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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Do blue galaxy-clusters have hot intracluster gas?

Abstract We present herein a systematic X-ray analysis of blue galaxy clusters at z = 0.84 discovered by the Subaru telescope. The sample consisted of 43 clusters identified by combining red-sequence and blue-cloud surveys, covering a wide range of emitter fractions (i.e., 0.3–0.8). The spatial extent of the over-density region of emitter galaxies was approximately 1 Mpc in radius. The average cluster mass was estimated as 0.6(<1.5) × 1014 M⊙ from the stacked weak-lensing measurement. We analyzed the XMM-Newton archival data, and measured the X-ray luminosity of the hot intracluster medium. As a result, diffuse X-ray emission was marginally detected in 14 clusters, yielding an average luminosity of 5 × 1042 erg s−1. To the contrary, it was not significant in 29 clusters. The blue clusters were significantly fainter than the red-dominated clusters, and the X-ray luminosity did not show any meaningful correlation either with emitter fraction or richness. The X-ray surface brightness was low, but the amount of gas mass was estimated to be comparable to that observed in the 1013–1014 M⊙ cluster. Based on the results, we suggest that the blue clusters are at the early formation stage, and the gas is yet to be compressed and heated up to produce appreciable X-rays. Follow-up spectroscopic measurements are essential to clarify the dynamical status and co-evolution of galaxies and hot gas in the blue clusters.

Misato, Rana↗
DOE OSTI2021

Direct observation of the exotic β – γ – α decay mode in the T z = – 1 nucleus Na 20

The exotic β – γ – α decay mode of 20 Na has been directly observed for the first time in the Day-one experiment at the Beijing Radioactive Ion-beam Facility. The 20 Na source was produced by using a 100-MeV proton beam bombarding a stack of microporous MgO thick target and delivered as an intense mass separated beam after online ionization. A high-efficiency simultaneous measurement of β, γ, and α transitions enables the β-delayed γ – γ and α – γ coincidence spectroscopy. Here three β – γ – α exotic decay sequences in 20 Na are discovered, which expands the rare decay modes observed in β decay. Moreover, a β – α –decay sequence to the 6130-keV 3 – state of 16 O is observed, which is likely through the 12367-keV 1 + state in 20 Ne. The experimentally deduced B(F) and B(GT) are compared to the shell-model calculation, the allowed β transition strengths can be well accounted for by using sd shell-model space interactions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2022

The first crystal structures of hybrid and parallel four-tetrad intramolecular G-quadruplexes

Abstract G-quadruplexes (GQs) are non-canonical DNA structures composed of stacks of stabilized G-tetrads. GQs play an important role in a variety of biological processes and may form at telomeres and oncogene promoters among other genomic locations. Here, we investigate nine variants of telomeric DNA from Tetrahymena thermophila with the repeat (TTGGGG)n. Biophysical data indicate that the sequences fold into stable four-tetrad GQs which adopt multiple conformations according to native PAGE. Excitingly, we solved the crystal structure of two variants, TET25 and TET26. The two variants differ by the presence of a 3′-T yet adopt different GQ conformations. TET25 forms a hybrid [3 + 1] GQ and exhibits a rare 5′-top snapback feature. Consequently, TET25 contains four loops: three lateral (TT, TT, and GTT) and one propeller (TT). TET26 folds into a parallel GQ with three TT propeller loops. To the best of our knowledge, TET25 and TET26 are the first reported hybrid and parallel four-tetrad unimolecular GQ structures. The results presented here expand the repertoire of available GQ structures and provide insight into the intricacy and plasticity of the 3D architecture adopted by telomeric repeats from T. thermophila and GQs in general.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

An End-To-End Earthquake Detection Method for Joint Phase Picking and Association Using Deep Learning

Earthquake monitoring by seismic networks typically involves a workflow consisting of phase detection/picking, association, and location tasks. In recent years, the accuracy of these individual stages has been improved through the use of machine learning techniques. Here, in this study, we introduce a new end-to-end approach that improves overall earthquake detection accuracy by jointly optimizing each stage of the detection pipeline. We propose a neural network architecture for the task of multi-station processing of seismic waveforms recorded over a seismic network. This end-to-end architecture consists of three sub-networks: a backbone network that extracts features from raw waveforms, a phase picking sub-network that picks P- and S-wave arrivals based on these features, and an event detection sub-network that aggregates the features from multiple stations to associate and detect earthquakes across a seismic network. We use these sub-networks together with a shift-and-stack module based on back-projection that introduces kinematic constraints on arrival times, allowing the neural network model to generalize to different velocity models and to variable station geometry in seismic networks. We evaluate our proposed method on the STanford EArthquake Dataset (STEAD) and on the 2019 Ridgecrest, CA earthquake sequence. The results demonstrate that our end-to-end approach can effectively pick P- and S-wave arrivals and achieve earthquake detection accuracy rivaling that of other state-of-the-art approaches. Because our approach preserves information across tasks in the detection pipeline, it has the potential to outperform approaches that do not.

58 GEOSCIENCES↗
NASA NTRS2013

HST-WFC3 Near-Infrared Spectroscopy of Quenched Galaxies at zeta approx 1.5 from the WISP Survey: Stellar Populations Properties

We combine Hubble Space Telescope (HST) G102 and G141 near-IR (NIR) grism spectroscopy with HST/WFC3- UVIS, HST/WFC3-IR, and Spitzer/IRAC [3.6 microns] photometry to assemble a sample of massive (log(Mstar/M solar mass) at approx 11.0) and quenched (specific star formation rate < 0.01 G/yr(exp −1) galaxies at zeta approx 1.5. Our sample of 41 galaxies is the largest with G102+G141 NIR spectroscopy for quenched sources at these redshifts. In contrast to the local universe, zeta approx 1.5 quenched galaxies in the high-mass range have a wide range of stellar population properties. We find that their spectral energy distributions (SEDs) are well fitted with exponentially decreasing star formation histories and short star formation timescales (τau less than or equal to 100 M/yr). Quenched galaxies also show a wide distribution in ages, between 1 and 4 G/yr. In the (u − r)0-versus-mass space quenched galaxies have a large spread in rest-frame color at a given mass. Most quenched galaxies populate the zeta appro. 1.5 red sequence (RS), but an important fraction of them (32%) have substantially bluer colors. Although with a large spread, we find that the quenched galaxies on the RS have older median ages (3.1 G/yr) than the quenched galaxies off the RS (1.5 G/yr). We also show that a rejuvenated SED cannot reproduce the observed stacked spectra of (the bluer) quenched galaxies off the RS. We derive the upper limit on the fraction of massive galaxies on the RS at zeta approx 1.5 to be <43%.We speculate that the young quenched galaxies off the RS are in a transition phase between vigorous star formation at zeta > 2 and the zeta approx 1.5 RS. According to their estimated ages, the time required for quenched galaxies off the RS to join their counterparts on the z approx. 1.5 RS is of the order of approx. 1G/yr.

HST WFC#↗
NASA NTRS2008

Ares I-X Flight Test Vehicle Similitude to the Ares I Crew Launch Vehicle

The Ares I-X Flight Test Vehicle is the first in a series of flight test vehicles that will take the Ares I Crew Launch Vehicle design from development to operational capability. The test flight is scheduled for April 2009, relatively early in the Ares I design process so that data obtained from the flight can impact the design of Ares I before its Critical Design Review. Because of the short time frame (relative to new launch vehicle development) before the Ares I-X flight, decisions about the flight test vehicle design had to be made in order to complete analysis and testing in time to manufacture the Ares I-X vehicle hardware elements. This paper describes the similarities and differences between the Ares I-X Flight Test Vehicle and the Ares I Crew Launch Vehicle. Areas of comparison include the outer mold line geometry, aerosciences, trajectory, structural modes, flight control architecture, separation sequence, and relevant element differences. Most of the outer mold line differences present between Ares I and Ares I-X are minor and will not have a significant effect on overall vehicle performance. The most significant impacts are related to the geometric differences in Orion Crew Exploration Vehicle at the forward end of the stack. These physical differences will cause differences in the flow physics in these areas. Even with these differences, the Ares I-X flight test is poised to meet all five primary objectives and six secondary objectives. Knowledge of what the Ares I-X flight test will provide in similitude to Ares I as well as what the test will not provide is important in the continued execution of the Ares I-X mission leading to its flight and the continued design and development of Ares I.

Huebner, Lawrence D.↗
NASA NTRS2009

Ares I-X Flight Test Vehicle Similitude to the Ares I Crew Launch Vehicle

The Ares I-X Flight Test Vehicle is the first in a series of flight test vehicles that will take the Ares I Crew Launch Vehicle design from development to operational capability. Ares I-X is scheduled for a 2009 flight date, early enough in the Ares I design and development process so that data obtained from the flight can impact the design of Ares I before its Critical Design Review. Decisions on Ares I-X scope, flight test objectives, and FTV fidelity were made prior to the Ares I systems requirements being baselined. This was necessary in order to achieve a development flight test to impact the Ares I design. Differences between the Ares I-X and the Ares I configurations are artifacts of formulating this experimental project at an early stage and the natural maturation of the Ares I design process. This paper describes the similarities and differences between the Ares I-X Flight Test Vehicle and the Ares I Crew Launch Vehicle. Areas of comparison include the outer mold line geometry, aerosciences, trajectory, structural modes, flight control architecture, separation sequence, and relevant element differences. Most of the outer mold line differences present between Ares I and Ares I-X are minor and will not have a significant effect on overall vehicle performance. The most significant impacts are related to the geometric differences in Orion Crew Exploration Vehicle at the forward end of the stack. These physical differences will cause differences in the flow physics in these areas. Even with these differences, the Ares I-X flight test is poised to meet all five primary objectives and six secondary objectives. Knowledge of what the Ares I-X flight test will provide in similitude to Ares I - as well as what the test will not provide - is important in the continued execution of the Ares I-X mission leading to its flight and the continued design and development of Ares I.

Huebner, Lawrence D.↗
NASA NTRS1995

Secondary structure in solution of two anti-HIV-1 hammerhead ribozymes as investigated by two-dimensional 1H 500 MHz NMR spectroscopy in water

Two hammerhead chimeric RNA/DNA ribozymes (HRz) were synthesized in pure form. Both were 30 nucleotides long, and the sequences were such that they could be targeted to cleave the HIV-1 gag RNA. Named HRz-W and HRz-M, the former had its invariable core region conserved, the latter had a uridine in the invariable region replaced by a guanine. Their secodary structures were determined by 2D NOESY 1H 500 MHz NMR spectroscopy in 90% water and 10% D2(0), following the imino protons. The data show that both HRz-M and HRz-W form identical secondary structures with stem regions consisting of continuous stacks of AT and GT pairs. An energy minimized computer model of this stem region is provided. The results suggest that the loss of catalytic activity that is known to result when an invariant core residue is replaced is not related to the secondary structure of the ribozymes in the absence of substrate.

NASA Discipline Exobiology↗
NASA NTRSDate not supplied

Sedimentology and Stratigraphy of the Lower Delta Sequence, Jezero Crater, Mars.

In April 2022, the Mars 2020 Perseverance rover arrived at the base of the ancient delta in Jezero crater after completing the first year of its mission exploring and sampling aqueously altered igneous rocks of the present-day crater floor. Perseverance then spent ~200 sols exploring the lower ~25 m of rock exposed within the eastern scarp of the Jezero delta, a sedimentary sequence informally named the ‘Shenandoah’ formation. This study describes the sedimentology and stratigraphy of the Shenandoah formation explored by Perseverance at two sections—'Cape Nukshak’ and ‘Hawksbill Gap’—including a description, interpretation, and depositional framework for the facies that comprise it.

K. M. Stack↗
DOE OSTI2021

WALLABY pilot survey: H i gas disc truncation and star formation of galaxies falling into the Hydra I cluster

ABSTRACT We present results from our analysis of the Hydra I cluster observed in neutral atomic hydrogen (H i) as part of the Widefield ASKAP L-band Legacy All-sky Blind Survey (WALLABY). These WALLABY observations cover a 60-square-degree field of view with uniform sensitivity and a spatial resolution of 30 arcsec. We use these wide-field observations to investigate the effect of galaxy environment on H i gas removal and star formation quenching by comparing the properties of cluster, infall, and field galaxies extending up to ∼5R200 from the cluster centre. We find a sharp decrease in the H i-detected fraction of infalling galaxies at a projected distance of ∼1.5R200 from the cluster centre from $\sim 85{{\ \rm per\ cent}}$ to $\sim 35{{\ \rm per\ cent}}$. We see evidence for the environment removing gas from the outskirts of H i-detected cluster and infall galaxies through the decrease in the H i to r-band optical disc diameter ratio. These galaxies lie on the star-forming main sequence, indicating that gas removal is not yet affecting the inner star-forming discs and is limited to the galaxy outskirts. Although we do not detect galaxies undergoing galaxy-wide quenching, we do observe a reduction in recent star formation in the outer disc of cluster galaxies, which is likely due to the smaller gas reservoirs present beyond the optical radius in these galaxies. Stacking of H i non-detections with H i masses below $M_{\rm {HI}}\lesssim 10^{8.4}\, \rm {M}_{\odot }$ will be required to probe the H i of galaxies undergoing quenching at distances ≳60 Mpc with WALLABY.

Reynolds, T. N. (ORCID:0000000266065953)↗
NASA NTRS2008

Microwave Soil Moisture Retrieval Under Trees

Soil moisture is recognized as an important component of the water, energy, and carbon cycles at the interface between the Earth's surface and atmosphere. Current baseline soil moisture retrieval algorithms for microwave space missions have been developed and validated only over grasslands, agricultural crops, and generally light to moderate vegetation. Tree areas have commonly been excluded from operational soil moisture retrieval plans due to the large expected impact of trees on masking the microwave response to the underlying soil moisture. Our understanding of the microwave properties of trees of various sizes and their effect on soil moisture retrieval algorithms at L band is presently limited, although research efforts are ongoing in Europe, the United States, and elsewhere to remedy this situation. As part of this research, a coordinated sequence of field measurements involving the ComRAD (for Combined Radar/Radiometer) active/passive microwave truck instrument system has been undertaken. Jointly developed and operated by NASA Goddard Space Flight Center and George Washington University, ComRAD consists of dual-polarized 1.4 GHz total-power radiometers (LH, LV) and a quad-polarized 1.25 GHz L band radar sharing a single parabolic dish antenna with a novel broadband stacked patch dual-polarized feed, a quad-polarized 4.75 GHz C band radar, and a single channel 10 GHz XHH radar. The instruments are deployed on a mobile truck with an 19-m hydraulic boom and share common control software; real-time calibrated signals, and the capability for automated data collection for unattended operation. Most microwave soil moisture retrieval algorithms developed for use at L band frequencies are based on the tau-omega model, a simplified zero-order radiative transfer approach where scattering is largely ignored and vegetation canopies are generally treated as a bulk attenuating layer. In this approach, vegetation effects are parameterized by tau and omega, the microwave vegetation opacity and single scattering albedo. One goal of our current research is to determine whether the tau-omega model can work for tree canopies given the increased scatter from trees compared to grasses and crops, and. if so, what are effective values for tau and omega for trees.

O'Neill, P.↗
DOE OSTI2022

High-throughput detection of T-DNA insertion sites for multiple transgenes in complex genomes

Abstract Background Genetic engineering of crop plants has been successful in transferring traits into elite lines beyond what can be achieved with breeding techniques. Introduction of transgenes originating from other species has conferred resistance to biotic and abiotic stresses, increased efficiency, and modified developmental programs. The next challenge is now to combine multiple transgenes into elite varieties via gene stacking to combine traits. Generating stable homozygous lines with multiple transgenes requires selection of segregating generations which is time consuming and labor intensive, especially if the crop is polyploid. Insertion site effects and transgene copy number are important metrics for commercialization and trait efficiency. Results We have developed a simple method to identify the sites of transgene insertions using T-DNA-specific primers and high-throughput sequencing that enables identification of multiple insertion sites in the T 1 generation of any crop transformed via Agrobacterium . We present an example using the allohexaploid oil-seed plant Camelina sativa to determine insertion site location of two transgenes. Conclusion This new methodology enables the early selection of desirable transgene location and copy number to generate homozygous lines within two generations.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS2024

Depositional History of the Upper Sequence of the Western Fan: Evidence for Late-Stage Fluvial and Potential Igneous Activity, Jezero Crater, Mars

Within Jezero crater, a 45 km diameter Noachian-aged crater on Mars, the Upper Fan group (UFg) stratigraphy records the youngest interval of sediment deposition via aqueous activity on the western fan. From orbital images, the UFg surface is characterized by ridges interpreted to be associated with channels that can be group based on orientation into distinct elongate and fan-shaped deposits. UFg deposits primarily consist of a sandstone to granule conglomerate facies covered by a lithified boulder conglomerate or dense accumulations of loose boulders along the surface. The coarse-grained nature of UFg deposits and the unconformable contact with the underlying fan stratigraphy suggest that the UFg represents a higher-energy shift from the relatively longer-lived, lower-energy aqueous systems interpreted in underlying fan stratigraphy. The Mars 2020 Perseverance rover encountered the main exposures of the UFg deposits beginning on Sol 755 and has been continuously collecting data along its northwestward traverse across the fan, enabling reconciliation of orbitally-derived geomorphology with in-situ observations from the rover and Ingenuity helicopter. This work represents a combined assessment of the geomorphology and the sedimentology and stratigraphy of the UFg in order to establish its depositional and emplacement history. Determining the origins of the Upper Fan sequence will clarify how, when, and in what order aqueous environments evolved through time within Jezero crater (e.g. crater infill, overflow, breach, and lake level drop;). Finally, this work will provide critical context for the three rock samples within the UFg sample suite.

Mars 2020↗
DOE OSTI2023

Laboratory-Scale Coal-Derived Graphene Process (Final Report)

The Energy & Environmental Research Center (EERC) conducted a laboratory-scale coal-derived graphene (CDG) project focused on developing a technological process for making graphene from four U.S. domestic coal or coal wastes, including lignite from North Dakota, subbituminous coal from Wyoming, bituminous coal from Utah, and anthracite from Pennsylvania. The project was divided into two performance or budget periods (BPs), with BP1 comprising the up-front laboratory experiments to make graphene materials from coal beginning on May 1, 2020, to April 30, 2022. BP2 was conducted from May 1, 2022, to April 30, 2023, and was focused on analyzing the CDG process economic feasibility and the technical gaps for technological scale-up and commercialization. During this project, a few different coal-derived high-value products have been demonstrated, including graphite, graphene oxide (GO), reduced graphene oxide (rGO), and graphene quantum dots (GQDs). A new graphite microstructure was discovered and named “croissant graphite” because of the exterior morphological and textural resemblance to croissant food items sold in commercial groceries stores. The new graphite structure and the associated preparation from coal or coal waste feedstocks has been the subject of a U.S. patent application. The systematic experimental processes involving coal cleaning, upgrading, and conversion to high-value carbon products culminated into a developed upgraded coal-to-products (UCP) technology that is being pursued for potential fast-track commercialization, if funding is available. It is envisioned that commercialization of the UCP technology would increase consumption of U.S. domestic coals or coal wastes to make environmentally sustainable high-value products for the electronics industry, high-energy-storage applications, and clean energy technologies such as electric vehicle (EV) lithium-ion batteries (LIBs), for which graphite has become a critical mineral commodity. Croissant graphite microstructures, when observed by field emission scanning electron microscopy (FESEM), display wavy surface morphology and often grow from a base that is made of graphitized particles with honeycomb-like layers, which are believed to be graphene layers. While more studies are needed to fully ascertain the mechanisms of the croissant graphite microstructure formation, it is postulated that their growth may begin from curling of the graphene sheets into ribbon-like structures, and continuous growth and densification of the ribbon-like structures forms croissant microstructures. Additional studies are ongoing to evaluate the electrochemical performance of croissant graphite for LIB applications and to determine the experimental conditions necessary to tune on/off croissant formation so that it can be either optimized or suppressed depending on performance evaluation results. In addition to the discovery of croissant graphite, the graphitization process from the four coal ranks in general was successful. X-ray diffraction (XRD) analysis showed that the degree of graphitization (DoG) ranged from 12% to 80% in an early sample set, and further optimization on lignite coal produces a DoG of about 92%, which was spectacular to see as lignite is the lowest-rank coal. Thus, it is expected that the graphitization performance for higher-rank coals will be similar or better when optimized as well. The coal-derived graphite was used to make GO and rGO. Analytical characterization, e.g., by methods such as Raman spectroscopy, XRD, Fourier transform infrared (FTIR) spectroscopy and FESEM, showed that the sequence of converting the coal to graphite, exfoliating it to GO, and then chemically reducing the GO to rGO was successful. Although coal naturally contains aromatic compounds and some relatively small-sized condensed aromatic units, it does not contain graphene sheets. In the UCP process, the aromatic domains in the coals, particularly low-rank coals, are concentrated and condensed further into graphene sheets, which are ordered into a 3D stack during graphitization. The synthesized graphite is then unpacked by methods such as exfoliation to various graphene products. GQDs were synthesized from all four coal types, and their optical properties were demonstrated to be tunable by the coal precursor preprocessing treatments. In all four coal types, enhanced optical properties were observed for the produced GDQs with incremental improvements made to the coal precursors. GQDs produced from raw coal samples displayed lower ultraviolet–visible (UV–Vis) spectroscopy absorbance intensity compared to those obtained from cleaned and upgraded coal residues. The photoluminescence (PL) intensities also varied with pretreatment conditions and with the concentration of GQDs in aqueous solutions. GQDs obtained from anthracite show longer emission wavelengths and can be excited by visible light as opposed to GQDs derived from the other coal ranks. UV fluorescence 3D maps and spectra revealed that the emission wavelength at which the GQDs solutions display the highest intensity was slightly redshifted based on the coal precursor pretreatments. In low-rank coal (lignite and subbituminous) samples, two clusters were observed in the maps for GQDs, which may suggest that there are potentially two types of fluorophores in solution or two main size populations. The ability to tune the properties of GQDs based on processing methods can be exploited to make GQDs for various optical display or optoelectronics applications. The results also highlight the importance of removing coal-borne impurities to improve the quality of the coal precursor for preparation of graphene products. Coal and/or coal wastes preprocessing methods were developed and applied to clean and upgrade the coal precursors prior to graphitization and subsequent conversion to graphene products. The preprocessing methods involve high specific-gravity separations, mineral acid cleaning (no hydrofluoric acid), and subsequent upgrading by reducing the coal-borne heteroatom (nitrogen, sulfur, and oxygen) content using proprietary chemical agents. Analytical characterization revealed that the preprocessing steps were successful, with ash reductions that range from 38% to 80% and residual ash content that was below the 5 wt% initial target. Based on proximate and ultimate analysis, the heteroatom reduction reactions produced upgraded coal residues with the oxygen content reduced by 8% to 24%, with additional reductions in the nitrogen and sulfur contents. An initial assessment of the waste streams from the UCP process shows very small to negligible environmental impact due to CO 2 , NO x , and SO x because most process steps are performed under inert atmosphere with argon. Consequently, reactive oxygen environments that tend to create these species are avoided. The inorganic and potentially hazardous species are released into aqueous waste streams that are easy to handle for proper disposal. The liquid waste streams were found to contain low-level concentrations of rare-earth elements (REEs), which could be concentrated and recovered as value-added by-products. Additionally, the volatile and gaseous fractions from carbonization and heat treatment contain useful organic compounds that can also be recovered as potential valuable by-products. Thus, the UCP technology is considered an environmentally sustainable and promising emerging technology for making high-value products from coal and coal wastes, with potential additional value-added by-products. Analysis of potential markets for the coal-derived carbon products shows a strong demand in both niche market sectors and across a wide variety of other industrial sectors. Graphite is currently considered a critical mineral commodity that has a large and growing demand in the LIB industry for EV applications. Based on data from Fortune Business Insights (2022) and Marketwatch (2023) reports, the average global graphite market is projected to reach about 33 billion by 2028, growing at a compound annual growth rate (CAGR) of about 7%, with much of this growth expected to be in the LIB industry. GO and rGO have strong market potentials in various application areas, such as coatings for anticorrosion, anti-icing, and antimicrobial protection, thermal barriers, wear resistance, sensors, additive manufacturing such as 3D inks, and others. GQDs are the emerging key player in the bioimaging, photovoltaics, and light-emitting diodes (LEDs) applications, with the potential to replace traditional semiconductor quantum dots (SQDs), which are based on metallic systems that are more toxic and more expensive. Biomedical applications of GQDs are becoming more attractive because of low to no toxicity and extremely low cost compared to SQDs. The major challenges for scale-up and commercialization of coal-derived carbon products such as graphene vary from the inherent attributes of graphene itself to reluctance to accept graphene in new manufacturing processes because of the uncertainty of the unknown. The 2D nature of graphene materials with a thickness of one atom presents significant challenges to proper handling/processing, and process scale-up becomes difficult because it requires high-end, expensive equipment, even for routine handling and analysis for quality assurance and control. Pristine graphene can also be extremely difficult to work into other matrices, thus hindering downstream processibility, especially at large scale. Currently, the cost of graphene and graphene products is still high and presents an economic risk that tends to slow down investment in scaling up emerging technologies. The lack of a standard for graphene materials for quality assurance and quality control poses a great challenge not only for the markets but also for commercialization efforts. A first-look economic feasibility analysis of the UCP technology provided valuable information that suggests the UCP process would be feasible, especially when it is scaled to a pilot scale and could be more competitive at the full scale. Graphitization was found to be the most energy-consuming and most capital-intensive step in the overall process. In small laboratory- and bench-scale experiments, labor is a significant contributor to the total process costs. Although these energy, capital, and labor constraints contribute to a higher selling price for the product, a preliminary economic model suggests that the process would be feasible at large scale when the process is fully integrated, optimized, and automated.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2025

Turbo‐charging crop improvement: harnessing multiplex editing for polygenic trait engineering and beyond

Multiplex CRISPR editing has emerged as a transformative platform for plant genome engineering, enabling the simultaneous targeting of multiple genes, regulatory elements, or chromosomal regions. This approach is effective for dissecting gene family functions, addressing genetic redundancy, engineering polygenic traits, and accelerating trait stacking and de novo domestication. Its applications now extend beyond standard gene knockouts to include epigenetic and transcriptional regulation, chromosomal engineering, and transgene‐free editing. These capabilities are advancing crop improvement not only in annual species but also in more complex systems such as polyploids, undomesticated wild relatives, and species with long generation times. At the same time, multiplex editing presents technical challenges, including complex construct design and the need for robust, scalable mutation detection. We discuss current toolkits and recent innovations in vector architecture, such as promoter and scaffold engineering, that streamline workflows and enhance editing efficiency. High‐throughput sequencing technologies, including long‐read platforms, are improving the resolution of complex editing outcomes such as structural rearrangements—often missed by standard genotyping—when targeting repetitive or tandemly spaced loci. To fully realize the potential of multiplex genome engineering, there is growing demand for user‐friendly, synthetic biology‐compatible, and scalable computational workflows for gRNA design, construct assembly, and mutation analysis. Experimentally validated inducible or tissue‐specific promoters are also highly desirable for achieving spatiotemporal control. As these tools continue to evolve, multiplex CRISPR editing is poised to become a foundational technology of next‐generation crop improvement to address challenges in agriculture, sustainability, and climate resilience.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Nature of the galaxies on top of quasars producing Mg ii absorption

ABSTRACT Quasar–galaxy pairs at small separations are important probes of gas flows in the disc–halo interface in galaxies. We study host galaxies of 198 Mg ii absorbers at 0.39 ≤ zabs ≤ 1.05 that show detectable nebular emission lines in the Sloan Digital Sky Survey (SDSS) spectra. We report measurements of impact parameter (5.9 ≤ D [kpc] ≤ 16.9) and absolute B-band magnitude (−18.7 ≤ MB ≤ −22.3 mag) of host galaxies of 74 of these absorbers using multiband images from the Dark Energy Spectroscopic Instrument (DESI) Legacy Imaging Survey, more than doubling the number of known host galaxies with D ≤ 17 kpc. This has allowed us to quantify the relationship between Mg ii rest equivalent width (W2796) and D, with best-fitting parameters of W2796 (D = 0) = 3.44 ± 0.20 Å and an exponential scale length of 21.6$^{+2.41}_{-1.97}\, \mathrm{ kpc}$. We find a significant anticorrelation between MB and D, and MB and W2796, consistent with the brighter galaxies producing stronger Mg ii absorption. We use stacked images to detect average emissions from galaxies in the full sample. Using these images and stacked spectra, we derive the mean stellar mass (9.4 ≤ log(M*/M⊙) ≤ 9.8), star formation rate (2.3 ≤ SFR [M⊙ yr−1] ≤ 4.5), age (2.5–4 Gyr), metallicity (12 + log(O/H) ∼ 8.3), and ionization parameter (log q [cm s−1] ∼ 7.7) for these galaxies. The average M* found is less than that of Mg ii absorbers studied in the literature. The average SFR and metallicity inferred are consistent with that expected in the main sequence and the known stellar mass–metallicity relation, respectively. High spatial resolution follow-up spectroscopic and imaging observations of this sample are imperative for probing gas flows close to the star-forming regions of high-z galaxies.

Astronomy & Astrophysics↗
DOE OSTI2023

Time-reversal symmetry breaking superconductivity between twisted cuprate superconductors

Twisted interfaces between stacked van der Waals (vdW) cuprate crystals present a platform for engineering superconducting order parameters by adjusting stacking angles. Using a cryogenic assembly technique, we construct twisted vdW Josephson junctions (JJs) at atomically sharp interfaces between Bi 2 Sr 2 CaCu 2 O 8+x crystals, with quality approaching the limit set by intrinsic JJs. Near 45° twist angle, we observe fractional Shapiro steps and Fraunhofer patterns, consistent with the existence of two degenerate Josephson ground states related by time-reversal symmetry (TRS). By programming the JJ current bias sequence, we controllably break TRS to place the JJ into either of the two ground states, realizing reversible Josephson diodes without external magnetic fields. Furthermore, our results open a path to engineering topological devices at higher temperatures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

SAGAbg. II. The Low-mass Star-forming Sequence Evolves Significantly between 0.05 < z < 0.21

The redshift-dependent relation between galaxy stellar mass and star formation rate (SFR), known as the star-forming sequence (SFS), is a key observational yardstick for galaxy assembly. We use the SAGAbg-A sample of background galaxies from the Satellites Around Galactic Analogs (SAGA) Survey to model the low-redshift evolution of the low-mass SFS. The sample is comprised of 23,258 galaxies with Hα-based SFRs spanning 6 < log 10 (M * /[M ⊙ ]) < 10 and z < 0.21 (t < 2.5 Gyr). Although it is common to bin or stack galaxies at z ≲ 0.2 for galaxy population studies, the difference in lookback time between z = 0 and z = 0.21 is comparable to the time between z = 1 and z = 2. We develop a model to account for both the physical evolution of low-mass SFS and the selection function of the SAGA Survey, allowing us to disentangle redshift evolution from redshift-dependent selection effects across the SAGAbg-A redshift range. Our findings indicate significant evolution in the SFS over the last ∼2.5 Gyr, with a rising normalization: $\langle$SRF(M * = 10 8.5 M ⊙ )$\rangle$ (z) = 1.24$^{+0.25}_{–0.23}$z – 1.47$^{+0.03}_{–0.03}$. We also identify the redshift limit at which a static SFS is ruled out at the 95% confidence level, which is z = 0.05 based on the precision of the SAGAbg-A sample. Comparison with cosmological hydrodynamic simulations reveals that some contemporary simulations underpredict the recent evolution of the low-mass SFS. This demonstrates that the recent evolution of the low-mass SFS can provide new constraints on the assembly of the low-mass Universe and highlights the need for improved models in this regime.

79 ASTRONOMY AND ASTROPHYSICS↗