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At least 361 records · Page 20

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NASA NTRS1986

Diode laser measurements of line strengths and widths in the 4.5-micron bands of N2O

Line-strength measurements in the N2O nu3-fundamental region using a tunable diode-laser spectrometer. From these measurements and the Herman-Wallis factor determined by Boissy et al. (1975), the nu-3-fundamental band strength is found to be 1203 + or - 22 per sq cm atm at 297 K. Line-broadening parameters for two nu-3-fundamental lines were determined using nitrogen (N2) as the broadening gas. Measured strengths and N2 line-broadening parameters for several hot-band lines are also presented.

Lowenstein, M.↗

NASA NTRS1983

Line strength measurements using diode lasers - The nu2 band of H2S

The strengths of 94 lines in the nu2 band of H2S have been measured with an average accuracy of 3 percent using a tunable diode laser. The line strengths are determined from the peak absorption of nearly Doppler-shaped lines. A detailed error analysis of this measurement method is given. Ratios of the measured line strengths to strengths calculated assuming no vibration-rotation interactions are shown to range from as low as 0.057 to as high as 4.71.

Strow, L. L.↗

NASA NTRS1988

Response function of a tunable diode laser spectrometer from an iterative deconvolution procedure

A deconvolution procedure commonly used for resolution enhancement of spectra has been applied to the determination of the response function of a tunable diode laser spectrometer. The method is sufficiently fast and simple for routine application when correcting for nonnegligible instrumental broadening. Absolute linestrengths of CH4 in the 1327/cm region and line positions of HNO3 in the 1335/cm region, measured with the aid of the deconvolution technique, are reported here.

May, Randy D.↗

NASA NTRS1987

Performance measurements of a diode laser optical communications link with Q = 4 PPM signaling

The theoretical and measured performance characteristics of a direct detection optical communication system are reported. The system consisted of a semiconductor diode laser, silicon avalanche photodiode detector, and used Q = 4 optical pulse position modulation signaling to transmit binary source data at a rate of 25 megabits/sec. Operation at a receiver bit error probability of 10 to the -6th was demonstrated at received signal energies corresponding to an average of 160 detected photons per PPM symbol, or 80 photons per source bit.

Sun, X.↗

NASA NTRS2002

In Situ Measurements of N2O and CH4 During SOLVE on the ER-2 Using a New Tunable Diode Laser Instrument

This report is the final report for Cooperative Agreement NCC2-1105: 'In Situ Measurements of N2O and CH4 during SOLVE on the ER-2 using a new tunable diode laser instrument.' The tasks outlined in the proposal are listed below with a brief comment. The publications and the conference presentations are listed. Finally the important publications are attached. The Cooperative Agreement made possible a research effort to produce high precision and high accuracy in situ measurements of methane and nitrous oxide on the ER-2 during the SOLVE field campaign and to analyze these measurements. These measurements of CH4 and N2O were of utmost importance to studies of the ozone losses in the Arctic winter and spring. The concentrations measured over a large spatial and temporal range allowed the separation of the dynamical and chemical ozone loss. The most important results of the SOLVE program were contained in two scientific papers. This Cooperative Agreement allowed the participation of the Argus instrument in the program and the analysis of the data.

Jost, Hansjurg↗

NASA NTRS2002

Calibration and Data Retrieval Algorithms for the NASA Langley/Ames Diode Laser Hygrometer for the NASA Trace-P Mission

This paper describes the procedures and algorithms for the laboratory calibration and the field data retrieval of the NASA Langley / Ames Diode Laser Hygrometer as implemented during the NASA Trace-P mission during February to April 2000. The calibration is based on a NIST traceable dewpoint hygrometer using relatively high humidity and short pathlength. Two water lines of widely different strengths are used to increase the dynamic range of the instrument in the course of a flight. The laboratory results are incorporated into a numerical model of the second harmonic spectrum for each of the two spectral window regions using spectroscopic parameters from the HITRAN database and other sources, allowing water vapor retrieval at upper tropospheric and lower stratospheric temperatures and humidity levels. The data retrieval algorithm is simple, numerically stable, and accurate. A comparison with other water vapor instruments on board the NASA DC-8 and ER-2 aircraft is presented.

Podolske, James R.↗

NASA NTRS1987

Tunable diode laser measurements of absolute linestrengths in the HNO3 band near 5.8 microns

Absolute line strengths of selected lines in the nu 2 band of HNO3 have been measured using a tunable diode laser spectrometer operating in a sweep integration mode. The direct measurement technique has been employed to obtain line intensities at 296 K for 22 isolated lines in the 1720-1725/cm region. The reported line strengths have estimated uncertainties of 4 percent, a significant portion of this uncertainty arising from spectral interference from hot band transitions. From these line-strength measurements, an integrated band intensity of 1375/sq cm per atm at 296 K is inferred.

May, Randy D.↗

NASA NTRS2011

Supersonic Mass Flux Measurements via Tunable Diode Laser Absorption and Non-Uniform Flow Modeling

Measurements of mass flux are obtained in a vitiated supersonic ground test facility using a sensor based on line-of-sight (LOS) diode laser absorption of water vapor. Mass flux is determined from the product of measured velocity and density. The relative Doppler shift of an absorption transition for beams directed upstream and downstream in the flow is used to measure velocity. Temperature is determined from the ratio of absorption signals of two transitions (lambda(sub 1)=1349 nm and lambda(sub 2)=1341.5 nm) and is coupled with a facility pressure measurement to obtain density. The sensor exploits wavelength-modulation spectroscopy with second-harmonic detection (WMS-2f) for large signal-to-noise ratios and normalization with the 1f signal for rejection of non-absorption related transmission fluctuations. The sensor line-of-sight is translated both vertically and horizontally across the test section for spatially-resolved measurements. Time-resolved measurements of mass flux are used to assess the stability of flow conditions produced by the facility. Measurements of mass flux are within 1.5% of the value obtained using a facility predictive code. The distortion of the WMS lineshape caused by boundary layers along the laser line-of-sight is examined and the subsequent effect on the measured velocity is discussed. A method for correcting measured velocities for flow non-uniformities is introduced and application of this correction brings measured velocities within 4 m/s of the predicted value in a 1630 m/s flow.

Chang, Leyen S.↗

NASA NTRS1985

Remote displacement measurements using a laser diode

A technique for measuring displacements remotely to minimum distances of 8 mm with a resolution of 2 microns is described. A dynamic interferometer method is employed using a frequency-ramped laser diode. A direct measurement of the period of the resulting beat signal is used to determine the displacement.

Beheim, G.↗

NASA NTRS1987

Optical communication with semiconductor laser diodes

A 25 megabit/sec direct detection optical communication system that used Q=4 PPM signalling was constructed and its performance measured under laboratory conditions. The system used a single-mode AlGaAs laser diode transmitter and low noise silicon avalanche photodiode (APD) photodetector. Comparison of measured performance with the theoretical revealed that modeling the APD output as a Gaussian process under conditions of negligible background radiation and low (less than 10 to the -12 power A) APD bulk leakage currents leads to substantial underestimates of optimal APD gain to use and overestimates of system bit error probability. A procedure is given to numerically compute system performance which uses the more accurate Webb's Approximation of the exact Conradi distribution for the APD ouput signal that does not require excessive amounts of computer time (a few minutes of VAX 8600 CPU time per system operating point). Examples are given which illustrate the breakdown of the Gaussian approximation in assessing system performance. This system achieved a bit error probability of 10 to the -6 power at a received signal energy corresponding to an average of 60 absorbed photons/bit and optimal APD gain of 700.

Davidson, F.↗

NASA NTRS1986

Application of an InGaAsP diode laser to probe photodissociation dynamics - I(asterisk) quantum yields from n- and i-C3F7I and CH3I by laser gain vs absorption spectroscopy

Initial measurements on I-asterisk yields of alkyl iodides at 266 nm are reported using gain vs. absorption spectroscopy with an InGaAsP diode probe laser. The results are 102 percent + or - 4 percent, 102 percent + or - 7 percent, and 73 percent + or - 4 percent for n-C3F7I, i-C3F7I, and CH3I respectively. Future prospects for the development of diode laser systems and for their use in dynamical studies are discussed.

Hess, W. P.↗

NASA NTRS1991

Tunable diode laser absorption sensor for temperature and velocity measurements of O2 in air flows

A fast and nonintrusive velocity and temperature diagnostic based on oxygen absorption is presented. The system uses a GaAlAs tunable diode laser, ramped and modulated in wavelength at high frequency. Detection is performed at twice the modulating frequency, leading to second harmonic absorption lineshapes. Velocity is inferred from the wavelength shift of the absorption line center due to the Doppler effect. Temperature is determined by comparing experimental and calculated lineshapes. Capabilities of the technique for studies of transient high-speed flows are demonstrated in shock tube experiments. Good agreement is obtained with predicted temperatures and velocities when pressure-induced shifts are accounted for.

Philippe, L. C.↗

NASA NTRS1985

Tunable diode laser Stark modulation spectroscopy for rotational assignment of the HNO3 7.5-micron band

The technique of Stark modulation spectroscopy for unraveling and assigning rotationally resolved dense molecular spectra has been employed using a tunable diode laser (TDL) source. Doppler-limited absorption and Stark modulation spectra of the HNO3 7.5-micron band near the 1326/cm band origin are presented with preliminary values of the excited-state rovibrational constants derived from both TDL and Bomem Fourier transform IR spectra.

Webster, C. R.↗

NASA NTRS1991

Multiple Integrated In-Line Diode Lasers

Proposed integrated in-line array of semiconductor lasers intended to provide high reliability and/or long operating lifetime. Multiple integrated collinear semiconductor lasers share common optical waveguide but individually electrically excited. When one device fails, another switched on. Important advantage in systems in which both reliability of diode lasers and alignment of those lasers with other optical components critical.

Connolly, John C.↗

NASA NTRS1983

Stratospheric species measurements with tunable diode laser absorption spectroscopy

A balloon-borne instrument for stratospheric research has been developed with the capability to simultaneously measure several chemically related species in situ, for a full diurnal cycle. The instrument utilizes tunable infrared diode lasers (TDLs) to provide the radiation in selected wavelength regions for sensitive absorption spectroscopy over a one-km round-trip path. The TDL radiation is directed to a remote retroreflector which is lowered 500 m below the instrument gondola. A HeNe laser and co-aligned TV camera with CID imaging are used for retroreflector tracking. Currently the instrument operates with two TDLs, and the capability exists to measure four stratospheric species: NO, NO2, O3, and H2O. The number of operating TDLs can be expanded to four, resulting in the possibility of measuring several additional trace species.

Menzies, R. T.↗

DOE OSTI2025

Longitudinal position dependence of dark line defect growth rate in high-power diode lasers at 790 nm

Using a nondestructive, in situ near-infrared defect imaging technique, we obtained time-resolved images of dark line defect (DLD) growth in the cavities of several high-power 790-nm diode lasers and calculated individual DLD growth rates. A clear longitudinal spatial dependence in the DLD growth rate was observed, in which the DLD growth rate was faster near the anti-reflective (AR) facet. Longitudinal spatial hole burning simulation results indicate that the total photon density increases toward the AR facet, while the carrier density decreases toward the AR facet. Here, these results suggest that photon absorption plays a key role in enhancing DLD growth beyond the contribution of the traditional carrier capture mechanism. Asymmetric DLD growth that was preferentially directed toward the high-reflectivity facet was also observed, providing further support for the role of photon absorption in the growth process. To account for these findings, we propose a photon-accelerated mechanism for the enhancement of DLD growth in which the slower carrier capture process in the traditional recombination-enhanced dislocation glide mechanism is replaced by a faster photon absorption process.

Engineering - Electronic and electrical engineerin↗

NASA NTRS2002

Near-infrared diode laser based spectroscopic detection of ammonia: a comparative study of photoacoustic and direct optical absorption methods

A photoacoustic spectroscopic (PAS) and a direct optical absorption spectroscopic (OAS) gas sensor, both using continuous-wave room-temperature diode lasers operating at 1531.8 nm, were compared on the basis of ammonia detection. Excellent linear correlation between the detector signals of the two systems was found. Although the physical properties and the mode of operation of both sensors were significantly different, their performances were found to be remarkably similar, with a sub-ppm level minimum detectable concentration of ammonia and a fast response time in the range of a few minutes.

NASA Discipline Life Sciences Technologies↗

NASA NTRS1987

Absolute 1* quantum yields for the ICN A state by diode laser gain versus absorption spectroscopy

Absolute I* quantum yields were measured as a function of wavelength for room temperature photodissociation of the ICN A state continuum. The temperature yields are obtained by the technique of time-resolved diode laser gain-versus-absorption spectroscopy. Quantum yields are evaluated at seven wavelengths from 248 to 284 nm. The yield at 266 nm is 66.0 +/- 2% and it falls off to 53.4 +/- 2% and 44.0 +/- 4% at 284 and 248 respectively. The latter values are significantly higher than those obtained by previous workers using infrared fluorescence. Estimates of I* quantum yields obtained from analysis of CN photofragment rotational distributions, as discussed by other workers, are in good agreement with the I* yields. The results are considered in conjunction with recent theoretical and experimental work on the CN rotational distributions and with previous I* yield results.

Hess, Wayne P.↗