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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Evidence of plasma‐driven decomposition of common plastics exposed to an atmospheric nonthermal discharge

Abstract A nonthermal, pulsed spark discharge is applied to three polymer powders in Ar and Ar– gas mixtures. Hydrogen is introduced to assess plasma‐driven decomposition. Gaseous decomposition products, including methane, acetylene, and ethylene, are observed with Fourier‐transform infrared (FTIR). Surface modifications are observed on the residual polymer via attenuated total internal reflection‐FTIR. Time‐averaged rotational, vibrational, and excitation temperatures are characterized in the discharge. The plasma density is found to be around , with rotational and vibrational temperatures ranging from 1500 to 2200 K and an excitation temperature of 1–2 eV. While spark properties did not change with either gas composition or polymer composition, it was determined that the addition of hydrogen promoted higher concentrations of gaseous phase products (promoting hydrogenolysis).

36 MATERIALS SCIENCE↗
DOE OSTI2020

Experimental and theoretical evidence for hydrogen doping in polymer solution-processed indium gallium oxide

The field-effect electron mobility of aqueous solution-processed indium gallium oxide (IGO) thin-film transistors (TFTs) is significantly enhanced by polyvinyl alcohol (PVA) addition to the precursor solution, a >70-fold increase to 7.9 cm 2 /Vs. To understand the origin of this remarkable phenomenon, microstructure, electronic structure, and charge transport of IGO:PVA film are investigated by a battery of experimental and theoretical techniques, including In K-edge and Ga K-edge extended X-ray absorption fine structure (EXAFS); resonant soft X-ray scattering (R-SoXS); ultraviolet photoelectron spectroscopy (UPS); Fourier transform-infrared (FT-IR) spectroscopy; time-of-flight secondary-ion mass spectrometry (ToF-SIMS); composition-/processing-dependent TFT properties; high-resolution solid-state 1 H, 71 Ga, and 115 In NMR spectroscopy; and discrete Fourier transform (DFT) analysis with ab initio molecular dynamics (MD) liquid-quench simulations. The 71 Ga{ 1 H} rotational-echo double-resonance (REDOR) NMR and other data indicate that PVA achieves optimal H doping with a Ga···H distance of ~3.4 Å and conversion from six- to four-coordinate Ga, which together suppress deep trap defect localization. This reduces metal-oxide polyhedral distortion, thereby increasing the electron mobility. Finally, hydroxyl polymer doping thus offers a pathway for efficient H doping in green solvent-processed metal oxide films and the promise of high-performance, ultra-stable metal oxide semiconductor electronics with simple binary compositions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Classification of electronic nematicity in three-dimensional crystals and quasicrystals

Electronic nematic order has been reported in a rich landscape of materials, encompassing not only a range of intertwined correlated and topological phenomena but also different underlying lattice symmetries. Motivated by these findings, we investigate the behavior of electronic nematicity as the spherical symmetry of three-dimensional (3D) space is systematically lowered by the lattice environment. Here, we consider all 32 crystallographic point groups as well as four major classes of quasicrystalline point groups, given the recent observations of electronic phases of interest in quasicrystalline materials and artificial twisted quasicrystals. Valuable insights are gained by establishing a mapping between the five-component charge-quadrupolar nematic order parameter of the electronic fluid and the 3D tensorial order parameter of nematic liquid crystals. We find that a uniaxial nematic state is only generically realized in polyhedral point groups (icosahedral and cubic), with the nematic director pointing along different sets of rotational symmetry axes. Interestingly, icosahedral point groups are the only ones in which the five nematic order parameter components transform as the same irreducible representation, making them the closest analog of 3D isotropic nematics. In axial point groups, one of the nematic components is always condensed, whereas the other four components decompose into an in-plane and an out-of-plane nematic doublet, resulting in biaxial nematic ground states. Because these two nematic doublets behave as Z q clock order parameters, this allows us to identify the types of crystals and quasicrystals that can host interesting electronic nematic phenomena enabled by the critical properties of the q ≥ 4 clock model, such as emergent continuous nematic fluctuations in 3D, critical phases with quasi-long-range nematic order in two dimensions (2D), and Ashkin-Teller nematicity in 2D.

3-dimensional systems↗
DOE OSTI2022

Simultaneous single-shot rotation–vibration non-equilibrium thermometry using pure rotational fs/ps CARS coherence beating

Here, we report the development of a simple and sensitive two-beam hybrid femtosecond/picosecond pure rotational coherent anti-Stokes Raman scattering (fs/ps CARS) method to simultaneously measure the rotational and vibrational temperatures of diatomic molecules. Rotation–vibration non-equilibrium plays a key role in the chemistry and thermalization in low-temperature plasmas as well as thermal loading of hypersonic vehicles. This approach uses time-domain interferences between ground state and vibrationally excited N 2 molecules to intentionally induce coherence beating that leads to apparent non-Boltzmann distributions in the pure rotational spectra. These distortions enable simultaneous inference of both the rotational and vibrational temperatures. Coherence beating effects were observed in single-shot fs/ps CARS measurements of a 75 Torr N 2 DC glow discharge and were successfully modeled for rotational and vibrational temperature extraction. We show that this method can be more sensitive than a pure rotational fs/ps CARS approach using a spectrally narrow probe pulse. Lastly, we experimentally measured the beat frequencies via Fourier transform of the time-domain response and obtained excellent agreement with the model.

42 ENGINEERING↗
NASA NTRS1973

Numerical calculation of the three dimensional transonic flow over a yawed wing.

Results are presented of calculations of the three dimensional steady transonic flow over a finite yawed wing. The full potential flow equation is solved in a transformed coordinate system which permits the boundary conditions to be satisfied exactly. The correct differential properties are enforced by rotating the difference scheme to conform with the flow direction, and fast convergence is assured by simulating a time dependent equation designed to settle quickly to a steady state. Computed lift drag ratios are consistent with the results of wind tunnel tests of a yawed wing conducted by R. T. Jones (1972).-

Jameson, A.↗
NASA NTRS1991

Determination of absolute strengths of N2 quadrupole lines from high-resolution ground-based IR solar observations

The strength of S-branch lines of the N2 (1-0) electric quadrupole vibration-rotation band are determined by an analysis of solar absorption spectra. The solar data were recorded with a Fourier transform spectrometer and are characterized by high resolution, and a high signal-to-noise ratio. By extrapolating equivalent width measurements of the lines from varying air masses to zero air mass, the line strengths are found for the transitions from S7 to S10. The results presented do not include half widths and are found to be accurate to within 5 percent, and following a redetermination the N2 transitions are accurate to within 0.0002/cm. Line-of-sight atmospheric air masses associated with remotely sensed IR spectroscopic observations can be determined directly by utilizing the highly accurate data.

Demoulin, P.↗
NASA NTRS1993

Dynamics of the atmospheres of the outer planets - Post-Voyager measurement objectives

Current knowledge about dynamics and thermal structure on the outer planets is reviewed with the aim of identifying important measurements which should be made in the post-Voyager era. The existence of jets and cloud bands is the puzzle that underlies all others. Discussion focuses on the particular case of Jupiter because documentation is most complete. Recent dynamical work has successfully reproduced much of the behavior of jets and spots with simple models that contain few parameters. It is argued that the gross dynamical parameters, such as density stratification and rotation rate, are the keys to their behaviors, rather than the particular specifics of radiative forcing, cloud distributions, thermodynamic transformations. Voyager data have shown that the jet systems decay with height in the region above the visible clouds. Therefore the highest priority must be given to establishing dynamical parameters that characterize levels within and beneath the clouds. These require determination of the deep structure of the jets, of the density stratification, and of the horizontal density contrasts. The deep regions are not easily accessible, and these measurements present challenging opportunities. Indirect inferences about the controlling processes may sometimes be possible by observing waves and other activity in the more easily accessible stratosphere, and some of these issues are also discussed.

Gierasch, Peter J.↗
NASA NTRS2014

Effects of Dopant on Depoling Temperature in Modified BiScO3 - PbTiO3

In recent years there has been a renewed interest for high temperature piezoelectrics for both terrestrial and aerospace applications. These applications are limited in part by the operating temperature, which is usually taken as one half of the Curie temperature (Tc), and is 200C for one of the most widely used commercial piezoelectrics, Pb(Zr,Ti)O3 (PZT). In an effort to increase Tc, subsequent research into high temperature Bi(BB)O3 PbTiO3 piezoelectrics led to the discovery of the morphotropic phase boundary (MPB) in the high-Tc BiScO3 PbTiO3 (BS-PT) system with a Tc of 460C and a d33 of 460 pmV. The Tc marks the ferroelectric to paraelectric phase transformation and while, in general, a phase transformation leads to thermal depoling in piezoelectrics with low or moderate Tcs, for high Tc piezoelectrics thermally assisted dipole rotation can lead to randomization of domains at temperatures below Tc. It becomes necessary to determine the depoling temperature (Td) which dictates the actual working temperature range. By doping for Sc and Ti the Td can be shifted while maintaining similar electromechanical properties as a function of temperature. The effect of this B-site doping on depoling temperature has been explored through the characterization of microstructure and weakhigh field measurements.

Actuator↗
DOE OSTI2022

Nontrivial nanostructure, stress relaxation mechanisms, and crystallography for pressure-induced Si-I → Si-II phase transformation

Crystallographic theory based on energy minimization suggests austenite-twinned martensite interfaces with specific orientation, which are confirmed experimentally for various materials. Pressure-induced phase transformation (PT) from semiconducting Si-I to metallic Si-II, due to very large and anisotropic transformation strain, may challenge this theory. Here, unexpected nanostructure evolution during Si-I → Si-II PT is revealed by combining molecular dynamics (MD), crystallographic theory, generalized for strained crystals, and in situ real-time Laue X-ray diffraction (XRD). Twinned Si-II, consisting of two martensitic variants, and unexpected nanobands, consisting of alternating strongly deformed and rotated residual Si-I and third variant of Si-II, form {111} interface with Si-I and produce almost self-accommodated nanostructure despite the large transformation volumetric strain of -0.237. The interfacial bands arrest the {111} interfaces, leading to repeating nucleation-growth-arrest process and to growth by propagating {110} interface, which (as well as {111} interface) do not appear in traditional crystallographic theory.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Novel angular velocity estimation technique for plasma filaments

Magnetic field aligned filaments such as blobs and edge localized mode filaments carry significant amounts of heat and particles to the plasma facing components and they decrease their lifetime. The dynamics of these filaments determine at least a part of the heat and particle loads. These dynamics can be characterized by their translation and rotation. In this paper, we present an analysis method novel for fusion plasmas, which can estimate the angular velocity of the filaments on frame-by-frame time resolution. After pre-processing, the frames are two-dimensional (2D) Fourier-transformed, then the resulting 2D Fourier magnitude spectra are transformed to log-polar coordinates, and finally the 2D cross-correlation coefficient function (CCCF) is calculated between the consecutive frames. The displacement of the CCCF’s peak along the angular coordinate estimates the angle of rotation of the most intense structure in the frame. Further, the proposed angular velocity estimation method is tested and validated for its accuracy and robustness by applying it to rotating Gaussian-structures. The method is also applied to gas-puff imaging measurements of filaments in National Spherical Torus Experiment plasmas.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1976

Low-energy electron scattering from CO. 2: Ab-initio study using the frame-transformation theory

The Wigner-Eisenbud R matrix method has been combined with the frame transformation theory to study electron scattering from molecular systems. The R matrix, calculated at the boundary point of the molecular core radius, has been transformed to the space frame in order to continue the solution of the scattering equations in the outer region where rotational motion of the nuclei is taken into account. This procedure has been applied to a model calculation of thermal energy electron scattering from CO.

Chandra, N.↗
NASA NTRS1980

The effects of seeing on the reflected spectrum of Uranus and Neptune

The results of a redetermination of the rotational periods of Uranus and Neptune, based on spectrograms obtained with the coude spectrograph of the 5 m Hale telescope, are presented. The effects of image motion on the shape of the spectral lines reflected by a planet rotating as a solid body and coherently scattering solar light, has been studied analytically. A general relation between the seeing transformed velocities at any point on the disk and those at the equator is established. It is shown that, for the case of Gaussian seeing, the brightness continuum of the smeared disk contains all the information required to derive the shape of the reflected lines. The shift, change in r.m.s. width, and asymmetry of the seeing transformed lines at the equator have been numerically evaluated for the brightness distribution of Uranus determined from Stratoscope II.

Muench, G.↗
NASA NTRS1985

Applications of variational principles in computing rotational flows

Ecer and Akay (1983) have developed a variational formulation of rotational flow for Euler equations. The present paper provides a summary of these developments. The considered variational formulation provides a transformation of a type considered by Clebsch (1859). In this transformation, a new set of variables replaces the more commonly used primitive variables u(i), rho and p. Here, u(i) denotes the velocity components, while rho is the density, and p the pressure. The employed transformation produces a natural uncoupling of the equations when written in a quasi-linear form. After obtaining the governing equations in terms of the 'Clebsch variables', a solution scheme developed for calculating steady flows is discussed. Attention is given to numerical solutions of Euler equations based on the derived variational principles, and a study of inviscid, separated flows is conducted.

Ecer, A.↗
NASA NTRS1988

Spectroscopic planetary detection

One of the most promising methods for the detection of extra-solar planets is the spectroscopic method, where a small Doppler shift (approximately 10 meters/sec) in the spectrum of the parent star reveals the presence of planetary companions. However, solar-type stars may show spurious Doppler shifts due to surface activity. If these effects are periodic, as is the solar activity cycle, then they may masquerade as planetary companions. The goal of this investigation is to determine whether the solar cycle affects the Doppler stability of integrated sunlight. Observations of integrated sunlight are made in the near infrared (approximately 2 micrometer), using the Kitt Peak McMath Fourier transform spectrometer, with an N2O gas absorption cell for calibration. Researchers currently achieve an accuracy of approximately 5 meters/sec. Solar rotation velocities vary by plus or minus 2000 meters/sec across the solar disk, and imperfect optical integration of these velocities is the principal source of error. We have been monitoring the apparent velocity of integrated sunlight since 1983. They initially saw a decrease of approximately 30 meters/sec in the integrated light velocity from 1983 through 1985, but in 1987 to 1988 the integrated light velocity returned to its 1983 level. It is too early to say whether these changes are solar-cycle related. Although the FTS, unlike a slit spectrograph, has a large field of view, researchers are always looking for ways to improve the optical integration of the solar disk. They recently made an improvement in the method used to optically collimate the FTS, and this has reduced the error level, eliminating some systematic effects seen earlier.

Deming, Drake↗
NASA NTRS1990

Some fundamentals regarding kinematics and generalized forces for multibody dynamics

In order to illustrate the various forms in which generalized forces can arise from diverse subsystem analyses in multibody dynamics, intrinsic dynamical equations for the rotational dynamics of a rigid body are derived from Hamilton's principle. Two types of generalized forces are derived: (1) those associated with the virtual rotation vector in some orthogonal basis, and (2) those associated with varying generalized coordinates. As one physical or kinematical result (such as a frequency or a specific direction cosine) cannot rely on this selection, a 'blind' coupling of two models in which generalized forces are calculated in different ways would be wrong. Both types should use the same rotational coordinates and should denote the virtual rotation on a similar basis according to method 1, or in terms of common rotational coordinates and their diversifications as in method 2. Alternatively, the generalized forces and coordinates of one model may be transformed to those of the other.

Hodges, Dewey H.↗
NASA NTRS1999

Omniview motionless camera orientation system

A device for omnidirectional image viewing providing pan-and-tilt orientation, rotation, and magnification within a hemispherical field-of-view that utilizes no moving parts. The imaging device is based on the effect that the image from a fisheye lens, which produces a circular image of at entire hemispherical field-of-view, which can be mathematically corrected using high speed electronic circuitry. More specifically, an incoming fisheye image from any image acquisition source is captured in memory of the device, a transformation is performed for the viewing region of interest and viewing direction, and a corrected image is output as a video image signal for viewing, recording, or analysis. As a result, this device can accomplish the functions of pan, tilt, rotation, and zoom throughout a hemispherical field-of-view without the need for any mechanical mechanisms. The preferred embodiment of the image transformation device can provide corrected images at real-time rates, compatible with standard video equipment. The device can be used for any application where a conventional pan-and-tilt or orientation mechanism might be considered including inspection, monitoring, surveillance, and target acquisition.

Zimmermann, Steven D.↗
DOE OSTI2023

Universal Stripe Symmetry of Short-Range Charge Density Waves in Cuprate Superconductors

The omnipresence of charge density waves (CDWs) across almost all cuprate families underpins a common organizing principle. However, a longstanding debate of whether its spatial symmetry is stripe or checkerboard remains unresolved. While CDWs in lanthanum- and yttrium-based cuprates possess a stripe symmetry, distinguishing these two scenarios is challenging for the short-range CDW in bismuth-based cuprates. Here, high-resolution resonant inelastic x-ray scattering is employed to uncover the spatial symmetry of the CDW in Bi 2 Sr 2-x La x CuO 6 + δ . Across a wide range of doping and temperature, anisotropic CDW peaks with elliptical shapes are found in reciprocal space. Based on Fourier transform analysis of real-space models, the results are interpreted as evidence of unidirectional charge stripes, hosted by mutually 90°-rotated anisotropic domains. This work paves the way for a unified symmetry and microscopic description of CDW order in cuprates.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Experimental study of multiple-orientation muon tomography with image optimization in sparse data environments

Due to the high penetrating power of cosmic-ray muons, they can be used to probe very thick and dense objects. As muons are charged particles, they can be tracked by ionization detectors, determining the position and direction of the muons. With detectors on either side of an object to measure particle direction change, scattering information within the object can be found. This can be used to produce a scattering-intensity image within the object related to density and atomic number. Such imaging is typically performed with a single detector-object orientation, taking advantage of the more intense downward flux of muons, producing planar imaging with some depth-of-field information in the third dimension. Several simulation studies were published with multiorientation tomography, which can form a three-dimensional representation faster than a single-orientation view. In this study, experimental muon-scatter-based tomography was performed using a concrete filled steel drum with several different metal wedges inside, with the drum between detector planes. Data were collected from different detector-object orientations by rotating the steel drum. The data collected from each orientation were combined using two different tomographic methods. A traditional inverse Radon transform approach used for computed tomography and a combination of multiple depth-of-field reconstructions were applied to the data. As cosmic-ray muon flux imaging is rate limited, the imaging techniques were compared for sparse data. Using the combined depth-of-field reconstruction technique, fewer detector-object orientations were needed to reconstruct images that could be used to differentiate the metal wedges.

47 OTHER INSTRUMENTATION↗