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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Magnetic order driven ultrafast phase transition in NdNiO 3

Ultrashort x-ray pulses can be used to disentangle magnetic and structural dynamics and are accordingly utilized here to study the photoexcitation of NdNiO 3 (NNO), a model nickelate exhibiting structural and magnetic dynamics that conspire to induce an insulator-to-metal transition (IMT). Here, during the course of the photoinduced IMT with above-gap excitation, we observe an ultrafast (< 180 fs) quenching of magnetic order followed by a time delayed collapse of the insulating phase probed by x-ray absorption and THz transmission (450 fs) that correlates with the slowest optical phonon mode involved in the structural transition. A simultaneous order-disorder response at the Ni site and displacive response at the Nd site coexist in the ultrafast magnetic response. Crucially, we observe the optical phonon through its coherent coupling with Nd magnetic order, demonstrating that the magnetic and structural degrees of freedom both contribute in driving the IMT. Density functional theory calculations reveal a consistent scenario where optically driven intersite charge transfer drives a collapse of antiferromagnetic order that in turn destabilizes the charge-ordered phase resulting in an IMT. These experiments provide different modalities for the control of electronic phase transitions in quantum materials based on the ultrafast interplay between structural and magnetic orders created by femtosecond photoexcitation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1981

On the power spectral density of quadrature modulated signals

The conventional (no-offset) quadriphase modulation technique suffers from the fact that hardlimiting will restore the frequency sidelobes removed by proper filtering. Thus, offset keyed quadriphase modulation techniques are often proposed for satellite communication with bandpass hardlimiting. A unified theory is developed which is capable of describing the power spectral density before and after the hardlimiting process. Using the in-phase and the quadrature phase channel with arbitrary pulse shaping, analytical results are established for generalized quadriphase modulation. In particular MSK, OPSK or the recently introduced overlapped raised cosine keying all fall into this general category. It is shown that for a linear communication channel, the power spectral density of the modulated signal remains unchanged regardless of the offset delay. Furthermore, if the in phase and the quadrature phase channel have identical pulse shapes without offset, the spectrum after bandpass hardlimiting will be identical to that of the conventional QPSK modulation. Numerical examples are given for various modulation techniques. A case of different pulse shapes in the in phase and the quadrature phase channel is also considered.

Yan, T. Y.↗
NASA NTRS1996

Surface Deformation and Coherence Measurements of Kilauea Volcano, Hawaii, from SIR-C Radar Interferometry

The shuttle imaging radar C/X synthetic aperture radar (SIR-C/X-SAR) radar on board the space shuttle Endeavor imaged Kilauea Volcano, Hawaii, in April and October 1994 for the purpose of measuring active surface deformation by the methods of repeat-pass differential radar interferometry. Observations at 24 cm (L band) and 5.6 cm (C band) wavelengths were reduced to interferograms showing apparent surface deformation over the 6-month interval and over a succession of 1-day intervals in October. A statistically significant local phase signature in the 6-month interferogram is coincident with the Pu'u O'o lava vent. Interpreted as deformation, the signal implies centimeter-scale deflation in an area several kilometers wide surrounding the vent. Peak deflation is roughly 14 cm if the deformation is purely vertical, centered southward of the Pu'u O'o caldera. Delays in the radar signal phase induced by atmospheric refractivity anomalies introduce spurious apparent deformation signatures, at the level of 12 cm peak-to-peak in the radar line-of-sight direction. Though the phase observations are suggestive of the wide-area deformation measured by Global Positioning System (GPS) methods, the atmospheric effects are large enough to limit the interpretation of the result. It is difficult to characterize centimeter-scale deformations spatially distributed over tens of kilometers using differential interferometry without supporting simultaneous, spatially distributed measurements of reactivity along the radar line of sight. Studies of the interferometric correlation of images acquired at different times show that L band is far superior to C band in the vegetated areas, even when the observations are separated by only 1 day. These results imply longer wavelength instruments are more appropriate for studying surfaces by repeat-pass observations.

Rosen, P. A.↗
NASA NTRS1973

Instrumentation for one-way satellite PTTI applications

A review of general principles and operational procedures illustrates how the typical passive user and omni receiving antenna can recover Precise Time and Time Interval (PTTI) information from a low altitude navigation satellite system for clock calibration and synchronization. Detailed discussions of concepts and theory of the receiver design are presented. The importance of RF correlation of the received and local PN encoded sequences is emphasized as a means of reducing delay uncertainties of the instrumentation to values compatible with nanosecond to submicrosecond PTTI objectives. Two receiver configurations were fabricated for use in satellite-to-laboratory experiments. In one receiver the delay-locked loop for PN signals synchronization used a dithered amplitude detection process while the second receiver used a complex sums phase detection method for measurement of delay error. The necessity for compensation of Doppler shift is discussed. Differences in theoretical signal acquisition and tracking performance of the design concepts are noted.

Osborne, A. E.↗
NASA NTRS1999

Relativistic Electrons Observed at UARS and the Interpretation of their Storm-Associated Intensity Variations

The High Energy Particle Spectrometer (HEPS) instrument on the Upper Atmosphere Research Satellite (UARS) provides a database of electron intensities well resolved in energy and pitch-angle. Because of its 57 deg. orbital inclination, UARS encounters with magnetic shells L greater than 2 occur quite far off-equator (B/B (sub 0) greater than 9), corresponding to equatorial pitch angle alpha (sub 0) greater than 20 deg. Data acquired by HEPS (October 1991 through September 1994) span the declining phase of Solar Cycle 22. To reveal the storm-associated time dependence of relativistic electron intensities over the wide range of energies (50 keV to 5 MeV) covered by HEPS, we divide the daily average of the measured spectrum at a given L value (bin width = 0.25) by the corresponding 500-day average and plot the results with a color scale that spans only 2.5 decades. The data show that our off-equatorial electron intensities typically increase with time after the end of recovery phase (not during main phase or recovery phase) of each geomagnetic storm. The delay in off-equatorial energetic electron response and the subsequent lifetime of the corresponding electron flux enhancement seem to increase with particle energy above 300 keV. The trend below 300 keV seems to be opposite, such that the delay varies inversely with electron energy. Our working hypothesis for interpretation is that stormtime radial transport tends to increase the phase-space densities of trapped relativistic electrons but typically leads to a flux increases at specified energies only as the current (as indicated by Dst) decays. Flux enhancements in early recovery phase are greatest for equatorially mirroring electrons, and to pitch-angle anisotropies are initially large. Subsequent pitch-angle diffusion broadens the flux enhancement to particles that mirror off equator, thus gradually increasing low-altitude electron intensities (as detected by HEPS/UARS) on time scales equal to about 20% of corresponding lifetimes against diffusion into the loss cone. Alternative interpretations will also be examined.

Pesnell, W. D.↗
DOE OSTI2024

Cooper minima in high-Z atoms: effects of correlation and relativity on np photoionization

Abstract Photoionization dipole transition matrix elements pass through a zero or attain a minimum that leaves imprints on photoionization parameters like the cross-section, angular distribution asymmetry parameter, phase shift, and photoionization time delay. This minimum is commonly known as the ‘Cooper minimum’ (CM). The CM, in general, is strongly affected by relativistic and correlation effects. Previous works investigated CM in the 6pand 5psubshell photoionization up toZ= 100 using the single-particle Dirac-Slater (DS) method. The present work extends the earlier work toZup to 120 using more accurate methods; Dirac–Hartree–Fock (DHF) which includes the relativistic effects and exchange correlations, and the relativistic random phase approximation (RRPA) which includes both initial and final state electron-electron correlations along with relativistic effects. In addition to the study of photoionization from the 6pand 5psubshells, the 4psubshell has also been investigated in the present work. To demonstrate the prominent effects in the high-Z atoms, Rn (Z= 86), Ra (Z= 88), No (Z= 102), Cn (Z = 112), Og (Z= 118), and Ubn (Z= 120) are investigated.

Optics↗
NASA NTRS1992

Tracking performance and cycle slipping in the all-digital symbol synchronizer loop of the block 5 receiver

Computer simulated noise performance of the symbol synchronizer loop (SSL) in the Block 5 receiver is compared with the theoretical noise performance. Good agreement is seen at the higher loop SNR's (SNR(sub L)'s), with gradual degradation as the SNR(sub L) is decreased. For the different cases simulated, cycle slipping is observed (within the simulation time of 10(exp 4) seconds) at SNR(sub L)'s below different thresholds, ranging from 6 to 8.5 dB, comparable to that of a classical phase-locked loop. An important point, however, is that to achieve the desired loop SNR above the seemingly low threshold to avoid cycle slipping, a large data-to-loop-noise power ratio, P(sub D)/(N(sub 0)B(sub L)), is necessary (at least 13 dB larger than the desired SNR(sub L) in the optimum case and larger otherwise). This is due to the large squaring loss (greater than or equal to 13 dB) inherent in the SSL. For the special case of symbol rates approximately equaling the loop update rate, a more accurate equivalent model accounting for an extra loop update period delay (characteristic of the SSL phase detector design) is derived. This model results in a more accurate estimation of the noise-equivalent bandwidth of the loop.

Aung, M.↗
DOE OSTI2026

In-situ synchrotron X-ray investigation of phase evolution in gas atomized powder enabling manufacturing of nanoscale oxide-dispersion strengthened ferritic steels

Here, we present an investigation of Fe-14Cr-3W-0.4Y-0.4Zr-0.18Ti (wt.%) as a reduced-activation oxide-dispersion strengthened (ODS) ferritic steel, an alternative to the “14YWT” structural alloys designed for nuclear energy applications. Gas atomization reaction synthesis (GARS) was used to produce these Zr-modified powders with a non-equilibrium (metastable) phase that enable a heat treatment (delayed) route for producing nanoscale oxide-dispersion strengthening. In situ synchrotron X-ray diffraction and transmission electron microscopy were used to analyze phase evolution as a function of temperature and time, revealing formation of highly dispersed oxide nanoprecipitate phases at temperatures above those needed for powder consolidation and shaping of components. This would allow fabrication of net-shape parts using conventional powder-processing methods prior to thermal activation of a reaction producing nanocrystalline Y-(Ti, Zr)-O particles, with a size of 20 ± 7 nm. These results can inform processing of tubes, cladding, sheets, and plates for use in advanced fission and fusion reactors.

In-situ synchrotron X-ray diffraction↗
NASA NTRS1992

A gallium-arsenide digital phase shifter for clock and control signal distribution in high-speed digital systems

The design, implementation, testing, and applications of a gallium-arsenide digital phase shifter and fan-out buffer are described. The integrated circuit provides a method for adjusting the phase of high-speed clock and control signals in digital systems, without the need for pruning cables, multiplexing between cables of different lengths, delay lines, or similar techniques. The phase of signals distributed with the described chip can be dynamically adjusted in eight different steps of approximately 60 ps per step. The IC also serves as a fan-out buffer and provides 12 in-phase outputs. The chip is useful for distributing high-speed clock and control signals in synchronous digital systems, especially if components are distributed over a large physical area or if there is a large number of components.

Fouts, Douglas J.↗
DOE OSTI2021

Medium and Heavy Duty Vehicle Powertrain Electrification and Fleet Demonstration

The Contract Award Grant # EE0007513 dated 2 June, 2016 is for the design, development and demonstration of medium duty package delivery vehicles that will result in a 100% increase in fuel economy as measured in miles per gallon. The project was proposed in 3 phases over two budget periods. The Phases were: 1. Modeling and Simulation – This phase was completed and formed the basis of the specifications for the design and build of the physical systems. The modeling and simulation was conducted by AVL and used real world package delivery routes that AVL mapped. The motors, battery pack, range extender and balance of plant support systems were modeled and iterated until a system with the desired fuel economy improvement was realized. Early design of the major subsystems using the actual vehicle space constraints was also completed. This phase was successfully completed in May of 2017. 2. 1st Build and FE Confirmation - This phase was completed and resulted in the final design, release, procurement and build of all major vehicle systems for commissioning into the first vehicle. The work was a partnered effort between McLaren and AVL. McLaren built the eAxle system while AVL built the range extender and integrated the range extender, battery and balance of plant sub-systems into the first vehicle with a control system to make it operate. Prior to the end of this phase a real world HIL system test gave evidence that the fuel economy improvement would be achieved in the real world. This phase was exited with a 7 month delay due mostly to procurement and supply base issues and ended in May, 2018. 3. Final Build and Demonstration - This phase included the final build and commissioning of the four program vehicles and the operation of a demonstration on a set of routes near San Diego California. During this phase, a multitude of issues arose in different systems in the vehicle. These issue resolution exercises were quite complex and caused repeated delays but were all successfully completed. It should also be noted that an early commercialization analysis resulted in the conclusion that the complexity of the system would not make it cost effective, leading to the start of a follow-on design that used newly available component technologies to specify a more cost effective system. This design will be repurposed and put into demonstration on a separately (non-DOE) funded program. It was decided and agreed with DOE that this phase should be considered completed. The knowledge and know-how gained on this program has been incorporated into and transferred to the new program. This phase and the entire program was considered closed on June 1, 2021.

33 ADVANCED PROPULSION SYSTEMS↗
NASA NTRS1999

Spot Radiative Ignition and Subsequent Three Dimensional Flame Spread Over Thin Cellulose Fuels

Spontaneous radiative ignition and transition to flame spread over thin cellulose fuel samples was studied aboard the USMP-3 STS-75 Space Shuttle mission, and in three test series in the 10 second Japan Microgravity Center (JAMIC). A focused beam from a tungsten/halogen lamp was used to ignite the center of the fuel sample while an external air flow was varied from 0 to 10 cm/s. Non-piloted radiative ignition of the paper was found to occur more easily in microgravity than in normal gravity. Ignition of the sample was achieved under all conditions studied (shuttle cabin air, 21%-50% O2 in JAMIC), with transition to flame spread occurring for all but the lowest oxygen and flow conditions. While radiative ignition in a quiescent atmosphere was achieved, the flame quickly extinguished in air. The ignition delay time was proportional to the gas-phase mixing time, which is estimated using the inverse flow rate. The ignition delay was a much stronger function of flow at lower oxygen concentrations. After ignition, the flame initially spread only upstream, in a fan-shaped pattern. The fan angle increased with increasing external flow and oxygen concentration from zero angle (tunneling flame spread) at the limiting 0.5 cm/s external air flow, to 90 degrees (semicircular flame spread) for external flows at and above 5 cm/s, and higher oxygen concentrations. The fan angle was shown to be directly related to the limiting air flow velocity. Despite the convective heating from the upstream flame, the downstream flame was inhibited due to the 'oxygen shadow' of the upstream flame for the air flow conditions studied. Downstream flame spread rates in air, measured after upstream flame spread was complete and extinguished, were slower than upstream flame spread rates at the same flow. The quench regime for the transition to flame spread was skewed toward the downstream, due to the augmenting role of diffusion for opposed flow flame spread, versus the canceling effect of diffusion at very low cocurrent flows.

Olson, Sandra L.↗
NASA NTRS1987

Turbulence as a contributor to intermediate energy storage during solar flares

Turbulence is considered as a method for converting the energy observed as mass motions during the impulsive phase into thermal energy observed during the gradual phase of solar flares. The kinetic energy of the large-scale eddies driven by the upflowing material continuously cascades to smaller scale eddies until viscosity is able to convert it into thermal energy. The general properties of steady state, homogeneous, fluid turbulence is a nonmagnetic plasma and the properties of turbulent decay are reviewed. The time-dependent behavior of the velocities and energies observed by the X-Ray Polychromator (XRP) instrument on the SMM during the November 5, 1980 flare are compared with the properties of turbulence. This study indicates that turbulence may play a role in flare energies and may account for a fraction of the total amount of thermal energy observed during the gradual phase. The rate at which the observed flare velocities decrease is consistent with the decay of turbulent energy but may be too rapid to account for the entire time delay between the impulsive and gradual phases.

Bornmann, P. L.↗
DOE OSTI2021

FTO regulates myoblast proliferation by controlling CCND1 expression in an m6A-YTHDF2-dependent manner

Highlights: • Silencing FTO delays cell cycle and inhibits cell proliferation. • FTO regulates cell proliferation depending on its m{sup 6}A demethylation activity. • Silencing FTO suppresses CCND1 expression via YTHDF2-mediated mRNA degradation. • Knockdown YTHDF2 eliminates the cell cycle arrest in FTO-deficient cells. N6-Methyladenosine (m{sup 6}A) modification is the most abundant chemical modification in mRNA, and it participates in various biological processes, such as cell differentiation and proliferation. However, little is known about the function of m{sup 6}A demethylase fat mass and obesity-associated (FTO) in myoblast proliferation. Here, we demonstrated that knockdown of FTO can significantly inhibit myoblast proliferation and promote apoptosis. RNA sequencing analysis revealed that a lot of downregulated genes in FTO knockdown cells are associated with cell cycle and apoptosis. Furthermore, silencing FTO drastically decreased cyclin D1 (CCND1) expression through YTHDF2-mediated mRNA degradation, thereby delaying the progression of G1 phase, and leading to impaired myoblast proliferation. These findings unraveled that FTO regulates myoblast proliferation by controlling CCND1 expression in an m{sup 6}A-YTHDF2-dependent manner, which highlights the critical roles of m{sup 6}A modification in myoblast proliferation.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2024

Picosecond volume expansion drives a later-time insulator–metal transition in a nano-textured Mott insulator

There is significant technological interest in developing ever faster switching between different electronic and magnetic states of matter. Manipulating properties at terahertz rates requires accessing the intrinsic timescales of both electrons and associated phonons, which is possible with short-pulse photoexcitation. However, in many Mott insulators, the electronic transition is accompanied by the nucleation and growth of percolating domains of the changed lattice structure, leading to empirical timescales dominated by slowly coarsening dynamics. Here, in this study, we use time-resolved X-ray diffraction and reflectivity measurements to show that the photoinduced insulator-to-metal transition in an epitaxially strained Mott insulating thin film occurs without observable domain formation and coarsening effects, allowing the study of the intrinsic electronic and lattice dynamics. Above a fluence threshold, the initial electronic excitation drives a fast lattice rearrangement, which is followed by a slower electronic evolution into a metastable nonequilibrium state. Microscopic model calculations based on time-dependent dynamical mean-field theory and semiclassical lattice dynamics explain the threshold behaviour and elucidate the delayed onset of the electronic phase transition. This work highlights the importance of combined electronic and structural studies in unravelling the physics of dynamic transitions and the timescales of photoinduced processes. During a photoinduced phase transition, electronic rearrangements are usually faster than lattice ones. Time-resolved measurements now show that the insulator-to-metal transition in a thin-film Mott insulator is preceded by lattice reconfiguration.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Effects of Velocity on Radar Waveforms

A common assumption in pulse-Doppler radar is that when interrogating a point, or point-like target, the received echo waveform is an attenuated and time-delayed, but otherwise faithful facsimile of the transmitted waveform. The effects of a relative line-of-sight velocity between radar and target is often presumed to manifest only as a pulse-to-pulse time delay, usually simplified as a phase shift. However, a significant line-of-sight velocity will also in fact substantially perturb the received waveform even for a single pulse, and may need to be accounted for, and compensated during radar signal processing.

42 ENGINEERING↗
DOE OSTI2020

The 100 pc White Dwarf Sample in the SDSS Footprint

In this work, we present follow-up spectroscopy of 711 white dwarfs within 100 pc, and we present a detailed model atmosphere analysis of the 100 pc white dwarf sample in the Sloan Digital Sky Survey footprint. Our spectroscopic follow-up is complete for 83% of the white dwarfs hotter than 6000 K, where the atmospheric composition can be constrained reliably. We identify 1508 DA white dwarfs with pure hydrogen atmospheres. The DA mass distribution has an extremely narrow peak at 0.59 M ⊙ and reveals a shoulder from relatively massive white dwarfs with M = 0.7–0.9 M ⊙. Comparing this distribution with binary population synthesis models, we find that the contribution from single stars that form through mergers cannot explain the overabundance of massive white dwarfs. In addition, the mass distribution of cool DAs shows a near absence of M > 1 M ⊙ white dwarfs. The pile-up of 0.7–0.9 M ⊙ and the disappearance of M > 1 M ⊙ white dwarfs is consistent with the effects of core crystallization. Even though the evolutionary models predict the location of the pile-up correctly, the delay from the latent heat of crystallization by itself is insufficient to create a significant pile-up, and additional cooling delays from related effects like phase separation are necessary. We also discuss the population of infrared-faint (ultracool) white dwarfs and demonstrate for the first time the existence of a well-defined sequence in color and magnitude. Curiously, this sequence is connected to a region in the color–magnitude diagrams where the number of white dwarfs with a helium-dominated atmosphere is low. This suggests that the infrared-faint white dwarfs likely have mixed H/He atmospheres.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Timing the r -process Enrichment of the Ultra-faint Dwarf Galaxy Reticulum II

The ultra-faint dwarf galaxy Reticulum II (Ret II) exhibits a unique chemical evolution history, with ${72}_{-12}^{+10}$% of its stars strongly enhanced in r-process elements. We present deep Hubble Space Telescope photometry of Ret II and analyze its star formation history. As in other ultra-faint dwarfs, the color–magnitude diagram is best fit by a model consisting of two bursts of star formation. If we assume that the bursts were instantaneous, then the older burst occurred around the epoch of reionization, forming ~80% of the stars in the galaxy, while the remainder of the stars formed ~3 Gyr later. When the bursts are allowed to have nonzero durations, we obtain slightly better fits. The best-fitting model in this case consists of two bursts beginning before reionization, with approximately half the stars formed in a short (100 Myr) burst and the other half in a more extended period lasting 2.6 Gyr. Considering the full set of viable star formation history models, we find that 28% of the stars formed within 500 ± 200 Myr of the onset of star formation. The combination of the star formation history and the prevalence of r-process-enhanced stars demonstrates that the r-process elements in Ret II must have been synthesized early in its initial star-forming phase. We therefore constrain the delay time between the formation of the first stars in Ret II and the r-process nucleosynthesis to be less than 500 Myr. This measurement rules out an r-process source with a delay time of several Gyr or more, such as GW170817.

79 ASTRONOMY AND ASTROPHYSICS↗