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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21

Metal-Supported Ceria Electrolyte-based SOFC Stack for Scalable, Low-Cost, High-Efficiency and Robust Stationary Power Systems (Final Report)

This is the end of project report for the DOE Project DE-FE-0027844 “Metal-Supported Ceria Electrolyte-based SOFC Stack for Scalable, Low-Cost, High-Efficiency and Robust Stationary Power Systems”. The objectives of the project were to develop several technologies required for the mass adoption of Solid Oxide Fuel Cell systems for medium to large power generation applications. The key achievements of this project were: 1) Development of fuel cells with complete internal fuel reforming capability. 2) Fuel cell power scale up with production of cells with larger active areas. 3) Assembly of an integrated 5 kW modular stack platform capable of installation into medium to large power systems. 4) Demonstration of a 10 kW Fuel Cell Power System utilizing the integrated 5 kW modular stack platform. 5) Cost modelling to show system cost of $1,500/kW are achievable at production volumes. 6) Development of cathode air poison getters for reduced degradation and extended fuel cell life. 7) Assessment of fuel poison on anode degradation, particularly poisons frequently produced from the process of gasification of coal. The Cummins led Voice of Customer (VOC) work identified several significant markets for natural gas powered fuel cell systems, where the end customer is interested in reducing energy consumption and emissions, or increasing reliability of electrical supply. Data centers and truck Auxiliary Power Units (APU) were highlighted as 2 key future markets for fuel cell systems.

30 DIRECT ENERGY CONVERSION↗

Improved Zirconia Oxygen-Separation Cell

Cell structure distributes feed gas more evenly for more efficent oxygen production. Multilayer cell structure containing passages, channels, tubes, and pores help distribute pressure evenly over zirconia electrolytic membrane. Resulting more uniform pressure distribution expected to improve efficiency of oxygen production.

Walsh, John V.↗

Nondestructive Visualization of Defects and Crack Propagation of Shuttle-Foam

Shuttle insulating foam is a low-density closed-cell solid-gas composite. A chief barrier to understanding foam loss has been extreme difficulties in nondestructively visualizing defects of the foam that is almost transparent to x-rays. Here we show that defects, crack propagation, and cell structure can be clearly and nondestructively observed by turning the density inhomogeneity across foam structures into a source for phase contrast imaging. This provides a new powerful way to help understand foam loss.

Hu, Zheng-Wei↗

Investigating Liquid Water Transport in Different Pore Structure of Gas Diffusion Layers for PEMFC Using Lattice Boltzmann Method

Proton exchange membrane fuel cells (PEMFC) require a gas diffusion layer (GDL) to aid in the transport of liquid fuel to the catalyst layer. In this work, direct modeling using the Lattice Boltzmann Method (LBM) was applied to X-ray CT scans of four different carbon gas diffusion layers to understand the mass transport properties through the samples. Three injection orientations were used to study local saturation levels, water evolution through the sample, and mass transport behavior at breakthrough conditions. The LBM, combined with computational fluid dynamic modeling techniques, can accurately predict liquid saturation at the macro and micro scale, which provides more insight into the mass transport phenomena through the GDL. The change of pore structure and orientation in both the in-plane and through-plane determines the path that liquid water must take, which could aid or impact PEMFC performance. The outcomes from this work will also benefit any research that needs knowledge of internal mass transport qualities of gas diffusion media.

Sepe, M.↗

Faradaic efficiency in protonic-ceramic electrolysis cells

Abstract Proton-conducting ceramics (e.g. doped barium zirconates or cerates) are typically mixed ionic-electronic conductors (MIECs). The electronic conduction, typically in the form of positively charged small polarons or electron holes, leads to ‘electronic leakage.’ In an ideal steam-electrolysis cell, one gas-phase H 2 molecule is produced from every two electrons delivered from an external power source. In other words, such ideal behavior achieves 100% faradaic efficiency. However, the electronic flux associated with MIEC membranes contributes to reduced faradaic efficiency. The present paper develops a model that predicts the behavior of faradaic efficiency as a function of electrolysis-cell operating conditions. Although the model framework is more general, the paper focuses on the behavior of a cell based upon a BaCe 0.7 Zr 0.1 Y 0.1 Yb 0.1 O 3 − δ (BCZYYb) membrane. The study predicts the effects of operating conditions, including temperature, pressure, and gas compositions.

Zhu, Huayang↗

Modeling of a Solid Oxide Fuel Cell as Part of a Predictive Functional Model for Aerospace Fuel-Cell Systems

This paper will discuss initial efforts at modeling a solid oxide fuel cell (SOFC) for aerospace applications. Fuel cells historically have been used in spacecraft from the Gemini to the Shuttle era for providing spacecraft power with the added benefit of producing water for crew use. However, there are many potential applications for fuel cells and electrolyzers in spaceflight, including oxygen generation, in-situ resource utilization (ISRU) and propellant production. This proof-of-concept model has been developed using a commercial multiphysics modeling software package. Two-dimensional and one-dimensional isothermal models were created based on a certain SOFC design and results were compared to test data from the real system. Local Butler-Volmer kinetic relations were adjusted, and an effective porous medium approach was taken in order to capture how the many interconnects between cells in the gas channels affected fluid flow. The model was able to reproduce polarization curves derived from test data within around 0.02 Volts for a given current density. This model could be adapted to model a solid oxide electrolyzer, proton exchange membrane fuel cell, or other type of fuel cell technology in order to understand how these types of technologies could fit into broader spacecraft designs and advance the capabilities of spaceflight systems.

Mary Lou Nadeau↗

Modeling of a Solid Oxide Fuel Cell as Part of a Predictive Functional Model for Aerospace Fuel-Cell Systems

This paper will discuss initial efforts at modeling a solid oxide fuel cell (SOFC) for aerospace applications. Fuel cells historically have been used in spacecraft from the Gemini to the Shuttle era for providing spacecraft power with the added benefit of producing water for crew use. However, there are many potential applications for fuel cells and electrolyzers in spaceflight, including oxygen generation, in-situ resource utilization (ISRU) and propellant production. This proof-of-concept model has been developed using a commercial multiphysics modeling software package. Two-dimensional and one-dimensional isothermal models were created based on a certain SOFC design and results were compared to test data from the real system. Local Butler-Volmer kinetic relations were adjusted, and an effective porous medium approach was taken in order to capture how the many interconnects between cells in the gas channels affected fluid flow. The model was able to reproduce polarization curves derived from test data within around 0.02 Volts for a given current density. This model could be adapted to model a solid oxide electrolyzer, proton exchange membrane fuel cell, or other type of fuel cell technology in order to understand how these types of technologies could fit into broader spacecraft designs and advance the capabilities of spaceflight systems.

Mary Lou Nadeau↗

Modeling of a Solid Oxide Fuel Cell as Part of a Predictive Functional Model for Aerospace Fuel-Cell Systems

This paper will discuss initial efforts at modeling a solid oxide fuel cell (SOFC) for aerospace applications. Fuel cells historically have been used in spacecraft from the Gemini to the Shuttle era for providing spacecraft power with the added benefit of producing water for crew use. However, there are many potential applications for fuel cells and electrolyzers in spaceflight, including oxygen generation, in-situ resource utilization (ISRU) and propellant production. This proof-of-concept model has been developed using a commercial multiphysics modeling software package. Two-dimensional and one-dimensional isothermal models were created based on a certain SOFC design and results were compared to test data from the real system. Local Butler-Volmer kinetic relations were adjusted, and an effective porous medium approach was taken in order to capture how the many interconnects between cells in the gas channels affected fluid flow. The model was able to reproduce polarization curves derived from test data within around 0.02 Volts for a given current density. This model could be adapted to model a solid oxide electrolyzer, proton exchange membrane fuel cell, or other type of fuel cell technology in order to understand how these types of technologies could fit into broader spacecraft designs and advance the capabilities of spaceflight systems.

Mary Lou Nadeau↗

Modeling of a Solid Oxide Fuel Cell as Part of a Predictive Functional Model for Aerospace Fuel-Cell Systems

This paper will discuss initial efforts at modeling a solid oxide fuel cell (SOFC) for aerospace applications. Fuel cells historically have been used in spacecraft from the Gemini to the Shuttle era for providing spacecraft power with the added benefit of producing water for crew use. However, there are many potential applications for fuel cells and electrolyzers in spaceflight, including oxygen generation, in-situ resource utilization (ISRU) and propellant production. This proof-of-concept model has been developed using a commercial multiphysics modeling software package. Two-dimensional and one-dimensional isothermal models were created based on a certain SOFC design and results were compared to test data from the real system. Local Butler-Volmer kinetic relations were adjusted, and an effective porous medium approach was taken in order to capture how the many interconnects between cells in the gas channels affected fluid flow. The model was able to reproduce polarization curves derived from test data within around 0.02 Volts for a given current density. This model could be adapted to model a solid oxide electrolyzer, proton exchange membrane fuel cell, or other type of fuel cell technology in order to understand how these types of technologies could fit into broader spacecraft designs and advance the capabilities of spaceflight systems.

Mary Lou Nadeau↗

Device removes hydrogen gas from enclosed spaces

Hydrogen-oxidant galvanic cell removes small amounts of hydrogen gas continually released from equipment, such as vented silver-zinc batteries, in enclosed compartments where air venting is not feasible. These cells are used in satellite compartments.

Carson, W. N.↗

Applications study of advanced power generation systems utilizing coal-derived fuels, volume 2

Technology readiness and development trends are discussed for three advanced power generation systems: combined cycle gas turbine, fuel cells, and magnetohydrodynamics. Power plants using these technologies are described and their performance either utilizing a medium-Btu coal derived fuel supplied by pipeline from a large central coal gasification facility or integrated with a gasification facility for supplying medium-Btu fuel gas is assessed.

Robson, F. L.↗

Circular Reprocessing of Thermoset Polyurethane Foams

Thermoset polyurethane (PU) foams are widely used in industrial applications, but they cannot be recycled by conventional melt reprocessing because of their cross-linked structures. The introduction of carbamate exchange catalysts converts thermoset PU into covalent adaptable networks (CANs), which are amenable to reprocessing at elevated temperatures. However, this approach has produced solid PU films, which have fewer uses and lower commercial demand. In this work, simultaneous reprocessing and refoaming of thermoset PU foams is demonstrated by leveraging the melt-processability of PU CANs and allowing cell growth by gas generation in a twin-screw extruder. The optimal operating temperature of the refoaming process is determined through chemical, thermal, and structural analysis of PU foam extrudates. The foam-to-foam extrusion process produces controllable, continuous, and uniform foam structures, as characterized by cell diameter and cell number density. Low-density PU foams are obtained through a process simulating injection molding. The compression properties of reprocessed PU foam are compared with as-synthesized PU foam to demonstrate efficacy of the refoaming processes. These results demonstrate that PU foams can be prepared through recycling while maintaining microstructural and chemical integrity. In the future, this strategy may be applied to thermoset PU foams of various chemical compositions and shows promise for scalability.

36 MATERIALS SCIENCE↗

Design, Prototyping, and Testing of a Novel Flowpath with an Array of Six 3D Matrix Vitvo Bioreactors for the NASA Bioculture System

The NASA Bioculture System is an advanced cell culture closed-loop system containing highly automated flowpaths designed to conduct long term biology experiments on ISS with earth remote controllable medium flow, temperature, gas composition, medium exchange, cell sampling and fixation. This technology was already demonstrated with successful cardiomyocyte and osteocyte cultures experiments onboard the ISS and is now supporting NASA PI science. The Bioculture System, however, can only support 10 cassettes with disposable flowpaths, each containing a single hollow fiber bioreactor with a culture capacity of about 2ml. This constraint not only severely limits the number of investigators that can conduct experiments in space, but also subjects the experiments to limitations in the number of replicates and conditions that can be studied. To address these limitations, we sought a novel design solution to maximize the number of separate bioreactor cultures and volume that can be conducted simultaneously. To this end we designed, prototyped, and are now testing a six-Vitvo 3D Matrix 2ml bioreactor insert that replaces the conventional Bioculture System hollow fiber bioreactor. This design will allow the Bioculture System to support up to 60 different bioreactors and samples at once. Specifically, the novel gas-tight containment housing insert contains six COTS Rigenerand VITVO bioreactors stacked on each side of a heat sink powered by the existing heating element and pair of temperature sensors. Medium will be distributed into each bioreactor's cell-free chamber via its built-in Luer connector, then across the 3D matrix to the cell chamber, dissipating laminar flow and limiting fluid shear stresses that might mechanostimulate cell cultures. Gas (5% CO2 in air) will be supplied directly to the bioreactor gas-tight housing for exchange via the bioreactor flat-surface gas-permeable membranes, eliminating the need for the existing Bioculture System cassette oxygenator. If successfully implemented on ISS, this new multi-bioreactor insert for the Bioculture System has the potential to make real-time cell science experimentation in space more efficient and accessible to more investigators.

Ma, Kristin R.↗

Cellular thermosetting fluorodiepoxide polymers

Thermosetting fluoropolymer foams are made by mixing fluid form thermosetting fluoropolymer components having a substantial fluorine content, placing the mixture in a pressure tight chamber, filling the chamber with a gas, at relatively low pressure, that is unreactive with the fluoropolymer components, allowing the mixture to gel, removing the gelled fluoropolymer from the chamber and thereafter heating the fluoropolymer at a relatively low temperature to simultaneously sure and foam the fluoropolymer. The resulting fluoropolymer product is closed celled with the cells storing the gas employed for foaming. The fluoropolymer resins employed may be any thermosetting fluoropolymer including fluoroepoxies, fluoropolyurethanes and fluoroacrylates.

Lee, Sheng Y.↗