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At least 361 records · Page 20

Discovery of Interstellar Hydrogen Fluoride

We report the first detection of interstellar hydrogen fluoride. Using the Long Wavelength Spectrometer of the Infrared Space Observatory (ISO), we have detected the 121.6973 micron J = 2-1 line of HF in absorption toward the far-infrared continuum source Sagittarius B2. The detection is statistically significant at the 13 sigma level. On the basis of our model for the excitation of HF in Sgr B2, the observed line equivalent width of 1.0 nm implies a hydrogen fluoride abundance of approximately 3 x 10(exp -10) relative to H2. If the elemental abundance of fluorine in Sgr B2 is the same as that in the solar system, then HF accounts for approximately 2% of the total number of fluorine nuclei. We expect hydrogen fluoride to be the dominant reservoir of gas-phase fluorine in Sgr B2, because it is formed rapidly in exothermic reactions of atomic fluorine with either water or molecular hydrogen; thus, the measured HF abundance suggests a substantial depletion of fluorine onto dust grains. Similar conclusions regarding depletion have previously been reached for the case of chlorine in dense interstellar clouds. We also find evidence at a lower level of statistical significance (approximately 5 sigma) for an emission feature at the expected position of the 4(sub 32)-4(sub 23) 121.7219 micron line of water. The emission-line equivalent width of 0.5 nm for the water feature is consistent with the water abundance of 5 x 10(exp -6) relative to H2 that has been inferred previously from observations of the hot core of Sgr B2.

Neufeld, David A.↗

The Ratio of Ortho- to Para-H2 in Photodissociation Regions

We discuss the ratio of ortho- to para-H2 in photodissociation regions (PDRs). We draw attention to an apparent confusion in the literature between the ortho-to-para ratio of molecules in FUV-pumped vibrationally excited states and the total H2 ortho-to-para abundance ratio. These ratios are not the same because the process of FUV pumping of fluorescent H2 emission in PDRs occurs via optically thick absorption lines. Thus gas with an equilibrium ratio of ortho- to para-H2 equal to 3 will yield FUV-pumped vibrationally excited ortho-to-para ratios smaller than 3, because the ortho-H2 pumping rates are preferentially reduced by optical depth effects. Indeed, if the ortho and para pumping lines are on the "square root" part of the curve of growth, then the expected ratio of ortho and para vibrational line strengths is 3(sup 1/2) approximately 1.7, close to the typically observed value. Thus, contrary to what has sometimes been stated in the literature, most previous measurements of the ratio of ortho- to para-H2 in vibrationally excited states are entirely consistent with a total ortho-to-para ratio of 3, the equilibrium value for temperatures greater than 200 K. We present an analysis and several detailed models that illustrate the relationship between the total ratios of ortho- to para-H2 and the vibrationally excited ortho-to-para ratios in PDRs. Recent Infrared Space Observatory measurements of pure rotational and vibrational H2 emissions from the PDR in the star-forming region S140 provide strong observational support for our conclusions.

Sternberg, Amiel↗

Preliminary Investigation of an Active PLZT Lens

The design, analysis and preliminary testing of a prototype Adjustable Focus Optical Correction Lens (AFOCL) is described. The AFOCL is an active optical component composed of solid state lead lanthanum-modified zirconate titanate (PLZT) ferroelectric ceramic with patterned indium tin oxide (ITO) transparent surface electrodes that modulate the refractive index of the PLZT to function as an electro-optic lens. The AFOCL was developed to perform optical re-alignment and wavefront correction to enhance the performance of Ultra-Lightweight Structures and Space Observatories (ULSSO). The AFOCL has potential application as an active optical component within a larger optical system. As such, information from a wavefront sensor would be processed to provide input to the AFOCL to drive the sensed wavefront to the desired shape and location. While offering variable and rapid focussing capability (controlled wavefront manipulation) similar to liquid crystal based spatial light modulators (SLM), the AFOCL offers some potential advantages because it is a solid-state, stationary, low-mass, rugged, and thin optical element that can produce wavefront quality comparable to the solid refractive lens it replaces. The AFOCL acts as a positive or negative lens by producing a parabolic phase-shift in the PLZT material through the application of a controlled voltage potential across the ITO electrodes. To demonstrate the technology, a 4 mm diameter lens was fabricated to produce 5-waves of optical power operating at 2.051 micrometer wavelength. Optical metrology was performed on the device to measure focal length, optical quality, and efficiency for a variety of test configurations. The data was analyzed and compared to theoretical data available from computer-based models of the AFOCL.

Lightsey, W. D.↗

2-45 Micron Infrared Spectroscopy of Carbon-Rich Proto-Planetary Nebulae

Infrared Space Observatory (ISO) 2-45 micron observations of seven proto-planetary nebulae (PPNs) and two other carbon-rich objects are presented. The unidentified emission features at 21 and 30 microns are detected in six sources, including four new detections of the 30 micron feature. This previously unresolved 30 micron feature is now resolved and found to consist of a broad feature peaking at 27.2 microns (the '30 micron' feature) and a narrower feature at 25.5 microns (the '26 micron' feature). This new 26 micron feature is detected in eight sources and is particularly strong in IRAS Z02229 + 6208 and 16594-4656. The unidentified infrared (UIR) emission features at 3.3, 6.2, 7.7, and 11.3 microns which are commonly observed in planetary nebulae and H II regions, are also seen in these PPNs. However, their strengths relative to the continuum plateaus at 8 and 12 microns are weaker than in planetary nebulae. The 6.9 micron feature, seen almost exclusively in PPNs, is strong. New millimeter CO and HCN observations were made; they support the carbon-rich nature of the objects and yield the expansion velocities of the gaseous envelopes. The spectral energy distributions of these PPNs were fitted with a radiative-transfer model, taking into account the emission features at 21, 26, and 30 microns. A significant fraction of the total energy output is emitted in these features: as high as 20% in the 30 micron feature and 8% in the 21 micron feature. The fact that so much energy is carried in these features suggests that the material responsible for these features must be made of abundant elements and most likely involves carbon. SiS, appears to be ruled out as the emitter of the 21 micron feature due to the absence of a predicted companion feature.

Hrivnak, Bruce J.↗

The AstroBiology Explorer (ABE) MIDEX Mission

The Astrobiology Explorer (ABE) is a Medium-Class Explorer (MIDEX) mission concept currently under study at NASA's Ames Research Center. ABE will conduct infrared (IR) spectroscopic observations with much better sensitivity than Infrared Space Observatory (ISO) or the Stratospheric Observatory for Infrared Astronomy program (SOFIA) in order to address outstanding astrobiologically important problems in astrochemistry as well as important astrophysical investigations. The core observational astrobiology program would make fundamental scientific progress in understanding the cosmic history of molecular carbon, the distribution of organic matter in the diffuse interstellar medium, tracing the chemical history of complex organic molecules in the interstellar medium, and the evolution of organic ices in young planetary systems. The ABE instrument concept includes a 0.5 m aperture Cassegrain telescope and a suite of three moderate resolution (R = 1000 - 4000) spectrographs which cover the entire lambda = 2.5-20 micron spectral region. Use of large format (1024 x 1024 pixel or larger) IR detector arrays will allow each spectrograph to cover an entire octave of spectral range per exposure without any moving parts. The telescope is passively cooled by a sun shade to below 65 K, and the detectors are cooled with solid H2 cryogen to approximately 8 K. ABE will be placed in an Earth-trailing one AU solar orbit by a Delta II launch vehicle. This energetically favorable orbit provides a low thermal background, affords good access to the entire sky over the one year mission lifetime, and allows adequate communications bandwidth. The spacecraft will be stabilized in three axes and will be pointed to an accuracy of approximately one arcsecond at ABE's several thousand individual scientific targets.

Greene, Thomas↗

ISO Spectroscopy of Proto-Planetary Nebulae

The goal of this program was to determine the chemical properties of the dust shells around protoplanetary nebulae (PPNs) through a study of their short-wavelength (6-45 micron) infrared spectra. PPNs are evolved stars in transition from the asymptotic giant branch to the planetary nebula stages. Spectral features in the 10 to 20 gm region indicate the chemical nature (oxygen- or carbon-rich), and the strengths of the features relate to the physical properties of the shells. A few bright carbon-rich PPNs have been observed to show PAH features and an unidentified 21 micron emission feature. We used the Infrared Space Observatory (ISO) to observe a sample of IRAS sources that have the expected properties of PPNs and for which we have accurate positions. Some of these have optical counterparts (proposal SWSPPN01) and some do not (SWSPPN02). We had previously observed these from the ground with near-infrared photometry and, for those with visible counterparts, visible photometry and spectroscopy, which we have combined with these new ISO data in the interpretation of the spectra. We have completed a study of the unidentified emission feature at 21 micron in eight sources. We find the shape of the feature to be the same in all of the sources, with no evidence of any substructure. The ratio of the emission peak to continuum ranges from 0.13 to 1.30. We have completed a study of seven PPNs and two other carbon-rich objects for which we had obtained ISO 2-45 micron observations. The unidentified emission features at 21 and 30 micron were detected in six sources, including four new detections of the 30 micron feature. This previously unresolved 30 micron feature was resolved and found to consist of a broad feature peaking at 27.2 micron (the "30 micron" feature) and a narrower feature peaking at 25.5 micron (the "26 micron" feature). This new 26 micron feature is detected in eight sources and is particularly strong in IRAS Z02229+6208 and 16594-4656. The unidentified features at 3.3, 6,2, 7.7, and 11.3 micron, which are commonly observed in planetary nebulae and HII regions, are also seen in these PPNs. However, their strengths relative to the continuum plateaus at 8 and 12 micron are weaker than in planetary nebulae. The 6.9 micron feature, seen almost exclusively in PPNs, is strong. The spectral energy distributions of these PPNs were fitted with a radiative-transfer model, taking into account the emission features at 21, 26, and 30 micron. A significant fraction of the total energy output is emitted in these features: as high as 20% in the 30 micron feature and 8% in the 21 micron feature. The fact that so much energy is carried in these features suggests that the material responsible for this feature must be made of abundant elements, and most likely involves carbon. The change in the in feature strengths from stronger aliphatic bonds in PPNs to stronger aromatic bonds in PNs suggests a chemical and physical evolution in the carbonaceous circumstellar dust during this transition time scale of a few thousand years.

Hrivnak, Bruce J.↗

Photochemical Modeling of CH3 Abundances in the Outer Solar System

Recent measurements of methyl radicals (CH3) in the upper atmospheres of Saturn and Neptune by the Infrared Space Observatory (ISO) provide new constraints to photochemical models of hydrocarbon chemistry in the outer solar system. The derived column abundances of CH3 on Saturn above 10 mbar and Neptune above the 0.2 mbar pressure level are (2.5 - 6.0) x 10(exp 13) / sq cm and (0.7 - 2.8) x 10(exp 13) / sq cm, respectively. We use the updated Caltech/Jet Propulsion Laboratory photochemical model, which incorporates hydrocarbon photochemistry, vertical molecular and bulk atmospheric eddy diffusion, and realistic radiative transfer modeling, to study the CH3 abundances in the upper atmosphere of the giant planets and Titan. We identify the key reactions that control the concentrations of CH3 in the model, such as the three-body recombination reaction, CH3 + CH3 + M yields C2H6 + M. We evaluate and extrapolate the three-body rate constant of this reaction to the low-temperature limit (1.8 x 10(exp -16) T(sup -3.75) e(sup -300/T), T < 300 K) and compare methyl radical abundances in five atmospheres: Jupiter, Saturn, Uranus, Neptune, and Titan. The sensitivity of our models to the rate coefficients for the reactions H + CH3 + M yields CH4 + M, H + C2H3 yields C2H2 + H2, (sup 1)CH2 + H2 yields CH3 + H, and H + C2H5 yields 2CH3, the branching ratios of CH4 photolysis, vertical mixing in the five atmospheres, and Lyman alpha photon enhancement at the orbit of Neptune have all been tested. The results of our model CH3 abundances for both Saturn (5.1 x 10(exp 13) / sq cm) and Neptune (2.2 x 10(exp 13) / sq cm) show good agreement with ISO Short Wavelength Spectrometer measurements. Using the same chemical reaction set, our calculations also successfully generate vertical profiles of stable hydrocarbons consistent with Voyager and ground-based measurements in these outer solar system atmospheres. Predictions of CH3 column concentrations (for p <= 0.2 mbar) in the atmospheres of Jupiter (3.3 x 10(exp 13) /sq cm), Uranus (2.5 x 10(exp 12) / sq cm), and Titan (1.9 x 10(exp 15) / sq cm) may be checked by future observations.

Lee, Anthony Y. T.↗

Quiescent Giant Molecular Cloud Cores in the Galactic Center

We have used the Long Wavelength Spectrometer (LWS) aboard the Infrared Space Observatory (ISO) to map the far-infrared continuum emission (45-175 micrometer) toward several massive Giant Molecular Cloud (GMC) cores located near the Galactic center. The observed far-infrared and submillimeter spectral energy distributions imply low temperatures (approx. 15 - 22 K) for the bulk of the dust in all the sources, consistent with external heating by the diffuse ISRF and suggest that these GMCs do not harbor high- mass star-formation sites, in spite of their large molecular mass. Observations of FIR atomic fine structure lines of C(sub II) and O(sub I) indicate an ISRF enhancement of approx. 10(exp 3) in the region. Through continuum radiative transfer modeling we show that this radiation field strength is in agreement with the observed FIR and submillimeter spectral energy distributions, assuming primarily external heating of the dust with only limited internal luminosity (approx. 2 x 10(exp 5) solar luminosity). Spectroscopic observations of millimeter-wave transitions of H2CO, CS, and C-34S carried out with the Caltech Submillimeter Observatory (CSO) and the Institut de Radio Astronomie Millimetrique (IRAM) 30-meter telescope indicate a gas temperature of approx. 80 K, significantly higher than the dust temperatures, and density of approx. 1 x 10(exp 5)/cc in GCM0.25 + 0.01, the brightest submillimeter source in the region. We suggest that shocks caused by cloud collisions in the turbulent interstellar medium in the Galactic center region are responsible for heating the molecular gas. This conclusion is supported by the presence of wide-spread emission from molecules such as SiO, SO, and CH3OH, which are considered good shock tracers. We also suggest that the GMCs studied here are representative of the "typical", pre-starforming cloud population in the Galactic center.

Lis, D. C.↗

ISO Guest Observer Data Analysis and LWS Instrument Team Activities

The following is an interim annual report. Dr. Smith is currently on an extended TDY to the Istituto di Fisica dello Spazio Interplanetario (IFSI) at the Consilio Nazionale delle Richerche (CNR) in Rome, Italy, where he has been working on a related NASA grant in support of analysis of Infrared Space Observatory (ISO) data on star formation in Ultra Luminous Infrared Galaxies and our galaxy. Work emphasizes development of metal mesh grids for use in spacecraft, and the design and fabrication of test elements by the Naval Research Laboratory, Washington D.C. Work has progressed well, but slowly, on that program due to the departure of a key engineer. NASA has been advised of the delay, and granted a no-cost extension, whereby SAO has authorized a delay in the final report from NRL. Nevertheless NRL has continued to make progress. Two papers have been submitted to refereed journals related to this program, and a new design for mesh operating in the 20-40 micron region has been developed. Meetings continue through the summer on these items. A new technical scientist has been made a job offer and hopefully will be on board NRL shortly, although most of the present grant work is already completed. A more complete report, with copies of the submitted papers, designs, and other measures of progress, will be submitted to NASA in September when Dr. Smith returns from his current TDY.

Smith, Howard↗

An Explorer-Class Astrobiology Mission

In this paper we describe a potential new Explorer-class space mission, the AstroBiology Explorer (ABE), consisting of a relatively modest dedicated space observatory having a 50 cm aperture primary mirror which is passively cooled to T less than 65 K, resides in a low-background orbit (heliocentric orbit at 1 AU, Earth drift-away), and is equipped with a suite of three moderate order (m approx. 10) dispersive spectrographs equipped with first-order cross-dispersers in an "echellette" configuration and large format (1024xl024 pixel) near- and mid-IR detector arrays cooled by a modest amount of cryogen. Such a system would be capable of addressing outstanding problems in Astrochemistry and Astrophysics that are particularly relevant to Astrobiology and addressable via astronomical observation. The observational program of this mission would make fundamental scientific progress in each of the key areas of the cosmic history of molecular carbon, the distribution and chemistry of organic compounds in the diffuse and dense interstellar media, and the evolution of ices and organic matter in young planetary systems. ABE could make fundamental progress in all of these areas by conducting an approximately one year mission to obtain a coordinated set of infrared spectroscopic observations over the 2.5-20 micrometers spectral range at spectral resolutions of R greater than or equal to 1000 of approximately 1000 galaxies, stars, planetary nebulae, and young star planetary systems.

Sandford, Scott↗

ISO Key Project: Exploring the Full Range of Quasar/AGN Properties

The origin of the infrared emission in Active Galactic Nuclei (AGN), whose strength is comparable to the optical/ultra-violet (OUV) emission, is generally thought to be a combination of thermal emission from dust and non-thermal, synchrotron emission. Although data are sparse, particularly in the far-infrared, the broad wavelength range of this emission suggests a wide range of temperatures and a combination of AGN and starburst heating mechanisms. The strength of the non-thermal emission is expected to be related to the radio emission. While this scenario is well-established, basic questions, such as the spatial and temperature distribution of the dust, the relative importance of AGN and starburst heating, and the significance of the non-thermal contribution, remain largely undetermined. The wide wavelength range of the Infrared Space Observatory (ISO) combined with its arcmin spatial resolution and increased sensitivity facilitated the observation of a larger subset of the AGN population than previously covered, allowing these questions to be investigated in more detail. This paper will review the spectral energy distributions (SED) of AGN with particular emphasis on the infrared emission and on ISO contributions to our knowledge. Preliminary results from ISO observations of X-ray selected and high-redshift AGN will be described.

Wilkes, B.↗

The Far-Infrared Spectral Energy Distributions of Quasars

The origin of the infrared emission in Active Galactic Nuclei (AGN), whose strength is comparable to the optical/ultraviolet (OUV) emission, is generally thought to be a combination of thermal emission from dust and non-thermal, synchrotron emission. Although data are sparse, particularly in the far-infrared, the broad wavelength range of this emission suggests a wide range of temperatures and a combination of AGN and starburst heating mechanisms. The strength of the non-thermal emission is expected to be related to the radio emission. While this scenario is well-established, basic questions, such as the spatial and temperature distribution of the dust, the relative importance of AGN and starburst heating, and the significance of the non-thermal contribution remain largely undetermined. The wide wavelength range of the Infrared Space Observatory (ISO) combined with its arcmin spatial resolution and increased sensitivity facilitated the observation of a larger subset of the AGN population than previously covered, allowing these questions to be investigated in more detail. This paper will review the spectral energy distributions (SED) of AGN with particular emphasis on the infrared emission and on ISO's contributions to our knowledge. Preliminary results from ISO observations of X-ray selected and high-redshift AGN will be described.

Wilkes, Belinda J.↗

Complete ISOPHOT (C200) Maps of a Nearby Prototypical GMC: W3 (Spring) or NGC7538 (Fall)

We were originally awarded Priority 3 time (approximately 60,000 sec) with Infrared Space Observatory (ISO) to obtain a complete ISOPHOT (PHT32-C200) map of a nearby prototypical giant molecular cloud (GMC). Following the FALL launch and revised estimates for the sensitivity of the ISOPHOT detectors, our program was modified to fit within the time constraints while still carrying out the main science requirements. The revised program requested long strip maps of our FALL target (NGC7538) using sequences of PHT37/38/39 observations with LWS observations of the brightest regions. The large number of AOTs required to cover each GMC required that our observations be spread over four separate proposals (PROP-01, PROP-02, PROP-03, PROP-04) which together comprise a single observing program. Our program was executed in early 1997; nearly 50,000 sec of data were obtained, including all of our requested ISOPHOT C200 observations. None of the LWS data were taken.

Sanders, David B.↗

Infrared Spectroscopy of Star Formation in Galactic and Extragalactic Regions

This report details work done in a project involving spectroscopic studies, including data analysis and modeling, of star-formation regions using an ensemble of archival space-based data including some from the Infrared Space Observatory's Long Wavelength Spectrometer and Short Wavelength Spectrometer, and other spectroscopic databases. We will include four kinds of regions: (1) disks around more evolved objects; (2) young, low or high mass pre-main sequence stars in star-formation regions; (3) star formation in external, bright IR (infrared) galaxies; and (4) the galactic center. During this period, work proceeded fully on track and on time. Details on workshops and conferences attended and research results are presented. A preprint article entitled 'The Far Infrared Lines of OH as Molecular Cloud Diagnostics' is included as an appendix.

Smith, Howard A.↗

The Infrared Spectra of Nitriles and Related Compounds Frozen in Ar and H2O

We present the 2320-2050/cm (4.31-4.88 micron) infrared spectra of 16 solid state nitrites, isonitriles, and related compounds in order to facilitate the assignment of absorption features in a spectral region now becoming accessible to astronomers for the first time through the Infrared Space Observatory (ISO). This frequency range spans the positions of the strong C(is congruent to)N stretching vibration of these compounds and is inaccessible from the ground due to absorption by CO2 in the terrestrial atmosphere. Band positions, profiles, and intrinsic strengths (A values) were measured for compounds frozen in Ar and H2O matrices at 12 K. The molecular species examined included acetonitrile, benzonitrile phenylcyanide) 9-anthracenecarbonitrile, dimethylcyanamide, isopropy1nitrile (isobutyronitrile), methylacrylonitrile, crotononitrile, acrylonitrile (vinyl cyanide), 3-aminocrotononitrile, pyr-uvonitrile, dicyandiamide, cyanamide, n-butyfisocyanide, methylisocyanoacetate, dilsopropylcarbodiimide, and hydrogen cyanide. The C(is congruent to)N stretching bands of the majority of nitrites fall in the 2300-2200/cm (4.35-4.55 micron) range and have similar positions in both Ar and H2O matrices, although the bands are generally considerably broader in the H2O matrices. In contest, the isonitriles and a few exceptional nitrites and related species produce bands at lower frequencies spanning the 2200-2080/cm (4.55-4.81 micron) range. These features also have similar positions in both Am and H2O matrices and the bands are broader in the H2O matrices. Three of the compounds (pyruvonitrile, dicyandiamide, and cyanamide) show unusually large shifts of their C(is congruent to)N stretching frequencies when changing from Ar to H2O matrices. We attribute these shifts to the formation of H2O:nitrile complexes with these compounds. The implications of these results for the identification of the 2165/cm (4.62 micron) "XCN" interstellar feature and the 4550/cm (2.2 micron) feature of various objects in the solar system are discussed.

Bernstain, Max P.↗

Characteristics of Interstellar and Circumstellar Dust

This paper will review our current knowledge of circumstellar and interstellar dust from an astronomical point of view. About half of the interstellar dust volume consists of amorphous silicates. The remainder has to be made up of an carbonaceous component such as graphite, amorphous carbon (i.e., soot), Polycyclic Aromatic Hydrocarbon molecules (PAHs), and/or organic grain mantles (i.e., mixed polymers). The observational evidence for these components will be reviewed and their relative importance assessed. The emphasis will be on recent observations using the Infrared Space Observatory. Most of these dust components are formed in the outflows from stars in the late stages of their evolution (i.e., red giants, planetary nebulae, novae, supergiants, Wolf Rayet stars, and supernovae). Indeed, observation of such objects indicate an even richer spectrum of stardust components, including also SiC, MgS, and aluminates and crystalline silicates. These observations will be briefly discussed. The stardust budget of the galaxy will be reviewed and the relative importance of the various birth sites assessed. Finally, in recent years, isotopic composition studies have shown that some circumstellar and interstellar dust grains have been incorporated into solar system bodies such as planetary dust particles and meteorites without totally losing their identity. Among the components identified are SiC, graphite, diamonds, PAHs, aluminum oxides, as well as various trace element carbides. Studies of this kind have opened up a new window on the composition and structure of interstellar dust. These different sources of information on interstellar and circumstellar dust will be briefly contrasted.

Tielens, A. G. G. M.↗

An ISO and IUE Study of Planetary Nebula NGC 2440

The infrared and ultraviolet spectra of planetary nebula NGC 2440 is presented. The observations were made respectively by the Infrared Space Observatory (ISO) and International Ultraviolet Explorer (IUE) These data, in conjunction with published optical observations have been used to derive electron temperature and density. A trend of electron temperature with ionization potential is found. In particular the electron temperature increases from 11000 to 18000 K with increasing IBM. The electron density has a constant value of 4500/cu cm in agreement with previous determination. The chemical abundance has been derived for the following elements; helium, carbon, nitrogen, oxygen, neon, sulfur and argon. The ionization correction factor turns out to be very small (almost unnecessary) for all species except sulfur.

Salas, J. Bernard↗