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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20

Understanding Anomalous Gas-Phase Peak Shifts in Dip-and-Pull Ambient Pressure XPS Experiments

Dip-and-pull ambient pressure X-ray photoelectron spectroscopy (AP-XPS) holds promise to uncover elementary processes of (photo)electrochemistry. We show, however, that the sample for such experiments should preferably be nonporous and the potential on the surface homogeneous. We carried out dip-and-pull AP-XPS experiments on a hematite thin film sample under the photoelectrochemical oxygen evolution reaction (OER) and find unexpected O 1s core level shifts. Upon electrochemical biasing under simulated solar light illumination, the gas-phase water peak shifted more than the electrolyte peak. To uncover the origin of the unexpected larger shift of the gas-phase peak, we performed electrostatic simulations using COMSOL, to map the potential field in the relevant volume between the sample and the first aperture of the XPS spectrometer. A number of geometric models were considered. We find that when the potential on the sample surface is inhomogeneous, e.g., with ionically isolated electrolyte patches, the gas-phase peak of the spectrum can shift more than the peak due to the electrolyte film. This suggests that at the measured sample position, the local potential was not as set by the potentiostat. Despite this, we find reversible consumption and replenishment of hydroxide in the spectra, which, due to OH– being the reactant of the OER in alkaline electrolyte, makes sense chemically. We propose that this is linked to OH– diffusion across the measured sample position, driven by the potential dependent consumption and replenishment of OH– at the nearby well-connected surface regions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Flexible positioning of a large area detector using an industrial robot

The DIAD beamline for Dual Imaging and Diffraction at Diamond Light Source has opted to use an industrial robot to position its Dectris Pilatus 2M CdTe diffraction detector. This setup was chosen to enable flexible positioning of the detector in a quarter-sphere around the sample position whilst reliably holding the large weight of 139 kg of detector, detector mount and cabling in a stable position. Metrology measurements showed that the detector can be positioned with a linear repeatability of <19.7 µm and a rotational repeatability of <16.3 µrad. The detector position stays stable for a 12 h period with <10.1 µm of movement for linear displacement and <3.8 µrad for rotational displacement. X-ray diffraction from calibration samples confirmed that the robot is sufficiently stable to resolve lattice d-spacings within the instrumental broadening given by detector position and beam divergence.

36 MATERIALS SCIENCE↗

Evaluating the ProtoDUNE-SP Detector Performance to Measure a 6 GeV/c Positive Kaon Inelastic Cross Section on Argon

The ProtoDUNE Single-Phase Liquid Argon Time Projection Chamber \\ (ProtoDUNE-SP LArTPC) is a prototype for the Deep Underground Neutrino Experiment (DUNE), a future long-baseline neutrino oscillation experiment. Based at the CERN Neutrino Platform, ProtoDUNE-SP LArTPC collected data from a charged test beam in the fall of 2018. It then took data of cosmic-ray muons from November 2018 to the summer of 2020. The main goals of the prototype were to measure parameters related to charged particle passage in argon and evaluate the performance of the detector to inform future DUNE Far Detector development. The test beam provided kaons, pions, muons, protons, and electrons to the detector. These particles represent common final state particles in neutrino interactions, therefore providing information to DUNE on modeling charged particles in argon for its neutrino physics program. In addition to neutrino physics, DUNE has proposed an analysis using the DUNE Far Detector module to set limits for proton decay through the decay channel $p\rightarrow K^++\bar{\nu}$. This measurement would require information on kaons in argon, providing ProtoDUNE-SP LArTPC another opportunity to aid DUNE. This thesis describes the calibration of ProtoDUNE-SP and its detector performance, which serves as a benchmark for the performance of the DUNE Far Detector modules. A specific calibration highlighted is the evaluation of the liquid argon purity in the detector. These measurements use cosmic-ray muons reconstructed in the detector that are calibrated and matched to data from scintillator strips external to the TPC, known as the Cosmic Ray Tagger (CRT). The thesis will discuss the algorithms to match the data between the ProtoDUNE-SP LArTPC and the CRT and discuss the liquid argon purity measurements using one of the algorithms. Data sets of calibrated tracks measured the liquid argon contamination as consistently below 100 ppt oxygen equivalent. After these discussions on the ProtoDUNE-SP LArTPC detector, the thesis will present an evaluation of the inclusive inelastic, sometimes referred to as a reactive, cross section on argon of kaons from the ProtoDUNE-SP test beam with an average momentum of 6 GeV/c.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Initial experiments on the end-point control of a flexible one-link robot

The present investigation is concerned with initial experiments regarding a specific unsolved control problem which appeared to be central to advances in the art of robotics. This problem involves the control of a flexible member (one link of a robot system). The position of the end-effector, called the end point or tip, is controlled by measuring that position and using the measurement as a basis for applying control torque to the other end of the flexible member, as for instance, the robot's elbow joint. A description is presented of the features of the first experimental arm which has been made, and an outline is provided of the general strategy for controlling it using its tip sensor and shoulder torquer.

Cannon, R. H., Jr.↗

Improved Angular Uncertainty Estimation for Compton Imagers

Compton imaging is a method for localizing a photon source using Compton scatter events as measured by a position sensitive photon detector. Using the measured interaction positions and energy depositions for a Compton event, a cone can be back projected which represents all possible origin locations for that source photon. Given enough Compton events, the source can be localized via identifying the regions where many of these cones intersect. An illustration of this effect is given in the figure below. The region intersected by the three cones in this case is a likely origin point for the photon source.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Diffusion coefficients estimated from turbulence data measured by the Metrac positioning system in Minneapolis field test

An analysis is presented of the tropospheric turbulence data obtained by the Metrac positioning system, a radio location system which employs the Doppler principle to track inexpensive expendable balloon-borne transmitters. A Minneapolis field test of the Metrac system provided one-second samples of transmitter frequency from balloons tracked by four ground stations for more than an hour. The derivation of diffusion coefficients from the turbulence data was conducted by two methods, yielding highly consistent results.

Gage, K. S.↗

The Solar Constant, Climate, and Some Tests of the Storage Hypothesis

Activity related modulation of the solar constant can have practical consequences for climate only if storage is involved, as opposed to a detailed balance between sunspot blocking and facular reemission. Four empirical tests are considered that might distinguish between these opposing interpretations: monochromatic measurements of positive and negative flux; comparison of modelled and measured irradiance variations; the interpretation of secular trends in irradiance data; and the direct test of an anticipated signal in climate records of surface air temperature. The yet unanswered question of the role of faculae as possible reemitters of blocked radiation precludes a definitive answer, although other tests suggest their role to be minor, and that storage and an 11 year modulation is implicated. A crucial test is the behavior of the secular trend in irradiance in the declining years of the present activity cycle.

Eddy, J. A.↗

Sensitivity of mesoscale-model forecast skill to some initial-data characteristics, data density, data position, analysis procedure and measurement error

The effects of horizontal and vertical data resolution, data density, data location, different objective analysis algorithms, and measurement error on mesoscale-forecast accuracy are studied with observing-system simulation experiments. Domain-averaged errors are shown to generally decrease with time. It is found that the vertical distribution of error growth depends on the initial vertical distribution of the error itself. Larger gravity-inertia wave noise is produced in forecasts with coarser vertical data resolution. The use of a low vertical resolution observing system with three data levels leads to more forecast errors than moderate and high vertical resolution observing systems with 8 and 14 data levels. Also, with poor vertical resolution in soundings, the initial and forecast errors are not affected by the horizontal data resolution.

Warner, Thomas T.↗

First epoch geodetic measurements with the Global Positioning System across the northern Caribbean plate boundary zone

The first geodetic survey across the northern Caribbean plate boundary zone with GPS was conducted in June 1986. Baseline vectors defined by the six-station regional GPS network ranged from 170 to 1260 km in length. Repeatability of independent daily baseline estimates was better than 8 mm plus 1.3 parts in 10 to the 8th of baseline length for horizontal components. The wet tropospheric path delay during the experiment was both high, sometimes exceeding 30 cm at zenith, and variable, sometimes exceeding 5 cm variation over several hours. Successful carrier phase cycle ambiguity resolution (bias fixing) could not be achieved prior to construction of a regional troposphere model. With optimum troposphere treatment and single-day orbital arcs, most biases on baselines were resolved up to about 550 km in length. With multiday orbital arcs most biases in the network were resolved regardless of baseline length. The results suggest that constraints on plate-boundary zone deformation in the Greater Antilles, and on the North America-Caribbean relative plate motion vector, can be obtained with a series of GPS experiments spanning less than 10 and 15 years, respectively.

Dixon, T. H.↗

A scheme for reducing the effect of selective availability on precise geodetic measurements from the Global Positioning System

From March to August 1990, the signals transmitted by the Block II satellites of the GPS were dithered under a policy of 'Selective Availability' (SA). The dithering appears as an about 10 to the -10th deviation of the satellite oscillator frequency, which, when accumulated over several minutes, can produce an error of about 100 cycles in the model for carrier beat phase. Differencing between simultaneously sampling receivers minimizes the error. If, however, the receivers do not sample simultaneously, it is necessary to model the frequency deviation. Such a model is here applied to data collected in March 1990 by TI4100 and Minimac receivers sampling at times separated by 0.92 s. Applying the algorithm significantly improves the rms scatter of the estimated relative position vectors. The rms scatter from a data set including dithered satellites is similar for both simultaneously and nonsimultaneously sampling receivers, a result which indicates that SA can be adequately modeled.

Feigl, Kurt L.↗

Precise determination of earth's center of mass using measurements from the Global Positioning System

Global Positioning System (GPS) data from a worldwide geodetic experiment were collected during a 3-week period early in 1991. Geocentric station coordinates were estimated using the GPS data, thus defining a dynamically determined reference frame origin which should coincide with the earth center of mass, or geocenter. The 3-week GPS average geocenter estimates agree to 7-13 cm with geocenter estimates determined from satellite laser ranging, a well-established technique. The RMS of daily GPS geocenter estimates were 4 cm for x and y, and 30 cm for z.

Vigue, Yvonne↗

HST observations of the core of the globular cluster NGC 6624

We have used the Faint Object Camera (FOC) on the Hubble Space Telescope (HST) to observe three fields near the center of the post-collapse globular cluster NGC 6624 in B and V. We use individual stellar positions and a maximum-likelihood technique to measure a position for the cluster center. We then transfer this position and the position of the x-ray source 4U 1820-30 to right ascension and declination, and correct an error of 1.8 sec in an earlier paper. From star counts, we obtain a density profile, with a power-law cusp of slope -0.84 +/- 0.16. No flat core is evident. We construct color-magnitude diagrams down to the main-sequence turnoff near the cluster center, and more than three magnitudes below the turnoff in the outermost field at r = 28 sec. The former diagram reveals a central population of blue stragglers, which has not previously been observed in this cluster. These blue stragglers are quite similar in specific frequency to those recently observed by HST in the core of 47 Tuc, and their presence adds to the growing evidence of stellar interactions in dense globular-cluster cores.

Sosin, Craig↗

Precise Kinematic Positioning with Simultaneous GPS Pseudorange and Carrier Phase Measurements

This paper investigates three precise kinematic positioning techniques with simultaneous GPS pseudorange and carrier phase measurements. These techniques are simple, efficient, and well suited for real-time positioning applications. A simulation/covariance analysis is carried out comparing the relative performance of these techniques. The analysis indicates that GPS carrier phase measurements significantly strengthen kinematic positioning. When wide-area differential GPS for reducing SA clock errors and GPS ephemeris errors is available, a low Earth orbiting satellite can be positioned to 0.5-0.8 m in accuracy (3-D RSS). The accuracy is superior to positioning with pseudorange measurements alone by a factor of 2 to 3. Relative positioning performance and complexity between the three techniques are compared.

['Kinematic↗

The Low Altitude Plasma Instrument /LAPI/

The Low Altitude Plasma Instrument on the Dynamics Explorer-B spacecraft provides high resolution velocity space measurements of positive ions and electrons from 5 eV to 32 keV and a monitor of electrons with energies above 35 keV. It consists of an array of 15 parabolic electrostatic analyzers spanning 180 deg in angle and two Geiger-Mueller counters mounted on a one-degree of freedom scan platform. The platform is controlled by a magnetometer that allows placement of the array to selected angles with respect to the magnetic field. Each parabolic analyzer simultaneously measures electrons and positive ions. The temporal resolution and energy range of the measurements and the detector complement to be sampled are programmable by ground command

Winningham, J. D.↗

Observing Tsunamis in the Ionosphere Using Ground Based GPS Measurements

Ground-based Global Positioning System (GPS) measurements of ionospheric Total Electron Content (TEC) show variations consistent with atmospheric internal gravity waves caused by ocean tsunamis following recent seismic events, including the Tohoku tsunami of March 11, 2011. We observe fluctuations correlated in time, space, and wave properties with this tsunami in TEC estimates processed using JPL's Global Ionospheric Mapping Software. These TEC estimates were band-pass filtered to remove ionospheric TEC variations with periods outside the typical range of internal gravity waves caused by tsunamis. Observable variations in TEC appear correlated with the Tohoku tsunami near the epicenter, at Hawaii, and near the west coast of North America. Disturbance magnitudes are 1-10% of the background TEC value. Observations near the epicenter are compared to estimates of expected tsunami-driven TEC variations produced by Embry Riddle Aeronautical University's Spectral Full Wave Model, an atmosphere-ionosphere coupling model, and found to be in good agreement. The potential exists to apply these detection techniques to real-time GPS TEC data, providing estimates of tsunami speed and amplitude that may be useful for future early warning systems.

total electron content (TEC)↗

Observing Traveling Ionospheric Disturbances Caused by Tsunamis Using GPS TEC Measurements

Ground-based Global Positioning System (GPS) measurements of ionospheric Total Electron Content (TEC) show variations consistent with atmospheric internal gravity waves caused by ocean tsunamis following two recent seismic events: the American Samoa earthquake of September 29, 2009, and the Chile earthquake of February 27, 2010. Fluctuations in TEC correlated in time, space, and wave properties with these tsunamis were observed in TEC estimates processed using JPL's Global Ionospheric Mapping Software. These TEC estimates were band-pass filtered to remove ionospheric TEC variations with wavelengths and periods outside the typical range of internal gravity waves caused by tsunamis. Observable variations in TEC appear correlated with the tsunamis in certain locations, but not in others. Where variations are observed, the typical amplitude tends to be on the order of 1% of the background TEC value. Variations with amplitudes ~ 0.1 - 0.2 TECU are observable with periods and timing affiliated with the tsunami. These observations are compared to estimates of expected tsunami-driven TEC variations produced by Embry Riddle Aeronautical University's Spectral Full Wave Model, an atmosphere-ionosphere coupling model, and found to be in good agreement in some locations, though there are cases when the model predicts an observable tsunami-driven signature and none is observed. These TEC variations are not always seen when a tsunami is present, but in these two events the regions where a strong ocean tsunami was observed did coincide with clear TEC observations, while a lack of clear TEC observations coincided with smaller tsunami amplitudes. There exists the potential to apply these detection techniques to real-time GPS TEC data, providing estimates of tsunami speed and amplitude that may be useful for early warning systems.

Galvan, David A.↗

Electric field measurements of DC-driven positive streamer coronas using the E-FISH method

This paper reports on electric field measurements, using the electric field-induced second harmonic (E-FISH) method, sampling the spatial structure and temporal development of DC-driven positive streamer coronas in atmospheric-pressure air at relevant timescales to examine the self-pulsating behavior of the discharge. The discharge is triggered from a point-to-plate geometry and consists of transient coronas, which bridge the inter-electrode gap and pulsate at about 3 kHz, superimposed with a persisting glow corona. The measurements presented challenge the phenomenological explanation for the pulsations based on field recovery at the anode driven by the evacuation of positive ions by electric drift effects and hint at a propagating wave-like feature from the plate-cathode to the tip-anode.

42 ENGINEERING↗