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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Water-vapor absorption line measurements in the 940-nm band by using a Raman-shifted dye laser

We report water-vapor absorption line measurements that are made by using the first Stokes radiation (930-982 nm) with HWHM 0.015/cm generated by a narrow-linewidth, tunable dye laser. Forty-five absorption line strengths are measured with an uncertainty of 6 percent and among them are fourteen strong lines that are compared with previous measurements for the assessment of spectral purity of the light source. Thirty air-broadened linewidths are measured with 8 percent uncertainty at ambient atmospheric pressure with an average of 0.101/cm. The lines are selected for the purpose of temperature-sensitive or temperature-insensitive lidar measurements. Results for these line strengths and linewidths are corrected for broadband radiation and finite laser linewidth broadening effects and compared with the high-resolution transmission molecular absorption.

Chu, Zhiping↗
NASA NTRS1976

Adequacy of classical inverse bremsstrahlung theory for low-temperature plasmas

The authors examine those plasma heating conditions under which a theory more accurate than the classical inverse bremsstrahlung theory should be used to predict absorption coefficients when laser energy is injected into the plasma. A correlation plot for measured absorption coefficients at three laser wavelengths versus those calculated by quantum mechanical theory yields a correlation coefficient for the least-squares fit of 0.994. A plot of the ratio of the quantum-mechanically corrected electron ion inverse bremsstrahlung absorption coefficient to that calculated by classical methods versus plasma temperature shows that at around 20 eV and above the differences between classical and quantum predictions are negligible, but significant errors could arise from application of classical theories to lower-temperature plasmas. Some recent experiments in the literature are shown to be worthy of reinterpretation in this light.

Billman, K. W.↗
NASA NTRS1995

Off-line-locked laser diode species monitor system

An off-line-locked laser diode species monitor system includes: reference means for including at least one known species having a first absorption wavelength; a laser source for irradiating the reference means and at least one sample species having a second absorption wavelength differing from the first absorption wavelength by a predetermined amount; means for locking the wavelength of the laser source to the first wavelength of the at least one known species in the reference means; a controller for defeating the means for locking and for displacing the laser source wavelength from said first absorption wavelength by said predetermined amount to the second absorption wavelength; and a sample detector device for determining laser radiation absorption at the second wavelength transmitted through the sample to detect the presence of the at least one sample species.

Lee, Jamine↗
NASA NTRS1981

Laser remote sensing of atmospheric temperature by observing resonant absorption of oxygen

A dual-frequency system is used to demonstrate the measurement of atmospheric temperature, through laser energy absorption monitoring at the center of an O2 resonant absorption line near 770 nm. It is shown that the average temperature of a 1 km path can be determined within 1.0 C, with a noise level of 0.3 C. An iterative algebraic expression for this method was developed, and is shown to be applicable in the troposphere; the effects of pressure and humidity on temperature determination were made clear by the algorithm and found to be small near the earth's surface.

Kalshoven, J. E., Jr.↗
NASA NTRS1978

A new concept for solar pumped lasers

A new approach is proposed in which an intermediate body heated by sunlight is used as the pumping source for IR systems, i.e., concentration solar radiation is absorbed and reradiated via an intermediate blackbody. This body is heated by focused sunlight to a high temperature and its heat losses are engineered to be small. The cooled laser tube (or tubes) is placed within the cavity and is pumped by it. The advantage is that the radiation spectrum is like a blackbody at the intermediate temperature and the laser medium selectively absorbs this light. Focusing requirements, heat losses, and absorption bandwidths of laser media are examined, along with energy balance and potential efficiency. The results indicate that for lasers pumped through an IR absorption spectrum, the use of an intermediate blackbody offers substantial and important advantages. The loss in radiative intensity for optical pumping by a lower-temperature body is partly compensated by the increased solid angle of exposure to the radiative environment.

Christiansen, W. H.↗
NASA NTRS1983

Experimental comparison of heterodyne and direct detection for pulsed differential absorption CO2 lidar

A pulsed dual-wavelength dual-CO2-laser differential-absorption lidar (DIAL) system has been developed which permits simultaneous heterodyne and direct detection of the same lidar returns. This system has been used to make an experimental comparison of the SNRs and statistical and temporal characteristics of the DIAL returns from several topographic targets. These results were found to be in general agreement with theory and were used to quantify the relative merits of the two detection techniques. The measured parameter values were applied to an analytical treatment to predict system trade-offs for the remote sensing of atmospheric species, with application to both path-averaged and range-resolved measurements.

Killinger, D. K.↗
NASA NTRS1976

Spectroscopic studies and analysis of the laser states of Nd/3+/ in YVO4

Polarized absorption and dye-laser excited fluorescence spectra of Nd/3+/ in the Y(3+) site of yttrium orthovanadate at 85 and 300 K are presented and analyzed. The absence of allowed transitions and the unusual concentration of line strength into one transition in pi polarization within a given line group is shown by the Judd-Ofelt theory to be a consequence of the D2d symmetry of the site and ion placements in the unit cell. An energy level scheme giving level positions, level identities, and observed transitions is presented. The principal laser line in this group at about 10640.9 A was found to be predominately pi polarized and to have a cross section of 30 x 10 to the 19th/sq cm, which is 4.6 times larger than the laser transition of Nd/3+/ in YAG.

Pappas Yaney, P.↗
NASA NTRS1977

Analysis of diffential absorption lidar technique for measurements of anhydrous hydrogen chloride from solid rocket motors using a deuterium fluoride laser

An active optical technique (differential absorption lidar (DIAL)) for detecting, ranging, and quantifying the concentration of anhydrous HCl contained in the ground cloud emitted by solid rocket motors (SRM) is evaluated. Results are presented of an experiment in which absorption coefficients of HCl were measured for several deuterium fluoride (DF) laser transitions demonstrating for the first time that a close overlap exists between the 2-1 P(3) vibrational transition of the DF laser and the 1-0 P(6) absorption line of HCl, with an absorption coefficient of 5.64 (atm-cm) to the -1 power. These measurements show that the DF laser can be an appropriate radiation source for detecting HCl in a DIAL technique. Development of a mathematical computer model to predict the sensitivity of DIAL for detecting anhydrous HCl in the ground cloud is outlined, and results that assume a commercially available DF laser as the radiation source are presented.

Bair, C. H.↗
NASA NTRS1977

Infrared heterodyne spectroscopy of atmospheric ozone

The absorption spectrum of atmospheric ozone is measured within a 1/cm region at 1100/cm, using an IR heterodyne detector (spectrometer with CO2 local oscillator) developed for astronomical work. Absorption spectra obtained by passing radiation from the tunable diode laser through an absorption cell, heterodyne spectra of atmospheric ozone, and a predicted atmospheric spectrum are compared. Water vapor absorbing in the region of interest (1100/cm) is also considered. Preliminary results encourage the use of diode laser local oscillators in tunable heterodyne detector systems for spectroscopy of atmospheric ozone and remote high-resolution spectroscopy of atmospheric constituents and pollutants.

Frerking, M. A.↗
NASA NTRS1987

Titanium-doped sapphire laser research and design study

Three main topics were considered in this study: the fundamental laser parameters of titanium-doped sapphire, characterization of commercially grown material, and design of a tunable, narrow-linewidth laser. Fundamental parameters investigated included the gain cross section, upper-state lifetime as a function of temperature and the surface-damage threshold. Commercial material was found to vary widely in the level of absorption of the laser wavelength with the highest absorption in Czochralski-grown crystals. Several Yi:sapphire lasers were constructed, including a multimode laser with greater than 50mJ of output energy and a single-transverse-mode ring laser, whose spectral and temporal characteristics were completely characterized. A design for a narrow-linewidth (single-frequency) Ti:sapphire laser was developed, based on the results of the experimental work. The design involves the use of a single-frequency, quasi-cw master oscillator, employed as an injection source for a pulsed ring laser.

Moulton, Peter F.↗
NASA NTRS1990

Accurate frequency of the 119 micron methanol laser from tunable far-infrared absorption spectroscopy

High-accuracy absorption spectroscopy of CH3OH in the far infrared is discussed. In addition to 22 transitions in the ground state, the frequency of the (n, tau, J, K), (0, 1, 16, 8) to (0, 2, 15, 7) transition in the nu5 excited vibrational level, which is responsible for the laser emission at 119 microns, was measured. The measured frequency is 2,522,782.57(10) MHz at zero pressure, with a pressure shift of 6.1(32) kHz/Pa (0.805/420/ MHz/torr). An accurate remeasurement of the laser emission frequency has also been performed, and the results are in good agreement.

Inguscio, M.↗
NASA NTRS2018

2.0 um Wavelength Injection Seed Semiconductor Laser for Lidar Transmitter for Global-Scale Measurements of CO2

Many of the high accuracy Earth science survey missions are planned to use laser-based remote sensing instruments. The 2-μm laser wavelength is of particular interest due to the presence of many CO2 and H20 absorption lines in its vicinity1. Transmitter architectures are typically composed of an optically pumped, frequency-stable, solid-state seed laser and a high-power optical amplifier.2, 3 Taking advantage of the reliability and relative simplicity of semiconductor lasers, this architecture can substantially improve by replacing the solid-state light source with semiconductor lasers of comparable performance. This approach will greatly improve the system reliability, and will simplify instrument integration and space qualification. There are currently very limited semiconductor lasers operating in the 2-m range with performance satisfactory enough for use as an injection seed in a laser absorption spectrometer. Optimally, seed lasers producing greater than 50 mW of continuous-wave (CW), with frequency jitter of less than 1 MHz are desired to reliably resolve the CO2 absorption lines near 2-µm. In this paper, we report the demonstration of high-power, single-longitudinal-mode laterally coupled distributed feedback (LC-DFB) lasers at 2.05 µm wavelength. We measured more than 80 mW of CW power at -10 ºC for devices with a 4-µm-wide ridge and 2-mm-long cavity.

Fradet, Mathieu↗
NASA NTRS1981

Theoretical studies of solar-pumped lasers

Estimates of the absorption and emission characteristics of molecules required to develop materials for solar-pumped lasers are addressed. These characteristics are described in terms of the Franck Condon factors, which are calculated from the molecular wave functions. Wave functions for vibrational levels in the lower and upper electronic states of I2 and NSe are calculated numerically and methods of checking errors discussed. Errors arise when the vibrational quantum numbers are high; but, using a calculated rather than measured value of the dissociation energy, wave functions up to the fiftieth vibrational level are obtained. A numerical method of evaluating the wave functions is given, which should be more accurate in the region of electronic transitions during absorption. Franck Condon factors, plotted versus the wavelength of the absorbed photons, are shown, and a check on the Franck Condon factors is made using the vibrational sum rule.

Harries, W. L.↗
NASA NTRS1983

A survey of laser and selected optical systems for remote measurement of pollutant gas concentrations

Applications of the Differential Absorption Lidar (DIAL) technique to the remote sensing of pollutant gases are surveyed. In the DIAl technique, the differential absorption of two laser beams reflected back to a receiver from a target determines the concentration of the gas being studied. The types of instruments available are considered in detail: dye lidar (to measure nitrogen dioxide, sulfur dioxide, and ozone); carbon dioxide laser (for ozone, ethylene, ammonia, and hydrazine), helium-neon laser (for methane); hydrogen fluoride laser (for HF); and tunable diode laser (for nitric oxide and carbon monoxide). DIAL instruments are compared with other optical remote sensors such as Fourier-transform infrared spectrometers, correlation spectrometers (COSPEC and GASPEC), and grating spectrometers; and criteria for the selection of an appropriate gas measuring system are suggested. Laser and other optical remote sensors are found to be cost effective in many cases, despite the fact that they are more costly than point-monitoring systems.

Grant, W. B.↗
NASA NTRS1990

Novel laser gain and time-resolved FTIR studies of photochemistry

Several techniques are discussed which can be used to explore laboratory photochemical processes and kinetics relevant to planetary atmospheres; these include time-resolved laser gain-versus-absorption spectroscopy and time-resolved Fourier transform infrared (FTIR) emission studies. The laser gain-versus-absorption method employed tunable diode and F-center lasers to determine the yields of excited photofragments and their kinetics. The time-resolved FTIR technique synchronizes the sweep of a commercial FTIR with a pulsed source of light to obtain emission spectra of novel transient species in the infrared. These methods are presently being employed to investigate molecular photodissociation, the yields of excited states of fragments, their subsequent reaction kinetics, Doppler velocity distributions, and velocity-changing collisions of translationally fast atoms. Such techniques may be employed in future investigations of planetary atmospheres, for example to study polycyclic aromatic hydrocarbons related to cometary emissions, to analyze acetylene decomposition products and reactions, and to determine spectral features in the near infrared and infrared wavelength regions for planetary molecules and clusters.

Leone, Stephen R.↗
NASA NTRS1987

Atmospheric remote sensing of water vapor, HCl and CH4 using a continuously tunable Co:MgF2 laser

A differential-absorption lidar system has been developed which uses a continuously tunable (1.5-2.3 micron) cobalt-doped magnesium fluoride laser as the radiation source. Preliminary atmospheric measurements of water vapor, HCl, and CH4 have been made with this system, including both path-averaged and ranged-resolved DIAL measurements at ranges up to 6 and 3 km, respectively.

Menyuk, Norman↗