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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21

Exclusive photoproduction of excited ρ mesons decaying to four pions in ultraperipheral Pb–Pb collisions at $\sqrt{s_{NN}}$ = 5.02 TeV

The intense photon fluxes from relativistic nuclei provide an opportunity to study photonuclear interactions in ultraperipheral collisions. In particular, it allows for the investigations of excited, light-flavour vector mesons. The measurement of coherently photoproduced 𝜋⁺𝜋 − 𝜋⁺𝜋 − final states in ultraperipheral Pb–Pb collisions at $\sqrt{s_{NN}}$ = 5.02 TeV is presented for the first time. The cross section, d𝜎/d𝑦, times the branching ratio (𝜌 → 𝜋⁺𝜋⁺𝜋 − 𝜋 − ) is found to be 47.8 ± 2.3 (stat.) ± 7.7 (syst.) mb in the rapidity interval |𝑦| < 0.5. The invariant mass distribution is not well described with a single Breit-Wigner resonance without an interference term. Including in- terference with a non-resonant contribution results in the mass and width values being too far from those reported in PDG, while the production of two interfering resonances, 𝜌(1450) and 𝜌(1700), also provides a good description of the data. The values of the masses (𝑚) and widths (Γ) of the resonances extracted from the fit assuming two interfering resonances are 𝑚₁ = 1385 ± 14 (stat.) ± 3 (syst.) MeV/𝑐², Γ₁ = 431 ± 36 (stat.) ± 82 (syst.) MeV/𝑐², 𝑚₂ = 1663 ± 13 (stat.) ± 22 (syst.) MeV/𝑐² and Γ₂ = 357 ± 31 (stat.) ± 49 (syst.) MeV/𝑐², respectively. The measured cross sections times the branching ratios are compared to recent theoretical predictions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Study of the interaction between $Ξ$ baryons and light mesons via femtoscopy at the LHC

Meson-baryon systems with strangeness content provide a unique laboratory for investigating the strong interaction and testing theoretical models of hadron structure and dynamics. In this work, the measured correlation functions for oppositely charged $Ξ$-K and $Ξ$ − 𝜋 pairs obtained in high-multiplicity pp collisions at $\sqrt{𝑠}$ = 13 TeV at the LHC are presented. For the first time, high-precision data on the $Ξ$-K interaction are delivered at small relative momenta. The scattering lengths, extracted via the Lednický–Lyuboshits expression of the pair wavefunction, indicate a repulsive and a shallow attractive strong interaction for the $Ξ$-K and $Ξ$ − 𝜋 systems, respectively. The $Ξ$(1620) and $Ξ$(1690) states are observed in the $Ξ$ − 𝜋 correlation function and their properties, mass and width, are determined. These measurements are in agreement with other available results. Such high-precision data can help refine the understanding of these resonant states, provide stronger constraints for chirally motivated potentials, and address the key challenge of describing the coupled-channel dynamics that may give rise to molecular configurations .

Femtoscopy↗

Detecting ecological signatures of long-term human activity across an elevational gradient in the Šumava Mountains, Central Europe

Central European mountains, including the Šumava Mountains located along the Czechia/Germany border, have a long and rich anthropogenic history. Yet, documenting prehistoric human impact in Central European mountain environments remains a challenge because of the need to disentangle climate and human-caused responses in terrestrial systems. Here, we present the first reconstructed water table depths (WTDs) from two sites, Pěkná and Blatenská slať, located in the Šumava Mountains. We compare these local WTD records with new and published pollen, non-pollen palynomorphs (NPPs), plant macrofossils, geochemistry and archeological records to investigate how changes in local hydrology and human activities impacted forest succession and fire activity throughout the Holocene across an elevational gradient. Using a generalized additive model, our results suggest that changes in forest succession and fire activity have been primarily caused by climate throughout the Holocene. However, humans have been utilizing mountain environments and their resources continuously since ∼4600 cal yr BP, thus playing a secondary role in modifying forest succession to increase resources beneficial to both humans and grazers. Over the last 1000 years, we provide evidence of directly observed human-caused modifications to the landscape. These results contribute to a growing body of literature illustrating human activities and landscape modifications in Central European mountains.

54 ENVIRONMENTAL SCIENCES↗

Paleoclimatic implications of glacial fluctuations in the Sierra Nevada del Cocuy, northern Andes, Colombia, during the Lateglacial and Holocene

The reconstruction of former mountain glaciers from geomorphic mapping and cosmogenic-nuclide surface-exposure dating provides a unique opportunity to infer patterns of past terrestrial climate variability. Tropical mountain glaciers are particularly valuable as there are comparatively few terrestrial climate proxies at equatorial latitudes relative to higher latitudes. As the single largest climate zone on Earth, the tropics play an outsized role in mediating global climate via the ocean-atmosphere transfer of latent heat and water vapor. Nonetheless, there remains a persistent gap in our understanding of how the tropics influenced – or were influenced by – the high-magnitude climate shifts of the Late Pleistocene, and whether this high-energy region simply responded to extratropical forcing or was itself a driver of global climatic change. To help address this knowledge gap, we analyzed geologic evidence for past glacial fluctuations in three adjacent valleys in the Sierra Nevada del Cocuy, the highest subrange of the Eastern Cordillera in the Colombian Andes, to provide a terrestrial record of atmospheric temperature during the latter part of Termination 1. Coupled with geomorphic mapping and paleo-snowline reconstructions, our beryllium-10 glacial chronology indicates that glaciers in the humid inner tropics underwent pronounced growth and gradual decay during the Antarctic Cold Reversal (14.5–12.8 ka) and Younger Dryas (12.8–11.7 ka) periods, respectively, following a trend that, according to directly dated moraine records from throughout both polar hemispheres, appears to have been global. While the specific mechanism(s) behind this large-scale behavior remains to be corroborated, we revisit the hypothesis that ocean-atmosphere heat transfer and water vapor flux are key drivers of abrupt Lateglacial temperature fluctuations. Subsequent to the Lateglacial, deglaciation of the Sierra Nevada del Cocuy accelerated during the Early Holocene, a pattern also observed in other tropical glacier records. More recently, the magnitude of snowline rise and glacier retreat over the last two centuries supports the view that modern tropospheric warming is anomalously strong at least relative to the last ∼16,000 years.

Andes↗

Valuing wind as a distributed energy resource: A literature review

As more distributed energy resources are deployed on electric grid systems across the world, it is important to identify, characterize, and quantify the value elements of different types of distributed energy resources so that policymakers, developers, and utilities can make informed energy deployment decisions. This paper focuses on the value of wind energy as a distributed energy resource (i.e., “distributed wind”). Because of a lack of distributed wind-specific valuation studies, in this review we document the current state of distributed energy resource valuation, analyze a wide array of distributed energy resource valuation metastudies, and identify several value elements for which we recommend developing more robust and standardized calculation methodologies for their potential inclusion in distributed wind valuation. These value elements are ancillary services and locational, resilience, reliability, and resource diversity benefits. Furthermore, this work lays the foundation for a future comprehensive framework for distributed wind valuation studies.

17 WIND ENERGY↗

Calcareous organic matter coatings sequester siderophores in alkaline soils

Although most studies on organic matter stabilization in soils have focused on adsorption to aluminosilicate and iron oxide minerals due to their strong interactions with organic nucleophiles, stabilization within alkaline soils has been empirically correlated with exchangeable Ca concentrations. Yet the extent of competing processes within natural soil remain unclear. We employed sub-micron scale techniques to investigate the minerology and organic carbon on individual fine particles within an alkaline soil from Eastern Washington. XRD, Mössbauer spectroscopy, TEM-EDX-SAED, and XPS analysis demonstrated a mineral assemblage dominated by quartz, feldspars, iron oxides, and calcite. Although exposed Si, Al, and Fe accounted for ~30% of the surface elemental composition, most of the organic carbon and nitrogen was associated with Ca-rich coatings. Adsorption isotherms of two siderophores with the same soil showed greater adsorption of pyoverdine compared with less polar enterobactin. Using NanoSIMS to map the distribution of isotopically labeled siderophores across the surfaces of fine grains, we observed a preference for binding to surfaces heavily coated with organic matter. We propose a mechanism of adsorption by which organic molecules aggregate within calcareous soils via calcium bridging, favoring the stabilization of larger molecules with a greater number of nucleophilic functional groups.

54 ENVIRONMENTAL SCIENCES↗

Moisture-mineral interactions drive bacterial and organic matter turnover in glacier-sourced riparian sediments undergoing pedogenesis

Glacial recession is occurring at unprecedented rates resulting in increased sediment accumula-tions in some riverine ecosystems. Increased sediment deposition has implications for ecosystem stability (e.g., floods and river paths) and environmental services (e.g., carbon sequestration). Soils and sediments have an enormous potential to retain carbon (C), predominantly due to sorp-tion to mineral surfaces. However, C persistence may be sensitive to climate-change induced temperature and moisture variations. We coupled ultrahigh resolution organic matter composition classification with bacterial characterization and respiration measurements to test the combined effects of temperature (4 vs 20°C) and moisture (50 vs 100% water-filled pore space) on C turn-over in sediments maintained under different mineralogical conditions (illite-amended vs non-amended). Here we show that the inhibition of CO 2 emissions from the combined effect of in-creased moisture content and illite was reflected in the turnover of key molecular signatures, such as the nominal oxidation state of C, often irrespective of temperature. However, shifts in bacteri-al communities from a coupled moisture-mineral interaction, were temperature-dependent. Our results highlight the importance of moisture in driving mineral-organic interactions and suggest that C in clay-rich, water-saturated sediments is both thermodynamically unfavorable and miner-al-protected from microbial consumption.

58 GEOSCIENCES↗

Inhibition of polyamine biosynthesis preserves β cell function in type 1 diabetes

In preclinical models, α-difluoromethylornithine (DFMO), an ornithine decarboxylase (ODC) inhibitor, delays the onset of type 1 diabetes (T1D) by reducing β cell stress. However, the mechanism of DFMO action and its human tolerability remain unclear. In this study, we show that mice with β cell ODC deletion are protected against toxin-induced diabetes, suggesting a cell-autonomous role of ODC during β cell stress. In a randomized controlled trial (ClinicalTrials.gov: NCT02384889) involving 41 recent-onset T1D subjects (3:1 drug:placebo) over a 3-month treatment period with a 3-month follow-up, DFMO (125–1,000 mg/m 2 ) is shown to meet its primary outcome of safety and tolerability. DFMO dose-dependently reduces urinary putrescine levels and, at higher doses, preserves C-peptide area under the curve without apparent immunomodulation. Transcriptomics and proteomics of DFMO-treated human islets exposed to cytokine stress reveal alterations in mRNA translation, nascent protein transport, and protein secretion. These findings suggest that DFMO may preserve β cell function in T1D through islet cell-autonomous effects.

60 APPLIED LIFE SCIENCES↗

Building a Healthy Urban Design Index (HUDI): how to promote health and sustainability in European cities

As global urbanisation accelerates, alongside declining environmental quality and increasing climate challenges, it is increasingly vital for urban planners and policy makers to integrate health and wellbeing considerations into urban planning. This study introduces the Healthy Urban Design Index (HUDI), a high-resolution spatial index developed for European cities. HUDI combines policy-relevant indicators related to urban design, sustainable transportation, environmental quality, and greenspace accessibility—key factors influencing human health and well-being. Unlike existing indices, which often focus on few or large metropolitan cities and lack spatial granularity, HUDI offers high resolution and extends its scope to small-sized and medium-sized cities, home to over 50% of Europe's population.

60 APPLIED LIFE SCIENCES↗

Damage-free Analysis of Biological Materials by Vibrational Spectroscopy in the EM

In summary, vibrational spectroscopy in the electron microscope promises to probe biological materials in a way that is similar to infrared spectroscopy, at a spatial resolution of about 30-50 nm, while circumventing radiation damage. Herein we are now focused on developing this technique fully, using a side-entry cryotransfer holder in a Nion HERMES electron microscope equipped with a fast and efficient EELS direct detector [10], and capable of 5 meV (and better) energy resolution. The results of these investigations will be reported at the meeting.

59 BASIC BIOLOGICAL SCIENCES↗

Revealing Soil Organic Matter-mineral Associations with Advanced Chemical Imaging Methods

Although macro-scale in nature, most biogeochemical processes are driven by interactions at the microand nano-scale. Therefore, precise characterization of both organic and inorganic system components requires multi-scale, often multi-capability approaches. In this work, we present the state-of-the-art characterization of organic matter-mineral associations by high-resolution correlated chemical imaging.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Environmental Contributions to Proton Sharing in Protein Low-Barrier Hydrogen Bonds

Hydrogen bonds (H-bonds) are central to biomolecular structure and dynamics. Although H-bonds are typically characterized by well-defined proton positions, proton delocalization has been proposed to play a role in facilitating enzyme catalysis and allostery in some systems. Experimentally locating protons is difficult, hampering the study of proton mobility in H-bonds. We used neutron crystallography, atomic resolution X-ray bond length analysis, and large quantum mechanics/molecular mechanics-Born–Oppenheimer molecular dynamics (QM/MM-BOMD) simulations to comprehensively characterize the shared proton/deuteron in a Glu–Asp low-barrier hydrogen bond (LBHB) in the bacterial protein YajL that is a conventional H-bond in the homologous disease-associated human protein DJ-1. X-ray bond length analysis of protiated and perdeuterated DJ-1 and YajL shows no significant effect of deuteron substitution on these carboxylic acid-carboxylate H-bonds but does reveal an effect at the active site glutamic acid near a cysteine thiolate. Residues in an H-bonded network that might favor LBHB formation in YajL were interrogated by the mutation of homologous residues in DJ-1. A distal DJ-1 substitution increases proton delocalization in the Glu–Asp H-bond, demonstrating that mutations within extended H-bond networks can modulate proton transfer barriers in carboxylic acid-carboxylate H-bonds. In addition, proton mobility in the H-bond is correlated with dimer-spanning motions in the QM/MM-BOMD simulations of YajL and DJ-1. Our results show that proton delocalization can be tuned using combined bioinformatic, structural, and computational information, opening the possibility of using engineered proton delocalization as a probe of H-bonding environments and as a tool to test hypotheses about LBHB function.

Lin, Jiusheng [University of Nebraska, Lincoln, NE↗