Keller, J. W.↗
NASA NTRS1998

An Improved Magnetic Field Model for Jupiter's Inner Magnetosphere Using a Microsignature of Amalthea

Observation of a particle absorption microsignature of the Jovian satellite Amalthea during the Pioneer II close flyby of Jupiter on December 3, 1974, has been described by McKibben et al. The microsignature was also observed by the University of Iowa/Pioneer II instrument in the distribution of protons in the kinetic energy range 0.61 less than T(sub p) less than 3.41 MeV but has not been previously reported. The finer time resolution and superior data quality of the latter observations provide a fresh basis for assessing the accuracy with which various published magnetic field models of Jupiter's magnetic field models describe Jupiter's magnetic field for radial distances of the order of or less than several planetary radii. The expected time of occurrence of the minimum of Amalthea's microsignature was calculated for each model and compared to the time of the observed minimum. The discrepancy between these two times was significant for each of the published models, but it could be reduced to zero by interpolating between two of the closely related models. The spherical harmonic coefficients of this combination model are tabulated. Also included is a novel method for calculating the intensity-time profile of the microsignature. In a later paper, the improved model is utilized to analyze the energetic particle measurements in Jupiter's innermost magnetosphere by the Galileo entry probe in December 1995.

Randall, Bruce A.↗
NASA NTRS2001

Total Electron-Impact Ionization Cross-Sections of CFx and NFx (x = 1 - 3)

The discrepancy between experimental and theoretical total electron-impact ionization cross sections for a group of fluorides, CFx, and NFx, (x = 1 - 3), is attributed to the inadequacies in previous theoretical models. Cross-sections calculated using a recently developed siBED (simulation Binary-Encounter-Dipole) model that takes into account the shielding of the long-range dipole potential between the scattering electron and target are in agreement with experimentation. The present study also carefully reanalyzed the previously reported experimental data to account for the possibility of incomplete collection of fragment ions and the presence of ion-pair formation channels. For NF3, our experimental and theoretical cross-sections compare well with the total ionization cross-sections recently reported by Haaland et al. in the region below dication formation.

Huo, Winifred M.↗
NASA NTRS1972

Dynamics of cavitating cascades

Brief accounts of the theoretical research conducted on the unsteady cavitation characteristics of liquid rocket engine turbopumps are reported. The objective is to produce estimates of the cavitation compliance and other unsteady characteristics which could then be used in analysis of the pogo instability. Blade cavitation is the particular pheonomenon which is investigated and line arized free streamline methods were employed in both quasistatic and complete dynamic cascade analyses of the unsteady flow. The simpler quasistatic analysis was applied to particular turbopumps but yielded values of compliances significantly smaller than those indirectly obtained from experiments. Reasons for this discrepancy are discussed. The complete dynamic analysis presents a new problem in fundamental hydrodynamics and, though the basic solution is presented, numerical results have not as yet been obtained.

Acosta, A. J.↗
NASA NTRS1982

Numerical simulation of steady supersonic flow over spinning bodies of revolution

A recently reported parabolized Navier-Stokes code has been employed to compute the supersonic flowfield about a spinning cone and spinning and nonspinning ogive cylinder and boattailed bodies of revolution at moderate incidence. The computations were performed for flow conditions where extensive measurements for wall pressure, boundary-layer velocity profiles, and Magnus force had been obtained. Comparisons between the computational results and experiment indicate excellent agreement for angles of attack up to 6 deg. At angles greater than 6 deg discrepancies are noted which are tentatively attributed to turbulence modeling errors. The comparisons for Magnus effects show that the code accurately predicts the effects of body shape for the selected models.

Sturek, W. B.↗
NASA NTRS1989

Comment on predissociation of O2 in the B state

Theoretical models and experimental data on the predissociation of O2 in the B state are analyzed, with a focus on the results reported by Wodtke et al. (1988). Absorption cross sections in the (11,0) Schumann-Runge band of O2 at 79 K (Yoshino et al., 1987) are matched to curves synthesized from lower fine-structure components for 5Pi(u) and 3Pi(u) predissociative mechanisms. It is concluded that the 3Pi(u) predominance proposed by Wodtke et al. is not justified by the data. In a reply by Wodtke and Huwel, the need for further studies to clarify the apparent discrepancies between absorption and emission spectroscopy is indicated.

Freeman, D. E.↗
NASA NTRS1994

Microelectronics Instrument Products Shock and Vibration Electro-optics: C-Qualification Test Report

In this test report all measurements made during testing are recorded in ATP 20049 DS data sheets and are included in the log. The motor/encoder (henceforth referred to as the UUT) test sequence began with a baseline functional evaluation, which demonstrated that the motor satisfied the operating torque, cogging torque, winding resistance, and mechanical requirements of SOW. In addition, the encoder electrical requirements were verified, as well as the alignment of the encoder outputs relative tc, the motor shaft position. There were no discrepancies observed in this portion of the test. The UUT was then exposed to a number of environments, including thermal vacuum, thermal cycling, random and sine vibration, and mechanical shock. During the thermal environments, the performance of the UUT under load was verified at specified points in the cycles, as described in ATP 20049. In addition, the UUT was bench tested between the two thermal environments. No anomalies were observed during the thermal tests. The load attachment method was subsequently corrected, and vibration of S/N 0002 began while 0003 was being repaired.

Source record↗
NASA NTRS2009

Precision Column CO2 Measurement from Space Using Broad Band LIDAR

In order to better understand the budget of carbon dioxide in the Earth's atmosphere it is necessary to develop a global high precision understanding of the carbon dioxide column. To uncover the missing sink" that is responsible for the large discrepancies in the budget as we presently understand it, calculation has indicated that measurement accuracy of 1 ppm is necessary. Because typical column average CO2 has now reached 380 ppm this represents a precision on the order of 0.25% for these column measurements. No species has ever been measured from space at such a precision. In recognition of the importance of understanding the CO2 budget to evaluate its impact on global warming the National Research Council in its decadal survey report to NASA recommended planning for a laser based total CO2 mapping mission in the near future. The extreme measurement accuracy requirements on this mission places very strong constraints on the laser system used for the measurement. This work presents an overview of the characteristics necessary in a laser system used to make this measurement. Consideration is given to the temperature dependence, pressure broadening, and pressure shift of the CO2 lines themselves and how these impact the laser system characteristics. We are examining the possibility of making precise measurements of atmospheric carbon dioxide using a broad band source of radiation. This means that many of the difficulties in wavelength control can be treated in the detector portion of the system rather than the laser source. It also greatly reduces the number of individual lasers required to make a measurement. Simplifications such as these are extremely desirable for systems designed to operate from space.

Heaps, William S.↗
DOE OSTI2024

Neptunyl Pyrrophen Complexes: Exploring Schiff Base Chemistry with Multidentate Acyclic Ligands and Transuranics

Here we report the synthesis, structure, and characterization of two novel neptunyl complexes (NpO 2 L1 and NpO 2 L2) constructed from phenylene-substituted benzyl ester bis(pyrrole)phenylenediamine (named “pyrrophen”) ligands. In both cases, the neptunium center exists in the +6 oxidation state,. As our specific interest is in exploring the chemistry of neptunium compounds containing the linear neptunyl ion (NpO 2 2+ ) through equatorially coordinating the metal by multidentate organic ligands, we have identified the differences that are likely to cause discrepancy between the two complexes by examining the ions and their coordinative environments through single-crystal X-ray crystallography, diffuse reflectance, and Raman spectroscopy. This is the first time pyrrophen has been utilized in Np chemistry and demonstrates a new platform to study 5 f electron participation and coordination.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Multigap nodeless superconductivity in the topological semimetal PdTe

Recently, PdTe was identified as a spin-orbit-coupled topological Dirac semimetal and was claimed to exhibit both bulk-nodal and surface-nodeless superconducting gaps. Here we report on ultra-low-temperature thermal-conductivity measurements on PdTe single crystals with T c = 4.5 K to investigate its superconducting gap structure. It is found that the residual linear term κ 0 /T is negligible in zero magnetic field. Furthermore, the field dependence of κ 0 ⁡(H)/T exhibits an S-shaped curve. These results suggest that PdTe has multiple nodeless superconducting gaps, which is at odds with the claimed bulk-nodal gap. The reason for the discrepancy is likely that previous angle-resolved photoemission spectroscopy measurements were only performed down to 2 K and cannot observe the smaller nodeless gap. As a result, the fully gapped superconducting state in PdTe is compatible with it being a topological superconductor candidate.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1931

Experiments with airplane brakes

This report begins by examining the forces on the brake shoes. For the determination of the load distribution over the shoes it was assumed that the brake linings follow Hooke's law, are neatly fitted and bedded in by wear. The assumption of Hooke's law, that is, the proportionality between compression of the lining and the absorption of force, is fulfilled to a certain extent for the loading, as becomes apparent from the load tests described further on. But there is a material discrepancy at unloading. From the load distribution we merely defined the position of the normal force resultant, while for the rest, the effect of the distribution was disregarded in the comparison of the different shoe dispositions.

Michael, Franz↗
NASA NTRS2019

Modeling Meteoroid Densities for Spacecraft Risk Assessment

This report describes the methodologies and algorithms that NASA’s Meteoroid Environment Office (MEO) currently utilizes to measure meteoroid densities. We discuss the needs for an accurate model for the meteoroid density distribution in its Meteoroid Engineering Model (MEM), and its potential implications for spacecraft design. The recently developed process is heavily derived from that of previous work, although subtle differences exist. A thorough comparison of the best-fit densities derived for sixty meteoroids in and with the process described here shows that discrepancies in final densities larger than a factor of two are measured for ∼ 20% of our test events. Such a level of discrepancy suggests that any density calculated using similar methods cannot be assumed to represent a unique fit to the data. Additional observational data for meteoroids beyond those utilized in this work will be essential for producing more reliable and repeatable density measurements.

Ehlert, Steven↗
NASA NTRS1981

Nonthermal hard X-ray emission from the nucleus of NGC 1275

Observations confirming the HEAO 1 discovery of a hard X-ray component in the X-ray spectrum of the Perseus cluster are reported. A comparison of the results with 1978 HEAO 1 observations and 1974 balloon limits shows that this component is variable on a time scale of one year. Synchrotron self-Compton models of the compact radio source centered on the nucleus of NGC 1275 predict a substantial secondary X-ray flux based on the observed radio data. While the observed X-ray flux is one-fourth the predicted value, uncertainties in the radio data are sufficient to account for the discrepancy. It is concluded that the hard X-ray flux originates in the active nucleus of the Seyfert galaxy NGC 1275 through the synchrotron self-Compton process.

Rothschild, R. E.↗
NASA NTRS1999

Sonic Boom Prediction Exercise: Experimental Comparisons

The success of a future High Speed Civil Transport (HSCT) depends on the ability to accurately assess and, possibly, modify the sonic boom signatures of potential designs. In 1992, the Sonic Boom Steering Committee initiated a prediction exercise to assess the current computational capabilities for the accurate and efficient prediction of sonic boom signatures and loudness levels. A progress report of this effort was given at the Sonic Boom Workshop held at NASA Ames Research Center in 1993 where predictions from CFD and Modified Linear Theory (MLT) methods were given. Comparisons between the methods were made at near-, mid- and far-field locations. However, at that time, experimental data from wind-tunnel tests were not available. The current paper presents a comparison of computational results with the now available experimental data. Further comparisons between the computational methods and analyses of the discrepancies in the results are presented.

Tu, Eugene↗
NASA NTRS2000

Intercomparison of Models Representing Direct Shortwave Radiative Forcing by Sulfate Aerosols

The importance of aerosols as agents of climate change has recently been highlighted. However, the magnitude of aerosol forcing by scattering of shortwave radiation (direct forcing) is still very uncertain even for the relatively well characterized sulfate aerosol. A potential source of uncertainty is in the model representation of aerosol optical properties and aerosol influences on radiative transfer in the atmosphere. Although radiative transfer methods and codes have been compared in the past, these comparisons have not focused on aerosol forcing (change in net radiative flux at the top of the atmosphere). Here we report results of a project involving 12 groups using 15 models to examine radiative forcing by sulfate aerosol for a wide range of values of particle radius, aerosol optical depth, surface albedo, and solar zenith angle. Among the models that were employed were high and low spectral resolution models incorporating a variety of radiative transfer approximations as well as a line-by-line model. The normalized forcings (forcing per sulfate column burden) obtained with the several radiative transfer models were examined, and the discrepancies were characterized. All models simulate forcings of comparable amplitude and exhibit a similar dependence on input parameters. As expected for a non-light-absorbing aerosol, forcings were negative (cooling influence) except at high surface albedo combined with small solar zenith angle. The relative standard deviation of the zenith-angle-averaged normalized broadband forcing for 15 models-was 8% for particle radius near the maximum in this forcing (approx. 0.2 microns) and at low surface albedo. Somewhat greater model-to-model discrepancies were exhibited at specific solar zenith angles. Still greater discrepancies were exhibited at small particle radii and much greater discrepancies were exhibited at high surface albedos, at which the forcing changes sign; in these situations, however, the normalized forcing is quite small quite small. Discrepancies among the models arise from inaccuracies in Mie calculations, differing treatment of the angular scattering phase function, differing wavelength and angular resolution, and differing treatment of multiple scattering. These results imply the need for standardized radiative transfer methods tailored to the direct aerosol forcing problem. However, the relatively small spread in these results suggests that the uncertainty in forcing arising from the treatment of radiative forcing of a well-characterized aerosol at well-specified surface albedo is smaller than some of the other sources of uncertainty in estimates of direct forcing by anthropogenic sulfate aerosols and anthropogenic aerosols generally.

Boucher, O.↗