Search NASA⌕ Search

SEARCH · Search NASA

Results for “ELEMENT ABUNDANCE”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
NASA NTRS2015

Lead Isotope Compositions of Acid Residues from Olivine-Phyric Shergottite Tissint: Implications for Heterogeneous Shergottite Source Reservoirs

Geochemical studies of shergottites suggest that their parental magmas reflect mixtures between at least two distinct geochemical source reservoirs, producing correlations between radiogenic isotope compositions and trace element abundances. These correlations have been interpreted as indicating the presence of a reduced, incompatible element- depleted reservoir and an oxidized, incompatible- element-enriched reservoir. The former is clearly a depleted mantle source, but there is ongoing debate regarding the origin of the enriched reservoir. Two contrasting models have been proposed regarding the location and mixing process of the two geochemical source reservoirs: (1) assimilation of oxidized crust by mantle derived, reduced magmas, or (2) mixing of two distinct mantle reservoirs during melting. The former requires the ancient Martian crust to be the enriched source (crustal assimilation), whereas the latter requires isolation of a long-lived enriched mantle domain that probably originated from residual melts formed during solidification of a magma ocean (heterogeneous mantle model). This study conducts Pb isotope and trace element concentration analyses of sequential acid-leaching fractions (leachates and the final residues) from the geochemically depleted olivine-phyric shergottite Tissint. The results suggest that the Tissint magma is not isotopically uniform and sampled at least two geochemical source reservoirs, implying that either crustal assimilation or magma mixing would have played a role in the Tissint petrogenesis.

Moriwaki, R.↗
NASA NTRSDate not supplied

The Significance of Helium in the Solar Wind: Insights from 1 AU

Doubly ionized helium is the 2nd most abundant element in the solar wind. The solar wind’s properties are a function of the source region on the Sun from which it emanates. This includesthe abundances of solar wind Helium and rarer, heavier elements. The speed of the solar wind, when observed near Earth, is also related to the type of source region from which the solar wind originated. Early solar wind models are unable to explain how the solar wind achieved the asymptotically fastest, non-transient speeds observed at 1 AU and the solar wind must be accelerated during transit through interplanetary space. Only recently have observations shown that the solar wind from different source regions is accelerated by different mechanisms. However, the solar wind speed is also known to be an insufficient for identifying the type of solar source from which it originated, likely because these different acceleration mechanisms accelerate the solar wind into two different speed regimes that overlap. Furthermore, the mechanism that provides the coronal plasma sufficient energy to accelerate into the solar wind is still undetermined. These mysteries are further complicated by the Sun’s evolution through its 11-year activity cycle and the impact of the solar cycle on in situ observations. Using solar wind observations of the helium abundance from the Wind spacecraft and heavy ion abundances from the Advanced Composition Explorer (ACE) along with observations of the Sunspot Number – a long-studied proxy for the Sun’s activity – we will discuss the imprint of different solar wind source regions on observations collected at 1 AU. We will draw inferences about the role of helium in the acceleration of coronal plasma into the solar wind. Using the Alfvénicity – a metric related to the solar wind acceleration that occurs during transit through interplanetary space – we will derive a solar wind classification scheme for near-Earth observations that is related to the differences in the source regions from which it emanates.

Benjamin Alterman↗
NASA NTRS1994

Metal abundances and kinematics of a high-redshift galaxy obtained with the Kech telescope

We use the Kech 10 m telescope and its high-resolution echelle spectrometer (HIRES) to obtain accurate high-resolution spectra of a quasar to determine element abundances of a probable foreground young galaxy with redshift z = 2.309. Precise measurements of absorption lines lead to the first accurate abundance determinations on Zn, Cr, and Ni at large redshifts. We find that (Zn/H) = -1.55 +/- 0.11, while (Cr/H) = -1.79 +/- 0.10 and (Ni/H) = -2.13 +/- 0.08. The Zn abundance indicates low metallicity, while the Cr and Ni abundances are consistent with depletion of these elements onto grains. We also find (O/H) less than 0.97. Therefore, the galaxy is more metal-deficient than the oldest disk stars in the Galaxy. The kinematic evidence is consistent with a thick disk of gas with rotation speed and radius comparable to the rotation speeds and radii of current luminous spiral galaxies. Therefore, a rotationally supported disk may be in place at z greater than 2.

Wolfe, Arthur M.↗
NASA NTRS2006

Elemental and Molecular Relative Abundances in the Ejecta of Eta Carinae

We are measuring relative elemental abundances for the ejecta in the line of sight from Eta Carinae using high dispersion spectroscopy with the HST/STIS and the VLT/UVES. While multiple velocity components have been identified, we focus on the -513 and -146 km/s components originating from the Homunculus and the Little Homunculus. Complicating factors are the complex nebular structures in the immediate vicinity of the bright, massive star: the very bright emission structures, Weigelt blobs B, C and D, the broad, clumpy structures of the extended wind apparently not photoionized by Eta Car B, and general scattered starlight from the extended wind and the dusty core of the circumstellar material. We have used the 3050 to 3160A region of overlap between STIS and UVES to intercompare equivalent widths of absorption lines to estimate the 'contributing factor', namely the amount of light originating from the star compared to nebular structures. While the extracted STIS spectra are from 0.1" wide aperture, the UVES spectra are limited by the 1" seeing conditions. Curiously we find that the scattering contribution in the UVES spectra changes with time, apparently with orbital phase of the 5.54-year period. This indicates that the dust may be modified by changes in the central source with phase. The noticeable drop in scattered light appears to occur about 1.7 years (phase 0.35) after the spectroscopic minimum. Relative abundances of iron peak elements and some molecules will be estimated. Observations in this study were accomplished with HST through STSci and with VLT through ESO and funded under STIS GTO resources.

Kober, G. V.↗
NASA NTRS1973

Rb-Sr systematics for chemically defined Apollo 15 and 16 materials

Concentrations of Rb and Sr and the Sr87/86 ratios are determined in a large number of Apollo 15 samples, including KREEP basalts, mare basalts, anorthosite breccia clasts, lithic fragments, a spinel-bearing clast, green glass samples, breccia matrix, and soils. Relative concentrations of Sm, Eu, Rb, and Sr are also examined in the samples, with particular attention to Rb/Sr systematics vs other trace element abundances and total chemical compositions of rocks. Analysis of crystalline KREEP samples rich in trace elements indicates that the differentiation of these rocks has extended to -4.25 AE age, a significantly later time than the presumed time of accretion of the moon.

Nyquist, L. E.↗
NASA NTRS1976

Nature of the carbon and sulfur phases and inorganic gases in the Kenna ureilite

Abundances of carbon and sulfur in the Kenna ureilite are 2.219 plus or minus 0.060 wt. % C and 0.179 plus or minus 0.008 wt. % S. Secondary carbonates resulting from terrestrial weathering account for 0.25 plus or minus 0.02 wt. % C. No hydrocarbons were detected during gas release measurements. Most of the carbon is in graphite, diamond, or lonsdaleite. The sample of Kenna contained 0.95 plus or minus 0.05 wt.% H2O. Total carbon and sulfur measurements were made on three additional ureilites: Havero, Dingo Pup Donga, and North Haig. Ureilite carbon abundances are similar to those of C-2 chondrites, whereas sulfur abundances are a factor of 10 less than C-2 chondrites and ordinary chondrites. The elemental abundances, ratios, and phases present in the ureilites rule out a direct genetic relationship between the ureilites and the carbonaceous chondrites.

Gibson, E. K., Jr.↗
NASA NTRS1986

Alkali norite, troctolites, and VHK mare basalts from breccia 14304

Six pristine rocks, two mare basalts, and four nonpristine highlands rocks were separated from breccia 14304 for consortium study. The pristine highlands rocks include representatives of the Mg troctolite-anorthosite and alkali suites of the Apollo 14 site. Two troctolite clasts have olivine and plagioclase compositions similar to one group of Apollo 14 troctolites and one also contains spinel. Incompatible element abundances in one are similar to those of 14305 troctolites, although the heavy rare earth elements pattern is distinct among Apollo 14 troctolites. Alkali lithologies include an alkali anorthosite and an alkali norite, the latter having a pristine igneous texture and resembling alkali gabbronites from Apollo 14 and 67975 in mineralogy and mineral compositions. It is suggested that Apollo 14 alkali lithologies and PO4-bearing Mg anorthosites formed from Mg-rich magmas that assimilated various amounts of material rich in P and REE. Another pristine clast from 14304 is an Mg-gabbronorite. The two mare basalt clasts are very high potassium basalts, whose parent magmas could have formed from a typical low-Ti, high-Al basaltic magmas by assimilation of K-rich material. Nonpristine 14304 clasts include melt-textured anorthosites and an augite-rich poikilitic melt rock.

Goodrich, C. A.↗
NASA NTRS2003

Solar Flare Abundances of Potassium, Argon, and Sulphur

The absolute coronal abundances of potassium has been determined for the first time from X-ray solar flare line and continuous spectra together with absolute and relative abundances of Ar and S. Potassium is of importance in the continuing debate concerning the nature of the coronal/photospheric element abundance ratios which are widely considered to depend on first ionization potential since it has the lowest FIP of any common element in the Sun. The measurements were obtained with the RESIK crystal spectrometer on the Coronas-F spacecraft. A differential emission measure DEM = const. x exp (-(beta)T(sub e) was found to be the most consistent with the data out of three models considered. We find that the coronal ratio [K/H] = 3.7 x 10(exp - 7), a factor 3 times photospheric, in agreement with other observations using line-to-line ratios. Our measured value for the coronal ratio [Ar/H] = 1.5 x 10(exp -6) is significantly less than photospheric, indicating that there is a slight depletion of this high-FIP element in the corona. For S (an intermediate-FIP element) we obtained [S/H] = 2.2 x 10(exp - 5), approximately the same as in previous work.

Oegerle, William↗
NASA NTRS1974

Bulk compositions of the moon and earth, estimated from meteorites

The present work calculates the bulk compositions of the earth and moon, based on the assumption that these planets formed by the same processes as chondrites. In terms of the model presented, the earth contains 9.2% early condensate and 1.5% carbonaceous, volatile-rich silicate. For the moon these percentages are 30.1 and 0.04, respectively. When lunar and terrestrial basalt data are normalized to these model compositions, element abundance patterns based on the percentages (assuming that each component carried its cosmic complement of trace elements) demonstrate the essential identity of igneous processes on both celestial bodies.

Ganapathy, R.↗
NASA NTRS1983

Kinetic effects on trace element partitioning

A potential difficulty regarding the application of trace element abundance data to problems in igneous petrogenesis is related to the possibility that partitioning of trace elements among minerals and melt may not be an equilibrium process. It may rather be controlled by kinetic processes, specifically the interplay between crystal growth and diffusion of the trace elements in crystals and melt. The present investigation has the objective to quantify kinetic effects on trace element partitioning. Crystals of olivine, pyroxene, and plagioclase were grown rapidly from synthetic melts resembling naturally-occurring mafic melts and doped with La, Sm, and Lu to quantify the magnitude of the effect of crystal growth rate on concentration of excluded trace elements. Olivine melt partitioning failed to show any appreciable kinetic effects, while diopside/melt distribution coefficients increased by 70 percent when the crystals grew very rapidly.

Lindstrom, D. J.↗
NASA NTRS1985

Theoretical Thermodynamics of Mixtures at High Pressures

The development of an understanding of the chemistry of mixtures of metallic hydrogen and abundant, higher-z material such as oxygen, carbon, etc., is important for understanding of fundamental processes of energy release, differentiation, and development of atmospheric abundances in the Jovian planets. It provides a significant theoretical base for the interpretation of atmospheric elemental abundances to be provided by atmospheric entry probes in coming years. Significant differences are found when non-perturbative approaches such as Thomas-Fermi-Dirac (TFD) theory are used. Mapping of the phase diagrams of such binary mixtures in the pressure range from approx. 10 Mbar to approx. 1000 Mbar, using results from three-dimensional TFD calculations is undertaken. Derivation of a general and flexible thermodynamic model for such binary mixtures in the relevant pressure range was facilitated by the following breakthrough: there exists an accurate nd fairly simple thermodynamic representation of a liquid two-component plasma (TCP) in which the Helmholtz free energy is represented as a suitable linear combination of terms dependent only on density and terms which depend only on the ion coupling parameter. It is found that the crystal energies of mixtures of H-He, H-C, and H-O can be satisfactorily reproduced by the same type of model, except that an effective, density-dependent ionic charge must be used in place of the actual total ionic charge.

Hubbard, W. B.↗
NASA NTRS2002

Trace-Element Analyses of Carbonate Minerals in the Gunflint Banded Iron Formation

We report on the petrography, mineralogy and trace-element abundances of individual carbonate grains in the Early Proterozoic Gunflint BIF (Banded Iron Formation). Trace-element data may be used as environmental recorders of the fluid evolution from which the various carbonate phases precipitated. Additional information is contained in the original extended abstract.

Pun, Aurora↗
NASA NTRS2014

Preliminary Report on U-Th-Pb Isotope Systematics of the Olivine-Phyric Shergottite Tissint

Geochemical studies of shergottites suggest that their parental magmas reflect mixtures between at least two distinct geochemical source reservoirs, producing correlations between radiogenic isotope compositions, and trace element abundances.. These correlations have been interpreted as indicating the presence of a reduced, incompatible-element- depleted reservoir and an oxidized, incompatible-element-rich reservoir. The former is clearly a depleted mantle source, but there has been a long debate regarding the origin of the enriched reservoir. Two contrasting models have been proposed regarding the location and mixing process of the two geochemical source reservoirs: (1) assimilation of oxidized crust by mantle derived, reduced magmas, or (2) mixing of two distinct mantle reservoirs during melting. The former clearly requires the ancient martian crust to be the enriched source (crustal assimilation), whereas the latter requires a long-lived enriched mantle domain that probably originated from residual melts formed during solidification of a magma ocean (heterogeneous mantle model). This study conducts Pb isotope and U-Th-Pb concentration analyses of the olivine-phyric shergottite Tissint because U-Th-Pb isotope systematics have been intensively used as a powerful radiogenic tracer to characterize old crust/sediment components in mantle- derived, terrestrial oceanic island basalts. The U-Th-Pb analyses are applied to sequential acid leaching fractions obtained from Tissint whole-rock powder in order to search for Pb isotopic source components in Tissint magma. Here we report preliminary results of the U-Th-Pb analyses of acid leachates and a residue, and propose the possibility that Tissint would have experienced minor assimilation of old martian crust.

Moriwaki, R.↗
NASA NTRS1985

Anomalous abundances of solar energetic particles and coronal gas: Coulomb effects and First Ionization Potential (FIP) ordering

The first ionization potential (FIP) ordering of elemental abundances in solar energetic particles and in the corona which can both be explained Coulomb effects is discussed. Solar energetic particles (SEP) and coronal gas have anomalous abundances relative to the photosphere. The anomalies are similar in both cases: which led to the conclusion that SEP acceleration is not selective, but merely preserves the source abundances. It is argued that SEP acceleration can be selective, because identical selectivity operates to determine the coronal abundances. The abundance anomalies are ordered by first ionization potential (FIP).

Mullan, D. J.↗
NASA NTRS2012

Interstellar Abundances Toward X Per, Revisited

The nearby X-ray binary X Per (HD 24534) provides a useful beacon with which to measure elemental abundances in the local ISM. We examine absorption features of O, Mg, and Si along this line of sight using spectra from the Chandra Observatory's LETG/ACIS-S and XMM-Newton's RGS instruments. In general, we find that the abundances and their ratios are similar to those of young F and G stars and the most recent solar values. We compare our results with abundances required by dust grain models.

Valencic, Lynne A.↗
NASA NTRS2014

Interstellar Abundances Toward X Per, Revisited

The nearby X-ray binary X Per (HD 24534) provides a useful beacon with which to measure elemental abundances in the local ISM. We examine absorption features of 0, Mg, and Si along this line of sight using spectra from the Chandra Observatory's LETG/ ACIS-S and XMM-Newton's RGS instruments. In general, we find that the abundances and their ratios are similar to those of young F and G stars and the most recent solar values. We compare our results with abundances required by dust grain models.

XPer↗
NASA NTRS1986

Abundances in cosmic rays

Elemental, isotopic, and antiproton abundances in cosmic ray sources are examined. The elemental abundances for very rare elements with atomic numbers (Z) greater than 30, for individual elements with Z less than 33, and for even-Z elements with Z less than 60 are compared with elemental abundances in the solar system. The effects of nucleosynthesis of the material and the cosmic ray acceleration process on the abundances of elements is discussed. It is observed that the cosmic ray sources differ in composition from the solar system; however, the abundances are generally the same. The observations of the cosmic ray antiprotons are described.

Israel, M. H.↗