Search NASA⌕ Search

SEARCH · Search NASA

Results for “surface complexation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 361 records · Page 20

Impact of low-temperature plasmas on Deinococcus radiodurans and biomolecules

The effects of cold plasma on Deinococcus radiodurans, plasmid DNA, and model proteins were assessed using microbiological, spectrometric, and biochemical techniques. In low power O(2) plasma (approximately 25 W, approximately 45 mTorr, 90 min), D. radiodurans, a radiation-resistant bacterium, showed a 99.999% reduction in bioburden. In higher power O(2) plasma (100 W and 500 mTorr), the reduction rate increased about 10-fold and observation by atomic force microscopy showed significant damage to the cell. Damage to cellular lipids, proteins, and chromosome was indicated by losses of infrared spectroscopic peaks at 2930, 1651, 1538, and 1245 cm(-1), respectively. In vitro experiments show that O(2) plasmas induce DNA strand scissions and cross-linking as well as reduction of enzyme activity. The observed degradation and removal of biomolecules was power-dependent. Exposures to 200 W at 500 mTorr removed biomolecules to below detection limits in 60 s. Emission spectroscopy indicated that D. radiodurans cells were volatilized into CO(2), CO, N(2), and H(2)O, confirming that these plasmas were removing complex biological matter from surfaces. A CO(2) plasma was not as effective as the O(2) plasma, indicating the importance of plasma composition and the dominant role of chemical degradation. Together, these findings have implications for NASA planetary protection schemes and for the contamination of Mars.

Evaluation Studies↗

The Contribution of CEOP Data to the Understanding and Modeling of Monsoon Systems

CEOP has contributed and will continue to provide integrated data sets from diverse platforms for better understanding of the water and energy cycles, and for validaintg models. In this talk, I will show examples of how CEOP has contributed to the formulation of a strategy for the study of the monsoon as a system. The CEOP data concept has led to the development of the CEOP Inter-Monsoon Studies (CIMS), which focuses on the identification of model bias, and improvement of model physics such as the diurnal and annual cycles. A multi-model validation project focusing on diurnal variability of the East Asian monsoon, and using CEOP reference site data, as well as CEOP integrated satellite data is now ongoing. Preliminary studies show that climate models have difficulties in simulating the diurnal signals of total rainfall, rainfall intensity and frequency of occurrence, which have different peak hours, depending on locations. Further more model diurnal cycle of rainfall in monsoon regions tend to lead the observed by about 2-3 hours. These model bias offer insight into lack of, or poor representation of, key components of the convective and stratiform rainfall. The CEOP data also stimulated studies to compare and contrasts monsoon variability in different parts of the world. It was found that seasonal wind reversal, orographic effects, monsoon depressions, meso-scale convective complexes, SST and land surface land influences are common features in all monsoon regions. Strong intraseasonal variability is present in all monsoon regions. While there is a clear demarcation of onset, breaks and withdrawal in the Asian and Australian monsoon region associated with climatological intraseasonal variabillity, it is less clear in the American and Africa monsoon regions. The examination of satellite and reference site data in monsoon has led to preliminary model experiments to study the impact of aerosol on monsoon variability. I will show examples of how the study of the dynamics of aerosol-water cycle interactions in the monsoon region, can be best achieved using the CEOP data and modeling strategy.

Lau, William K. M.↗

Ion Neutral Mass Spectrometer Measurements from Titan

Introduction: The Ion Neutral Mass Spectrometer (INMS) aboard the Cassini orbiter has obtained the first in situ composition measurements of the neutral densities of molecular nitrogen, methane, argon, and a host of stable carbon-nitrile compounds in its first flyby of Titan. The bulk composition and thermal structure of the moon s upper atmosphere do not appear to be changed since the Voyager flyby in 1979. However, the more sensitive techniques provided by modern in-situ mass spectrometry also give evidence for large-spatial-scale large-amplitude atmospheric waves in the upper atmosphere and for a plethora of stable carbon-nitrile compounds above 1174 km. Furthermore, they allow the first direct measurements of isotopes of nitrogen, carbon, and argon, which provide interesting clues about the evolution of the atmosphere. The atmosphere was first accreted as ammonia and ammonia ices from the Saturn sub-nebula. Subsequent photochemistry likely converted the atmosphere into molecular nitrogen. The early atmosphere was 1.5 to 5 times more substantial and was lost via escape over the intervening 4.5 billion years due to the reduced gravity associated with the relatively small mass of Titan. Carbon in the form of methane has continued to outgas over time from the interior with much of it being deposited in the form of complex hydrocarbons on the surface and some of it also being lost to space.

Waite, J. H., Jr.↗

Tholins as Coloring Agents on Outer Solar System Bodies

The red colors of many solid bodies in outer Solar System may be caused by tholins, which are refractory organic complexes, incorporated in their surface materials. Tholins synthesized in the laboratory are shown to match the colors of these bodies when their optical properties are used in rigorous scattering models. We review recent successes in modeling the spectra of icy outer Solar System bodies with tholins as the coloring agents. New work on the systematic laboratory synthesis and analysis of tholins made by cold plasma discharge in mixtures of gaseous CH4/N2 shows that the composition of the tholin depends strongly on the pressure in the reaction chamber, and only weakly on the mixing fraction of CH4 relative to N2. In tholins made at high pressure (e.g., 23 hPa) the abundance of aliphatic hydrocarbons is greater and the abundance of aromatic hydrocarbons is less than in tholins made at low pressure (e.g., 0.13 hPa). Tholins made at low deposition pressures show a greater abundance of N-H bonds.

Cruikshank, Dale P.↗

The contribution of CEOP data to the understanding and modeling of monsoon systems

CEOP has contributed and will continue to provide integrated data sets from diverse platforms for better understanding of the water and energy cycles, and for validating models. In this talk, I will show examples of how CEOP has contributed to the formulation of a strategy for the study of the monsoon as a system. The CEOP data concept has led to the development of the CEOP Inter-Monsoon Studies (CIMS), which focuses on the identification of model bias, and improvement of model physics such as the diurnal and annual cycles. A multi-model validation project focusing on diurnal variability of the East Asian monsoon, and using CEOP reference site data, as well as CEOP integrated satellite data is now ongoing. Similar validation projects in other monsoon regions are being started. Preliminary studies show that climate models have difficulties in simulating the diurnal signals of total rainfall, rainfall intensity and frequency of occurrence, which have different peak hours, depending on locations. Further more model diurnal cycle of rainfall in monsoon regions tend to lead the observed by about 2-3 hours. These model bias offer insight into lack of, or poor representation of key components of the convective,and stratiform rainfall. The CEOP data also stimulated studies to compare and contrasts monsoon variability in different parts of the world. It was found that seasonal wind reversal, orographic effects, monsoon depressions, meso-scale convective complexes, SST and land surface land influences are common features in all monsoon regions. Strong intraseasonal variability is present in all monsoon regions. While there is a clear demarcation of onset, breaks and withdrawal in the Asian and Australian monsoon region associated with climatological intraseasonal variability, it is less clear in the American and Africa monsoon regions. The examination of satellite and reference site data in monsoon has led to preliminary model experiments to study the impact of aerosol on monsoon variability. I will show examples of how the study of the dynamics of aerosol-water cycle interactions in the monsoon region, can be best achieved using the CEOP data and modeling strategy.

Lau, William K. M.↗

Stable Targets for Spaceborne Microwave Radiometer Calibration

Beginning in the 1970s, continuous observations of the Earth have been made by spaceborne microwave radiometers. Since these instruments have different observational characteristics, care must be taken in combining their data to form consistent long term records of brightness temperatures and derived geophysical quantities. To be useful for climate studies, data from different instruments must be calibrated relative to each other and to reference targets on the ground whose characteristics are stable and can be monitored continuously. Identifying such targets over land is not straightforward due to the heterogeneity and complexity of the land surface and cover. In this work, we provide an analysis of multi-sensor brightness temperature statistics over ocean, tropical forest, and ice sheet locations, spanning the period from 1978 to the present, and indicate the potential of these sites as continuous calibration monitoring targets.

microwave radiometers↗

Correlations Between Sea-Surface Salinity Tendencies and Freshwater Fluxes in the Pacific Ocean

Temporal changes in sea-surface salinity (SSS) from 21 years of a high resolution model integration of the Pacific Ocean are correlated with the freshwater flux that was used to force the integration. The correlations are calculated on a 1 x10 grid, and on a monthly scale to assess the possibility of deducing evaporation minus precipitation (E-P) fields from the salinity measurements to be taken by the upcoming Aquarius/SAC-D mission. Correlations between the monthly mean E-P fields and monthly mean SSS temporal tendencies are mainly zonally-oriented, and are highest where the local precipitation is relatively high. Nonseasonal (deviations from the monthly mean) correlations are highest along mid-latitude storm tracks and are relatively small in the tropics. The response of the model's surface salinity to surface forcing is very complex, and retrievals of freshwater fluxes from SSS measurements alone will require consideration of other processes, including horizontal advection and vertical mixing, rather than a simple balance between the two.

Li, Zhen↗

Titan Orbiter Aerorover Mission with Enceladus Science (TOAMES)

Cassini and Huygens have made exciting discoveries at Titan and Enceladus, and at the same time made us aware of how little we understand about these bodies. For example, the source, and/or recycling mechanism, of methane in Titan's atmosphere is still puzzling. Indeed, river beds (mostly dry) and lakes have been spotted, and occasional clouds have been seen, but the physics to explain the observations is still mostly lacking, since our "image" of Titan is still sketchy and quite incomplete. Enceladus, only -500 km in extent, is even more puzzling, with its fiery plumes of vapor, dust and ice emanating from its south polar region, "feeding" Saturn's E ring. Long term variability of magnetospheric plasma, neutral gas, E-ring ice grain density, radio emissions, and corotation of Saturn's planetary magnetic field in response to Enceladus plume activity are of great interest for Saturn system science. Both Titan and Enceladus are bodies of considerable astrobiological interest in view of high organic abundances at Titan and potential subsurface liquid water at Enceladus. We propose to develop a new mission to Titan and Enceladus, the Titan Orbiter Aerorover Mission with Enceladus Science (TOAMES), to address these questions using novel new technologies. TOAMES is a multi-faceted mission that starts with orbit insertion around Saturn using aerobraking with Titan's extended atmosphere. We then have an orbital tour around Saturn (for 1-2 years) and close encounters with Enceladus, before it goes into orbit around Titan (via aerocapture). During the early reconnaissance phase around Titan, perhaps 6 months long, the orbiter will use altimetry, radio science and remote sensing instruments to measure Titan's global topography, subsurface structure and atmospheric winds. This information will be used to determine where and when to release the Aerorover, so that it can navigate safely around Titan and identify prime sites for surface sampling and analysis. In situ instruments will sample the upper atmosphere which may provide the seed population for the complex organic chemistry on the surface. The Aerorover will probably use a "hot air" Montgolfier balloon concept using the waste heat from the MMRTG 1-2 kwatts. New technologies will need to be developed and miniaturization will be required to maintain functionality while controlling mass, power and cost. Duty cycling will be used. The Aerorover will have all the instruments needed to sample Titan's atmosphere and surface with possible methane lakes-rivers. It will e.g., use multi-spectral imagers and for last 6 months of mission, balloon payload will land on surface at predetermined site to take core samples of the surface and use seismometers to help probe the interior. All remote (and active) sensors on the orbiter will share a - 1 meter telescope, called MIDAS (Multiple Instrument Distributed Aperture Sensor). MIDAS observations in stable orbit at Titan can provide full global maps of Titan's surface and could additionally provide long term observations of the Saturn system including Enceladus for extended mission phases over many years, potentially for decades. Experience from the Hubble Space Telescope has shown strong public interest and commitment to exciting generational missions.

Sittler, Edward C.↗

Simulation of Grid-Fin Control Surfaces

Conference poster using previously disclosed techniques and methods (see ARC 16210 & 16212). We present simulations of grid-fin control surfaces to demonstrate geometric complexity and numerical robustness. These results have relevance to high-performance computing and performance of grid-fin-based control systems.

Aftosmis, Michael J.↗

Spatial Light Modulators as Optical Crossbar Switches

A proposed method of implementing cross connections in an optical communication network is based on the use of a spatial light modulator (SLM) to form controlled diffraction patterns that connect inputs (light sources) and outputs (light sinks). Sources would typically include optical fibers and/or light-emitting diodes; sinks would typically include optical fibers and/or photodetectors. The sources and/or sinks could be distributed in two dimensions; that is, on planes. Alternatively or in addition, sources and/or sinks could be distributed in three dimensions -- for example, on curved surfaces or in more complex (including random) three-dimensional patterns.

Juday, Richard↗

MODIS Aerosol Optical Depth Bias Adjustment Using Machine Learning Algorithms

To monitor the earth atmosphere and its surface changes, satellite based instruments collect continuous data. While some of the data is directly used, some others such as aerosol properties are indirectly retrieved from the observation data. While retrieved variables (RV) form very powerful products, they don't come without obstacles. Different satellite viewing geometries, calibration issues, dynamically changing atmospheric and earth surface conditions, together with complex interactions between observed entities and their environment affect them greatly. This results in random and systematic errors in the final products.

Albayrak, Arif↗

The Atomic to Molecular Transition in the Interstellar Medium

Study of H2 in UV and IR continues to surprise us with complexity of excitation state, OPR, and role in astrochemistry. Atomic H in molecular clouds is a very powerful tool suggesting that they are not "young" but that it takes millions of years to convert primarily atomic hydrogen clouds to 99.9% molecular form. Laboratory data suggests that H2 formation is efficient over broader range of temperatures than thought to be the case a few years ago, but range is still limited. Issues of complex grain morphology and surface structure make this a very difficult field in which to obtain definitively meaningful results. Ongoing and future observations of CI and CII will improve our understanding of the structure of clouds, their total mass, and how they have evolved and will continue to do so.

interstellar medium↗

Temporal Consistency Between Gross Primary Production and Solar-Induced Chlorophyll Fluorescence in the Ten Most Populous Megacity Areas over Years

The gross primary production (GPP) of vegetation in urban areas plays an important role in the study of urban ecology. It is difficult however, to accurately estimate GPP in urban areas, mostly due to the complexity of impervious land surfaces, buildings, vegetation, and management. Recently, we used the Vegetation Photosynthesis Model (VPM), climate data, and satellite images to estimate the GPP of terrestrial ecosystems including urban areas. Here, we report VPM-based GPP (GPPvpm) estimates for the world's ten most populous megacities during 2000-2014. The seasonal dynamics of GPPvpm during 2007-2014 in the ten megacities track well that of the solar-induced chlorophyll fluorescence (SIF) data from GOME-2 at 0.5deg x 0.5deg resolution. Annual GPPvpm during 2000-2014 also shows substantial variation among the ten megacities, and year-to-year trends show increases, no change, and decreases. Urban expansion and vegetation collectively impact GPP variations in these megacities. The results of this study demonstrate the potential of a satellite-based vegetation photosynthesis model for diagnostic studies of GPP and the terrestrial carbon cycle in urban areas.

urban↗

Lyman-Alpha Imaging Polarimetry with the CLASP2 Sounding Rocket Mission

Ultraviolet polarimetry offers a unique opportunity to explore the upper solar chromosphere and the transition region (TR) to the million-degree corona. These outer atmospheric regions play a key role in the transfer of mass and energy from the solar photosphere to the corona. With a sounding rocket experiment called the Chromospheric Lyman-Alpha Spectro-Polarimeter (CLASP), in September 2015 we succeeded in obtaining the first measurement of the linear polarization produced by scattering processes in the hydrogen Lyman-alpha line of the solar disk radiation. The analysis and interpretation of such spectro-polarimetric observation allowed us to obtain information on the geometrical complexity of the corrugated surface that delineates the TR, as well as on the magnetic field strength via the Hanle effect. At the same time, the CLASP slit-jaw (SJ) optics system, which is a Lyman-alpha filter imager characterized by a FWHM (Full Width Half Maximum) equals 7 nanometers, allowed us to obtain broad-band Stokes-I and Q/I images over a large field of view. The obtained broad-band Q/I images are dominated by the scattering polarization signals of the Lyman-alpha wings, and not by the much weaker line-center signals where the Hanle effect operates. On April 11, 2019, we performed another sounding rocket experiment, called the Chromospheric LAyer Spectro-Polarimeter (CLASP2). We used the same instrument after significant modifications in order to obtain spectro-polarimetric observations of a plage and a quiet region in the Mg II h & k lines. At the same time, the CLASP2 SJ optics system allowed us to obtain broad-band Q/I and U/I images around the Lyman-alpha wavelength, in addition to the well- known SJ intensity images.

Kano, Ryouhei↗

The California Baseline Ozone Transport Study (CABOTS)

Ozone is one of the six “criteria” pollutants identified by the U.S. Clean Air Act Amendment of 1970 as particularly harmful to human health. Concentrations have decreased markedly across the United States over the past 50 years in response to regulatory efforts, but continuing research on its deleterious effects have spurred further reductions in the legal threshold. The South Coast and San Joaquin Valley Air Basins of California remain the only two “extreme” ozone nonattainment areas in the United States. Further reductions of ozone in the West are complicated by significant background concentrations whose relative importance increases as domestic anthropogenic contributions decline and the national standards continue to be lowered. These background concentrations derive largely from uncontrollable sources including stratospheric intrusions, wildfires, and intercontinental transport. Taken together the exogenous sources complicate regulatory strategies and necessitate a much more precise understanding of the timing and magnitude of their contributions to regional air pollution. The California Baseline Ozone Transport Study was a field campaign coordinated across Northern and Central California during spring and summer 2016 aimed at observing daily variations in the ozone columns crossing the North American coastline, as well as the modification of the ozone layering downwind across the mountainous topography of California to better understand the impacts of background ozone on surface air quality in complex terrain.

Ian C. Faloona↗

Automating the Process of Optimization in Spacecraft Design

Spacecraft design optimization is a difficult problem, due to the complexity of optimization cost surfaces, and human expertise in optimization that is necessary in order to achieve good results. In this paper, we propose the use of a set of generic, metaheuristic optimization algorithms (e.g., generic algorithms, simulated annealing), which is configured for a particular optimization problem by an adaptive problem solver based on artificial intelligence and machine learning techniques. We describe work in progress on OASIS, a system for adaptive problem solving based on these principles.

optimization↗

Comment on the relation between the nonadiabatic coupling and the complex intersection of potential energy curves

Simple relations are discussed that provide a correspondence between the complex intersection of two potential surfaces and the nonadiabatic coupling matrix element between those surfaces. These are key quantities in semiclassical and quantum-mechanical theories of collision-induced electronic transitions. Within the two-state approximation, the complex intersection is shown to be directly related to the location and magnitude of the peak in the nonadiabatic coupling. Two cases have been considered: (1) the avoided crossing between two potential surfaces, and (2) the spin-orbit interaction due to a 2P halogen atom. Comparisons are made between the results of the two-state model and the results of ab initio quantum chemical calculations.

Jaffe, R. L.↗

Contamination on LDEF: Sources, distribution, and history

An introduction to contamination effects observed on the Long Duration Exposure Facility (LDEF) is presented. The activities reported are part of Boeing's obligation to the LDEF Materials Special Investigation Group. The contamination films and particles had minimal influence on the thermal performance of the LDEF. Some specific areas did have large changes in optical properties. Films also interfered with recession rate determination by reacting with the oxygen or physically shielding underlying material. Generally, contaminant films lessen the measured recession rate relative to 'clean' surfaces. On orbit generation of particles may be an issue for sensitive optics. Deposition on lenses may lead to artifacts on photographic images or cause sensors to respond inappropriately. Particles in the line of sight of sensors can cause stray light to be scattered into sensors. Particles also represent a hazard for mechanisms in that they can physically block and/or increase friction or wear on moving surfaces. LDEF carried a rather complex mixture of samples and support hardware into orbit. The experiments were assembled under a variety of conditions and time constraints and stored for up to five years before launch. The structure itself was so large that it could not be baked after the interior was painted with chemglaze Z-306 polyurethane based black paint. Any analysis of the effects of molecular and particulate contamination must account for a complex array of sources, wide variation in processes over time, and extreme variation in environment from ground to launch to flight. Surface conditions at certain locations on LDEF were established by outgassing of molecular species from particular materials onto adjacent surfaces, followed by alteration of those species due to exposure to atomic oxygen and/or solar radiation.

Pippin, Gary↗