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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Renormalization group improvement of the effective potential: an EFT approach

We apply effective field theory (EFT) methods to compute the renormalization group improved effective potential for theories with a large mass hierarchy. Our method allows one to compute the effective potential in a systematic expansion in powers of the mass ratio, as well as to sum large logarithms of mass ratios using renormalization group evolution. The effective potential is the sum of one-particle irreducible diagrams (1PI) but information about which diagrams are 1PI is lost after matching to the EFT, since heavy lines get shrunk to a point. We therefore introduce a tadpole condition in place of the 1PI condition, and use the renormalization group improved value of the tadpole in computing the effective potential. We explain why the effective potential computed using an EFT is not the same as the effective potential of the EFT. We illustrate our method using the O(N) model, a theory of two scalars in the unbroken and broken phases, and the Higgs-Yukawa model. Our leading-log result, obtained by integrating the one-loop β-functions, correctly reproduces the log-squared term in explicit two-loop calculations. Our method does not have a Goldstone boson infrared divergence problem.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

2023 Risk Management Plan and Register for Low-Power WEC for Non-Grid Applications

This is an updated risk management plan and risk register for the design, build and test of a novel, remote, low-power wave energy converter (WEC) for non-grid applications. This Columbia Power Technologies project seeks to develop a prototype low-power WEC that lowers the total cost of ownership and provides robust, new capabilities for customers in the maritime environment. The testing location for this prototype is the U.S. Navy Wave Energy Test Site (WETS) in Kaneohe Bay, O'ahu, Hawai'i. Detailed in the Risk Management Plan document is a Failure Modes, Effects, and Criticality Analysis (FMEC) that systematically identifies all potential failure modes and their effects on the system. Risk registers for major subsystems were completed according to the methodology described in the Risk Management Plan and are also included here.

16 TIDAL AND WAVE POWER↗
DOE OSTI2022

On the thermal oxidation of nuclear graphite relevant to high-temperature gas cooled reactors

Thermal oxidation of nuclear graphite components is highly undesirable because it can cause structural and property degradation that negatively affect a reactor's intended operation. In this work, the body of knowledge of nuclear graphite oxidation is highlighted, including when O 2 , H 2 O, and/or CO 2 are the oxidant. Oxidation conditions relevant to high-temperature gas-cooled reactors (i.e., when oxidation could occur either as an acute or chronic phenomenon) are emphasized. Here, the objective is to summarize graphite oxidation data in a practical and accessible way to inform future research and regulatory requirements. Although each grade of nuclear graphite is different, the oxidation mechanism has underlying commonalities. Although oxidation behavior is grade dependent, the general temperature dependence is well described by a sequence of elementary steps which become rate limiting. Because the regime transition temperature depends on sample microstructure, size, and oxidant supply rate, extrapolating results beyond the experimental range should be done cautiously. Gravimetric oxidation rate measurements generally replicate well. However, caution must be exercised when rates are estimated by other methods or for samples that deviate significantly in size. Air oxidation data for IG-110, NBG-18, and PCEA graphite is critically reviewed to emphasize this point. Despite the amount of experimental data, gaps remain. Sample size and shape effects are not fully explained. Data on the oxidant penetration depth are insufficient. Analytical assessments demonstrate that lower temperature oxidation does not necessarily imply that oxidation is uniform throughout the bulk. Oxidation occurs faster at higher temperature but is more localized to the exposed surface. Paradoxically, at equal mass loss percentage, low temperature oxidation leads to greater property degradation than at high temperature. The isolated effect of oxidation is important; however, a gap remains in the systematic understanding of any potential effect of neutron irradiation on graphite structure and reactivity.

36 MATERIALS SCIENCE↗
DOE OSTI2024

The melt memory effects in polymer crystallization

This paper presents a systematic review of the literature on the melt memory effects observed in polymers, an area that has engendered considerable debate for over 50 years. Recent advances in experimental techniques have provided fresh insights into how a polymer's thermal history influences its recrystallization behavior. It has been observed that given other conditions unchanged, the crystallization temperature during recrystallization decreases with an increase in the melt temperature T s above the melting point T m until a critical melt temperature is attained. This phenomenon also extends to the half-time of crystallization and the secondary structures, such as lamellar thickness, of semi-crystalline polymers. Despite these findings, a comprehensive constitutive model that encapsulates polymer melt memory effects remains elusive. Cutting-edge instrumentation, including in situ small and wide-angle X-ray scattering, temperature-controlled Fourier transform infrared spectroscopy, and flash differential scanning calorimetry, have posed significant challenges to the traditional nucleation and growth models established in the 1970s. These models are foundational to our understanding of polymer crystallization, which is an integral part of polymer processing and production. In this review, the historical contours of this discourse are traced, with an examination of both the recent experimental breakthroughs and theoretical advancements pertinent to polymer melt memory effects. In conclusion, this paper delves into the prevailing theories of polymer nucleation and crystallization and engages with theoretical discussions and numerical simulations that attempt to elucidate and rationalize these melt memory phenomena.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Effect of annealing on the tribological behavior of Zr-based bulk metallic glass

Bulk Metallic Glasses (BMGs) are promising materials for several applications owing to their high elastic limit and resistance to permanent deformation. However, BMGs have lower wear resistance than their crystalline counterparts during dry sliding. The formation of a composite material with crystalline phases dispersed in the BMG matrix through devitrification and partial crystallization at elevated temperatures has recently been proposed as an effective way to improve the wear resistance. However, our understanding of the origin of the improved wear behavior of annealed BMGs is still elusive. Here, a systematic evaluation of the effect of annealing temperature (from temperatures lower than the BMG glass transition temperature to temperatures higher than the BMG recrystallization temperature) on the friction and wear response of a Zr-based BMG, namely Vit105 (Zr 52.5 Cu 17.9 Ni 14.6 Al 10 Ti 5 ), was performed. The results indicate that annealing Vit105 improves its wear resistance while also reducing the steady-state friction response when the annealing temperature is close to the glass transition temperature. Notably, the formation of a transfer film on the sapphire countersurface is highly dependent on the applied normal load and sliding time. Finally, the wear mechanism was found to be strongly dependent on the annealing temperature as a transition from a predominantly adhesive wear mechanism to an abrasive-dominated one was observed as the annealing temperature crossed the glass transition temperature. Altogether, the results of this work aid to our understanding of the tribological behavior of Zr-based BMGs in general, while also providing clues to strategies for the effective use of BMGs in tribological applications.

Lien, Hsu-Ming [Univ. of Texas, Austin, TX (United↗
DOE OSTI2024

Impact of the magnetic horizon on the interpretation of the Pierre Auger Observatory spectrum and composition data

The flux of ultra-high energy cosmic rays reaching Earth above the ankle energy (5 EeV) can be described as a mixture of nuclei injected by extragalactic sources with very hard spectra and a low rigidity cutoff.Extragalactic magnetic fields existing between the Earth and the closest sources can affect the observed CR spectrum by reducing the flux of low-rigidity particles reaching Earth. We perform a combined fit of the spectrum and distributions of depth of shower maximum measured with the Pierre Auger Observatory including the effect of this magnetic horizon in the propagation of UHECRs in the intergalactic space.We find that, within a specific range of the various experimental and phenomenological systematics, the magnetic horizon effect can be relevant for turbulent magnetic field strengths in the local neighbourhood in which the closest sources lieof order B$_{rms}$ ≃ (50–100) nG (20 Mpc/d$_{s}$)( 100 kpc/L$_{coh}$)$^{1/2}$, with d$_{s}$ the typical intersource separation and L$_{coh}$ the magnetic field coherence length. When this is the case,the inferred slope of the source spectrum becomes softer and can be closer to the expectations of diffusive shock acceleration, i.e., ∝ E$^{-2}$.An additional cosmic-ray population with higher source density and softer spectra, presumably also extragalactic and dominating the cosmic-ray flux at EeV energies, is also required to reproduce the overall spectrum and composition results for all energies down to 0.6 EeV.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Signatures of Light Massive Relics on non-linear structure formation

ABSTRACT Cosmologies with Light Massive Relics (LiMRs) as a subdominant component of the dark sector are well-motivated from a particle physics perspective, and can also have implications for the σ8 tension between early and late time probes of clustering. The effects of LiMRs on the cosmic microwave background (CMB) and structure formation on large (linear) scales have been investigated extensively. In this paper, we initiate a systematic study of the effects of LiMRs on smaller, non-linear scales using cosmological N-body simulations; focusing on quantities relevant for photometric galaxy surveys. For most of our study, we use a particular model of non-thermal LiMRs but the methods developed generalizing to a large class of LiMR models – we explicitly demonstrate this by considering the Dodelson–Widrow velocity distribution. We find that, in general, the effects of LiMR on small scales are distinct from those of a ΛCDM universe, even when the value of σ8 is matched between the models. We show that weak lensing measurements around massive clusters, between ∼0.1 h−1Mpc and ∼10 h−1Mpc, should have sufficient signal-to-noise in future surveys to distinguish between ΛCDM and LiMR models that are tuned to fit both CMB data and linear scale clustering data at late times. Furthermore, we find that different LiMR cosmologies indistinguishable by conventional linear probes can be distinguished by non-linear probes if their velocity distributions are sufficiently different. LiMR models can, therefore, be best tested by jointly analyzing the CMB and late-time structure formation on both large and small scales.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Ligand Tuning in Cu(pyalk)2 Water Oxidation Electrocatalysis

Molecular copper water oxidation electrocatalysts have been extensively studied in recent years for their potential use in artificial photosynthetic systems for solar energy conversion. Although ligand modification and its ability to influence catalytic properties is a key advantage of molecular systems, there are, as yet, few examples of systematic studies of these effects. Our oxidatively resistant pyalk (2-pyridyl-2-propanoate) ligand forms a complex with copper(II) that catalyzes water oxidation and provides an attractive scaffold for systematic ligand tuning. Here, we report a series of analogous copper complexes with electron-donating (methoxy-) and -withdrawing (methoxycarbonyl-) groups at the para-position of the pyalk ligand. Trends in the pKa and redox potential align with first-principles predictions for the electron-withdrawing and electron-donating groups. While the modified complexes show good activity for water oxidation, lowered faradaic efficiency in comparison to the parent complex highlights the importance of stability considerations for catalyst tuning.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

A Hydro-particle-mesh Code for Efficient and Rapid Simulations of the Intracluster Medium

We introduce the cosmological HYPER code based on an innovative hydro-particle-mesh (HPM) algorithm for efficient and rapid simulations of gas and dark matter. For the HPM algorithm, we update the approach of Gnedin & Hui to expand the scope of its application from the lower-density intergalactic medium (IGM) to the higher-density intracluster medium (ICM). While the original algorithm tracks only one effective particle species, the updated version separately tracks the gas and dark matter particles, as they do not exactly trace each other on small scales. For the approximate hydrodynamics solver, the pressure term in the gas equations of motion is calculated using robust physical models. In particular, we use a dark matter halo model, ICM pressure profile, and IGM temperature–density relation, all of which can be systematically varied for parameter-space studies. We show that the HYPER simulation results are in good agreement with the halo model expectations for the density, temperature, and pressure radial profiles. Simulated galaxy cluster scaling relations for Sunyaev–Zel’dovich (SZ) and X-ray observables are also in good agreement with mean predictions, with scatter comparable to that found in hydrodynamic simulations. HYPER also produces lightcone catalogs of dark matter halos and full-sky tomographic maps of the lensing convergence, SZ effect, and X-ray emission. These simulation products are useful for testing data analysis pipelines, generating training data for machine learning, understanding selection and systematic effects, and for interpreting astrophysical and cosmological constraints.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Effect of relative humidity on the interlayer spacing of phosphate intercalated Mg, Al layered double hydroxide (hydrotalcite‐like) crystals

Abstract The availability of water and the type of interlayer anions present affect the arrangement and interlayer spacing of layered double hydroxide (LDH). A systematic study of the effect of relative humidity (RH) on the basal spacing of phosphate intercalated, magnesium aluminum LDHs (MgAl–PO 4 LDH) was conducted, confirming that MgAl‐PO 4 LDH exhibit distinct interlayer spacing corresponding to separate low‐ and high‐hydration states produced when exposed to low and high humidity conditions. The transition from the low‐ to high‐hydration form begins when RH exceeds 33% and is accompanied by the transition from one to two interlayers of water. An improved understanding of the effect of RH on MgAl–PO 4 LDHs will enable more accurate atomistic modeling and experimental characterization of MgAl–PO 4 LDHs and may lead to improvements in the tunability of MgAl‐PO 4 LDHs for commercial applications such as slow‐release fertilizer.

Reed, Titus↗
DOE OSTI2020

Water Freezes at Near-Zero Temperatures Using Carbon Nanotube-Based Electrodes under Static Electric Fields

Although static electric fields have been effective in controlling ice nucleation, the highest freezing temperature ( T f ) of water that can be achieved in an electric field ( E ) is still uncertain. In this study, we performed a systematic study of the effect of an electric field on water freezing by varying the thickness of a dielectric layer and the voltage across it in an electrowetting system. Results show that T f first increases sharply with E and then reaches saturation at –3.5 °C after a critical value E of 6 × 10 6 V/m. Using classical heterogeneous nucleation theory, it is revealed that this behavior is due to saturation in the contact angle of the ice embryo with the underlying substrate. Finally, we show that it is possible to overcome this freezing saturation by controlling the uniformity of the electric field using carbon nanotubes. We achieve a T f of –0.6 °C using carbon nanotube-based electrodes with an E of 3 × 10 7 V/m. This work sheds new light on the control of ice nucleation and has the potential to impact many applications ranging from food freezing to ice production.

25 ENERGY STORAGE↗
DOE OSTI2022

Collective effect of thermal plumes on temperature fluctuations in a closed Rayleigh–Benard convection cell

Here, we report a systematic study of the collective effect of thermal plumes on the probability density function (PDF) P(δT) of temperature fluctuations δT(t) in turbulent Rayleigh-Benard convection. By decomposing δT(t) into four basic fluctuation modes associated with single and multiple warm and cold plumes and a turbulent background, we derive an analytic form of P(δT) based on the convolutions of the five independent modes. To test the derived form of P(δT) in the multiple-plume regions, where the thermal plumes are heavily populated, we conduct time series measurements of temperature fluctuations in two convection cells; one is a vertical thin disk and the other is an upright cylinder of aspect ratio unity. For a given normalized position in most regions of the convection cell, all of the measured PDFs P(δT) for different Rayleigh numbers fall onto a single master curve, once δT is normalized by its rms value σ T . It is found that the measured P(δT / σT ) at different locations along the symmetric horizontal and vertical axes of the convection cells can all be well described by the derived form of P(δT / σT ). The fitted values of the parameters associated with the number of plumes in multiple plume clusters and their relative strengths and degrees of intermittency are closely linked to the spatial distribution of thermal plumes and local dynamics of the large-scale circulation in a closed convection cell. Our work thus provides a unified theoretical approach for understanding scalar PDFs in a turbulent field, which is very useful not only for the present study but also for the study of many turbulent mixing problems of practical interest.

42 ENGINEERING↗
DOE OSTI2022

Disentangling long and short distances in momentum-space TMDs

The extraction of nonperturbative TMD physics is made challenging by prescriptions that shield the Landau pole, which entangle long- and short-distance contributions in momentum space. The use of different prescriptions then makes the comparison of fit results for underlying nonperturbative contributions not meaningful on their own. We propose a model-independent method to restrict momentum-space observables to the perturbative domain. This method is based on a set of integral functionals that act linearly on terms in the conventional position-space operator product expansion (OPE). Artifacts from the truncation of the integral can be systematically pushed to higher powers in Λ QCD /k T . We demonstrate that this method can be used to compute the cumulative integral of TMD PDFs over k T ≤ k$^{cut}_{T}$ in terms of collinear PDFs, accounting for both radiative corrections and evolution effects. This yields a systematic way of correcting the naive picture where the TMD PDF integrates to a collinear PDF, and for unpolarized quark distributions we find that when renormalization scales are chosen near k$^{cut}_{T}$, such corrections are a percent-level effect. We also show that, when supplemented with experimental data and improved perturbative inputs, our integral functionals will enable model-independent limits to be put on the non-perturbative OPE contributions to the Collins-Soper kernel and intrinsic TMD distributions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Systematic Evaluation of Atmospheric Forcing, Surface Datasets, and Mesh Effects on Kilometer-Scale Land Surface and River Modeling

Earth system models are advancing toward kilometer-scale resolution to capture local climate impacts and extremes. High-resolution land and river modeling depends on multiple factors, including mesh, surface datasets, and atmospheric forcing, but their relative effects at kilometer scales remain unquantified. We evaluated five Energy Exascale Earth System Model land and river configurations over the Mid-Atlantic region using two mesh (1/8° structured versus variable-resolution unstructured mesh), two surface datasets (default versus newly developed), and three atmospheric forcings (NLDAS2, MSWX, GSWP). Evaluation against satellite, reanalysis, and in situ benchmarks across water, energy, and carbon cycles quantifies how these factors affect model performance. Forcing selection produces the largest bias reductions (12-99% across variables), followed by surface datasets (7-75%) and mesh (up to 21%). Forcing effects vary by variable, with MSWX reducing biases for snow water equivalent, evapotranspiration, albedo, temperature, and gross primary productivity, GSWP for snow cover and runoff, and NLDAS for soil moisture and streamflow. The use of newly developed surface datasets improves gross primary productivity (58% bias reduction) and evapotranspiration but increase soil moisture and albedo biases due to current modeling limitations. Variable-resolution unstructured mesh improves the simulation of small-basin streamflow through better capturing drainage networks, though mesh minimally affects other land variables. These findings provide important guidance for high-resolution modeling development and actionable science.

Land and River modeling↗
DOE OSTI2022

Ab initio nucleon-nucleus elastic scattering with chiral effective field theory uncertainties

Effective interactions for nucleon-nucleus elastic scattering from first principles require the use of the same nucleon-nucleon interaction in the structure and reaction calculations and a consistent treatment of the relevant operators at each order. Systematic investigations of the effect of truncation uncertainties of chiral nucleon-nucleon ( N N ) forces have been carried out for scattering observables in the two- and three-nucleons system as well as for bound-state properties of light nuclei. Here we extend this type of study to proton and neutron elastic scattering for 16 O and 12 C. Using the frameworks of the spectator expansion of multiple scattering theory as well as the no-core shell model, we employ one specific chiral interaction from the LENPIC collaboration and consistently calculate the leading-order effective nucleon-nucleus interaction up to the third chiral order, from which we extract elastic scattering observables. Then we apply pointwise as well as correlated uncertainty quantification for the estimation of the chiral truncation error. We calculate and analyze proton elastic scattering observables for 16 O and 12 C as well as neutron elastic scattering observables for 12 C between 65 and 185 MeV projectile kinetic energy. We find in all cases qualitatively similar results for the chiral truncation uncertainties as in few-body systems and assess them using similar diagnostic tools. The order-by-order convergence of the scattering observables for 16 O and 12 C is very reasonable around 100 MeV, while for higher energies the chiral expansion parameter becomes too large for convergence. Comparing proton and neutron differential cross sections reveals that their description is comparable up to around 100 MeV. Here, we also find a nearly perfect correlation between the differential cross section for neutron scattering and the N N Wolfenstein amplitudes for small momentum transfers. The diagnostic tools for studying order-by-order convergence in observables in few-body systems can be employed for observables in nucleon-nucleus scattering with only minor modifications provided the momentum scale in the problems is not too large. We also find that the chiral N N interaction on which our study is based gives a very good description of differential cross sections for 16 O and 12 C as low as 65-MeV projectile energy, particularly in the forward direction. In addition, the very forward direction of the neutron differential cross section mirrors the behavior of the N N interaction amazingly well.

6 ≤ A ≤ 19↗
DOE OSTI2025

On the numerical sensitivity of cellular automata grain structure predictions to large thermal gradients and cooling rates

Cellular automata (CA) models of as-solidified grain structure, originally developed and applied to casting, have become a common means of predicting grain structure resulting from Additive Manufacturing (AM) processes. The majority of these models are based on the decentered octahedron approach, which attempts to correct for the effect of grid anisotropy on the prediction of competitive solidification of dendritic grains. However, AM solidification occurs under cooling rates ($\dot{T}$) and thermal gradients (G) that are orders of magnitude larger than those encountered in casting, and no systematic investigation on the effect of the CA model cell size (Δx) and time step (Δt) on AM microstructure predictions has been performed. Here, in this study, such an investigation is first performed via simulation of individual grains of various crystallographic orientations with a fixed, unidirectional G, showing that CA prediction of the steady-state undercooling matched the expected values based on the interfacial response function at small G and deviated from the expected values at large G. Simulation of competitive growth of multiple grains showed a weakening of the predicted texture as G and Δx became large. Simulation of solidification under AM conditions, where G and $\dot{T}$ vary spatially across the melt pools, showed that not only does grain selection weaken and deviate from expectations at large Δx, but grains with crystallographic $\langle$100$\rangle$ aligned with the grid directions are more adversely affected by the temperature field discontinuities than grains with other crystallographic orientations. Despite the fact that the exact grain competition results depended on Δt, the overall texture development was notably less sensitive to Δt than Δx, provided that a reasonable value of Δt is selected based on the ratio of Δx to the maximum local solidification velocity in the simulation domain. Finally, from the directional solidification and AM simulation results, an analysis of computational cost compared to simulation resolution is performed based on an equation derived to quantify the relatively inaccuracy in grain selection based on the model and temperature field inputs. From this analysis, it is concluded that there is a need for algorithmic improvements to improve CA grain competition accuracy for large G processing conditions as sufficiently small Δx to resolve the necessary competition is intractable for many AM processing conditions.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Reducing the Susceptibility of Lumped-Element KIDs to Two-Level System Effects

Arrays of lumped-element kinetic inductance detectors (LEKIDs) optically coupled through an antenna-coupled transmission line are a promising candidate for future cosmic microwave background experiments. However, the dielectric materials used for the microstrip architecture are known to degrade the performance of superconducting resonators. In this paper, we investigate the feasibility of microstrip coupling to a LEKID, focusing on a systematic study of the effect of depositing amorphous silicon nitride on a LEKID. The discrete and spatially separated inductive and capacitive regions of the LEKID allow us to vary the degree of dielectric coverage and determine the limitations of the microstrip coupling architecture. We show that by careful removal of dielectric from regions of high electric field in the capacitor, there is minimal degradation in dielectric loss tangent of a partially covered lumped-element resonator. We present the effects on the resonant frequency and noise power spectral density and, using the dark responsivity, provide an estimate for the resulting detector sensitivity.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

The synergistic effects of central core size and end group engineering on performance of narrow bandgap nonfullerene acceptors

Understanding the relationship between the molecular structure and photoelectric properties of fused-ring non-fullerene acceptors (NFAs) is of far-reaching significance to the development of organic solar cells (OSCs). Herein, six NFAs based on multiple thiophenes (4 T, 6 T and 8 T) are employed to systematically probe the synergistic effects of extending central core size and terminal fluorination. The absorption results manifest that the molecular absorption is comprehensively affected by molecular crystallinity, planarity, conjugation length and intramolecular electron push–pull effect, simultaneously. The intensity of electron push–pull effect is not only related to the electron-donating ability of central core and the electron-withdrawing ability of end group, but also may be related to the distance between the positive and negative centers. The extension of central core leads to the more planar backbone and stronger crystallinity of NFAs, and less energy loss (E loss ) in its based OSC. Compared with the extension of central core, terminal fluorination has a greater impact on molecular photoelectric properties. The terminal fluorination significantly enhances the push–pull effect, lowers the energy levels, and slightly increases the vibrational relaxation. As a result, the strongest crystallinity and coplanarity of 8TIC-4F lead to a low vibrational relaxation of 0.18 eV, which makes PTB7-Th:8TIC-4F device exhibit a small E loss of 0.51 eV and a high efficiency of 10.4%. In addition, the fluorinated 6TIC-4F with suitable core size exhibits suitable energy level, absorption, crystallization, and phase separation morphology, making its as-cast device up to 11.61% efficiency. Finally, to the best of the authors’ knowledge, the PCE of 11.61% for PTB7-Th:6TIC-4F based device without any treatment is one of the highest values reported for the NAFs with over 1000 nm absorption.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗