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Ar-39-Ar-40 Age Dating Of Two Angrites and Two Brachinites

Angrites are a rare group (approximately 7 known) of igneous meteorites with basalt-like composition, which probably derive from a relatively small parent body that differs from those of other igneous meteorites. Angrites show evidence for extinct Mn-53, Sm-146, and Pu-244, and precise U-Pb, and Pb-Pb ages of 4.558 Gyr for two angrites define the time of early parent body differentiation. The Sm-147-Nd-143 ages of two angrites range between 4.53 +/- 0.04 and 4.56 +/- 0.04 Gyr, but no Ar-39-Ar-40 or Rb-Sr ages have been reported. Most angrites show no evidence for either shock brecciation or metamorphism. Brachinites are another very rare group' of differentiated meteorites consisting primarily of olivine, with minor augite, chromite, Fe-sulfides, and sometimes plagioclase and opx. Presence of excess Xe-129 and excess Cr53 from decay of Mn-53 in some brachinites indicate that they also formed very early. Brachinite petrogenesis is poorly defined. They may be igneous cumulates or metamorphic products of chondritic-like starting material. If after their formation, angrites and brachinites cooled quickly with minimal subsequent heating, then one might expect them to show uniquely old K-Ar ages, at least in comparison to other differentiated meteorites such as eucrites and mesosiderites. Most angrites and brachinites contain very little, if any K-feldspar, which has deterred measurements of their Ar-Ar ages. We made Ar-39-Ar-40 analyses on two angrites, LEW86010 (metamorphosed) and D'Orbigny, and on two brachinites, EET99402 and Brachina. All are finds. Any feldspar in angrites is highly calcic, with expected K concentrations of <100 ppm. We selected LEW86010 and D'Orbigny because they have been the objects of several other studies and because chemical analyses suggested [K] was approximately 70 ppm in both meteorites. Brachina contains approximately 9.9% plagioclase of higher K-content than angrites, and EET99402 is estimated to contain approximately 5% K-poor plagioclase. Other brachinites contain little to no feldspar. We have successfully measured Ar-Ar ages on a few meteorites and lunar anorthosites with [K] <100 ppm.

Garrison, Daniel↗

"Solar-Wind-Rich" Howardite: True Regolith vs. CM-Implanted Components

Howardite, eucrite and diogenite meteorites (collectively HED) likely originate from asteroid 4-Vesta [1], one of two asteroids targeted by NASA s Dawn mission. Many howardites (polymict breccias of E and D material) contain "regolithic" features, including impact-melt clasts, fragmental breccia clasts, and carbonaceous chondrite fragments. True regolithic nature can be determined through noble gas analysis, as Solar Wind (SW) is implanted into the upper-most surfaces of solar system bodies. Whilst previous work [2] suggested that high siderophile element contents (e.g. Ni of 300-1200 g/g) were regolith indicators, we found no obvious correlation between SW and these indicators in our initial howardite noble gas analyses [3]. We observed CM-like fragments in a number of our howardites, whose textures suggest late addition to the breccia assemblage [4]. As typical CMs contain mixtures of SW (in matrix) and planetary (in clasts) components [5], we investigate the dominance of such components in SW-rich howardites. This will help deter-mine the extent of implanted SW in HED grains vs. SW and planetary gases from CM fragments, and allow better understanding of regolith processes

Cartwright, Julia A.↗

In Situ Trace Element Measurements on Roda and the Origin of Diogenites

The origin of diogenites remains poorly understood. A recent model interprets many diogenites to have been formed from melts that were derived by remelting initial magma ocean cumulates, and these penultimate parent melts were then contaminated by melts derived from remelting of the basaltic (eucritic) crust to form the ultimate diogenite parent melts [1] (hereafter the remelting model). This is a very complicated petrogenesis that has profound implications for the geological evolution of 4 Vesta if correct. This model was developed based on trace element analyses of bulk rock samples that had been leached in acids to remove phosphates; the compositions of the residues were interpreted to be close to those of cumulus orthopyroxenes plagioclase, chromite and olivine [1]. In situ measurements of phases in diogenites can be used to test this model. We have begun a campaign of laser ablation ICP-MS of orthopyroxene grains in diogenites for this purpose. Here we report our first results on one diogenite, Roda. We have determined a suite of trace lithophile elements on nine, mm-sized pyroxene grains separated from Roda that have previously been studied [2, 3]. A key observation supporting the remelting model is the very low Eu/Eu* of leached residues; values too low to represent orthopyroxene that crystallized from melts with chondritic Sm/Eu and Gd/Eu [1]. (Eu* = Eu interpolated from REE diagrams.) Crustal remelts have low Sm/Eu and Gd/Eu, and orthopyroxenes that crystallized from parent melts contaminated by them would have very low Eu/Eu* [1]. Roda grains have Eu/Eu* of 0.243 to 0.026; the latter a value lower than any measured on bulk diogenite leached residues (0.041) [1]. There is a general negative correlation between Eu/Eu* and some incompatible elements (Zr, Nb, Hf), but not others (LREE). This appears inconsistent with the remelting model as it would suggest an evolving parent melt with La de-creasing as Zr increased and Eu/Eu* decreased. Grain R-15 includes trace-element-rich trapped melt phases [2, 3]. This grain has the highest Eu/Eu* and LREE contents, indicating that the trapped melt had a high Eu/Eu*. Thus, our first data on one diogenite do not provide support for the remelting model [1]. Roda is unusual in that its orthopyroxene grains show wide ranges in trace element contents [4]. Previous in situ REE analyses of grain R-15 did not reveal evidence for subsolidus equilibration with trace-element-rich trapped melt phases, and led to the suggestion that Roda may be polymict, with different grains representing different lithologies of diverse compositions [3]. Thus, based on our results on Roda, it is perhaps premature to abandon the remelting model. In situ measurements on a suite of diogenites is planned to further address this issue.

Mittlefehldt, David W.↗

Dawn Maps the Surface Composition of Vesta

By 7-October-2011, the Dawn mission will have completed Survey orbit and commenced high altitude mapping of 4-Vesta. We present a preliminary analysis of data acquired by Dawn's Framing Camera (FC) and the Visual and InfraRed Spectrometer (VIR) to map mineralogy and surface temperature, and to detect and quantify surficial OH. The radiometric calibration of VIR and FC is described. Background counting data acquired by GRaND are used to determine elemental detection limits from measurements at low altitude, which will commence in November. Geochemical models used in the interpretation of the data are described. Thermal properties, mineral-, and geochemical-data are combined to provide constraints on Vesta s formation and thermal evolution, the delivery of exogenic materials, space weathering processes, and the origin of the howardite, eucrite, and diogenite (HED) meteorites.

Prettyman, T.↗

Vesta Mineralogy: VIR maps Vesta's surface

The Dawn mission will have completed Survey orbit around 4 Vesta by the end of August 2011. We present a preliminary analysis of data acquired by the Visual and InfraRed Spectrometer (VIR) to map Vesta mineralogy. Thermal properties and mineralogical data are combined to provide constraints on Vesta's formation and thermal evolution. delivery of exogenic materials, space weathering processes, and origin of the howardite. eucrite, and diogenite (HED) meteorites.

Coradina, A.↗

Disturbances in the Isotopic Record of Asuka 881394

Asuka 881394 is a unique achondrite with a granulitic texture, very calcic approximately An(sub 98) plagioclase, and pigeonite that has not inverted to orthopyroxene. First thought to be a eucrite, recent Oisotopic studies show it has a closer affinity to angrites . Initial isotopic studies provided evidence for now extinct A-26, Mn-53, and Sm-146. A recent study confirmed an early chronology with an absolute Pb-207 - Pb-206 age of 4566.5 +/- 0.2 Ma, a new measurement of the Al-Mg formation interval as 3.7 +/- 0.1 Ma since Al-26/Al-27 = approximately 4.63 x 10(exp -5) for the E60 CAI, and a Mn-Cr formation interval of -6.0 +/- 0.2 Ma relative to LEW86010 ("LEW"). Absolute ages relative to age anchors presented by were 4563.4 +/- 0.2 Ma by Al- Mg and 4564.6 +/- 0.5 Ma by Mn-Cr. These ages are in good, but not perfect, agreement with the Pb-207 - Pb-206 age. Perhaps the most direct comparison of the early chronology of A881394 as determined by various workers is provided by reported Al-26/Al-27 values of 1.18 +/- 0.14, 1.28 +/- 0.07, and 2.1 +/- 0.4 x 10(exp -6). Analyses of mineral separates by TIMS and MC-ICPMS6] agree well, but the higher value obtained by in situ SIMS analysis is significant in light of the slight inconsistency between absolute ages inferred from the short-lived chronometers and the Pb-207 - Pb-206 age. We examine the possibility that inconsistencies in the earliest fine-scale chronology of Asuka 881394 may be related to isotopic "disturbances" observed in Ar-39 - Ar-40, Rb-97 - Sr-87, and Sm-147 - Nd-143 chronometers.

Nyquist, L. E.↗

Geochemical Mapping of 4 Vesta Begins

By December, the NASA Dawn spacecraft will have descended to a low altitude mapping orbit (LAMO), where the Gamma Ray and Neutron Detector (GRaND) will acquire global mapping data for up to four months. Measurements by GRaND will help answer elusive questions about how Vesta differentiated and the nature of processes that shaped Vesta s surface. The data will be analyzed to determine the abundances of Mg, Si, Fe, K, Th, and H at a spatial resolution of roughly 300 km full-width-at-half-maximum from a 465 km radius orbit. Thermal and fast neutron counting data will be analyzed to determine the neutron macroscopic absorption cross section and average atomic mass, providing constraints on additional elements, such as Ca and Al. GRaND will quantify the elemental composition of coarse spatial units identified by Dawn s Framing Camera (FC) and the Visible & Infrared Spectrometer (VIR). In addition, GRaND will map the mixing ratio of compositional end members selected from the howardite, eucrite and diogenite (HED) meteorites, determine the relative proportions of plagioclase and mafic minerals, and search for compositions that are absent or under-represented in the meteorite collection. While it is generally thought that Vesta s crust on a regional scale should be well-represented by linear mixing of HED whole-rock compositions, there are hints that Vesta may be more diverse than implied by this model. For example, the discovery of K-rich impact glasses in howardites suggests that K-rich rocks may be present on a portion of Vesta s surface, and the analysis of diogenites indicates considerable variability in the magmatic processes that formed them. The chemical composition of materials within Vesta s south polar structure may provide further clues to how it formed. An impact might have exposed mantle and lower crustal materials, which should have a distinctive compositional signature. We present the analysis of data acquired by GRaND from cruise through the descent to LAMO, including GRaND s sensitivity to different elements and geochemical processes.

Prettyman, Thomas H.↗

Macro vs. Micro: Relating the Spectral Properties of Vesta and the HED Meteorite

We present the main results obtained comparing the visible-near infrared (VIS-NIR) spectra Vesta s surface with howardites, eucrites, diogenites (HED). HEDs are commonly associated with Vesta s composition based on spectral similarities. Because of such association, much effort is being made to merge the information from HEDs as well as Vestoids - with that from Vesta to characterize the lithologic diversity of the surface of this asteroid and to infer clues regarding its thermal history. However, while the HEDs are a class of meteorites well studied in the laboratory, the only spectral data available for Vesta until now were telescopic observations which are limited in terms of observation conditions, spatial resolution and Signal to Noise Ratio. The Dawn spacecraft, orbiting around Vesta since July 2011, is performing detailed observations of this body and thus improving our knowledge of its properties. Dawn s scientific payload includes an imaging spectrometer, VIR-MS, sensitive to the VIS-NIR spectral range. VIR-MS began acquiring spectra during the approach phase started in May 2011 and will continue its observations through July 2012 when the spacecraft will depart Vesta to travel to Ceres. The VIR-MS spatial resolution depends upon the mission phase (approach, survey, high altitude, low altitude). However, spectra acquired by VIR-MS have already exceeded the spatial resolution of ground-based telescopic observations, with resolution in the approach phase ranging from 2.5 up to 0.8 km/pixel. Moreover, the observations are uniformly distributed in latitude and longitude allowing us to have a global view of Vesta s crust spectral properties. Using the information provided by VIR spectra, we studied the distribution of the spectral heterogeneities on the surface and we used our findings to perform a comparison with HEDs spectra in the VIS-NIR spectral range searching for analogies and/or incompatibilities. In our analysis, we focused on a method to compare the results obtained at microscopic scale on HEDs samples and the one obtained at macroscopic scale on the surface of Vesta. Finally, we discuss our results in the context of vestan thermal history. The intent of this study is to improve our understanding of the connection between Vesta and the HED samples, which is one of the primary Dawn scientific objectives. This work is supported by an Italian Space Agency (ASI) grant and by NASA through the Dawn project and a Dawn at Vesta Participating Scientist grant.

Ammannito, E.↗

Redetermination of the Sm-Nd Age and Initial (Epsilon)Nd of Lunar Troctolite 76535: Implications for Lunar Crustal Development

Lunar troctolite 76535 is an old lunar rock predating the era of the lunar cataclysmic bombardment, but its radiometrially determined ages have been discordant [1-3]. The most recent multi-chronometer study [4] gave preferred ages of 4226+/-35 Ma and 4236+/-15 Ma from a Pb-207/Pb-206 isochron and an U-Pb upper concordia intercept, resp. We derive an age of 4323+/-64 Ma from Sm-Nd data reported by [4] for the bulk rock and three mineral separates. They derived an age of approx.4.38 Ga from combined Rb-Sr data [3,4] by omitting data for olivine separates. Ar-39-Ar-40 ages of approx.4.2 Ga are summarized by [5]. New Sm-147-Nd-143 data presented here give an age of 4335+/-71 Ma in agreement with the Sm-Nd age from [4], whereas Sm-146-Nd-142 data give a model age T(sub LEW) = 4439+/-22 Ma. Further, initial (Epsilon)Nd-143 for 76535 conforms to the Nd-143 evolution expected in an urKREEP [6] reservoir, consistent with inheritance of urKREEP Sm-Nd systematics via assimilation. We show that urKREEP Sm-Nd systematics require the lunar initial (Epsilon)Nd-143 to exceed the Chondritic Uniform Reservoir (CHUR) value [7], but are consistent with evolution from initial (Epsilon)Nd-143 like that of the HED meteorite parent body as defined by a 4557+/-20 Ma internal isochron for the cumulate eucrites Y-980433 and Y- 980318 [8].

Nyquist, Laurence E.↗

Overview of Vesta Mineralogy Diversity

4 Vesta is known to have a surface of basaltic material through visible/near-infrared reflectance spectroscopy (1). Vesta s spectrum has strong absorption features centered near 0.9 and 1.9 m, indicative of Fe-bearing pyroxenes. The spectra of HED (howardite, eucrite and diogenite) meteorites have similar features (1). This led to the hypothesis that Vesta was the parent body of the HED clan (2,3) and the discovery of a dynamical Vesta family of asteroids (Vestoids) provides a further link between Vesta and HEDs (4). Data from the Dawn VIR (Visible InfraRed mapping Spectrometer) (5) characterize and map the mineral distribution on Vesta, strengthen the Vesta - HED linkage and provide new insights into Vesta s formation and evolution.

DeSanctis, M. C.↗

Dawn and the Vesta-HED Connection

Although it is difficult to explain exactly how eucrites and diogenites are related through simple magmatic processes, their shared oxygen isotopic compositions and the common occurrence of clasts of both lithologies in howardite breccias support derivation from a common parent body. For decades, HED meteorites have been linked to asteroid 4 Vesta, based on spectral similarities [1] and the discovery of a dynamical family (Vestoids) that provides a bridge between Vesta and nearby resonance escape hatches [2]. Although recently derived constraints on the rapidity of HED parent body differentiation, based on measurements of Al-26 in diogenites, have been used to argue against the Vesta-HED connection [3], new thermal evolution models [e.g., 4] appear to be heated and melted fast enough to account for this constraint. Data from the Dawn orbiter strengthen the Vesta - HED linkage and provide new insights into petrogenetic interpretations of these meteorites.

McSween, H. Y.↗

Geochemistry at 4 Vesta: Observations Using Fast Neutrons

Dawn is currently in orbit around the asteroid 4 Vesta, and one of the major objectives of the mission is to probe the relationship of Vesta to the Howardite, Eucrite, and Diogenite (HED) meteorites. As Vesta is an example of a differentiated planetary embryo, Dawn will also provide fundamental information about planetary evolution in the early solar system [1]. To help accomplish this overall goal, the Dawn spacecraft carries the Gamma-Ray and Neutron Detector (GRaND). GRaND uses planetary gamma-ray and neutron spectroscopy to measure the surface elemental composition of Vesta and will provide information that is unique and complementary to that provided by the other Dawn instruments and investigations. Gamma-ray and neutron spectroscopy is a standard technique for measuring planetary compositions [2], having successfully made measurements at near-Earth asteroids, the Moon, Mars, Mercury and now Vesta. GRaND has made the first measurements of the neutron spectrum from any asteroid (previous asteroid measurements were only made with gamma-rays). Dawn has been collecting data at Vesta since July 2011. The prime data collection period for GRaND is the Low-Altitude Mapping Orbit (LAMO), which started on 12 December 2011 and will last through spring 2012. During LAMO, the Dawn spacecraft orbits at an average altitude of ~210 km above the surface of Vesta, which allows good neutron and gamma-ray signals to be detected from Vesta. A description of the overall goals of GRaND and a summary of the initial findings are given elsewhere [3,4]. The subject of this study is to present the information that will be returned from GRaND using fast neutron measurements. Here, we discuss what fast neutrons can reveal about Vesta s surface composition, how such data can address Dawn science goals, and describe fast neutron measurements made in the early portion of the Vesta LAMO phase.

Lawrence, David J.↗

Modelling the Thermal History of Asteroid 4 Vesta

The asteroid 4 Vesta is widely thought to be the source of the HED (Howardite, Eucrite and Diogenite) meteorites, with this link supported by spectroscopic and dynamical studies. The availability of the HED meteorites for study and the new data being gained from the Dawn mission provides an excellent opportunity to investigate Vesta s history. In this study, modelling of Vesta has been undertaken to investigate its evolution from an unconsolidated chondritic body to a differentiated body with an iron core. In contrast to previous modelling, both heat and mass transfer are considered as coupled processes. This work draws on models of melt segregation in terrestrial environments to inform the evolution of Vesta into the differentiated body observed today. In order for a core to form in this body, a separation of the metallic iron from the silicates must take place. Temperatures in excess of the solidus temperatures for the Fe-FeS system and the silicates are therefore required. Thermal modelling has shown accretion before 2Myr leads to temperatures in excess of the silicate solidus.

Solano, James M.↗

Types and Distribution of Bright Materials in 4 Vesta

A strong case can be made that Vesta is the parent asteroid of the howardite, eucrite and diogenite (HED) meteorites [1]. As such, we have over a century of detailed sample analysis experience to call upon when formulating hypotheses regarding plausible lithologic diversity on Vesta. It thus came as a surprise when Dawn s Framing Camera (FC) first revealed distinctly localized materials of exceptionally low and high albedos, often closely associated. To understand the nature and origin of these materials, and how they inform us of the geological evolution of Vesta, task forces began their study. An initial step of the scientific endeavor is to develop a descriptive, non-genetic classification of objects to use as a basis for developing hypotheses and observational campaigns. Here we present a catalog of the types of light-toned deposits and their distribution across Vesta. A companion abstract [2] discusses possible origins of bright materials and the constraints they suggest for vestan geology.

Mittlefehldt, D. W.↗

Space Weathering on 4 Vesta: Processes and Products

The bulk properties of Vesta have previously been linked directly to the howardite, eucrite, and diogenite (HED) meteorites through remote mineral characterization of its surface from Earth-based spectroscopy [e.g., 1]. A long-standing enigma has been why does Vesta s surface appear to have suffered so little alteration from the space environment, whereas materials exposed on the Moon and some S-type asteroids are significantly changed (grains develop rims containing nano-phase opaques [e.g. 2]). The Dawn spacecraft is well suited to address this issue and is half through its extended mapping phase of this remarkable proto-planet [3]. On a local scale Dawn sees evidence of recent exposures at craters, but distinctive surface materials blend into background at older craters. The presence of space weathering processes are thus evident at Vesta, but the character and form are controlled by the unique environment and geologic history of this small body.

Pieters, C. M.↗

Chondritic Models of 4 Vesta: Comparison of Predicted Internal Structure and Surface Composition/Mineralogy with Data from the Dawn Mission

Understanding the physical and chemical processes which led to the formation of the terrestrial planets remains one of the principal challenges of the Earth and planetary science communities. However, direct traces of the earliest stages of planet building have generally been wiped out on larger bodies such as the Earth or Mars, obscuring our view of how that process occurred. On the other hand, the planet building process would appear to have been arrested prematurely in the region between Mars and Jupiter, now populated by several hundred thousand compositionally diverse objects that escaped accretion into larger planets. Of these, the asteroid 4 Vesta is of particular interest as it is large (520 km diameter), and known to have a basaltic surface dominated by pyroxenes [1, 2]. Furthermore, visible-IR spectra of Vesta obtained by ground and space-based telescopes are remarkably similar to laboratory spectra measured on meteorites of the Howardite-Eucrite-Diogenite clan (HED), leading to the paradigm that the HEDs came from Vesta [2]. Geochemical and petrological studies of the HEDs confirm the differentiated nature of the near-surface region of their parent body, and imply that crust extraction occurred well within the first 10Ma of solar system history [3]. Vesta is therefore a prime target for studies that aim to constrain the earliest stages of planet building, and for that reason it is currently the subject of the Dawn mission [4].

Toplis, M. J.↗

A Cabonaceous Chondrite Dominated Lithology from the HED Parent; PRA 04401

The paired howardite breccias Mt. Pratt (PRA) 04401 and PRA 04402 are notable for their high proportion of carbonaceous chondrite clasts [1]. They consist predominantly of coarse (0.1-7 mm) diogenite (orthopyroxene), eucrite (plagioclase + pyroxene), and carbonaceous chondrite clasts set in a finer grained matrix of these same materials. Coarse C-chondrite clasts up to 7 mm are composed mainly of fine-grained phyllosilicates with lesser sulfides and high-mg# anhydrous magnesian silicates. Most of these clasts appear to be texturally consistent with CM2 classification [1] and some contain relict chondrules. The clasts are angular and reaction or alteration textures are not apparent in the surrounding matrix. PRA 04401 contains about 70 modal% C-chondrite clasts while PRA 04402 contains about 7%. Although many howardites are known to contain abundant C-chondrite clasts [2,3,4], PRA 04401 is, to our knowledge, the most chondrite-rich howardite lithology identified to date. Low EPMA totals from CM2-type clasts in other howardites suggest that they frequently contain 10 wt% or more water [2], a figure consistent with their mineralogy. PRA 04401, therefore, demonstrates the potential for hydrous lithologies with greater than 5 wt% water to occur locally within the nominally anhydrous HED parent body. Since the origin of this water is xenogenic, it might therefore be concentrated in portions of the asteroid surface where it would be more readily observable by remote sensing techniques. We plan to further examine C-chondrite clasts in PRA 04401/2 with the intent of establishing firm chemical classification, estimating water content, and evaluating their relationship with the host breccia. To help place them in context of the HED parent, we will also compare these breccias with other howardites to evaluate which lithologies are likely to be more prevalent on the asteroid surface.

Herrin, Jason S.↗

Vesta Mineralogy after Dawn Global Observations

The Dawn mission has completed its mapping phases at Vesta and millions of spectra have been acquired by the Visible and InfraRed Mapping Spectrometer, VIR(1). VIR characterizes and maps the mineral distribution on Vesta -strengthening the Vesta HED linkage- and provides new insights into Vesta s formation and evolution(2,3). VIR spectra are dominated by pyroxene absorptions near 0.9 and 2.0 m and large thermal emission beyond 3.5 m. Although almost all surface materials exhibit howardite-like spectra, some large regions can be interpreted to be richer in eucritic (basaltic) material and others richer in diogenititic (Mg-orthopyroxenitic) material. The Rheasilvia basin contains Mg-pyroxene-rich terrains for example. Vesta' s surface shows considerable diversity at local scales. Many bright and dark areas(3,4) are associated with various geological features and show remarkably different morphology. Moreover, VIR detected statistically significant, but weak, variations at 2.8 m that have been interpreted as indicating the presence of OH-bearing phases on the surface(5). The OH distribution is uneven with large regions lacking this absorption feature. Associations of 2.8 m band with morphological structures indicate complex process responsible for OH. Vesta exhibits large spectral variations that often correlate with geological structures, indicating a complex geological and evolutionary history, more similar to that of the terrestrial planets than to other asteroids visited by spacecrafts.

ChristinaDeSanctis, Maria↗