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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
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NASA NTRS1987

Absolute I(asterisk) quantum yields for the ICN A state by diode laser gain-vs-absorption spectroscopy

Absolute I(asterisk) quantum yields have been measured as a function of wavelength for room temperature photodissociation of the ICN A state continuum. The yields are obtained by the technique of time-resolved diode laser gain-vs-absorption spectroscopy. Quantum yields are evaluated at seven wavelengths from 248 to 284 nm. The yield at 266 nm is 66.0 + or - 2 percent and it falls off to 53.4 + or - 2 percent and 44.0 + or - 4 percent at 284 and 248 nm, respectively. The latter values are significantly higher than those obtained by previous workers using infrared fluorescence. Estimates of I(asterisk) quantum yields obtained from analysis of CN photofragment rotational distributions, as discussed by other workers, are in good agreement with the I(asterisk) yields reported here. The results are considered in conjunction with recent theoretical and experimental work on the CN rotational distributions and with previous I(asterisk) quantum yield results.

Hess, Wayne P.↗
NASA NTRS1987

Reflectance- and radiance-based methods for the in-flight absolute calibration of multispectral sensors

Variations reported in the in-flight absolute radiometric calibration of the Coastal Zone Color Scanner (CZCS) and the Thematic Mapper (TM) on Landsat 4 are reviewed. At short wavelengths these sensors exhibited a gradual reduction in response, while in the midinfrared the TM showed oscillatory variations, according to the results of TM internal calibration. The methodology and results are presented for five reflectance-based calibrations of the Landsat 5 TM at White Sands, NM, in the period July 1984 to November 1985. These show a + or - 2.8 percent standard deviation for the six solar-reflective bands. Analysis and preliminary results of a second, independent calibration method, based on radiance measurements from a helicopter at White Sands, indicate that this is potentially an accurate method for corroborating the results from the reflectance-based method.

Slater, P. N.↗
NASA NTRS1986

Absolute radiometric calibration of the Thematic Mapper

Calibration data for the solar reflective bands of the Landsat-5 TM obtained from five in-flight absolute radiometric calibrations from July 1984-November 1985 at White Sands, New Mexico are presented and analyzed. Ground reflectance and atmospheric data were utilized to predict the spectral radiance at the entrance pupil of the TM and the average number of digital counts in each TM band. The calibration of each of the TM solar reflective bands was calculated in terms of average digital counts/unit spectral radiance for each band. It is observed that for the 12 reflectance-based measurements the rms variation from the means as a percentage of the mean is + or - 1.9 percent; for the 11 measurements in the IR bands, it is + or - 3.4 percent; and the rms variation for all 23 measurements is + or - 2.8 percent.

Slater, P. N.↗
NASA NTRS1987

Lyman alpha SMM/UVSP absolute calibration and geocoronal correction

Lyman alpha observations from the Ultraviolet Spectrometer Polarimeter (UVSP) instrument of the Solar Maximum Mission (SMM) spacecraft were analyzed and provide instrumental calibration details. Specific values of the instrument quantum efficiency, Lyman alpha absolute intensity, and correction for geocoronal absorption are presented.

Fontenla, Juan M.↗
NASA NTRS1986

Crystalline sulfur dioxide: Crystal field splittings, absolute band intensities and complex refractive indices derived from infrared spectra

The infrared absorption spectra of thin crystalline films of sulfur dioxide at 90 K are reported in the 2700 to 450/cm region. The observed multiplicity of the spectral features in the regions of fundamentals is attributed to factor group splittings of the modes in a biaxial crystal lattice and the naturally present minor S-34, S-36, and O-18 isotopic species. Complex refractive indices determined by an iterative Kramers-Kronig analysis of the extinction data, and absolute band strengths derived from them, are also reported in this region.

Khanna, R. K.↗
NASA NTRS1987

Absolute oscillator strengths for 108 lines of Si I between 163 and 410 nanometers

Measurements of neutral silicon oscillator strengths (f-values) obtained by absorption and emission techniques have been combined using the numerical procedure of Cardon et al. (1979) to produce 108 f-values for the Si I lines between 163 and 410 nm. Beam-foil-lifetime measurements were employed to determine the absolute scale. The present measurements have uncertainties of about 0.07 dex (+ or - 16 percent) at the 1-sigma level of confidence. Good agreement is obtained between the results and previous data. The data also provide upper limits for the f-values of 22 other lines and information on the lifetimes for 36 levels in Si I.

Smith, Peter L.↗
NASA NTRS1987

Tunable diode laser measurements of absolute linestrengths in the HNO3 band near 5.8 microns

Absolute line strengths of selected lines in the nu 2 band of HNO3 have been measured using a tunable diode laser spectrometer operating in a sweep integration mode. The direct measurement technique has been employed to obtain line intensities at 296 K for 22 isolated lines in the 1720-1725/cm region. The reported line strengths have estimated uncertainties of 4 percent, a significant portion of this uncertainty arising from spectral interference from hot band transitions. From these line-strength measurements, an integrated band intensity of 1375/sq cm per atm at 296 K is inferred.

May, Randy D.↗
NASA NTRS1988

Absolute intensities of CO2 lines in the 3140-3410/cm spectral region

Absolute intensities for 430 transitions belonging to eleven rotation-vibration bands of (C-12)(O-16)2, (C-13)(O-16)2, and (O-16)(C-18)(O-18) in the 3140-3410/cm spectral region have been determined by analyzing spectra recorded at 0.01/cm resolution with the Fourier transform spectrometer in the McMath solar telescope complex at the National Solar Observatory on Kitt Peak. The data were recorded at room temperature and low pressures (less than 10 torr) using a natural sample of carbon dioxide. Intensities were derived using a nonlinear least-squares spectral fitting procedure, and the values obtained for each band have been analyzed to determine the vibrational band intensity and nonrigid rotor coefficients. An alternative mathematical formulation is shown in the case of bands for which the Coriolis effect is large and the Q-branch line intensities were not determinable either because they were severely blended or absent from the spectra. Comparison are made between the results obtained in this study and other published values.

Benner, D. Chris↗
NASA NTRS1988

The absolute radiometric calibration of the advanced very high resolution radiometer

An increasing number of remote sensing investigations require radiometrically calibrated imagery from NOAA Advanced Very High Resolution Radiation (AVHRR) sensors. Although a prelaunch calibration is done for these sensors, there is no capability for monitoring any changes in the in-flight absolute calibration for the visible and near infrared spectral channels. Hence, the possibility of using the reflectance-based method developed at White Sands for in-orbit calibration of LANDSAT Thematic Mapper (TM) and SPOT Haute Resolution Visible (HVR) data to calibrate the AVHRR sensor was investigated. Three diffrent approaches were considered: Method 1 - ground and atmospheric measurements and reference to another calibrated satellite sensor; Method 2 - ground and atmospheric measurements with no reference to another sensor; and Method 3 - no ground and atmospheric measurements but reference to another satellite sensor. The purpose is to describe an investigation on the use of Method 2 to calibrate NOAA-9 AVHRR channels 1 and 2 with the help of ground and atmospheric measurements at Rogers (dry) Lake, Edwards Air Force Base (EAFB) in the Mojave desert of California.

Slater, P. N.↗
NASA NTRS1988

Absolute radiometric calibration of the NOAA AVHRR sensors

Three different approaches to the absolute radiometric calibration of the two reflective channels of the NOAA AVHRR sensors are presented. The first method involves ground and atmospheric measurements and reference to another calibrated satellite sensor. The second involves ground and atmospheric measurements with no reference to another sensor, while the third method involves no ground and atmospheric measurements but reference to another sensor. NOAA-9 and NOAA-10 AVHRR data sets are presented.

Teillet, P. M.↗
NASA NTRS1989

Tunable diode laser measurements of absolute line strengths in the 2nu2 band of N2O near 8 microns

The absolute intensities of five rotational transitions in the 2nu2 band of N2O near 8 microns have been measured with a tunable-diode laser-spectrometer. Measurements were reproducible within an average deviation of about 3 percent, and the experimental and calculated line strengths differed by only 1.5 percent. An analysis of the line strengths has yielded a band strength of S(v) = 6.98 + or - 0.26/sq cm per atm at 296 K. The band and line strengths are in excellent agreement with two recently reported values obtained by using Fourier transform-IR spectroscopy.

Tang, Lai-Wa↗
NASA NTRS1988

Absolute UV irradiance calibration of the Solar UV Spectral Irradiance Monitor (SUSIM) instruments

The Solar Ultraviolet Spectral Irradiance Monitor (SUSIM) flown on Spacelab 2 (SL2) and a second advanced instrument being prepared for flight on the Upper Atmospheric Research Satellite (UARS) are calibrated using a number of absolute UV irradiance standards in order to meet the stringent calibration goals of the SUSIM program. The SUSIM instruments, the methods of calibration, and the error analyses are described.

Vanhoosier, Michael E.↗
NASA NTRS1989

Morphological transitions in the rapid solidification regime - A re-examination of the fundamental validity of the absolute stability concept of Mullins and Sekerka

The validity of the notion of absolute stability (AS) of a planar solid-liquid interface, proposed by Mullins and Sekerka (M-S, 1964), was tested using experimental data obtained for a number of dilute Ag-Cu and Sn-In alloys and for ultrahigh-purity succinonitrile. It is shown that the restriction applied by the M-S theory is satisfied during the steady-state planar solidification in an undercooled melt, provided the undercooling is quite small. The findings obtained on the Ag-Cu and Sn-In alloys are compared with early measurements by Davis and Fryzuk (1971) in dilute Sn-In alloys with 25 to 400 ppm additions of In.

Laxmanan, V.↗
NASA NTRS1989

Radial velocity studies and absolute parameters of contact binaries. II - OO Aquilae

New high-precision radial velocities of the contact binary OO Aql have been obtained using the cross-correlation technique. The orbital elements have been corrected for proximity effects, using an analysis of published light curves of the system. The spectroscopically determined mass ratio of 0.843 is in excellent agreement with the photometrically determined value. OO Aql thus has one of the largest mass ratios observed for a contact binary. In contrast to almost all other contact binaries of G spectral type, the primary minimum is due to a transit by the less massive component, and thus the system is classified as an A-type contact binary. Absolute parameters are determined for OO Aql, which indicate that the primary component, although similar to the Sun in mass, is significantly more evolved. An age of about 8 Gyr and a metal abundance of one-half that of the Sun are determined. It seems that the system may have only recently evolved into contact, as suggested by Mochnacki, and that it is an important object for studies of the structure and evolution of contact binaries.

Hrivnak, Bruce J.↗
NASA NTRS1989

First year's results and field experience with the latest JILA absolute gravimeter

One of the six absolute gravity instruments developed and built by the Joint Institute for Laboratory Astrophysics (JILA) between 1982 and 1985 was tested under a variety of environmental conditions between May 1987 and 1988. Of the 30 sites visited during this period, 10 were occupied more than once. These reobservations indicate repeatability between 1 and 4 microgals.

Peter, G.↗
NASA NTRS1990

Absolute vacuum ultraviolet photoabsorption cross section studies of atomic and molecular species: Techniques and observational data

Absorption of a high energy photon (greater than 6 eV) by an isolated molecule results in the formation of highly excited quasi-discrete or continuum states which evolve through a wide range of direct and indirect photochemical processes. These are: photoionization and autoionization, photodissociation and predissociation, and fluorescence. The ultimate goal is to understand the dynamics of the excitation and decay processes and to quantitatively measure the absolute partial cross sections for all processes which occur in photoabsorption. Typical experimental techniques and the status of observational results of particular interest to solar system observations are presented.

Judge, D. L.↗
NASA NTRS1990

Color excesses, intrinsic colors, and absolute magnitudes of Galactic and Large Magellanic Cloud Wolf-Rayet stars

A new method of determining the color excesses of WR stars in the Galaxy and the LMC has been developed and is used to determine the excesses for 44 Galactic and 32 LMC WR stars. The excesses are combined with line-free, narrow-band spectrophotometry to derive intrinsic colors of the WR stars of nearly all spectral subtypes. No correlation of UV spectral index or intrinsic colors with spectral subtype is found for the samples of single WN or WC stars. There is evidence that early WN stars in the LMC have flatter UV continua and redder intrinsic colors than early WN stars in the Galaxy. No separation is found between the values derived for Galactic WC stars and those obtained for LMC WC stars. The intrinsic colors are compared with those calculated from model atmospheres of WR stars and generally good agreement is found. Absolute magnitudes are derived for WR stars in the LMC and for those Galactic WR stars located in clusters and associations for which there are reliable distance estimates.

Vacca, William D.↗
NASA NTRS1990

Three methods for the absolute calibration of the NOAA AVHRR sensors in-flight

Three techniques for the absolute calibration of two reflective channels of the NOAA AVHRR sensors are described and compared. The technique 1 is based on field measurements and refers to another calibrated satellite sensor; technique 2 utilizes the reflectance-based calibration method; and technique 3 estimates the calibration by reference to another satellite sensor. NOAA-9 and NOAA-10 AVHRR images are analyzed. It is observed that the responsivity of the images degrade compared to prelaunch calibration. The effect of degradation in responsivity of the AVHRR sensors on vegetation indices are studied. It is noted that the uncertainties in the calibration methods is about 7-10 percent making them useful for many applications.

Teillet, P. M.↗