Search NASA⌕ Search

SEARCH · Search NASA

Results for “Glass crystallization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
NASA NTRS2009

Progress of the NASAUSGS Lunar Regolith Simulant Project

Beginning in 2004 personnel at MSFC began serious efforts to develop a new generation of lunar simulants. The first two products were a replication of the previous JSC-1 simulant under a contract to Orbitec and a major workshop in 2005 on future simulant development. It was recognized in early 2006 there were serious limitations with the standard approach of simply taking a single terrestrial rock and grinding it. To a geologist, even a cursory examination of the Lunar Sourcebook shows that matching lunar heterogeneity, crystal size, relative mineral abundances, lack of H2O, plagioclase chemistry and glass abundance simply can not be done with any simple combination of terrestrial rocks. Thus the project refocused its efforts and approached simulant development in a new and more comprehensive manner, examining new approaches in simulant development and ways to more accurately compare simulants to actual lunar materials. This led to a multi-year effort with five major tasks running in parallel. The five tasks are Requirements, Lunar Analysis, Process Development, Feed Stocks, and Standards.

Rickman, Douglas↗
NASA NTRS1976

Processing FeB03 glass-ceramics in space

The possibility of preparing FeBO3 glass-ceramic in space is explored. A transparent glass-ceramic of FeBO3, due to its unique properties could be an excellent material for magneto-optic applications which currently utilize high price materials such as single crystals of Ga-YIG. The unique magneto-optic properties of FeBO3 were found to come from glass-ceramic but not from the glass form. It was anticipated and later confirmed that the FeBO3 glass-ceramics could not be prepared on earth. Phase separation and iron valence reduction, were identified as the two terrestrial manufacturing obstacles. Since the phase separation problem could be overcome by space processing, the preparation of FeBO3 glass-ceramic in space appears attractive.

Li, C. T.↗
NASA NTRS2013

Environmental Qualification of a Single-Crystal Silicon Mirror for Spaceflight Use

This innovation is the environmental qualification of a single-crystal silicon mirror for spaceflight use. The single-crystal silicon mirror technology is a previous innovation, but until now, a mirror of this type has not been qualified for spaceflight use. The qualification steps included mounting, gravity change measurements, vibration testing, vibration- induced change measurements, thermal cycling, and testing at the cold operational temperature of 225 K. Typical mirrors used for cold applications for spaceflight instruments include aluminum, beryllium, glasses, and glass-like ceramics. These materials show less than ideal behavior after cooldown. Single-crystal silicon has been demonstrated to have the smallest change due to temperature change, but has not been spaceflight-qualified for use. The advantage of using a silicon substrate is with temperature stability, since it is formed from a stress-free single crystal. This has been shown in previous testing. Mounting and environmental qualification have not been shown until this testing.

Hagopian, John↗
NASA NTRS1998

Reliability Modeling of Brittle Anisotropic Materials

A significant effort is being made to develop testing and design methodologies that will account for the lack of ductility and the strength anisotropy exhibited by brittle single crystals such as NiAl. The present approach is to modify existing test methods and brittle design methodologies, such as those applied to ceramics and glasses, and to experimentally verify the results. This paper focuses on the basic materials properties and strength behavior of a NiAl single crystal alloy and the development of a reliability model for the design of components subjected to multiaxial stresses.

Conceivably↗
NASA NTRS1978

Petrographic and petrological studies of lunar rocks

Clasts, rind glass, matrix glass, and matrix minerals from five Apollo 15 glass-coated breccias (15255, 15286, 15465, 15466, and 15505) were studied optically and with the SEM/microprobe. Rind glass compositions differ from sample to sample, but are identical, or nearly so, to the local soil, suggesting their origin by fusion of that soil. Most breccia samples contain green or colorless glass spheres identical to the Apollo 15 green glasses. These glasses, along with other glass shards and fragments, indicate a large soil component is present in the breccias. Clast populations include basalts and gabbros containing phases highly enriched in iron, indicative of extreme differentiation or fractional crystallization. Impact melts, anorthosites, and minor amounts of ANT suite material are also present among the clasts. Tektite glasses, impact melts, and breccias from the Zhamanshin structure, USSR, were also studied. Basic tektite glasses were found to be identical in composition to impact melts from the structure, but no satisfactory parent material has been identified in the limited suite of samples available.

Winzer, S. R.↗
NASA NTRS1994

Experimental study of lunar and SNC (Mars) magmas

The overall objectives of this research were to evaluate the role of C-O-S-Cl degassing processes in explaining vesiculation, oxidation state and fire-fountaining of lunar magmas by analysis of individual lunar glass spherules, and by experimental determination of equilibrium abundances and diffusion rates of C, S and Cl melt species in lunar glass compositions; and to determine possible primitive SNC magma compositions and the mineralogy of the mantle from which they were derived, and to evaluate P, T, XH2O etc. conditions at which they crystallize to form the SNC meteorites. After funding for one year, a project on the A15 volcanic green glass has been completed to the point of writing a first manuscript. Carbon-oxygen species C-O and CO2 are below detection limits (20 ppm) in these glasses, but there is up to 500 ppm S with concentrations both increasing and decreasing toward the spherule margins. Calculations and modeling indicate that C species could have been present in the volcanic gases, however. In a second project, experiments with low PH2O have resulted in refined estimates of the early intercumulus melt composition in the Chassigny meteorite which is generally accepted as a sample from Mars.

Rutherford, Malcolm J.↗
NASA NTRS1985

The preparation and characterization of a lithium borate glass prepared by the gel technique

The preparation of an amorphous lithium borate gel by the metal organic procedure is described. In addition, a preliminary evaluation of the behavior of the gel upon heating is given. In particular the crystallization tendency of the gel is studied with the aid of DTA and X-ray diffraction, and the structural changes in the gel are monitored with the aid of IR spectroscopy. The glass produced from the lithium borate gel is compared to both the gel precursor material and a glass of similar composition prepared by conventional techniques. Specifically, the relevant water contents, crystallization behavior, and structural features are contrasted.

Weinberg, M. C.↗
NASA NTRS1977

Very low Ti /VLT/ basalts - A new mare rock type from the Apollo 17 drill core

Phaneritic fragments, vitrophyres, and glass beads of a new very low Ti (VLT) mare basalt are found in the Apollo 17 drill core. VLT lithic fragments are characterized by TiO2 content of approximately 0.5%, Mg/(Mg + Fe) of approximately 0.52, CaO/Al2O3 of approximately 0.9, and low alkali content. Although mineral systematics and modal composition of VLT basalt are similar to Apollo 12 and 15 low Ti basalts, VLT basalts cannot be related to these mare basalts by crystal fractionation. Since VLT basalt is isochemical with some of the less mafic green glasses, fractionation of VLT magma from a liquid of green-glass composition is a possibility. Spectral reflectance studies suggest that VLT-type basalts may be relatively common in mare basins.

Vaniman, D. T.↗
NASA NTRS2000

Thermal Stability of Otto Fuel Prepolymer

Otto Fuel II contains a nitrate ester, plasticizer, and 2-NPDA as a stabilizer. Otto Fuel with stabilizers from three vendors was investigated by dynamic and isothermal differential scanning calorimetry (DSC) using samples sealed in a glass ampoule and by Isothermal Microcalorimetry (IMC) using 10 gram samples aged at 75 C for 35 days. DSC kinetics did not show differences between the stabilizer; the samples had an activation energy of 36.7 +/- 0.6 kcal/mol. However, IMC analysis was sensitive enough to detect small differences between the stabilizer, namely energy of interaction values of 7 to 14 Joules. DSC controlled cooling and heating at 5 C/min from 30 to -60 to 40 C experiments were similar and showed a crystallization peak at -48 +/- 1 C during cooling, and upon heating there was a glass transition temperature step at approx. -54 +/- 0.5 C and a melting peak at -28 +/- 0.4 C.

Tompa, Albert S.↗
NASA NTRS2000

Thermal Stability of Otto Fuel Prepolymer

Otto Fuel II contains a nitrate ester, plasticizer, and 2-NDPA as a stabilizer. Otto Fuel with stabilizers from three vendors was investigated by dynamic and isothermal DSC using samples sealed in a glass ampoule and by Isothermal Microcalorimetry (IMC) using 10 gram samples aged at 75 C for 35 days. DSC kinetics did not show differences between the stabilizer; the samples had an activation energy of 36.7 +/- 0.6 kcal/mol. However, IMC analysis was sensitive enough to detect small differences between the stabilizer, namely energy of interaction values of 7 to 14 Joules. DSC controlled cooling and heating at 5 C/min from 30 to -60 to 40 C experiments were similar and showed a crystallization peak at -48 +/- 1 C during cooling, and upon heating there was a glass transition temperature step at approx. -54 +/- 0.5 C and a melting peak at -28 +/- 0.4 C.

Tompa, Albert S.↗
NASA NTRS1972

Stimulated parametric fluorescence induced by picosecond pump pulses.

Stimulated parametric fluorescence emission tunable over the range from 0.96 to 1.16 microns has been obtained using a barium sodium niobate crystal pumped by a frequency-doubled and mode-locked neodymium:glass laser. The pump radiation in the form of a train of picosecond pulses produced infrared parametric fluorescence pulses, less than 10 psec in duration and with average peak powers on the order of 300 W when pumped with a power density of 300 MW/sq cm.

Rabson, T. A.↗
NASA NTRS1977

Mare basalt petrogenesis

Melting experiments in vacuum at Fe-saturation for high-Ti lunar basalt compositions 70215 and 15318 Red Glass, and low-Ti basalt composition 15555-15016, have defined equilibrium crystallization sequences and the liquid lines of descent, and show that much of the chemical variety in the samples is due to near-surface fractionation processes. The various groups within the high-Ti suite, however, cannot be interrelated by such processes, nor can the high-Ti suite be a near-surface derivative of a low-Ti parent magma.

Kesson, S. E.↗
NASA NTRS1984

Origin of the Moon: In search of the holy grail

The Moon's origin could be deduced with certainty if its bulk chemistry were known. However, determination of this chemistry is difficult because of the profound and complex redistribution of elements that occurred in the outer portions of the Moon during crystallization of the magma ocean. The compositions of 23 varieties of volcanic glass, erupted from depths approaching 300 miles, were used to predict the chemistry of a special glass (genesis glass) having a direct link to primordial lunar matter. A sample of glass with the predicted composition was discovered. This allows a new estimate to be made of the Moon's bulk composition. The data indicate that the Moon shares some intriquing chemical similarities with the Earth's mantle. Both genesis glass and lunar gas are furnishing definitive data on the Moon's composition and origin.

Delano, J. W.↗
NASA NTRS1987

Refractory interplanetary dust particles

Criteria are described by which refractory interplanetary dust particles (IDPs) can be differentiated from the products of spacecraft debris. These criteria have been used to discover and characterize IDPs that are composed predominantly of refractory phases. Two of these particles contain hibonite, perovskite, spinel, refractory glass, and a melilite; only hibonite was identified within a third. The grain size for all particles ranges from 0.05 to 1 micrometer, so that they are much finer grained than the refractory calcium- and aluminum-rich inclusions in meteorites. The glass-containing refractory IDPs may be primitive nebular condensates that never completely crystallized and thus have been preserved extant.

Zolensky, Michael E.↗
NASA NTRS1992

Investigation of microgravity effects on solidification phenomena of selected materials

A Get Away Special (GAS) experiment payload to investigate microgravity effects on solidification phenomena of selected experimental samples has been designed for flight. It is intended that the first flight of the assembly will (1) study the p-n junction characteristics for advancing semiconductor device applications, (2) study the effects of gravity-driven convection on the growth of HgCd crystals, (3) compare the textures of the sample which crystallizes in microgravity with those found in chondrite meteorites, and (4) modify glass optical characteristics through divalent oxygen exchange. The space flight experiment consists of many small furnaces. While the experiment payload is in the low gravity environment of orbital flight, the payload controller will sequentially activate the furnaces to heat samples to their melt state and then allow cooling to resolidification in a controlled fashion. The materials processed in the microgravity environment of space will be compared to the same materials processed on earth in a one-gravity environment. This paper discusses the design of all subassemblies (furnance, electronics, and power systems) in the experiment. A complete description of the experimental materials is also presented.

Maag, Carl R.↗
NASA NTRS1992

Space Station Furnace Facility. Volume 1: Requirements definition and conceptual design study, executive summary

The Space Station Freedom Furnace (SSFF) Study was awarded on June 2, 1989, to Teledyne Brown Engineering (TBE) to define an advanced facility for materials research in the microgravity environment of Space Station Freedom (SSF). The SSFF will be designed for research in the solidification of metals and alloys, the crystal growth of electronic and electro-optical materials, and research in glasses and ceramics. The SSFF is one of the first 'facility' class payloads planned by the Microgravity Science and Applications Division (MSAD) of the Office of Space Science and Applications of NASA Headquarters. This facility is planned for early deployment during man-tended operations of the SSF with continuing operations through the Permanently Manned Configuration (PMC). The SSFF will be built around a general 'Core' facility which provides common support functions not provided by SSF, common subsystems which are best centralized, and common subsystems which are best distributed with each experiment module. The intent of the facility approach is to reduce the overall cost associated with implementing and operating a variety of experiments. This is achieved by reducing the launch mass and simplifying the hardware development and qualification processes associated with each experiment. The Core will remain on orbit and will require only periodic maintenance and upgrading while new Furnace Modules, samples, and consumables are developed, qualified, and transported to the SSF. The SSFF Study was divided into two phases: phase 1, a definition study phase, and phase 2, a design and development phase. The definition phase 1 is addressed. Phase 1 was divided into two parts. In the first part, the basic part of the effort, covered the preliminary definition and assessment of requirements; conceptual design of the SSFF; fabrication of mockups; and the preparation for and support of the Conceptual Design Review (CoDR). The second part, the option part, covered requirements update and documentation; refinement of the selected conceptual design through additional trades and analyses; design, fabrication, and test of the Development Model; and design, fabrication, and test of the Interrack Demonstration Unit; and support of the requirements definition review (RDR). The purpose of part 2 was to prove concept feasibility.

Source record↗
NASA NTRS2004

Rb-Sr and Sm-Nd Isotopic Studies of Shergottite Y980459 and a Petrogenetic Link Between Depleted Shergottites and Nakhlites

Y980459 was found near the Minami-Yamato Nunataks, Antarctica in 1998 and was recently classified as an olivine-bearing shergottite. It petrographically resembles many other olivine-phyric shergottites mostly found in hot deserts, e.g. DaG476/489, SaU005/094, Dohfar 019, NWA 1068/1110, NWA 1195 and EETA 79001 lith.A. However, Y980459 is unique among these meteorites in several respects. It is apparently very fresh and only weakly shocked. Also, it completely lacks plagioclase, but contains abundant residual volcanic glass. This group of olivine-phyric shergottites is characterized by variable crystallization ages from approx.172 Ma to approx.575 Ma and ejection ages from approx.1 Ma to approx.20 Ma. They probably represent volcanic melts originated from the deep Martian mantle. We performed Rb-Sr and Sm-Nd isotopic analyses on Y980459 to determine its crystallization age and compared its age and isotopic signatures with those obtained from other olivine-phyric shergottites and QUE 94201, the other Antarctic olivine-free shergottite. QUE 94201 and some olivine-phyric shergottites e.g. DaG, SaU, Doh and EETA lith A have similar depleted-LREE patterns and are herein referred to as depleted shergottites. A petrogenetic model correlating depleted shergottites and nakhlites is also proposed. Preliminary Rb-Sr and Sm-Nd isotopic data for Y980459 were presented earlier at the NIPR, Japan, in 2003.

Shih, C.-Y.↗