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At least 361 records · Page 20

Flexible thermoset towpregs by electrostatic powder fusion coating

Thermoset prepregs of expoxy and polyimide have been produced by electrostatic deposition of charged fluidized polymer powders on spread continuous fiber tows. The powders are melted onto the fibers by radiant heating to adhere the polymer to the fiber. This process produces towpreg uniformly and rapidly without imposing severe stresses on the fibers. The towpregs produced by this novel process were consolidated to make unidirectional laminates for mechanical testing. Low void content samples have been made and demonstrated by C-scan and scanning electron microscopy. The mechanical properties of unidirectional laminates are equivalent to composites fabricated by conventional techniques.

Yang, Pei-Hua↗

Symposium (International) on Combustion, 23rd, Universite d'Orleans, France, July 22-27, 1990, Proceedings

The present symposium on combustion discusses reaction kinetics, NO(x) kinetics, premixed, diffusion, and nonsteady flames, turbulent combustion, hazardous waste, fluidized bed combustion, coal boilers and furnaces, engines, heterogeneous kinetics, heterogeneous, droplet, and microgravity combustion, and high-temperature synthesis. Attention is given to reactions of biphenyl, methylnaphthalenes, and phenanthrene with atomic oxygen in the gas phase, the oxidation of ortho-xylene, the effects of water on combustion kinetics at high pressure, and the formation and measurement of N2O in combustion systems. Topics addressed include large ions in premixed benzene-oxygen flames, the structure and kinetics of CH4/N2O flames, the propagation of unsteady hydrogen premixed flames near flammability limits, and the basic structure of lean propane flames. Also considered are OH measurements of piloted diffusion flames of nitrogen-diluted methane near extinction, waste combustion, preferential oxidation of carbon surfaces, and reburning mechanisms in a pulverized coal combustor.

Source record↗

Critical technology experiment results for lightweight space heat receiver

Critical technology experiments have been performed on thermal energy storage modules in support of the NASA Advanced Solar Dynamic Brayton Heat Receiver Program. The modules, wedge-shaped canisters containing lithium fluoride (LiF), were designed to minimize the mechanical stresses that occur during the phase change of the LiF. Nickel foam inserts were placed in two of the test canisters to provide thermal conductivity enhancement and to distribute the void volume throughout the canister. A procedure was developed for reducing the nickel oxides on the nickel foam to enhance the wicking ability of the foam. The canisters were filled with LiF and closure-welded at the NASA Lewis Research Center. Two canisters, one with a nickel foam insert, the other without an insert, were thermally cycled in various orientations in a fluidized bed furnace. Computer-aided tomography was successfully used to nondestructively determine void locations in the canisters. Finally, canister dimensional stability was measured after thermal cycling with an inspection fixture.

Schneider, Michael G.↗

Fluid outflows from Venus impact craters - Analysis from Magellan data

Many impact craters on Venus have unusual outflow features originating in or under the continuous ejecta blankets and continuing downhill into the surrounding terrain. These features clearly resulted from flow of low-viscosity fluids, but the identity of those fluids is not clear. In particular, it should not be assumed a priori that the fluid is an impact melt. A number of candidate processes by which impact events might generate the observed features are considered, and predictions are made concerning the rheological character of flows produce by each mechanism. A sample of outflows was analyzed using Magellan images and a model of unconstrained Bingham plastic flow on inclined planes, leading to estimates of viscosity and yield strength for the flow materials. It is argued that at least two different mechanisms have produced outflows on Venus: an erosive, channel-forming process and a depositional process. The erosive fluid is probably an impact melt, but the depositional fluid may consist of fluidized solid debris, vaporized material, and/or melt.

Asimow, Paul D.↗

General-Purpose Element-Extracting Process

Proposed ore-refining or element-extracting process nonspecific: decomposes any ore or other raw material into constituent elements, regardless of composition. Enables conversion of ores into elements and recombination of elements into usefulmaterials as necessary. Effected on small scale to supplement such other mineral-refining processes as fluidized-bed reduction or carbochlorination. Alternatively, effected on large scale to produce wide range of materials. Conceived to provide materials for self-sufficient lunar base from such local ores as anorthite, ilmenite, and olivine. Proves useful on Earth in recovery or extraction of scarce, valuable, or hazardous materials.

Curreri, Peter A.↗

The distribution and modes of occurrence of impact melt at lunar craters

Numerous studies of the returned lunar samples as well as geologic and remote-sensing investigations have emphasized the importance of impact melts on the surface of the Moon. Information concerning the distribution and relative volumes is important for (1) an improved understanding of cratering processes, (2) kinetic energy estimates and energy partitioning studies, (3) the proper interpretation of melt-bearing lunar samples, and (4) comparative planetology studies. The identification of major flows of fluidized material associated with impact craters on the surface of Venus has increased interest in impact melt flows on the other terrestrial planets. For a number of years, we have been investigating the distribution, modes of occurrence, and relative and absolute amounts of impact melt associated with lunar craters as well as the manner in which melt volumes vary as a function of crater size, morphology, and target characteristics. The results of this effort are presented.

Hawke, B. Ray↗

What can we learn about impact mechanics from large craters on Venus?

More than 50 unequivocal peak-ring craters and multiringed impact basins have been identified on Venus from Earth-based Arecibo, Venera 15/16, and Magellan radar images. These ringed craters are relatively pristine, and so serve as an important new dataset that will further understanding of the structural and rheological properties of the venusian surface and of impact mechanics in general. They are also the most direct analogues for craters formed on the Earth in Phanerozoic time. Finite-element simulations of basin collapse and ring formation were undertaken in collaboration with V. J. Hillgren (University of Arizona). These calculations used an axisymmetric version of the viscoelastic finite element code TECTON, modeled structures on the scale of Klenova or Meitner, and demonstrated two major points. First, viscous flow and ring formation are possible on the timescale of crater collapse for the sizes of multiringed basins seen on Venus and heat flows appropriate to the plant. Second, an elastic lithosphere overlying a Newtonian viscous asthenosphere results mainly in uplift beneath the crater. Inward asthenospheric flow mainly occurs at deeper levels. Lithospheric response is dominantly vertical and flexural. Tensional stress maxima occur and ring formation by normal faulting is predicted in some cases, but these predicted rings occur too far out to explain observed ring spacings on Venus (or on the Moon). Overall, these estimates and models suggest that multiringed basin formation is indeed possible at the scales observed on Venus. Furthermore, due to the strong inverse dependence of solid-state viscosity on stress, the absence of Cordilleran-style ring faulting in craters smaller than Meitner or Klenova makes sense. The apparent increase in viscosity of shock-fluidized rock with crater diameter, greater interior temperatures accessed by larger, deeper craters, and decreased non-Newtonian viscosity associated with larger craters may conspire to make the transition with diameter from peak-ring crater to Orientale-type multiringed basin rather abrupt.

Mckinnon, William B.↗

Lunar surface mining for automated acquisition of helium-3: Methods, processes, and equipment

In this paper, several techniques considered for mining and processing the regolith on the lunar surface are presented. These techniques have been proposed and evaluated based primarily on the following criteria: (1) mining operations should be relatively simple; (2) procedures of mineral processing should be few and relatively easy; (3) transferring tonnages of regolith on the Moon should be minimized; (4) operations outside the lunar base should be readily automated; (5) all equipment should be maintainable; and (6) economic benefit should be sufficient for commercial exploitation. The economic benefits are not addressed in this paper; however, the energy benefits have been estimated to be between 250 and 350 times the mining energy. A mobile mining scheme is proposed that meets most of the mining objectives. This concept uses a bucket-wheel excavator for excavating the regolith, several mechanical electrostatic separators for beneficiation of the regolith, a fast-moving fluidized bed reactor to heat the particles, and a palladium diffuser to separate H2 from the other solar wind gases. At the final stage of the miner, the regolith 'tailings' are deposited directly into the ditch behind the miner and cylinders of the valuable solar wind gases are transported to a central gas processing facility. During the production of He-3, large quantities of valuable H2, H2O, CO, CO2, and N2 are produced for utilization at the lunar base. For larger production of He-3 the utilization of multiple-miners is recommended rather than increasing their size. Multiple miners permit operations at more sites and provide redundancy in case of equipment failure.

Li, Y. T.↗

Impact-generated winds on Venus: Causes and effects

The pressure of the dense atmosphere of Venus significantly changes the appearance of ejecta deposits relative to craters on the Moon and Mercury. Conversely, specific styles and sequences of ejecta emplacement can be inferred to represent different intensities of atmospheric response winds acting over different timescales. Three characteristic timescales can be inferred from the geologic record: surface scouring and impactor-controlled (angle and direction) initiation of the long fluidized run-out flows; nonballistic emplacement of inner, radar-bright ejecta facies and radar-dark outer facies; and very late reworking of surface materials. These three timescales roughly correspond to processes observed in laboratory experiments that can be scaled to conditions on Venus (with appropriate assumptions): coupling between the atmosphere and earlytime vapor/melt (target and impactor) that produces an intense shock that subsequently evolves into blast/response winds; less energetic dynamic response of the atmosphere to the outward-moving ballistic ejecta curtain that generates nonthermal turbulent eddies; and late recovery of the atmosphere to impact-generated thermal and pressure gradients expressed as low-energy but long-lived winds. These different timescales and processes can be viewed as the atmosphere equivalent of shock melting, material motion, and far-field seismic response in the target. The three processes (early Processes, Atmospheric Processes, and Late Recovery Winds) are discussed at length.

Schultz, Pater H.↗

Powder towpreg process development

The process for dry powder impregnation of carbon fiber tows being developed at LaRC overcomes many of the difficulties associated with melt, solution, and slurry prepregging. In the process, fluidized powder is deposited on spread tow bundles and fused to the fibers by radiant heating. Impregnated tows have been produced for preform, weaving, and composite materials applications. Design and operating data correlations were developed for scale up of the process to commercial operation. Bench scale single tow experiments at tow speeds up to 50 cm/sec have demonstrated that the process can be controlled to produce weavable towpreg. Samples were woven and molded into preform material of good quality.

Baucom, Robert M.↗

ASRM propellant and igniter propellant development and process scale-up

A program of formulation and process development for ANB-3652 motor propellant was conducted to validate design concepts and screen critical propellant composition and process parameters. Design experiments resulted in the selection of a less active grade of ferric oxide to provide better burning rate control, the establishment of AP fluidization conditions that minimized the adverse effects of particle attrition, and the selection of a higher mix temperature to improve mechanical properties. It is shown that the propellant can be formulated with AP and aluminum powder from various producers. An extended duration pilot plant run demonstrated stable equipment operation and excellent reproducibility of propellant properties. A similar program of formulation and process optimization culminating in large batch scaleup was conducted for ANB-3672 igniter propellant. The results for both ANB-3652 and ANB 37672 confirmed that their processing characteristics are compatible with full-scale production.

Landers, L. C.↗

Fractal dimensions of rampart impact craters on Mars

Ejecta blanket morphologies of Martian rampart craters may yield important clues to the atmospheric densities during impact, and the nature of target materials (e.g., hard rock, fine-grained sediments, presence of volatiles). In general, the morphologies of such craters suggest emplacement by a fluidized, ground hugging flow instead of ballistic emplacement by dry ejecta. We have quantitatively characterized the shape of the margins of the ejecta blankets of 15 rampart craters using fractal geometry. Our preliminary results suggest that the craters are fractals and are self-similar over scales of approximately 0.1 km to 30 km. Fractal dimensions (a measure of the extent to which a line fills a plane) range from 1.06 to 1.31. No correlations of fractal dimension with target type, elevation, or crater size were observed, though the data base is small. The range in fractal dimension and lack of correlation may be due to a complex interplay of target properties (grain size, volatile content), atmospheric pressure, and crater size. The mere fact that the ejecta margins are fractals, however, indicates that viscosity and yield strength of the ejecta were at least as low as those of basalts, because silicic lava flows are not generally fractals.

Ching, Delwyn↗

Production of O2 on the Moon: A lab-top demonstration of ilmenite reduction with hydrogen

Estimates of the costs of transporting materials from Earth to the Moon are around $25,000 per pound. Therefore, it is imperative that we learn to utilize the resources on the Moon to partially offset these 'astronomical' expenses. The production of oxygen on the Moon utilizing indigenous materials is crucial to the establishment and development of an autonomous lunar colony. Besides obvious biologic needs, this lunar liquid oxygen (LLOX) could result in tremendous cost savings on fuel for effective transportation systems, particularly with its export to low-Earth orbit. Over 20 different process concepts were proposed and evaluated for the production of oxygen from lunar materials. Simplicity, low energy, easily attainable feedstock, and low resupply mass are the keywords for the process(es) which will ultimately be selected for the initial production of oxygen on the Moon. One of these schemes, which has received considerable study to date, is the hydrogen reduction of ilmenite. In fact, Carbotek, Inc. (Houston, TX) patented an ilmenite, hydrogen-reduction technique involving a three-stage, fluidized-bed process for the production of LLOX. A lab-top demonstration unit of the basic concepts of this oxygen generation process that was constructed by our group at the University of Tennessee is explained. It utilizes many of the principles which must be addressed in designing an effective production plant for operation on the Moon.

Taylor, Lawrence A.↗

Degradation of TCE using sequential anaerobic biofilm and aerobic immobilized bed reactor

Bacteria capable of degrading trichloroethylene (TCE) were isolated from contaminated wastewaters and soil sites. The aerobic cultures were identified as Pseudomonas aeruginosa (four species) and Pseudomonas fluorescens. The optimal conditions for the growth of aerobic cultures were determined. The minimal inhibitory concentration values of TCE for Pseudomonas sps. were also determined. The aerobic cells were immobilized in calcium alginate in the form of beads. Degradation of TCE by the anaerobic and dichloroethylene (DCE) by aerobic cultures was studied using dual reactors - anaerobic biofilm and aerobic immobilized bed reactor. The minimal mineral salt (MMS) medium saturated with TCE was pumped at the rate of 1 ml per hour into the anaerobic reactor. The MMS medium saturated with DCE and supplemented with xylenes and toluene (3 ppm each) was pumped at the rate of 1 ml per hour into the fluidized air-uplift-type reactor containing the immobilized aerobic cells. The concentrations of TCE and DCE and the metabolites formed during their degradation by the anaerobic and aerobic cultures were monitored by GC. The preliminary study suggests that the anaerobic and aerobic cultures of our isolates can degrade TCE and DCE.

Chapatwala, Kirit D.↗

IUTAM symposium on hydrodynamic diffusion of suspended particles

Hydrodynamic diffusion refers to the fluctuating motion of nonBrownian particles (or droplets or bubbles) which occurs in a dispersion due to multiparticle interactions. For example, in a concentrated sheared suspension, particles do not move along streamlines but instead exhibit fluctuating motions as they tumble around each other. This leads to a net migration of particles down gradients in particle concentration and in shear rate, due to the higher frequency of encounters of a test particle with other particles on the side of the test particle which has higher concentration or shear rate. As another example, suspended particles subject to sedimentation, centrifugation, or fluidization, do not generally move relative to the fluid with a constant velocity, but instead experience diffusion-like fluctuations in velocity due to interactions with neighboring particles and the resulting variation in the microstructure or configuration of the suspended particles. In flowing granular materials, the particles interact through direct collisions or contacts (rather than through the surrounding fluid); these collisions also cause the particles to undergo fluctuating motions characteristic of diffusion processes. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

Diffusion↗

Incipient Melt Formation and Devitrification at the Wanapitei Impact Structure, Ontario, Canada

The Wanapitei impact structure is approximately 8 km in diameter and lies within Wanapitei Lake, approximately 34 km northeast of the city of Sudbury. Rocks related to the 37 Ma impact event are found only in Pleistocene glacial deposits south of the lake. Most of the target rocks are metasedimentary rocks of the Proterozoic Huronian Supergroup. An almost completely vitrified, inclusion-bearing sample investigated here represents either an impact melt or a strongly shock metamorphosed, pebbly wacke. In the second, preferred interpretation, a number of partially melted and devitrified clasts are enclosed in an equally highly shock metamorphosed arkosic wacke matrix (i.e., the sample is a shocked pebbly wacke), which records the onset of shock melting. This interpretation is based on the glass composition, mineral relicts in the glass, relict rock textures, and the similar degree of shock metamorphism and incipient melting of all sample components. Boulder matrix and clasts are largely vitrified and preserve various degrees of fluidization, vesiculation, and devitrification. Peak shock pressure of approximately 50-60 GPa and stress experienced by the sample were somewhat below those required for complete melting and development of a homogeneous melt. The rapid cooling and devitrification history of the analyzed sample is comparable to that reported recently from glasses in the suevite of the Ries impact structure in Germany and may indicate that the analyzed sample experienced an annealing temperature after deposition of somewhere between 650 C and 800 C.

Dressler, B. O.↗

IUTAM Symposium on Hydrodynamic Diffusion of Suspended Particles

The focus of the symposium was on multiparticle hydrodynamic interactions which lead to fluctuating motion of the particles and resulting particle migration and dispersion or diffusion. Implications of these phenomena were described for sedimentation, fluidization, suspension flows, granular flows, and fiber suspensions. Computer simulation techniques as well as experimental techniques were described. Each session had an invited leadoff talk which overviewed the session topic as well as described the speaker's own related research. Ample time for discussion was included after each talk as well as at the end of each session. The symposium started with a keynote talk on the first evening on What is so puzzling about hydrodynamic diffusion?, which set the tone for the rest of the meeting by emphasizing both recent advances and unanswered issues.

Davis, R. H.↗

Lunar Basins: New Evidence from Gravity for Impact-Formed Mascons

The prominent gravity highs (mascons) associated with uncompensated mass anomalies in lunar mare basins are a dramatic expression of the present-day rigidity of the lunar lithosphere. First discovered in Lunar Orbiter tracking data, these about 350-mGal gravity highs have been redetermined from the analysis of Clementine and historical tracking. These highs coincide with topographic lows, indicating nonisostatic support. One of the rediscoveries of this analysis is the encirclement of the highs by substantial negative anomalies over topographic highs. Recent gravity fields are providing the increased resolution necessary to determine the causes of this unique mascon signature. The compensation of the basin anomalies remains controversial. The mascon highs have long been interpreted as the result of mare loading, subsequent to the decay of residual stresses resulting from the impact. Substantially more mare fill is required to produce mascon highs than has been inferred on geological grounds, and the amount of near-surface mass deficit required to produce a gravity most exceeds bounds inferred from terrestrial examples. This problem is most acute for the youngest basin, Orientale. Recent gravity fields from Lunar Prospector have suggested mascon highs associated with nonmare basins such as Mendel-Rydberg, or minimally filled basins like Humboldtianum, further calling this explanation into question. We suggest that the mascon gravity signal is produced by a combination of crustal thickness changes, manifested by central mantle uplift, outward displacement of crust, and downward flexure of the lithosphere under mare loading. The mantle uplift is superisostatic, maintained by residual stresses resulting from the process of impact cratering and modification. In particular, the process of crater collapse and mantle rebound terminates abruptly, leaving the mantle plug in a non-equilibrium state, surrounded by a ring of thickened crust. Viscous relaxation over geological timescales has erased some but not all of the signature of the impact process. Mantle uplift inferred from gravity modeling is inversely correlated with age. While the oldest basins such as South Pole Aitken are mainly compensated isotatically, the younger basins appear to have been in a state of superisostatic loading prior to mare emplacement. If this is true, this places an important constraint on the impact process at basin scales. The idea that rebound of the transient crater via acoustic fluidization may freeze substantial stresses imcomplete to this day, may be tested by examining the gravity signatures of major basins on terrestrial bodies. The moon provides the clearest resolved examples to date, but uncertainty in gravity knowledge remains problematic.

Neumann, Gregory A.↗