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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1995

The correlated k-distribution technique as applied to the AVHRR channels

Correlated k-distributions have been created to account for the molecular absorption found in the spectral ranges of the five Advanced Very High Resolution Radiometer (AVHRR) satellite channels. The production of the k-distributions was based upon an exponential-sum fitting of transmissions (ESFT) technique which was applied to reference line-by-line absorptance calculations. To account for the overlap of spectral features from different molecular species, the present routines made use of the multiplication transmissivity property which allows for considerable flexibility, especially when altering relative mixing ratios of the various molecular species. To determine the accuracy of the correlated k-distribution technique as compared to the line-by-line procedure, atmospheric flux and heating rate calculations were run for a wide variety of atmospheric conditions. For the atmospheric conditions taken into consideration, the correlated k-distribution technique has yielded results within about 0.5% for both the cases where the satellite spectral response functions were applied and where they were not. The correlated k-distribution's principal advantages is that it can be incorporated directly into multiple scattering routines that consider scattering as well as absorption by clouds and aerosol particles.

Kratz, David P.↗
NASA NTRS2017

Multispectral Snapshot Imagers Onboard Small Satellite Formations for Multi-Angular Remote Sensing

Multispectral snapshot imagers are capable of producing 2D spatial images with a single exposure at selected, numerous wavelengths using the same camera, therefore operate differently from push broom or whiskbroom imagers. They are payloads of choice in multi-angular, multi-spectral imaging missions that use small satellites flying in controlled formation, to retrieve Earth science measurements dependent on the targets Bidirectional Reflectance-Distribution Function (BRDF). Narrow fields of view are needed to capture images with moderate spatial resolution. This paper quantifies the dependencies of the imagers optical system, spectral elements and camera on the requirements of the formation mission and their impact on performance metrics such as spectral range, swath and signal to noise ratio (SNR). All variables and metrics have been generated from a comprehensive, payload design tool. The baseline optical parameters selected (diameter 7 cm, focal length 10.5 cm, pixel size 20 micron, field of view 1.15 deg) and snapshot imaging technologies are available. The spectral components shortlisted were waveguide spectrometers, acousto-optic tunable filters (AOTF), electronically actuated Fabry-Perot interferometers, and integral field spectrographs. Qualitative evaluation favored AOTFs because of their low weight, small size, and flight heritage. Quantitative analysis showed that waveguide spectrometers perform better in terms of achievable swath (10-90 km) and SNR (greater than 20) for 86 wavebands, but the data volume generated will need very high bandwidth communication to downlink. AOTFs meet the external data volume caps well as the minimum spectral (wavebands) and radiometric (SNR) requirements, therefore are found to be currently feasible in spite of lower swath and SNR.

Nag, Sreeja↗
NASA NTRS2004

Progress of Multicolor Single Detector to Detector Array Development for Remote Sensing

Knowledge of the spatial and temporal distribution of atmospheric species such as CO2, O3, H2O, and CH4 is important for understanding the chemistry and physical cycles involving Earth s atmosphere. Although several remote sensing techniques are suitable for such measurements they are considered high cost techniques involving complicated instrumentation. Therefore, simultaneous measurement of atmospheric species using a single remote sensing instrument is significant for minimizing cost, size and complexity. While maintaining the instrument sensitivity and range, quality of multicolor detector, in terms of high quantum efficiency and low noise are vital for these missions. As the first step for developing multicolor focal plan array, the structure of a single element multicolor detector is presented in this paper. The detector consists of three p-n junction layers of Si, GaSb and InAs wafer bonded to cover the spectral range UV to 900 nm, 800 nm to 1.7 m, and 1.5 m to 3.4 m, respectively. Modeling of the absorption coefficient for each material was carried out for optimizing the layers thicknesses for maximum absorption. The resulted quantum efficiency of each layer has been determined except InAs layer. The optical and electrical characterization of each layer structure is reported including dark current and spectral response measurements of Si pin structure and of GaSb and InAs p-n junctions. The effect of the material processing is discussed.

Abedin, M. Nurul↗
NASA NTRS1977

SETI - A preliminary search for narrowband signals at microwave frequencies

In the search for intelligent signals of extraterrestrial origin, certain forms of signals merit immediate and special attention. Extremely narrowband signals of spectral width similar to our own television transmissions are most favored energetically and least likely to be confused with natural celestial emission. A search of selected stars has been initiated using observational and data processing techniques optimized for the detection of such signals. These techniques allow simultaneous observation of 10 to the 5th to 10 to the 6th channels within the observed spectral range. About two hundred nearby (within 80 LY) solar type stars have been observed at frequencies near the main microwave transitions of the hydroxyl radical. In addition, several molecular (hydroxyl) masers and other non-thermal sources have been observed in this way in order to uncover any possible fine spectral structure of natural origin and to investigate the potential of such an instrument for radioastronomy.

Cuzzi, J. N.↗
NASA NTRS2006

Space-Based Near-Infrared CO2 Measurements: Testing the Orbiting Carbon Observatory Retrieval Algorithm and Validation Concept Using SCIAMACHY Observations over Park Falls, Wisconsin

Space-based measurements of reflected sunlight in the near-infrared (NIR) region promise to yield accurate and precise observations of the global distribution of atmospheric CO2. The Orbiting Carbon Observatory (OCO) is a future NASA mission, which will use this technique to measure the column-averaged dry air mole fraction of CO2 (XCO2) with the precision and accuracy needed to quantify CO2 sources and sinks on regional scales (approx.1000 x 1000 sq km and to characterize their variability on seasonal timescales. Here, we have used the OCO retrieval algorithm to retrieve XCO2 and surface pressure from space-based Scanning Imaging Absorption Spectrometer for Atmospheric Chartography (SCIAMACHY) measurements and from coincident ground-based Fourier transform spectrometer (FTS) measurements of the O2 A band at 0.76 mm and the 1.58 mm CO2 band for Park Falls,Wisconsin. Even after accounting for a systematic error in our representation of the O2 absorption cross sections, we still obtained a positive bias between SCIAMACHY and FTS XCO2 retrievals of approx.3.5%. Additionally, the retrieved surface pressures from SCIAMACHY systematically underestimate measurements of a calibrated pressure sensor at the FTS site. These findings lead us to speculate about inadequacies in the forward model of our retrieval algorithm. By assuming a 1% intensity offset in the O2 A band region for the SCIAMACHY XCO2 retrieval, we significantly improved the spectral fit and achieved better consistency between SCIAMACHY and FTS XCO2 retrievals. We compared the seasonal cycle of XCO2 at Park Falls from SCIAMACHY and FTS retrievals with calculations of the Model of Atmospheric Transport and Chemistry/Carnegie-Ames-Stanford Approach (MATCH/CASA) and found a good qualitative agreement but with MATCH/CASA underestimating the measured seasonal amplitude. Furthermore, since SCIAMACHY observations are similar in viewing geometry and spectral range to those of OCO, this study represents an important test of the OCO retrieval algorithm and validation concept using NIR spectra measured from space. Finally, we argue that significant improvements in precision and accuracy could be obtained from a dedicated CO2 instrument such as OCO, which has much higher spectral and spatial resolutions than SCIAMACHY. These measurements would then provide critical data for improving our understanding of the carbon cycle and carbon sources and sinks.

carbon dioxide↗
NASA NTRS1987

A thermal emission spectrometer for field use

A field portable spectrometer has been built at the Jet Propulsion Laboratory which is suitable for collecting data relevant to remote sensing applications in the 4.7- to 5.6- and 8- to 12-micrometer atmospheric windows. The instrument employs a single cooled HgCdTe detector and a continuously variable filter wheel analyzer. The spectral range covered is 5- to 14.5-micrometers and the resolution is approximately 1.5 percent of the wavelength. A description of the hardware is followed by a discussion of the data processing steps leading to emissivity and radiance spectra. A section is devoted to the evaluation of the instrument performance with respect to spectral resolution, radiometric precision, and accuracy. Several examples of spectra acquired in the field are included.

Hoover, Gordon↗
NASA NTRS2006

Herschel and the Molecular Universe

Over the next decade, space-based missions will open up the universe to high spatial and spectral resolution studies at infrared and submillimeter wavelengths. This will allow us to study, in much greater detail, the composition and the origin and evolution of molecules in space. Moreover, molecular transitions in these spectral ranges provide a sensitive probe of the dynamics and the physical and chemical conditions in a wide range of objects at scales ranging from budding planetary systems to galactic and extragalactic sizes. Hence, these missions provide us with the tools to study key astrophysical and astrochemical processes involved in the formation and evolution of planets, stars, and galaxies. These new missions can be expected to lead to the detection of many thousands of new spectral features. Identification, analysis and interpretation of these features in terms of the physical and chemical characteristics of the astronomical sources will require detailed astronomical modeling tools supported by laboratory measurements and theoretical studies of chemical reactions and collisional excitation rates on species of astrophysical relevance. These data will have to be made easily accessible to the scientific community through web-based data archives. In this paper, we will review the Herschel mission and its expected impact on our understanding of the molecular universe.

Tielens, A. G. G. M.↗
NASA NTRS2011

Thermal Optical Properties of Lunar Dust Simulants and Their Constituents

The total reflectance spectra of lunar simulant dusts (< 20 mm particles) were measured in order to determine their integrated solar absorptance (alpha) and their thermal emittance (epsilon) for the purpose of analyzing the effect of dust on the performance of thermal control surfaces. All of the simulants except one had a wavelength-dependent reflectivity (p (lambda)) near 0.10 over the wavelength range of 8 to 25 microns and so are highly emitting at room temperature and lower. The 300 K emittance (epsilon) of all the lunar simulants except one ranged from 0.78 to 0.92. The exception was Minnesota Lunar Simulant 1 (MLS-1), which has little or no glassy component. In all cases the epsilon was lower for the < 20 micron particles than for larger particles reported earlier. There was considerably more variation in the lunar simulant reflectance in the solar spectral range (250 to 2500 nm) than in the thermal infrared. As expected, the lunar highlands simulants were more reflective in this wavelength range than the lunar mare simulants. The integrated solar absorptance (alpha) of the simulants ranged from 0.39 to 0.75. This is lower than values reported earlier for larger particles of the same simulants (0.41 to 0.82), and for representative mare and highlands lunar soils (0.74 to 0.91). Since the of some mare simulants more closely matched that of highlands lunar soils, it is recommended that and values be the criteria for choosing a simulant for assessing the effects of dust on thermal control surfaces, rather than whether a simulant has been formulated as a highlands or a mare simulant.

Gaier, James R.↗
NASA NTRS2011

Thermal Optical Properties of Lunar Dust Simulants and Their Constituents

The total reflectance spectra of lunar simulant dusts (less than 20 micrometer particles) were measured in order to determine their integrated solar absorptance (alpha) and their thermal emittance (e) for the purpose of analyzing the effect of dust on the performance of thermal control surfaces. All of the simulants except one had a wavelength-dependant reflectivity (p(lambda)) near 0.10 over the wavelength range of 8 to 25 micrometers, and so are highly emitting at room temperature and lower. The 300 K emittance (epsilon) of all the lunar simulants except one ranged from 0.78 to 0.92. The exception was Minnesota Lunar Simulant 1 (MLS-1), which has little or no glassy component. In all cases the epsilon was lower for the less 20 micrometer particles than for larger particles reported earlier. There was considerably more variation in the lunar simulant reflectance in the solar spectral range (250 to 2500 nanometers) than in the thermal infrared. As expected, the lunar highlands simulants were more reflective in this wavelength range than the lunar mare simulants. The integrated solar absorptance (alpha) of the simulants ranged from 0.39 to 0.75. This is lower than values reported earlier for larger particles of the same simulants (0.41 to 0.82), and for representative mare and highlands lunar soils (0.74 to 0.91). Since the alpha of some mare simulants more closely matched that of highlands lunar soils, it is recommended that and values be the criteria for choosing a simulant for assessing the effects of dust on thermal control surfaces, rather than whether a simulant has been formulated as a highlands or a mare simulant.

Gaier, James R.↗
NASA NTRS2017

Advanced Characterisation of Aerosol Size Properties from Measurements of Spectral Optical Depth Using the GRASP Algorithm

This study evaluates the potential of using aerosol optical depth (τ (sub a)) measurements to characterise the microphysical and optical properties of atmospheric aerosols. With this aim, we used the recently developed GRASP (Generalized Retrieval of Aerosol and Surface Properties) code for numerical testing of six different aerosol models with different aerosol loads. The direct numerical simulations (self-consistency tests) indicate that the GRASP-AOD retrieval provides modal aerosol optical depths (fine and coarse) to within 0.01 of the input values. The retrieval of the fine-mode radius, width and volume concentration are stable and precise if the real part of the refractive index is known. The coarse-mode properties are less accurate, but they are significantly improved when additional a priori information is available. The tests with random simulated errors show that the uncertainty in the bimodal log-normal size distribution parameters increases as the aerosol load decreases. Similarly, the reduction in the spectral range diminishes the stability of the retrieved parameters. In addition to these numerical studies, we used optical depth observations at eight AERONET locations to validate our results with the standard AERONET inversion products. We found that bimodal log-normal size distributions serve as useful input assumptions, especially when the measurements have inadequate spectral coverage and/or limited accuracy, such as moon photometry. Comparisons of the mode median radii between GRASP-AOD and AERONET indicate average differences of 0.013µm for the fine mode and typical values of 0.2–0.3µm for the coarse mode. The dominant mode (i.e. fine or coarse) indicates a 10 % difference in mode radii between the GRASP-AOD and AERONET inversions, and the average of the difference in volume concentration is around 17 % for both modes. The retrieved values of the fine-mode τ(sub a)(500) using GRASP-AOD are generally between those values obtained by the standard AERONET inversion and the values obtained by the AERONET spectral deconvolution algorithm (SDA), with differences typically lower than 0.02 between GRASP-AOD and both algorithms. Finally, we present some examples of application of GRASP-AOD inversion using moon photometry and the airborne PLASMA sun photometer during the ChArMEx summer 2013 campaign in the western Mediterranean.

Torres, Benjamin↗
NASA NTRS2016

Overview of Global Monitoring of Terrestrial Chlorophyll Fluorescence from Space

Despite the critical importance of photosynthesis for the Earth system, understanding how it is influenced by factors such as climate variability, disturbance history, and water or nutrient availability remains a challenge because of the complex interactions and the lack of GPP measurements at various temporal and spatial scales. Space observations of the sun-induced chlorophyll fluorescence (SIF) electromagnetic signal emitted by plants in the 650-850nm spectral range hold the promise of providing a new view of vegetation photosynthesis on a global basis. Global retrievals of SIF from space have recently been achieved from a number of spaceborne spectrometers originally intended for atmospheric research. Despite not having been designed for land applications, such instruments have turned out to provide the necessary spectral and radiometric sensitivity for SIF retrieval from space. The first global measurements of SIF were achieved in 2011 from spectra acquired by the Japanese GOSAT mission launched in 2009. The retrieval takes advantage of the high spectral resolution provided by GOSATs Fourier Transform Spectrometer (FTS) which allows the evaluation of the in-filling of solar Fraunhofer lines by SIF. Unfortunately, GOSAT only provides a sparse spatial sampling with individual soundings separated by several hundred kilometers. Complementary, the Global Ozone Monitoring Experiment-2 (GOME-2) instruments onboard MetOp-A and MetOp-B enable SIF retrievals since 2007 with a continuous and global spatial coverage. GOME-2 measures in the red and near-infrared (NIR) spectral regions with a spectral resolution of 0.5 nm and a pixel size of up to 40x40 km2. Most recently, another global and spatially continuous data set of SIF retrievals at 740 nm spanning the 2003-2012 time frame has been produced from ENVISATSCIAMACHY. This observational scenario has been completed by the first fluorescence data from the NASA-JPL OCO-2 mission (launched in July 2014) and the upcoming Copernicus' Sentinel 5-Precursor to be launched in early 2016. OCO-2 and TROPOMI offer the possibility of monitoring SIF globally with a 100-fold improvement in spatial and temporal resolution with respect to the current measurements from the GOSAT, GOME-2 and SCIAMACHY missions. In this contribution, we will provide an overview of existing global SIF data sets derived from space-based atmospheric spectrometers and will demonstrate the potential of such data to improve our knowledge of vegetation photosynthesis and gross primary production at the synoptic scale. We will show examples of ongoing research exploiting SIF data for an improved monitoring of photosynthetic activity in different ecosystems, including large crop belts worldwide, the Amazon rainforest and boreal evergreen forests.

vegetation agriculture satellite↗
NASA NTRS2016

Ames S-32 O-16 O-18 Line List for High-Resolution Experimental IR Analysis

By comparing to the most recent experimental data and spectra of the SO2 628 ν1/ν3 bands (see Ulenikov et al., JQSRT 168 (2016) 29-39), this study illustrates the reliability and accuracy of the Ames-296K SO2 line list, which is accurate enough to facilitate such high-resolution spectroscopic analysis. The SO2 628 IR line list is computed on a recently improved potential energy surface (PES) refinement, denoted Ames-Pre2, and the published purely ab initio CCSD(T)/aug-cc-pVQZ dipole moment surface. Progress has been made in both energy level convergence and rovibrational quantum number assignments agreeing with laboratory analysis models. The accuracy of the computed 628 energy levels and line list is similar to what has been achieved and reported for SO2 626 and 646, i.e. 0.01-0.03 cm(exp −1) for bands up to 5500 cm(exp −1). During the comparison, we found some discrepancies in addition to overall good agreements. The three-IR-list based feature-by-feature analysis in a 0.25 cm(exp −1) spectral window clearly demonstrates the power of the current Ames line lists with new assignments, correction of some errors, and intensity contributions from varied sources including other isotopologues. We are inclined to attribute part of detected discrepancies to an incomplete experimental analysis and missing intensity in the model. With complete line position, intensity, and rovibrational quantum numbers determined at 296 K, spectroscopic analysis is significantly facilitated especially for a spectral range exhibiting such an unusually high density of lines. The computed 628 rovibrational levels and line list are accurate enough to provide alternatives for the missing bands or suspicious assignments, as well as helpful to identify these isotopologues in various celestial environments. The next step will be to revisit the SO2 828 and 646 spectral analyses.

Sulfur dioxide↗
NASA NTRS1973

Spectral and Total Normal Emittance of Reusable Surface Insulation Materials

Measurements of spectral and total normal emittance have been made on three types of reusable external insulation materials proposed for space shuttles. Emittances were measured in the spectral range 1 to 15 micrometer at temperatures of 800 K and 1100 K using a radiometric measurement technique. Results indicated that the total normal emittance of these materials was less than 0.8 between 800 K and 1300 K. The total normal emittance decreased with increasing temperature. The three ceramic coating candidate materials exhibited a similar spectral emittance distribution.

Kantsios, A. G.↗
NASA NTRSDate not supplied

Twenty Years of Terra MODIS Spatial Performance Using the Spectro-Radiometric Calibration Assembly

The Moderate Resolution Imaging Spectroradiometer (MODIS) instrument on-board the NASA’s Earth Observing System Terra satellite has continued successful Earth-sensing operations for over 20 years. To aid in its mission in providing calibrated science data to the worldwide user community, the MODIS instrument is equipped with several on-board calibrators designed to measure changes in the instrument response over time. One such calibrator is the Spectro-Radiometric Calibration Assembly (SRCA), which can provide a source signal for radiometric, spectral, or spatial characterization. When commanded into its spatial calibration mode, the SRCA is able to produce light across the MODIS band spectral range (0.412μm to 14.2μm) at a variety of signal levels thanks to several internal halogen lamps, an IR glow bar, and a neutral density filter. This signal, used in combination with commanded sub-sample measurements of the MODIS detectors, provides a basis for determining changes in the spatial performance of the MODIS spectral bands. This work summarizes the spatial calibration process using the SRCA and presents 20 years of Terra MODIS spatial performance characterized through co-registration between MODIS bands, detectors, and focal plane assemblies. Results from pre-launch testing using the Integration and Alignment Collimator and the SRCA are incorporated in the history of the Terra MODIS mission-long spatial performance. We also note modifications to the spatial characterization methodology brought on by changes to the SRCA’s operational configuration and changes to the MODIS spectral band performance, particularly after the recovery from the safe-mode event in February 2016. Results are compared against the MODIS design specifications.

MODIS↗
NASA NTRS2019

A Neural Network Correction to the Scalar Approximation in Radiative Transfer

The next generation of advanced high-resolution sensors in geostationary orbit will gather detailed information for studying the Earth system. There is an increasing desire to perform observing system simulation experiments (OSSEs) for new sensors during the development phase of the mission in order to better leverage information content from the new and existing sensors. Forward radiative transfer calculations that simulate the observing characteristics of a new instrument are the first step to an OSSE, and they are computationally intensive. The scalar approximation to the radiative transfer equation, a simplification of the vector representation, can save considerable computational cost, but produces errors in top of the atmosphere (TOA) radiance as large as 10% due to neglecting polarization effects. This article presents an artificial neural network technique to correct scalar TOA radiance over both land and ocean surfaces to within 1% of vector-calculated radiance. A neural network was trained on a database of scalar-vector TOA radiance differences at a large range of solar and viewing angles for several thousand realistic atmospheric vertical profiles that were sampled from a high resolution (7 km) global atmospheric transport model. The profiles include Rayleigh scattering and aerosol scattering and absorption. Training and validation of the neural network was demonstrated for two wavelengths in the ultraviolet-visible (US-Vis) spectral range (354 nm and 670 nm). The significant computational savings accrued from using a scalar approximation plus neural network correction approach to simulating TOA radiance will make feasible hyperspectral forward simulations of high-resolution sensors on geostationary satellites, such as TEMPO, GOES-R, GEMS, and SENTINEL-4.

TOA↗
NASA NTRS2021

DSN Radio Astronomy Spectrometer

The Deep Space Network (DSN) enables NASA to communicate with its deep space spacecraft. By virtue of its large antennas, the DSN can be used as a powerful instrument for radio astronomy. In particular, Deep Space Station (DSS) 43, the 70 m antenna at the Canberra Deep Space Communications Complex (CDSCC) has a K-band radio astronomy system covering a 10 GHz bandwidth at 17 to 27 GHz. This spectral range covers a number of atomic and molecular lines, produced in a rich variety of interstellar gas conditions. A new high-resolution spectrometer was deployed at CDSCC in November 2019 and connected to the K-band downconverter. The system has two different firmware modes: 1) Using a 65k-pt FFT to provide 32,768 spectral channels at ~30.5 kHz (0.45 km/s velocity resolution) and 2) Using a 16k-pt polyphase filterbank (PFB) to provide 8,192 spectral channels with ~122 kHz resolution (1.8 km/s velocity resolution). Previous work extensively described the spectrometer system. In this paper we present added functionality and updates to the commissioned spectrometer. The changes include developments in system timing, metadata, firmware and data products.

Bradford, Brian↗
NASA NTRS1991

Galileo infrared imaging spectroscopy measurements at Venus

During the 1990 Galileo Venus flyby, the Near Infrared Mapping Spectrometer investigated the night-side atmosphere of Venus in the spectral range 0.7 to 5.2 micrometers. Multispectral images at high spatial resolution indicate substantial cloud opacity variations in the lower cloud levels, centered at 50 kilometers altitude. Zonal and meridional winds were derived for this level and are consistent with motion of the upper branch of a Hadley cell. Northern and southern hemisphere clouds appear to be markedly different. Spectral profiles were used to derive lower atmosphere abundances of water vapor and other species.

Carlson, R. W.↗
NASA NTRS1976

Combustion contribution to noise in jet engines

The relative importance of combustion as a source of noise in a flow regime representative of a subsonic jet engine exhaust was investigated. The combustion noise source characteristics were obtained from pressure and temperature fluctuation measurements in the combustor and exhaust nozzle. The similarity between the fluctuations in this source region and the far field noise were compared. In the jet exhaust velocity range between 450 and 660 ft/sec investigated in detail, the frequencies of dominant pressure and temperature fluctuations in the combustor were also the frequencies of the dominant far field noise. The overall noise levels were 14 to 20 dB higher than from a corresponding clean jet in the same velocity range. Thus it seemed clear that the unsteadiness associated with the combustion process was responsible for the dominant noise in the far field. A simple analysis to predict the far field noise due to the internal pressure fluctuations causing exit plane velocity fluctuations produced trends closely resembling the measured results, but under predicted the far field noise over the spectral range examined. The possible reason for the higher far field noise is direct transmission of acoustic waves through the nozzle, which was not accounted for in the prediction scheme.

Plett, E. G.↗