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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 361 records · Page 20
All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

g-LIMIT: A Vibration Isolation System for the Microgravity Science Glovebox

For many microgravity science experiments using the Microgravity Science Glovebox (MSG), the ambient acceleration environment will exceed desirable levels. To provide a more quiescent acceleration environment, a vibration isolation system named g-LIMIT (GLovebox Integrated Microgravity Isolation Technology) is being designed. g-LIMIT is the next generation of technology developed for and demonstrated by STABLE on the USML-2 mission in October 1995. Although g-LIMIT is a sub-rack level isolation system that can be used in a variety of applications, g-LIMIT is uniquely optimized for MSG implementation. Standard MSG structural and umbilical interfaces will be used so that the isolation mount is transparent to the user with no additional accommodation requirements. g-LIMIT consists of three integrated isolator modules, each of which is comprised of a dual axis actuator, two axes of acceleration sensing, two axes of position sensing, control electronics, and data transmission capabilities in a minimum-volume package. In addition, this system provides the unique capability for measuring absolute acceleration of the experiment independent of accelerometers as a by-product of the control system and will have the capability of generating pristine accelerations to enhance experiment operations. g-LIMIT is scheduled for flight during the UF-2 mission and will be available to glovebox investigators immediately after characterization testing.

Whorton, Mark S.↗
DOE OSTI2021

Acoustic mapping by picosecond ultrasonics for elastic property measurement: Experimental demonstration on a TRISO fuel compact

Picosecond ultrasonics has been demonstrated on a tristructural isotropic (TRISO) fuel compact to measure the elastic properties of each compact layer. This technique utilizes an ultrashort pump laser pulse to excite vibrations in a gold transducer film covering the surface of each component and a second probe laser pulse to record the resulting acoustic strain induced change in optical reflectance. From the damping of this film vibration, the acoustic reflection coefficient, which couples the elastic properties of the transducer film and the sample, can be obtained, enabling a calculation of the sample’s acoustic velocity and elastic modulus. Overall, results obtained from this method are consistent with known values of elastic moduli, namely that the SiC coating is the stiffest component of the compact while the carbonaceous matrix is the most compliant. Nanoindentation was conducted as a benchmark technique on the same sample and shows satisfactory agreement with the results of picosecond ultrasonics. Compared to other methods like nanoindentation, picosecond ultrasonics is multimodal with a capability of measuring several key properties simultaneously and has potentials to be coupled into optical fibers for remote sensing. Thus, these demonstration measurements reveal the methodology to be a promising candidate for in-situ and high-throughput optical characterizations of nuclear materials.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS2001

The g-LIMIT Microgravity Vibration Isolation System for the Microgravity Science Glovebox

For many microgravity science experiments in the International Space Station, the ambient acceleration environment will be exceed desirable levels. To provide a more quiescent acceleration environment to the microgravity payloads, a vibration isolation system named g-LIMIT (GLovebox Integrated Microgravity Isolation Technology) is being designed. g-LIMIT is a sub-rack level isolation system for the Microgravity Science Glovebox that can be tailored to a variety of applications. Scheduled for launch on the UF-1 mission, the initial implementation of g-LIMIT will be a Characterization Test in the Microgravity Science Glovebox. g-LIMIT will be available to glovebox investigators immediately after characterization testing. Standard MSG structural and umbilical interfaces will be used so that the interface requirements are minimized. g-LIMIT consists of three integrated isolator modules, each of which is comprised of a dual axis actuator, two axes of acceleration sensing, two axes of position sensing, control electronics, and data transmission capabilities in a small-volume package. In addition, this system provides the unique capability for measuring quasi-steady acceleration of the experiment independent of accelerometers as a by-product of the control system and will have the capability of generating user-specified pristine accelerations to enhance experiment operations.

Whorton, Mark S.↗
NASA NTRS2005

Space Qualification of Laser Diode Arrays

Laser instruments have great potential in enabling a new generation of remote-sensing scientific instruments. NASA s desire to employ laser instruments aboard satellites, imposes stringent reliability requirements under severe conditions. As a result of these requirements, NASA has a research program to understand, quantify and reduce the risk of failure to these instruments when deployed on satellites. Most of NASA s proposed laser missions have base-lined diode-pumped Nd:YAG lasers that generally use quasi-constant wave (QCW), 808 nm Laser Diode Arrays (LDAs). Our group has an on-going test program to measure the performance of these LDAs when operated in conditions replicating launch and orbit. In this paper, we report on the results of tests designed to measure the effect of vibration loads simulating launch into space and the radiation environment encountered on orbit. Our primary objective is to quantify the performance of the LDAs in conditions replicating those of a satellite instrument, determine their limitations and strengths which will enable better and more robust designs. To this end we have developed a systematic testing strategy to quantify the effect of environmental stresses on the optical and electrical properties of the LDA.

Troupaki, Elisavet↗
NASA NTRSDate not supplied

Design, Fabrication, Testing and Validation of a Ruggedized Fiber Optic Sensing System (FOSS) for Launch Application

Fiber-optic sensors based on fiber Bragg grating (FBG) is desirable for structural health monitoring and is used for various aerospace applications such as measuring strain and temperature, where a single optical fiber can multiplex hundreds of FBG sensors. The National Aeronautics and Space Administration (NASA) Armstrong Flight Research Center (AFRC) (Edwards, California) has been developing an optical fiber-based sensing suite called Fiber Optics Sensing System (FOSS) over the past two decades. Successful strain monitoring flight demonstrations such as the NASA Ikhana (General Atomics, San Diego, California) remotely piloted aircraft and the X-56A Multi-Utility Technology Testbed (Lockheed Martin Corporation, Bethesda, Maryland) remotely piloted subscale aircraft have been performed. Interest in adapting fiber-optic sensors for aerospace applications has led to commissioning the development of a ruggedized FOSS system for spaceflight through the NASA Launch Services Program (LSP) at the NASA Kennedy Space Center (KSC) (Merritt Island, Florida). In this paper, a ruggedized FOSS suitable for a launch environment is discussed in detail. Thermal analysis and enclosure design will be discussed as well as environmental testing such as shock, random vibration, thermal vacuum, and electromagnetic interference/electromagnetic compatibility (EMI/EMC). With all relevant environmental testing completed, a ruggedized FOSS unit has successfully passed all testing and is now deemed space-launch ready.

Allen R. Parker, Jr↗
NASA NTRS2000

g-LIMIT Status Briefing

For many microgravity science experiments in the International Space Station, the ambient acceleration environment will be exceed desirable levels. To provide a more quiescent acceleration environment to the microgravity payloads, a vibration isolation system named g-LIMIT (GLovebox Integrated Microgravity Isolation Technology) is being designed. g-LIMIT is a sub-rack level isolation system that can be tailored to a variety of applications. Scheduled for launch on the UF-1 mission, the initial implementation of g-LIMIT will be a Characterization Test in the Microgravity Science Glovebox (MSG). g-LIMIT will be available to glovebox investigators immediately after characterization testing. Standard MSG structural and umbilical interfaces will be used so that the isolation mount is transparent to the user with no additional accommodation requirements. g-LIMIT consists of three integrated isolator modules, each of which is comprised of a dual axis actuator, two axes of acceleration sensing, two axes of position sensing, control electronics, and data transmission capabilities in a minimum-volume package. In addition, this system provides the unique capability for measuring absolute acceleration of the experiment independent of accelerometers as a by-product of the control system and will have the capability of generating pristine accelerations to enhance experiment operations.

Whorton, Mark↗
NASA NTRS1983

Inelastic electron tunneling spectroscopy

Inelastic electron tunneling spectroscopy is a useful technique for the study of vibrational modes of molecules adsorbed on the surface of oxide layers in a metal-insulator-metal tunnel junction. The technique involves studying the effects of adsorbed molecules on the tunneling spectrum of such junctions. The data give useful information about the structure, bonding, and orientation of adsorbed molecules. One of the major advantages of inelastic electron tunneling spectroscopy is its sensitivity. It is capable of detecting on the order of 10 to the 10th molecules (a fraction of a monolayer) on a 1 sq mm junction. It has been successfully used in studies of catalysis, biology, trace impurity detection, and electronic excitations. Because of its high sensitivity, this technique shows great promise in the area of solid-state electronic chemical sensing.

Khanna, S. K.↗
NASA NTRS2012

Mechanical and Vibration Testing of Carbon Fiber Composite Material with Embedded Piezoelectric Sensors

Piezoelectric materials have been proposed as a means of decreasing turbomachinery blade vibration either through a passive damping scheme, or as part of an active vibration control system. For polymer matrix fiber composite (PMFC) blades, the piezoelectric elements could be embedded within the blade material, protecting the brittle piezoceramic material from the airflow and from debris. Before implementation of a piezoelectric element within a PMFC blade, the effect on PMFC mechanical properties needs to be understood. This study attempts to determine how the inclusion of a packaged piezoelectric patch affects the material properties of the PMFC. Composite specimens with embedded piezoelectric patches were tested in four-point bending, short beam shear, and flatwise tension configurations. Results show that the embedded piezoelectric material does decrease the strength of the composite material, especially in flatwise tension, attributable to failure at the interface or within the piezoelectric element itself. In addition, the sensing properties of the post-cured embedded piezoelectric materials were tested, and performed as expected. The piezoelectric materials include a non-flexible patch incorporating solid piezoceramic material, and two flexible patch types incorporating piezoelectric fibers. The piezoceramic material used in these patches was Navy Type-II PZT.

Duffy, Kirsten P.↗
NASA NTRS2004

Bearingless Switched-Reluctance Motor Improved

The Morrison rotor, named after its inventor, is a hybrid rotor for use in a switched reluctance electric motor. The motor is characterized as bearingless in the sense that it does not rely on conventional mechanical bearings: instead, it functions as both a magnetic bearing and a motor. Bearingless switched-reluctance motors are attractive for use in situations in which large variations in temperatures and/or other extreme conditions preclude the use of conventional electric motors and mechanical bearings. In the Morrison motor, as in prior bearingless switched-reluctance motors, a multipole rotor is simultaneously levitated and rotated. In the prior motors, simultaneous levitation and rotation are achieved by means of two kinds of stator windings: (1) main motor windings and (2) windings that exert levitating forces on a multipole rotor. The multipole geometry is suboptimum for levitation because it presents a discontinuous surface to the stator pole faces, thereby degrading the vibration suppression capability of the magnetic bearing. The Morrison rotor simplifies the stator design in that it contains only one type of winding. The rotor is a hybrid that includes both (1) a circular lamination stack for levitation and (2) a multipole lamination stack for rotation. Simultaneous levitation and rotation at 6000 rpm were achieved with a prototype that included six rotor poles and eight stator poles. During normal operation, two of the four pairs of opposing stator poles (each pair at right angles to the other pair) levitate the rotor. The remaining two pairs of stator poles exert torque on the six-pole rotor lamination stack to produce rotation. The relative length of the circular and multipole lamination stacks on the rotor can be chosen to tailor the performance of the motor for a specific application. For a given overall length, increasing the length of the multipole stack relative to the circular stack results in an increase in torque relative to the levitation load capacity and vice versa.

Morrison, Carlos R.↗
NASA NTRS2008

NASA Tech Briefs, January 2008

Topics covered include: Induction Charge Detector with Multiple Sensing Stages; Generic Helicopter-Based Testbed for Surface Terrain Imaging Sensors; Robot Electronics Architecture; Optimized Geometry for Superconducting Sensing Coils; Sensing a Changing Chemical Mixture Using an Electronic Nose; Inertial Orientation Trackers with Drift Compensation; Microstrip Yagi Antenna with Dual Aperture-Coupled Feed; Patterned Ferroelectric Films for Tunable Microwave Devices; Micron-Accurate Laser Fresnel-Diffraction Ranging System; Efficient G(sup 4)FET-Based Logic Circuits; Web-Enabled Optoelectronic Particle-Fallout Monitor; SiO2/TiO2 Composite for Removing Hg from Combustion Exhaust; Lightweight Tanks for Storing Liquefied Natural Gas; Hybrid Wound Filaments for Greater Resistance to Impacts; Making High-Tensile-Strength Amalgam Components; Bonding by Hydroxide-Catalyzed Hydration and Dehydration; Balanced Flow Meters without Moving Parts; Deflection-Compensating Beam for Use inside a Cylinder; Four-Point-Latching Microactuator; Curved Piezoelectric Actuators for Stretching Optical Fibers; Tunable Optical Assembly with Vibration Dampening; Passive Porous Treatment for Reducing Flap Side-Edge Noise; Cylindrical Piezoelectric Fiber Composite Actuators; Patterning of Indium Tin Oxide Films; Gimballed Shoulders for Friction Stir Welding; Improved Thermal Modulator for Gas Chromatography; Nuclear-Spin Gyroscope Based on an Atomic Co-Magnetometer; Utilizing Ion-Mobility Data to Estimate Molecular Masses; Optical Displacement Sensor for Sub-Hertz Applications; Polarization/Spatial Combining of Laser-Diode Pump Beams; Spatial Combining of Laser-Diode Beams for Pumping an NPRO; Algorithm Optimally Orders Forward-Chaining Inference Rules; Project Integration Architecture; High Power Amplifier and Power Supply; Estimating Mixing Heights Using Microwave Temperature Profiler; and Multiple-Cone Sunshade for a Spaceborne Telescope.

Source record↗
NASA NTRS2010

Visible Nulling Coronagraphy Testbed Development for Exoplanet Detection

Three of the recently completed NASA Astrophysics Strategic Mission Concept (ASMC) studies addressed the feasibility of using a Visible Nulling Coronagraph (VNC) as the prime instrument for exoplanet science. The VNC approach is one of the few approaches that works with filled, segmented and sparse or diluted aperture telescope systems and thus spans the space of potential ASMC exoplanet missions. NASA/Goddard Space Flight Center (GSFC) has a well-established effort to develop VNC technologies and has developed an incremental sequence of VNC testbeds to advance the this approach and the technologies associated with it. Herein we report on the continued development of the vacuum Visible Nulling Coronagraph testbed (VNT). The VNT is an ultra-stable vibration isolated testbed that operates under high bandwidth closed-loop control within a vacuum chamber. It will be used to achieve an incremental sequence of three visible light nulling milestones of sequentially higher contrasts of 10(exp 8) , 10(exp 9) and 10(exp 10) at an inner working angle of 2*lambda/D and ultimately culminate in spectrally broadband (>20%) high contrast imaging. Each of the milestones, one per year, is traceable to one or more of the ASMC studies. The VNT uses a modified Mach-Zehnder nulling interferometer, modified with a modified "W" configuration to accommodate a hex-packed MEMS based deformable mirror, a coherent fiber bundle and achromatic phase shifters. Discussed will be the optical configuration laboratory results, critical technologies and the null sensing and control approach.

Lyon, Richard G.↗
DOE OSTI2021

NACHOS, a CubeSat-based high-resolution UV-Visible hyperspectral imager for remote sensing of trace gases: system overview and science objectives

Here, the Nano-satellite Atmospheric Chemistry Hyperspectral Observation System (NACHOS) is a high-throughput (f/2.9), high spectral resolution (~1.3 nm optical resolution, 0.6 nm sampling) Offner-design hyperspectral imager operating in the 300-500 nm spectral region. The 1.5U instrument payload (1U optical system, 0.5U electronics module) is hosted by a 1.5U LANL-designed CubeSat bus to comprise a 3U complete satellite. Spectroscopically similar to NASA’s Ozone Monitoring Instrument (OMI), which provides wide-field global mapping of ozone and other gases at coarse spatial resolution, NACHOS fills the complementary niche of targeted measurements at much higher spatial resolution. With 350 across-track spatial pixels and a 15-degree across-track field of view, NACHOS will provide spectral imaging at roughly 0.4 km per pixel from 500 km altitude. NACHOS incorporates highly streamlined gas-retrieval algorithms for rapid onboard processing, alleviating the need to routinely downlink massive hyperspectral data cubes. We will discuss the instrument design, challenges in achieving mechanical robustness to launch vibration in such a compact instrument, the onboard calibration system, and gas-retrieval data downlink strategy. We will also discuss potential science missions, including monitoring of NO 2 as an easily detected proxy for anthropogenic fossil-fuel greenhouse gases, monitoring lowlevel SO 2 degassing at pre-eruptive volcanoes, H 2 CO from wildfires, and characterization of aerosols. The long-term vision is for a many-satellite constellation that could provide both high spatial resolution and frequent revisits for selected targets of interest. As an initial technology demonstration of this vision, the NACHOS project is currently slated to launch two CubeSats in early 2022.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS2003

Improved Bearingless Switched-Reluctance Motor

The Morrison rotor, named after its inventor, is a hybrid rotor for use in a bearingless switched-reluctance electric motor. The motor is characterized as bearingless in the sense that it does not rely on conventional mechanical bearings: instead, it functions as both a magnetic bearing and a motor. Bearingless switched-reluctance motors are attractive for use in situations in which large variations in temperatures and/or other extreme conditions preclude the use of conventional electric motors and mechanical bearings. In the Morrison motor, as in a prior bearingless switched-reluctance motor, a multipole rotor is simultaneously levitated and rotated. In the prior motor, simultaneous levitation and rotation are achieved by means of two kinds of stator windings: (1) main motor windings and (2) windings that exert levitating forces on a multipole rotor. The multipole geometry is suboptimum for levitation in that it presents a discontinuous surface to the stator pole faces, thereby degrading the vibration-suppression capability of the magnetic bearing. The Morrison rotor simplifies the stator design in that the stator contains only one type of winding. The rotor is a hybrid that includes both (1) a circular lamination stack for levitation and (2) a multipole lamination stack for rotation. A prototype includes six rotor poles and eight stator poles (see figure). During normal operation, two of the four pairs of opposing stator poles (each pair at right angles to the other pair) levitate the rotor. The remaining two pairs of stator poles exert torque on the six-pole rotor lamination stack to produce rotation. The relative lengths of the circular and multipole lamination stacks on the rotor can be chosen to tailor the performance of the motor for a specific application. For a given overall length, increasing the length of the multipole stack relative to the circular stack results in an increase in torque relative to levitation load capacity and stiffness, and vice versa.

Morrison, Carlos R.↗
DOE OSTI2023

Recursive Use of the Short-Time Fast Fourier Transform for Signature Analysis in Continuous Processes

Although a nuclear reactor is a hostile environment for sensing and electrical communications, the reactor core is amenable to acoustic communication. An acoustic measurement infrastructure (AMI) has been installed in the Advanced Test Reactor (ATR) to record acoustic signals that can capture its different operating regimes. AMI uses coolant pumps as continuous signal sources, coolant and structural components as transmission lines, and accelerometers to capture system motion. A recursive signal processing technique based on the short-time fast Fourier transform (STFFT) for continuous processes provides unique signatures for diagnostic and prognostic analyses from the system motion data. Here this article presents a recursive STFFT methodology that processes acoustic signals from continuous industrial processes. The article first discusses the initial STFFT use with simulated data to elucidate the basic principles necessary to understand and interpret the STFFT results from actual pump vibration data. Each repetitive use of the STFFT on pump vibration data using the results from the prior STFFT processing will generate additional complimentary time-frequency-based signatures. These signatures are generated by the coolant pumps operating under different process conditions. After each use of the STFFT, the resulting signatures provide exemplary examples of the diversity and intuitive nature of recursively using the STFFT. This article focuses on recursively using the STFFT to provide numerous complimentary and diverse signatures that will ultimately be inputs for machine learning algorithms that provide predictive data analytics. The intuitive nature of the information and signatures from recursive STFFT processing will also bring intuitive interpretation capabilities to machine learning and predictive data analytic techniques.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
NASA NTRS2006

Use of Photoelastic Modulators for High-accuracy Spectropolarimetric Imaging of Aerosols

Passive multiangular, multispectral, and polarimetric sensing approaches each have unique strengths for the measurement of tropospheric aerosol column abundances and microphysical properties. Current spaceborne multispectral and multiangular aerosols sensors operate at approximately 1 km resolution. Under NASA's Instrument Incubator Program, we are developing an electro-optic imaging approach that will enable adding high-accuracy polarimetry to such observations. To achieve a degree of linear polarization (DOLP) uncertainty of 0.5%, our approach temporally modulates the linear-polarization component of incoming light at a rapid rate, enabling each detector within a focal-plane array, combined with polarization analyzers, to measure the relative proportions of the linear Stokes components Q or U to the total intensity. Our system uses tandem photoelastic modulators (PEMs) within a high-reflectance, low diattenuation camera design. The two PEMs vibrate at slightly different resonant frequencies, leading to modulation of the polarized light at a heterodyne frequency of ~25 Hz. High-speed (1 kHz) readout of the detector arrays samples the output waveforms from which Q/I and U/I are derived. We report on experimental and theoretical analyses of PEM and optical system performance, along with plans for developing ruggedized PEMs capable of withstanding launch and on-orbit stresses.

photoelastics↗
DOE OSTI2024

Effects of Structural Constraints on Excited-State Properties in Dimeric Cu(I) Diimine Complexes

Copper(I) bis-diimine complexes have played important roles in light-activated processes that can lead to their potential applications in photocatalysis and chemical sensing. Their metal-to-ligand charge-transfer (MLCT) excited-state properties are tunable by various structural factors. Dimeric Cu(I) complexes with connecting diimine derivative ligands offer another structural tuning platform for the excited-state properties. Here, we investigate excited-state properties in two covalently connected dimeric Cu(I)'s with varying structural constraints exerted by the number of carbons in the polyethylene bridge (C0 and C4) connecting the two copper(I) diimine moieties. An interesting feature of Cu(I) diimine complexes is their ability to flatten following a photoinduced structural change. Herein, we observe larger structural constraints and more structural rearrangement required upon excitation of the longer bridged complex C4 to achieve a conformation toward a more flattened tetrahedral coordination geometry compared to the shorter bridged C0. Vibrational wavepacket analysis of these complexes further supports the effect of these structural constraints where we observe a more rapid dephasing of the C0 complex, as opposed to the C4 complex, despite similar normal mode vibrations. The experimental results were supplemented by TDDFT calculations. In conclusion, the studies provide insight into using metal-metal interactions through constraints to tune excited-state dynamics and pathways.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1993

Extraction of auxiliary data from AVIRIS distribution tape for spectral, radiometric, and geometric quality assessment

Remotely sensed data are affected by system (sensor and platform), and scene related effects. For quantitative investigations the spectral, radiometric characteristics of the system and scene have to be known. The relevant effects and their possible influence on an image have to be specifically determined for every remote sensing system and adequate description parameters need to be updated and reported on a regular basis as they are carried out, e.g., for the AVIRIS system. It is evident that the strength of the influence of similar effects in very dependent on the accessibility of auxiliary information about such sensor systems. Degradation in a spaceborne system can normally be just reported and cannot be corrected. In contrast, an airborne sensor can be evaluated, maintained and improved periodically. Such maintenance efforts are particularly important because airborne systems are exposed to extreme and changing environments. These include tens of takeoffs and landing each year as well as extreme changes in temperature and humidity on the tarmac and in flight. For the AVIRIS system there are environmental stresses such as changes in temperature, air pressure, humidity, vibration of the platform or scene-related reasons like atmospheric conditions, and topography. The information contained in the auxiliary files included with the AVIRIS data can be used to assess these effects and compensate for them. In addition the spectral, radiometer and geometric calibration data contained in the auxiliary file are required for quantitative analysis of the data. The paper describes tools to access the auxiliary information that characterizes the AVIRIS system. These tools allow the examination of parameters that may impact the quality of the measured AVIRIS image. An example of the use of this auxiliary data was carried out with regard to a parametric geocoding approach. Emphasis is placed on the reported auxiliary information that describes the geometric character of the AVIRIS data in 1991. Results are presented using data from the AVIRIS flight #910705, run 6 and 7 of the NASA MAC Europe 1991 campaign in a test site in Central Switzerland.

Meyer, Peter↗
DOE OSTI2024

Chiral Electrokinetic Phenomena in Single Nanopores

Abstract The arrangement of solvent molecules and ions at solid–liquid interfaces determines electrochemical properties that are important in separations platforms, sensing technologies, and energy‐storage systems. Here we show that single glass and polymer pores in contact with propylene carbonate (PC) solutions of LiClO 4 exhibit an effective surface potential that is modulated by the enantiomeric excess of the solvent. In particular, electrochemical and electrokinetic measurements of ionic transport through glass pipettes and polymer pores reveal that the effective surface potential is significantly lower in solutions prepared using enantiomerically pure PC than in solutions prepared using racemic PC. Both pore systems became positively charged in all racemic solutions examined in the range of LiClO 4 concentrations between 1 mM and 100 mM, whereas solutions in ( R )‐(+)‐PC induced a positive surface potential only at concentrations above ~5 mM. The effective surface potential is quantified through asymmetry in current–voltage curves and zeta‐potential measurements. Vibrational sum‐frequency‐generation experiments on LiClO 4 solutions in racemic and enantiomerically pure PC indicate that the surface lipid‐bilayer‐like region in the former is more strongly organized than in the latter, dictating the favorable positions for lithium and perchlorate ions in each case. The more ordered molecular packing in the racemic liquid leads to accumulation of lithium ions on the outside of the bilayer, creating a higher effective positive charge. Our results highlight the extreme sensitivity of the interfacial potential on molecular organization of the solvent, and the relatively unexplored role that chirality can play in electrokinetic phenomena.

Alanis, Kristen↗