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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Effect of fuel nitrogen and hydrogen content on emissions in hydrocarbon combustion

The results of an investigation of the effect of operating conditions and fuel properties on emission for the two-stage combustion of fuels with significant organic nitrogen content are presented. The way in which the emissions of nitrogen oxides and carbon monoxide are affected by the decreased hydrogen content and the increased organic nitrogen content of coal-derived fuels is discussed. Limited measurements of smoke from the rich-lean combustion of simulated syncrude fuels indicate relatively high smoke emissions in spite of the very lean second-stage burning. This fact, together with the high observed carbon monoxide emissions, suggests that trade-offs will be necessary between the conditions that minimize NOx and those that control CO and smoke emissions.

Bittker, D. A.↗
NASA NTRS1994

Ignition and combustion characteristics of metallized propellants, phase 2

Experimental and analytical investigations focusing on aluminum/hydrocarbon gel droplet secondary atomization and its effects on gel-fueled rocket engine performance are being conducted. A single laser sheet sizing/velocimetry diagnostic technique, which should eliminate sizing bias in the data collection process, has been designed and constructed to overcome limitations of the two-color forward-scatter technique used in previous work. Calibration of this system is in progress and the data acquisition/validation code is being written. Narrow-band measurements of radiant emission, discussed in previous reports, will be used to determine if aluminum ignition has occurred in a gel droplet. A one-dimensional model of a gel-fueled rocket combustion chamber, described in earlier reports, has been exercised in conjunction with a two-dimensional, two-phase nozzle code to predict the performance of an aluminum/hydrocarbon fueled engine. Estimated secondary atomization effects on propellant burnout distance, condensed particle radiation losses to the chamber walls, and nozzle two phase flow losses are also investigated. Calculations indicate that only modest secondary atomization is required to significantly reduce propellant burnout distances, aluminum oxide residual size, and radiation heat losses. Radiation losses equal to approximately 2-13 percent of the energy released during combustion were estimated, depending on secondary atomization intensity. A two-dimensional, two-phase nozzle code was employed to estimate radiation and nozzle two phase flow effects on overall engine performance. Radiation losses yielded a one percent decrease in engine Isp. Results also indicate that secondary atomization may have less effect on two-phase losses than it does on propellant burnout distance and no effect if oxide particle coagulation and shear induced droplet breakup govern oxide particle size. Engine Isp was found to decrease from 337.4 to 293.7 seconds as gel aluminum mass loading was varied from 0-70 wt percent. Engine Isp efficiencies, accounting for radiation and two phase flow effects, on the order of 0.946 were calculated for a 60 wt percent gel, assuming a fragmentation ratio of five.

Mueller, D. C.↗
NASA NTRS1972

Performance of a swirl-can combustor at idle conditions

Test results of a full annulus swirl-can combustor operated at simulated engine idle conditions indicated that significant improvements in combustion efficiency and accompanying reductions in pollutants could be realized with radial scheduling of fuel. Test conditions were an inlet air temperature of 478 K, a pressure of 4 atmospheres, and a reference velocity of 26 meters per second. At a fuel-air ratio of 0.008, radial scheduling of fuel increased combustion efficiency from less than 50 percent with no scheduling to nearly 100 percent and produced emission index values of unburned hydrocarbons and carbon monoxide of 10 and 40, respectively.

Niedzwiecki, R. W.↗
NASA NTRS1987

Combustion rate limits of hydrogen plus hydrocarbon fuel: Air diffusion flames from an opposed jet burner technique

Combustion of H2/hydrocarbon (HC) fuel mixtures may be considered in certain volume-limited supersonic airbreathing propulsion applications. Effects of HC addition to H2 were evaluated, using a recent argon-bathed, coaxial, tubular opposed jet burner (OJB) technique to measure the extinction limits of counterflow diffusion flames. The OJB flames were formed by a laminar jet of (N2 and/or HC)-diluted H2 mixture opposed by a similar jet of air at ambient conditions. The OJB data, derived from respective binary mixtures of H2 and methane, ethylene, or propane HCs, were used to characterize BLOWOFF and RESTORE. BLOWOFF is a sudden breaking of the dish-shaped OJB flame to a stable torus or ring shape, and RESTORE marks sudden restoration of the central flame by radial inward flame propagation. BLOWOFF is a measure of kinetically-limited flame reactivity/speed under highly stretched, but relatively ideal impingement flow conditions. RESTORE measures inward radial flame propagation rate, which is sensitive to ignition processes in the cool central core. It is concluded that relatively small molar amounts of added HC greatly reduce the reactivity characteristics of counterflow hydrogen-air diffusion flames, for ambient initial conditions.

Pellett, Gerald L.↗
NASA NTRS2014

Gaseous Non-Premixed Flame Research Planned for the International Space Station

Thus far, studies of gaseous diffusion flames on the International Space Station (ISS) have been limited to research conducted in the Microgravity Science Glovebox (MSG) in mid-2009 and early 2012. The research was performed with limited instrumentation, but novel techniques allowed for the determination of the soot temperature and volume fraction. Development is now underway for the next experiments of this type. The Advanced Combustion via Microgravity Experiments (ACME) project consists of five independent experiments that will be conducted with expanded instrumentation within the stations Combustion Integrated Rack (CIR). ACMEs goals are to improve our understanding of flame stability and extinction limits, soot control and reduction, oxygen-enriched combustion which could enable practical carbon sequestration, combustion at fuel lean conditions where both optimum performance and low emissions can be achieved, the use of electric fields for combustion control, and materials flammability. The microgravity environment provides longer residence times and larger length scales, yielding a broad range of flame conditions which are beneficial for simplified analysis, e.g., of limit behaviour where chemical kinetics are important. The detailed design of the modular ACME hardware, e.g., with exchangeable burners, is nearing completion, and it is expected that on-orbit testing will begin in 2016.

microgravity↗
NASA NTRS1997

Enhancement of Mixing and Reaction in High-speed Combustor Flowfields

Research has been underway for a number of years, both in the United States and abroad, to develop advanced aerospace propulsion systems for use late in this century and beyond. One program is now underway at the NASA Langley Research Research has been underway for a number of years, both in the United States and abroad, to develop advanced aerospace propulsion systems for use late in this century and beyond. One program is now underway at the NASA Langley Research Center to develop a hydrogen-fueled supersonic combustion ramjet (scramjet) that is capable of propelling a vehicle at hypersonic speeds in the atmosphere. A part of that research has been directed toward the optimization of the scramjet combustor and, in particular, the efficiency of fuel-air mixing and reaction taking place in the engine. In the high-speed vehicle configurations currently being considered, achieving a high combustor efficiency becomes particularly difficult. With increasing combustor Mach number, the degree of fuel-air mixing that can be achieved through natural convective and diffusive processes is reduced leading to an overall decrease in combustion efficiency and thrust. Compressible shear layers and jets provide a good model for studying the physical processes occurring in high speed mixing and combustion in a scramjet. Mixing layers are characterized by large scale eddies that form due to the high shear that is present between the fuel and the air streams. These eddies entrain the fuel and air into the mixing region between the fluids leading to increased surface area and locally steep concentration gradients. Molecular diffusion then occurs across the strained interfaces. In an early study of high-speed mixing, Brown and Roshko show that the spreading rate of a supersonic mixing layer decreases with increasing Mach number, exhibiting a factor of three decrease in spread rate as compared with an incompressible mixing layer with the same density ratio. They conclude that the reduced spread rate is primarily due to compressibility. Papamoschou and Roshko also observe that the spreading rate of compressible mixing layers is significantly reduced over that of incompressible layers. To characterize the structure of the flow quantitatively, they define a convective Mach number. The reduction in mixing layer spreading rate is shown in these experiments to correlate well with increasing convective Mach number.

Drummond, J. Philip↗
NASA NTRS1995

Fundamental phenomena on fuel decomposition and boundary-layer combustion processes with applications to hybrid rocket motors

The experimental study on the fundamental processes involved in fuel decomposition and boundary-layer combustion in hybrid rocket motors is continuously being conducted at the High Pressure Combustion Laboratory of The Pennsylvania State University. This research will provide a useful engineering technology base in the development of hybrid rocket motors as well as a fundamental understanding of the complex processes involved in hybrid propulsion. A high-pressure, 2-D slab motor has been designed, manufactured, and utilized for conducting seven test firings using HTPB fuel processed at PSU. A total of 20 fuel slabs have been received from the Mcdonnell Douglas Aerospace Corporation. Ten of these fuel slabs contain an array of fine-wire thermocouples for measuring solid fuel surface and subsurface temperatures. Diagnostic instrumentation used in the test include high-frequency pressure transducers for measuring static and dynamic motor pressures and fine-wire thermocouples for measuring solid fuel surface and subsurface temperatures. The ultrasonic pulse-echo technique as well as a real-time x-ray radiography system have been used to obtain independent measurements of instantaneous solid fuel regression rates.

Kuo, Kenneth K.↗
NASA NTRS1973

Thermodynamic and transport properties of air and its products of combustion with ASTMA-A-1 fuel and natural gas at 20, 30, and 40 atmospheres

The isentropic exponent, molecular weight, viscosity, specific heat at constant pressure, thermal conductivity, Prandtl number, and enthalpy were calculated for air, the combustion products of ASTM-A-1 jet fuel and air, and the combustion products of natural gas and air. The properties were calculated over a temperature range from 300 to 2800 K in 100 K increments and for pressures of 20, 30 and 40 atmospheres. The data for natural gas and ASTM-A-1 were calculated for fuel-air ratios from zero to stoichiometric in 0.01 increments.

Poferl, D. J.↗
NASA NTRS1984

Combustion gas properties of various fuels of interest to gas turbine engineers

A series of computations were made using the gas property computational schemes of Gordon and McBride to compute the gas properties and species concentration of ASTM-Jet A and dry air. The computed gas thermodynamic properties in a revised graphical format which gives information which is useful to combustion engineers is presented. A series of reports covering the properties of many fuel and air combinations will be published. The graphical presentation displays on one chart of the output of hundreds of computer sheets. The reports will contain microfiche cards, from which complete tables and graphs can be obtained. The extent of the planned effort and is documented samples of the many tables and charts that will be available on the microfiche cards are presented.

Jones, R. E.↗
NASA NTRS1976

Effect of inlet temperature and pressure on emissions from a premixing gas turbine primary zone combustor

Experiments were conducted to determine the performance of a premixing prevaporizing gas turbine primary zone combustor design over a range of combustor inlet temperatures from 700 to 1000 K and a range of inlet pressures from 40 to 240 N/sq cm. The 1 meter long combustor could be operated at pressures up to and including 120 N/sq cm without autoignition in the premixing duct or flashback from the stabilized combustion zone. Autoignition occurred in the mixer tube at the 240 N/sq cm pressure level with an entrance temperature of 830 K and a mixer residence time of 4 msec. Measured NOx level, combustion inefficiency, and hydrocarbon emission index correlated well with adiabatic flame temperature. The NOx levels varied from approximately 0.2 to 2.0 g NO2/kg fuel at combustion inefficiencies from 4 to 0.04 percent, depending upon adiabatic flame temperature and pressure. Measured NOx levels were sensitive to pressure. Tests were made at equivalence ratios ranging from 0.35 to 0.65. The overall total pressure drop for the configuration varied slightly with reference velocity and equivalence ratio, but never exceeded 3 percent.

Roffe, G.↗
NASA NTRS1984

Heat pipes to reduce engine exhaust emissions

A fuel combustor is presented that consists of an elongated casing with an air inlet conduit portion at one end, and having an opposite exit end. An elongated heat pipe is mounted longitudinally in the casing and is offset from and extends alongside the combustion space. The heat pipe is in heat transmitting relationship with the air intake conduit for heating incoming air. A guide conduit structure is provided for conveying the heated air from the intake conduit into the combustion space. A fuel discharge nozzle is provided to inject fuel into the combustion space. A fuel conduit from a fuel supply source has a portion engaged in heat transfer relationship of the heat pipe for preheating the fuel. The downstream end of the heat pipe is in heat transfer relationship with the casing and is located adjacent to the downstream end of the combustion space. The offset position of the heat pipe relative to the combustion space minimizes the quenching effect of the heat pipe on the gaseous products of combustion, as well as reducing coking of the fuel on the heat pipe, thereby improving the efficiency of the combustor.

Schultz, D. F.↗
NASA NTRS2005

Review of HxPyOz-Catalyzed H + OH Recombination in Scramjet Nozzle Expansions; and Possible Phosphoric Acid Enhancement of Scramjet Flameholding, from Extinction of H3PO4 + H2 - Air Counterflow Diffusion Flames

Recent detailed articles by Twarowski indicate that small quantities of phosphorus oxides and acids in the fuel-rich combustion products of H2 + phosphine (PH3) + air should significantly catalyze H, OH and O recombination kinetics during high-speed nozzle expansions -- to reform H2O, release heat, and approach equilibrium more rapidly and closely than uncatalyzed kinetics. This paper is an initial feasibility study to determine (a) if addition of phosphoric acid vapor (H3PO4) to a H2 fuel jet -- which is much safer than using PH3 -- will allow combustion in a high-speed scramjet engine test without adverse effects on localized flameholding, and (b) if phosphorus-containing exhaust emissions are environmentally acceptable. A well-characterized axisymmetric straight-tube opposed jet burner (OJB) tool is used to evaluate H3PO4 addition effects on the air velocity extinction limit (flame strength) of a H2 versus air counterflow diffusion flame. Addition of nitric oxide (NO), also believed to promote catalytic H-atom recombination, was evaluated for comparison. Two to five mass percent H3PO4 in the H2 jet increased flame strength 4.2%, whereas airside addition decreased it 1%. Adding 5% NO to the H2 caused a 2% decrease. Products of H-atom attack on H3PO4 produced an intense green chemiluminescence near the stagnation point. The resultant exothermic production of phosphorus oxides and acids, with accelerated H-atom recombination, released sufficient heat near the stagnation point to increase flame strength. In conclusion, the addition of H3PO4 vapor (or more reactive P sources) to hydrogen in scramjet engine tests may positively affect flameholding stability in the combustor and thrust production during supersonic expansion -- a possible dual benefit with system design / performance implications. Finally, a preliminary assessment of possible environmental effects indicates that scramjet exhaust emissions should consist of phosphoric acid aerosol, with gradual conversion to phosphate aerosol. This is compared to various natural abundances and sources.

Pellett, Gerald↗
NASA NTRS1929

Effect of oxygen on the ignition of liquid fuels

The ignition temperature, ignition lag, and ignition strength of simple and homogeneous fuels in combustion air of small oxygen content differ from what they are in air of greater oxygen content. In the case of small oxygen content, these fuels behave as if mixed unevenly. In the case of air with a definite oxygen content, the simple fuels have two ignition points, between which ignition takes place within a certain temperature range. The phenomena are explained by pyrogenous decomposition, comparison of the individual heat quantities, and the effect of the walls.

IGNITION - EFFECT OF OXYGEN↗