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At least 361 records · Page 20

Detecting Airborne Mercury by Use of Gold Nanowires

Like the palladium chloride (PdCl2) films described in the immediately preceding article, gold nanowire sensors have been found to be useful for detecting airborne elemental mercury at concentrations on the order of parts per billion (ppb). Also like the PdCl2 films, gold nanowire sensors can be regenerated under conditions much milder than those necessary for regeneration of gold films that have been used as airborne-Hg sensors. The interest in nanowire sensors in general is prompted by the expectation that nanowires of a given material covering a given surface may exhibit greater sensitivity than does a film of the same material because nanowires have a greater surface area. In preparation for experiments to demonstrate this sensor concept, sensors were fabricated by depositing gold nanowires, variously, on microhotplate or microarray sensor substrates. In the experiments, the electrical resistances were measured while the sensors were exposed to air at a temperature of 25 C and relative humidity of about 30 percent containing mercury at various concentrations from 2 to 70 ppb (see figure). The results of this and other experiments have been interpreted as signifying that sensors of this type can detect mercury at ppb concentrations in room-temperature air and can be regenerated by exposure to clean flowing air at temperatures <40 C.

Ryan, Margaret↗

Multiphysics and Multiscale Modeling of Coupled Transport of Chloride Ions in Concrete

Chloride ions (Cl−)-induced corrosion is one of the main degradation mechanisms in reinforced concrete (RC) structures. In most situations, the degradation initiates with the transport of Cl− from the surface of the concrete towards the reinforcing steel. The accumulation of Cl− at the steel-concrete interface could initiate reinforcement corrosion once a threshold Cl− concentration is achieved. An accurate numerical model of the Cl− transport in concrete is required to predict the corrosion initiation in RC structures. However, existing numerical models lack a representation of the heterogenous concrete microstructure resulting from the varying environmental conditions and the indirect effect of time dependent temperature and relative humidity (RH) on the water adsorption and Cl− binding isotherms. In this study, a numerical model is developed to study the coupled transport of Cl− with heat, RH and oxygen (O2) into the concrete. The modeling of the concrete microstructure is performed using the Virtual Cement and Concrete Testing Laboratory (VCCTL) code developed by the U.S. National Institute of Standards and Technology (NIST). The concept of equivalent maturation time is utilized to eliminate the limitation of simulating concrete microstructure using VCCTL in specific environmental conditions such as adiabatic. Thus, a time-dependent concrete microstructure, which depends on the hydration reactions coupled with the temperature and RH of the environment, is achieved to study the Cl− transport. Additionally, Cl− binding isotherms, which are a function of the pH of the concrete pore solution, Cl− concentration, and weight fraction of mono-sulfate aluminate (AFm) and calcium-silicate-hydrate (C-S-H), obtained from an experimental study by the same authors are utilized to account for the Cl− binding of cement hydration products. The temperature dependent RH diffusion was considered to account for the transport of Cl− with moisture transport. The temperature and RH diffusion in the concrete domain, composite theory, and Cl− binding and water adsorption isotherms are used in combination, to estimate the ensuing Cl− diffusion field within the concrete. The coupled transport process of heat, RH, Cl−, and O2 is implemented in the Multiphysics Object-Oriented Simulation Environment (MOOSE) developed by the U.S. Idaho National Laboratory (INL). The model was verified and validated using data from multiple experimental studies with different concrete mixture proportions, curing durations, and environmental conditions. Additionally, a sensitivity analysis was performed to identify that the water-to-cement (w/c) ratio, the exposure duration, the boundary conditions: temperature, RH, surface Cl− concentration, Cl− diffusion coefficient in the capillary water, and the critical RH are the important parameters that govern the Cl− transport in RC structures. In a case study, the capabilities of the developed numerical model are demonstrated by studying the complex 2D diffusion of Cl− in a RC beam located in two different climatic regions: warm and humid weather in Galveston, Texas, and cold and dry weather in North Minnesota, Minnesota, subjected to time varying temperature, RH, and surface Cl− concentrations.

composite theory↗

Desiccant humidity control system

A water vapor and carbon dioxide sorbent material (designated HS-C) was developed for potential application to the space shuttle and tested at full scale. Capacities of two percent for carbon dioxide and four percent for water vapor were achieved using space shuttle cabin adsorption conditions and a space vacuum for desorption. Performance testing shows that water vapor can be controlled by varying the air process flow, while maintaining the ability to remove carbon dioxide. A 2000 hour life test was successfully completed, as were tests for sensitivity to cleaning solvent vapors, vibration resistance, and flammability. A system design for the space shuttle shows a 200 pound weight advantage over competitive systems and an even larger advantage for longer missions.

Lunde, P. J.↗

Feasibility Assessment of an EVA Glove Sensing Platform to Evaluate Potential Hand Injury Risk Factors

Injuries to the hands are common among astronauts who train for extravehicular activity (EVA). When the gloves are pressurized, they restrict movement and create pressure points during tasks, sometimes resulting in pain, muscle fatigue, abrasions, and occasionally more severe injuries such as onycholysis. A brief review of the Lifetime Surveillance of Astronaut Health's injury database reveals that 58% of total astronaut hand and arm injuries from NBL training between 1993 and 2010 occurred either to the fingernail, MCP, or fingertip. The purpose of this study was to assess the potential of using small sensors to measure force acting on the fingers and hand within pressurized gloves and other variables such as blood perfusion, skin temperature, humidity, fingernail strain, skin moisture, among others. Tasks were performed gloved and ungloved in a pressurizable glove box. The test demonstrated that fingernails saw greater transverse strain levels for tension or compression than for longitudinal strain, even during axial fingertip loading. Blood perfusion peaked and dropped as the finger deformed during finger presses, indicating an initial dispersion and decrease of blood perfusion levels. Force sensitive resistors to force plate comparisons showed similar force curve patterns as fingers were depressed, indicating suitable functionality for future testing. Strategies for proper placement and protection of these sensors for ideal data collection and longevity through the test session were developed and will be implemented going forward for future testing.

Reid, Christopher R.↗

Estimating ocean-air heat fluxes during cold air outbreaks by satellite

Nomograms of mean column heating due to surface sensible and latent heat fluxes were developed. Mean sensible heating of the cloud free region is related to the cloud free path (CFP, the distance from the shore to the first cloud formation) and the difference between land air and sea surface temperatures, theta sub 1 and theta sub 0, respectively. Mean latent heating is related to the CFP and the difference between land air and sea surface humidities q sub 1 and q sub 0 respectively. Results are also applicable to any path within the cloud free region. Corresponding heat fluxes may be obtained by multiplying the mean heating by the mean wind speed in the boundary layer. The sensible heating estimated by the present method is found to be in good agreement with that computed from the bulk transfer formula. The sensitivity of the solutions to the variations in the initial coastal soundings and large scale subsidence is also investigated. The results are not sensitive to divergence but are affected by the initial lapse rate of potential temperature; the greater the stability, the smaller the heating, other things being equal. Unless one knows the lapse rate at the shore, this requires another independent measurement. For this purpose the downwind slope of the square of the boundary layer height is used, the mean value of which is also directly proportional to the mean sensible heating. The height of the boundary layer should be measurable by future spaceborn lidar systems.

Chou, S. H.↗

Real-Time Tracking of Carbon Dioxide Concentration Using an Optical Microsphere Resonator Sensor

Whispering gallery mode resonator sensors are nondisruptive optical sensors that can detect and monitor perturbations in a gaseous environment. Through its resonant properties of peak wavelength, amplitude, and quality factor (Q factor), changes in concentration can be quantified within seconds and monitored over days with great stability. In addition, the small footprint, low cost, and high sensitivity are ideal properties for a disposable sensor that can be utilized in extreme environments. Further, the large Q factor of the resonant cavity enables long interaction lengths and amplifies the effect of small changes in the background refractive index, which is detectable in picometer shifts of the resonance wavelength. However, this measurement is susceptible to changes in other environmental factors such as temperature, pressure, and humidity, which manifest on the picometer wavelength scale, reinforcing the need to decouple the variables. In this work, we compare the spectral response of different diameter resonators to carbon dioxide, nitrogen, and its mixtures, observing the spectral shifting and broadening of the cavity resonance near 1550 nm. In addition, the effect of environmental temperature on spectral shifting due to the thermo-optic effect is characterized and quantified. Lastly, the gas concentrations are changed in real time to showcase the tracking and recovery capabilities of the resonator sensor.

47 OTHER INSTRUMENTATION↗

Getting the GeoSTAR Instrument Concept Ready for a Space Mission

The Geostationary Synthetic Thinned Array Radiometer - GeoSTAR - is a microwave sounder intended for geostationary satellites. First proposed for the EO-3 New Millennium mission in 1999, the technology has since been developed under the Instrument Incubator Program. Under IIP-03 a proof-of-concept demonstrator operating in the temperature sounding 50 GHz band was developed to show that the aperture synthesis concept results in a realizable, stable and accurate imaging-sounding radiometer. Some of the most challenging technology, such as miniature low-power 183- GHz receivers used for water vapor sounding, was developed under IIP-07. The first such receiver has recently been adapted for use in the High Altitude MMIC Sounding Radiometer (HAMSR), which was previously developed under IIP-98. This receiver represents a new state of the art and outperforms the previous benchmark by an order of magnitude in radiometric sensitivity. It was first used in the GRIP hurricane field campaign in 2010, where HAMSR became the first microwave sounder to fly on the Global Hawk UAV. Now, under IIP-10, we will develop flight-like subsystems and a brassboard testing system, which will facilitate rapid implementation of a space mission. GeoSTAR is the baseline payload for the Precipitation and All-weather Temperature and Humidity (PATH) mission - one of NASA's 15 "decadal-survey" missions. Although PATH is currently in the third tier of those missions, the IIP efforts have advanced the required technology to a point where a space mission can be initiated in a time frame commensurate with second-tier missions. An even earlier Venture mission is also being considered.

millimeter-wave↗

Indicator Devices for Detection of Trace Gaseous Hydrazines

The relatively recent decrease in the acceptable time-weighted-average for hydrazines from 100 parts-per-billion (ppb) to 10 ppb rendered many trace hydrazine detectors either insensitive or inaccurate. Development of a rapid detection method for hydrazines at the new 10-ppb concentration was necessary so that test area personnel could reliably assess airborne hydrazines concentrations of a potentially contaminated area prior to entry. The reduction of Au(III) to Au(0) by hydrazines is a well characterized reaction and application of the corresponding yellow to purple color change was selected as a potentially useful means for detection of trace hydrazines in air. Tests with small quantities of KAuCl4 deposited on a variety of substrates were conducted using verified sources of 1,1-dimethylhydrazine, methylhydrazine, and hydrazine at approximately 10 ppb in air. Substrates tested were glass fiber filter paper, glass beads, anion exchange resin (AuCl4- form), and diatomaceous earth. The most successful of these substrates were glass fiber filter paper and diatomaceous earth. The KAuC14 impregnated glass fiber filter paper appeared to be somewhat light sensitive so further tests were conducted using the diatomaceous earth substrate. KAuCl4 concentration, substrate particle size, and sampler configuration were evaluated. Based on these tests, the device selected for further evaluation was a 5mm OD by 50mm glass tube containing 0.02-0.03g of 45/60 mesh diatomaceous earth coated with 2 percent KAuCl4. When connected to a sampling pump, response of the device to changes in relative humidity, ambient light, and high levels of other fluids, which might also be found in a propellant test area, was evaluated. False positive responses were not detected for exposures to relative humidity changes from 10 to 80 percent, sunlight for greater than 10 minutes, or percent levels of ammonia, isopropyl alcohol, nitrogen dioxide, and hydrogen. In addition, body emissions did not produce a false positive response in view of potential application for use inside protective clothing. The device was shown to reliably detect less than 10 ppb of the hydrazines tested using a 10 to 20L sample followed by a 2 to 5 minute color development time. Some field tests were conducted in parallel with conventional acidic firebrick sorbent tubes. There was generally very good agreement between the devices and firebrick sorbent tubes when greater than 10 ppb of a hydrazine was present.

Dee, Lou A.↗

Development of a two-dimensional zonally averaged statistical-dynamical model. I - The parameterization of moist convection and its role in the general circulation

The moist convection parameterization used in the GISS 3-D GCM is adapted for use in a two-dimensional (2-D) zonally averaged statistical-dynamical model. Experiments with different versions of the parameterization show that its impact on the general circulation in the 2-D model does not parallel its impact in the 3-D model unless the effect of zonal variations is parameterized in the moist convection calculations. A parameterization of the variations in moist static energy is introduced in which the temperature variations are calculated from baroclinic stability theory, and the relative humidity is assumed to be constant. Inclusion of the zonal variations of moist static energy in the 2-D moist convection parameterization allows just a fraction of a latitude circle to be unstable and enhances the amount of deep convection. This leads to a 2-D simulation of the general circulation very similar to that in the 3-D model. The experiments show that the general circulation is sensitive to the parameterized amount of deep convection in the subsident branch of the Hadley cell. The more there is, the weaker are the Hadley cell circulations and the westerly jets. The experiments also confirm the effects of momentum mixing associated with moist convection found by earlier investigators and, in addition, show that the momentum mixing weakens the Ferrel cell. An experiment in which the moist convection was removed while the hydrological cycle was retained and the eddy forcing was held fixed shows that moist convection by itself stabilizes the tropics, reduces the Hadley circulation, and reduces the maximum speeds in the westerly jets.

Yao, Mao-Sung↗

Document Monitor

The charters of Freedom Monitoring System will periodically assess the physical condition of the U.S. Constitution, Declaration of Independence and Bill of Rights. Although protected in helium filled glass cases, the documents are subject to damage from light vibration and humidity. The photometer is a CCD detector used as the electronic film for the camera system's scanning camera which mechanically scans the document line by line and acquires a series of images, each representing a one square inch portion of the document. Perkin-Elmer Corporation's photometer is capable of detecting changes in contrast, shape or other indicators of degradation with 5 to 10 times the sensitivity of the human eye. A Vicom image processing computer receives the data from the photometer stores it and manipulates it, allowing comparison of electronic images over time to detect changes.

Source record↗

Intercomparison of Aerosol Volume Size Distributions Derived from AERONET Ground-Based Remote Sensing and LARGE in Situ Aircraft Profiles During the 2011–2014 DRAGON and DISCOVER-AQ Experiments

Aerosol volume size distribution (VSD) retrievals from the Aerosol Robotic Network (AERONET) aerosol monitoring network were obtained during multiple DRAGON (Distributed Regional Aerosol Gridded Observational Network) campaigns conducted in Maryland, California, Texas and Colorado from 2011 to 2014. These VSD retrievals from the field campaigns were used to make comparisons with near-simultaneous in situ samples from aircraft profiles carried out by the NASA Langley Aerosol Group Experiment (LARGE) team as part of four campaigns comprising the DISCOVER-AQ (Deriving Information on Surface conditions from Column and Vertically Resolved Observations Relevant to Air Quality) experiments. For coincident (1 h) measurements there were a total of 91 profile-averaged fine-mode size distributions acquired with the LARGE ultra-high sensitivity aerosol spectrometer (UHSAS) instrument matched to 153 AERONET size distributions retrieved from almucantars at 22 different ground sites. These volume size distributions were characterized by two fine-mode parameters, the radius of peak concentration (rpeak_conc) and the VSD fine-mode width (widthpeak_conc). The AERONET retrievals of these VSD fine-mode parameters, derived from ground-based almucantar sun photometer data, represent ambient humidity values while the LARGE aircraft spiral profile retrievals provide dried aerosol (relative humidity; RH< 20 %) values. For the combined multiple campaign dataset, the average difference in rpeak_conc was 0:0330:035 μm (ambient AERONET values were 15.8% larger than dried LARGE values), and the average difference in widthpeak_conc was 0:0420:039 μm (AERONET values were 25.7% larger). For a subset of aircraft data, the LARGE data were adjusted to account for ambient humidification. For these cases, the AERONET–LARGE average differences were smaller, with rpeak_conc differing by 0:0110:019 μm (AERONET values were 5.2% larger) and widthpeak_conc average differences equal to 0:0300:037 μm (AERONET values were 15.8% larger).

Schafer, Joel S.↗

The global decline in the sensitivity of vegetation productivity to precipitation from 2001 to 2018

The sensitivity of vegetation productivity to precipitation (S ppt ) is a key metric for understanding the variations in vegetation productivity under changing precipitation and predicting future changes in ecosystem functions. However, a comprehensive assessment of S ppt over all the global land is lacking. Here, we investigated spatial patterns and temporal changes of S ppt across the global land from 2001 to 2018 with multiple streams of satellite observations. We found consistent spatial patterns of S ppt with different satellite products: S ppt was highest in dry regions while low in humid regions. Grassland and shrubland showed the highest S ppt , and evergreen needle-leaf forest and wetland showed the lowest. Temporally, S ppt showed a generally declining trend over the past two decades (p < .05), yet with clear spatial heterogeneities. The decline in S ppt was especially noticeable in North America and Europe, likely due to the increase in precipitation. In central Russia and Australia, however, S ppt showed an increasing trend. Biome-wise, most ecosystem types exhibited significant decrease in S ppt , while grassland, evergreen broadleaf forest, and mixed forest showed slight increases or non-significant changes in S ppt . Our finding of the overall decline in S ppt implies a potential stabilization mechanism for ecosystem productivity under climate change. However, the revealed S ppt increase for some regions and ecosystem types, in particular global grasslands, suggests that grasslands might be increasingly vulnerable to climatic variability with continuing global climate change.

54 ENVIRONMENTAL SCIENCES↗

Using Meteorological Data to Evaluate Worldwide PV Degradation Rates

Here we automate the process to enable the creation of world maps for specific PV durability metrics. The end goal is to create a tool for the creation of world maps predicting the sensitivity of modules to degradation to inform the development and utilization of module testing standards and to provide information to module designers. TMY (Typical Meteorological Year) Data was aggregated from sites around the world to render insight into factors contributing to the degradation of solar modules. The focus of aggregating data was to create a single dataset to work with utilizing Solar Irradiance values combined with Ambient Temperature, Relative Humidity, Wind Speed and Dew-Point Temperature.

14 SOLAR ENERGY↗

Evaluating cloud liquid detection against Cloudnet using cloud radar Doppler spectra in a pre-trained artificial neural network

Detection of liquid-containing cloud layers in thick mixed-phase clouds or multi-layer cloud situations from ground-based remote-sensing instruments still poses observational challenges, yet improvements are crucial since the existence of multi-layer liquid layers in mixed-phase cloud situations influences cloud radiative effects, cloud lifetime, and precipitation formation processes. Hydrometeor target classifications such as from Cloudnet that require a lidar signal for the classification of liquid are limited to the maximum height of lidar signal penetration and thus often lead to underestimations of liquid-containing cloud layers. Here we evaluate the Cloudnet liquid detection against the approach of Luke et al. (2010) which extracts morphological features in cloud-penetrating cloud radar Doppler spectra measurements in an artificial neural network (ANN) approach to classify liquid beyond full lidar signal attenuation based on the simulation of the two lidar parameters particle backscatter coefficient and particle depolarization ratio. We show that the ANN of Luke et al. (2010) which was trained under Arctic conditions can successfully be applied to observations at the mid-latitudes obtained during the 7-week-long ACCEPT field experiment in Cabauw, the Netherlands, in 2014. In a sensitivity study covering the whole duration of the ACCEPT campaign, different liquid-detection thresholds for ANN-predicted lidar variables are applied and evaluated against the Cloudnet target classification. Independent validation of the liquid mask from the standard Cloudnet target classification against the ANN-based technique is realized by comparisons to observations of microwave radiometer liquid-water path, ceilometer liquid-layer base altitude, and radiosonde relative humidity. In addition, a case-study comparison against the cloud feature mask detected by the space-borne lidar aboard the CALIPSO satellite is presented. Three conclusions were drawn from the investigation. First, it was found that the threshold selection criteria of liquid-related lidar backscatter and depolarization alone control the liquid detection considerably. Second, all threshold values used in the ANN framework were found to outperform the Cloudnet target classification for deep or multi-layer cloud situations where the lidar signal is fully attenuated within low liquid layers and the cloud radar is able to detect the microphysical fingerprint of liquid in higher cloud layers. Third, if lidar data are available, Cloudnet is at least as good as the ANN. The times when Cloudnet outperforms the ANN in liquid detections are often associated with situations where cloud dynamics smear the imprint of cloud microphysics on the radar Doppler spectra.

54 ENVIRONMENTAL SCIENCES↗

A model of the tropical Pacific sea surface temperature climatology

A model for the climatological mean sea surface temperature (SST) of the tropical Pacific Ocean is developed. The upper ocean response is computed using a time dependent, linear, reduced gravity model, with the addition of a constant depth frictional surface layer. The full three-dimensional temperature equation and a surface heat flux parameterization that requires specification of only wind speed and total cloud cover are used to evaluate the SST. Specification of atmospheric parameters, such as air temperature and humidity, over which the ocean has direct influence, is avoided. The model simulates the major features of the observed tropical Pacific SST. The seasonal evolution of these features is generally captured by the model. Analysis of the results demonstrates the control the ocean has over the surface heat flux from ocean to atmosphere and the crucial role that dynamics play in determining the mean SST in the equatorial Pacific. The sensitivity of the model to perturbations in the surface heat flux, cloud cover specification, diffusivity, and mixed layer depth is discussed.

Seager, Richard↗

Methods for LWIR Radiometric Calibration and Characterization

The utility of a remote sensing system increases with its ability to retrieve surface temperature or radiance accurately. Research applications, such as sea temperature and power plant discharge, require a 0.2 C resolution or better for absolute temperature retrievals. Other applications, including agriculture water stress detection, require at least a 1 C resolution. To achieve these levels of accuracy routinely, scientists must perform laboratory and onboard calibration, as well as in-flight vicarious radiometric characterization. A common approach used for in-flight radiometric characterization incorporates a well-calibrated infrared radiometer that is mounted on a bouy and placed on a uniform water body. The radiometer monitors radiant temperature along with pressure, humidity, and temperature measurements of an associated column of atmosphere. On very still waters, however, a buoy can significantly distrub these measurements. Researchers at NASA's Stennis Space Center (SSC) have developed a novel approach of using an uncooled infrared camera mounted on a boom to quantify buoy effects. Another critical aspect of using buoy-mounted infrared radiometers is the need for extensive laboratory characterization of the instruments' radiometric sensitivity, field of view, and spectral response. Proper surface temperature retrieval also requires detailed knowledge of both the upward emission and the reflected sky emission. Recent work at SSC has demonstrated that the use of a polarization-based radiometer operating at the Brewster angle can greatly simplify temperature retrieval as well as improve overall accuracy.

Ryan, Robert↗

Microphysical Characterization of Ice in Hurricane Erin for Wideband Passive Microwave Comparisons

In order to better understand the characteristics of frozen hydrometeors in hurricane systems, computed brightness temperatures were compared with observations of Hurricane Erin from CAMEX-4 radiometers on the ER-2 aircraft. These wideband observations ranged from 10.7 to 183 plus or minus 10 GHz. In order to initialize the cloud profiles used in the radiative transfer calculations, radar reflectivities from an ER-2 instrument were converted to mass contents at specified height levels. Dropsonde data from the ER-2 and modeled Hurricane Andrew data were used to generate profiles of temperature, pressure, and relative humidity and to provide surface wind speed and ocean temperature. Four different ice (size and density) parameterizations were used to compute brightness temperature values. The comparisons between the calculated and observed brightness temperatures show that in general the Grenfell and Warren particle size distribution does the best job of matching the observations for most of the high frequencies. These high frequencies (greater than or equal to 85 GHz) are particularly sensitive to frozen particles. The Sehkon and Srivastava particle size distribution produced brightness temperatures that were too cold in most cases. On the other hand, the fluffy snow particle parameterizations with and without a melting layer produced brightness temperatures that were much warmer than the observations at these high frequencies. All low frequency calculations track the observations well except in the eye of Hurricane Erin where the surface wind speed and/or near surface temperatures were not properly adjusted to warm the brightness temperature calculations to values closer to the observations. Overall, this work shows that selecting a proper ice particle parameterization can be difficult and additional in situ measurements are needed to define appropriate parameterizations.

Skofronick-Jackson, G.↗

GPS=A Good Candidate for Data Assimilation?

The Global Positioning System (GPS) enables positioning anywhere about our planet. The microwave signals sent by the 24 transmitters are sensitive to the atmosphere. Using the radio occultation technique, it is possible to perform soundings, with a Low Earth Orbiter (700 km) GPS receiver. The insensitiveness to clouds and aerosols, the relatively high vertical resolution (1.5 km), the self-calibration and stability of the GPS make it a priori a potentially good observing system candidate for data assimilation. A low-computing cost simple method to retrieve both temperature and humidity will be presented. Comparisons with radiosonde show the capability of the GPS to resolve the tropopause. Options for using GPS for data assimilation and remaining issues will be discussed.

Poli, P.↗