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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21

Evaluation of Low-Gravity Smoke Particulate for Spacecraft Fire Detection

Tests were conducted on the International Space Station to evaluate the smoke particulate size from materials and conditions that are typical of those expected in spacecraft fires. Five different materials representative of those found in spacecraft (Teflon, Kapton, cotton, silicone rubber and Pyrell) were heated to temperatures below the ignition point with conditions controlled to provide repeatable sample surface temperatures and air flow. The air flow past the sample during the heating period ranged from quiescent to 8 cm/s. The effective transport time to the measurement instruments was varied from 11 to 800 seconds to simulate different smoke transport conditions in spacecraft. The resultant aerosol was evaluated by three instruments which measured different moments of the particle size distribution. These moment diagnostics were used to determine the particle number concentration (zeroth moment), the diameter concentration (first moment), and the mass concentration (third moment). These statistics were combined to determine the diameter of average mass and the count mean diameter and by assuming a log-normal distribution, the geometric mean diameter and the geometric standard deviations were also calculated. Smoke particle samples were collected on TEM grids using a thermal precipitator for post flight analysis. The TEM grids were analyzed to determine the particle morphology and shape parameters. The different materials produced particles with significantly different morphologies. Overall the majority of the average smoke particle sizes were found to be in the 200 to 400 nanometer range with the quiescent cases and the cases with increased transport time typically producing with substantially larger particles. The results varied between materials but the smoke particles produced in low gravity were typically twice the size of particles produced in normal gravity. These results can be used to establish design requirements for future spacecraft smoke detectors.

Fire↗

Materials Combustion Testing and Combustion Product Sensor Evaluations in FY12

NASA Centers continue to collaborate to characterize the chemical species and smoke particles generated by the combustion of current space-rated non-metallic materials including fluoropolymers. This paper describes the results of tests conducted February through September 2012 to identify optimal chemical markers both for augmenting particle-based fire detection methods and for monitoring the post-fire cleanup phase in human spacecraft. These studies follow up on testing conducted in August 2010 and reported at ICES 2011. The tests were conducted at the NASA White Sands Test Facility in a custom glove box designed for burning fractional gram quantities of materials under varying heating profiles. The 623 L chamber was heavily instrumented to quantify organics (gas chromatography/mass spectrometry), inorganics by water extraction followed by ion chromatography, and select species by various individual commercially-available sensors. Evaluating new technologies for measuring carbon monoxide, hydrogen cyanide, hydrogen fluoride, hydrogen chloride and other species of interest was a key objective of the test. Some of these sensors were located inside the glovebox near the fire source to avoid losses through the sampling lines; the rest were located just outside the glovebox. Instruments for smoke particle characterization included a Tapered Element Oscillating Microbalance Personal Dust Monitor (TEOM PDM) and a TSI Dust Trak DRX to measure particle mass concentration, a TSI PTrak for number concentration and a thermal precipitator for collection of particles for microscopic analysis. Materials studied included Nomex(R), M22759 wire insulation, granulated circuit board, polyvinyl chloride (PVC), Polytetrafluoroethylene (PTFE), Kapton(R), and mixtures of PTFE and Kapton(R). Furnace temperatures ranged from 340 to 640 C, focusing on the smoldering regime. Of particular interest in these tests was confirming burn repeatability and production of acid gases with different fuel mixture compositions, as well as the dependence of aerosol concentrations on temperature.

Combustion↗

Opposed Flame Spreading Along a Structured PMMA Sample in Exploration Atmosphere Under Microgravity

As part of SAFFIRE V experiments on the ISS supply spacecraft CYGNUS, flame propagation along different surface structures on a PMMA sample was investigated in opposed flow. The sample was 200 x 400 mm (length x width) with a thickness of 10 mm and contained ribs of different widths (1-10 mm), each 3 mm high, on both sides, arranged in the flow direction. The total thickness of the specimen was thus 16 mm for the ribs. For the first 360 s after ignition with a Kanthal wire, the flow velocity was 20 cm/s in the opposed direction. Then the flow velocity was reduced to 5 cm/s for a duration of 300 s before it was switched off to terminate the experiment. The experimental pressure was 761 hPa and the oxygen concentration was 26.9 vol %. These conditions correspond to atmospheric conditions envisioned for future exploration missions. It was found that the flames ignited downstream propagated forward along the rib edges surprisingly fast with up to 0.88 mm/s (1 mm rib width). Also, it was observed that the wider the rib, the slower the propagation. The widest rib (10 mm) already showed two largely independent edge flames. Unintentionally, the experiment showed how sensitive the flames are to small perturbations of the flow field, as remnants of a preceding and upstream experiment disturbed the incoming flow stratification partially.

microgravity↗

Opposed flame spreading along a structured PMMA-sample in exploration atmosphere under microgravity

As part of SAFFIRE V experiments on the ISS supply spacecraft CYGNUS, flame propagation along different surface structures on a PMMA sample was investigated in opposed flow. The sample was 200 x 400 mm (length x width) with a thickness of 10 mm and contained ribs of different widths (1-10 mm), each 3 mm high, on both sides, arranged in the flow direction. The total thickness of the specimen was thus 16 mm for the ribs. For the first 360 s after ignition with a Kanthal wire, the flow velocity was 20 cm/s in the opposed direction. Then the flow velocity was reduced to 5 cm/s for a duration of 300 s before it was switched off to terminate the experiment. The experimental pressure was 761 hPa and the oxygen concentration was 26.9 vol %. These conditions correspond to atmospheric conditions envisioned for future exploration missions. It was found that the flames ignited downstream propagated forward along the rib edges surprisingly fast with up to 0.88 mm/s (1 mm rib width). Also, it was observed that the wider the rib, the slower the propagation. The widest rib (10 mm) already showed two largely independent edge flames. Unintentionally, the experiment showed how sensitive the flames are to small perturbations of the flow field, as remnants of a preceding and upstream experiment disturbed the incoming flow stratification partially.

fire safety↗

Vehicle Modeling During the Burning of Thermally Thick Samples in the Saffire V Experiments

In order to design a safer spacecraft in terms of fire prevention, detection and cleanup, the transport of combustion products and heat must be predicted. Large-scale fire data was provided by the Saffire payload within Northrup Grumman’s Cygnus vehicle after a resupply mission to the ISS. Solid materials, including thick thermoplastic samples were ignited to study flame spread and the effect a fire has on a vehicle. Sensors that measured species and temperature were placed within Cygnus. A model using Pyrosim was developed to predict the thick fuel burn events from Saffire V by using sensor data from Cygnus. The heat transfer coefficient between the cabin air and cargo was previously calibrated using the cotton fuel burn event, and provided a good prediction of the temperature response within the vehicle during the two thick fuel experiments. The difference between the Saffire inlet CO 2 sensor, and the forward port standoff CO 2 sensor, which is the closest to the Saffire outlet, was used as an input into the model. This method provided an excellent prediction of the CO 2 response in the other parts of the Cygnus.

fire safety↗

Compartment Fire Modeling of a Crew Cabin in 1-g and Lunar-g

A fire inside a spacecraft poses one of the greatest dangers to the crew and mission success. As missions become more complex and longer in duration, the risk of a fire becomes more probable and catastrophic. A greater understanding of the effects of a fire inside a crewed vehicle at potential exploration atmospheres is needed. These exploration atmospheres, such as those being proposed for upcoming Lunar missions, include higher oxygen concentrations and lower pressures, also known as Normoxic conditions. Full scale fire testing, such as those performed during previous space programs, is the most straightforward way to obtain this understanding. These tests are difficult to implement in 1-g and even more challenging to attempt in Lunar-g. Modeling can help inform experiments aimed at determining flammability properties of common materials at exploration atmospheres, as well as determine the effect a fire has inside a spacecraft. A model can also be easily simulated in Lunar-g to predict the effect of gravity on fire propagation. This work focuses on a model of a theoretical partial crew cabin, with potential fire sources being a laptop and a Nomex sleeping bag. A simulation of the crew cabin during a high Heat Release Rate (HRR) fire and low HRR fire at 1-g was compared to simulations at Lunar-g. It was found that in both the low and high HRR cases, the temperature in the cabin was higher in the Lunar-g case than in the 1-g case. This is likely due to the hot products moving out the door of the crew cabin faster in the 1-g case. Modeling case studies like these will help guide future full-scale flammability experiments on Earth and allow for the prediction of fire spread in a Lunar gravity environment in order to design a safer crew cabin.

Fire Safety↗

Foam composite structures

The need to include fire resistant foams into state of the art aircraft interior paneling to increase passenger safety in aircraft fires was studied. Present efforts were directed toward mechanical and fire testing of panels with foam inclusions. Skinned foam filled honeycomb and PBI structural foams were the two constructions investigated with attention being directed toward weight/performance/cost trade-off. All of the new panels demonstrated improved performance in fire and some were lighter weight but not as strong as the presently used paneling. Continued efforts should result in improved paneling for passenger safety. In particular the simple partial filling (fire side) of state-of-the-art honeycomb with fire resistant foams with little sacrifice in weight would result in panels with increased fire resistance. More important may be the retarded rate of toxic gas evolution in the fire due to the protection of the honeycomb by the foam.

Delano, C. B.↗

Defining the State of Safety (SOS) for Lithium-Ion Batteries in EVs: A Discussion

The demand for lithium-ion batteries (LIBs) is skyrocketing, driven by the rapid growth of electric vehicles (EVs) and grid energy storage. However, current LIBs rely on flammable electrolytes, making them susceptible to thermal runaway and fires. Despite ongoing research and development efforts to enhance safety, fire incidents in EVs and energy storage systems persist. As LIB deployment increases, so too does the risk of fires. Therefore, it's crucial to define a "State of Safety" for LIBs - encompassing both operational safety and post-incident safety, such as after a car accident. This concept can help stakeholder and first responders to effectively manage LIB fire risks.

25 ENERGY STORAGE↗

Chemistry laboratory safety manual available

Chemistry laboratory safety manual outlines safe practices for handling hazardous chemicals and chemistry laboratory equipment. Included are discussions of chemical hazards relating to fire, health, explosion, safety equipment and procedures for certain laboratory techniques and manipulations involving glassware, vacuum equipment, acids, bases, and volatile solvents.

Elsbrock, R. G.↗