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Evaluating Lunar Water Processing System Model Configurations for Small Scale Oxygen and Hydrogen Production Within JAXA'S ISRU Technology
Introduction: In-Situ Resource Utilization (ISRU) refers to novel methods of extracting and processing local resources for use in life support and propulsion systems, reducing or eliminating the required consumables to be transferred from Earth. Current estimates of water-ice availability embedded in regolith within the Moon’s permanently shadowed regions (PSR’s) range between 1-5% by weight. However, the composition and characteristics of the “wet” regolith is unknown. Alternate ISRU excavation techniques and Concept of Operations (ConOps) must be explored to optimize surface system operations based on these factors. To assess the feasibility of different ISRU subsystem technologies and compare system architecture configurations, an interchangeable system model was generated to incorporate technologies spanning excavation of raw materials to storage of products and determine optimal arrangement of total system processing needs. Total Mass, Volume, and Power (M/V/P) requirements were computed for 168 design iterations of this water processing plant. System Model: In FY24, the System Engineering and Integration (SE&I) ISRU Modeling and Analysis (SIMA) team developed a lunar water processing system model using the Mission Analysis and Integration Tool (MAIT) to estimate the M/V/P for ISRU subsystems operating under a wide range of Hydrogen (H2) and Oxygen (O2) production targets for the Space Technology Mission Directorate (STMD) [1]. Based on Japan Aerospace Exploration Agency’s (JAXA) surface operational requirements, this system architecture was modified to include the ability to excavate consolidated icy regolith (versus granular ice excavation using Kennedy Space Center’s (KSC) ISRU Pilot Excavator, IPEx) and explore the feasibility of processing the lunar water both inside and outside of the PSR. For the consolidated icy regolith case study, excavation was performed via a mobility transport chassis outfitted with The Regolith Ice Drill for Exploring New Terrain (TRIDENT) for drilling [2] and the Cold Operable Lunar Deployable Arm (COLDArm) [3] for regolith transfer. The system model determines the required rover and payload. M/V/P to handle the required regolith processing rates. The regolith is then sorted and heated to sublimate the ice (via an auger dryer). The exiting high temperature, low pressure vapor is cleaned of volatiles (via cold trap) and electrolyzed to produce H2 and O2. These products are then dried, liquified with 20 K and 90 K cryocoolers (for H2 and O2, respectively), and stored in cylindrical tanks. Study Goals: Due to the different ConOps options of regolith transport to the ridge for processing versus processing it directly inside the PSR, as well as the unknown regolith/water-ice composition, new excavation techniques and their power configurations are being evaluated within a ISRU system architecture for production targets less than NASA’s pilot plant (1 mT). This analysis investigates the feasibility of numerous excavation techniques, power architectures, and logistical operations and determines an optimal system configuration with regards to M/V/P. It aims to investigate which parameters, both locally and globally, have the greatest effect on each subsystem within the plant. This can be used to identify the most critical components of the plant, and guide future decisions on allocating funding for research and development. The results from this study may provide subsystem developers with appropriate interfaces with excavation subsystems and downstream processes, and assessing the overall feasibility of each excavation technique, power architecture, and logistical timeframe. References: [1] Carlson, A. et. al. (2024) ICES. [2] Zacny, K., et. al. (2024) “ASCE Earth and Space”. [3] McCormick, R., et. Al. (2024) IEEE Xplore.
An investigation of the effect of surface impurities on the adsorption kinetics of hydrogen chemisorbed onto iron
The goal was to develop an understanding of heterogeneous kinetic processes for those molecular species which produce gaseous hydrogen degradation of the mechanical properties of metallic structural materials. Although hydrogen degradation of metallic materials is believed to result from dissolved protonic hydrogen, the heterogeneous hydrogen interface transport processes often dominate the kinetics of the degradation process. The initial step in the interface transport process is the dissociative chemisorption of the molecular species at the metal surface followed by hydrogen absorption into and transport through the bulk. Modern advanced aerospace applications often require the use of structural materials in high pressure hydrogen environments at temperatures which range from low cryogenic temperatures to very high temperatures (1300 K and greater). Materials proposed for these applications, such as the titanium aluminides, beta-titanium alloys, nickel- and cobalt-based superalloys, molybdenum-rhenium alloys, beryllium, and various beryllides, need to possess a high degree of immunity from hydrogen induced degradation of mechanical properties. In the present program, the interaction of hydrogen with the surfaces of alpha-2 (Ti3Al) titanium aluminide, gamma (TiAl) titanium aluminide, and beryllium were studied. The interaction of low pressure hydrogen with gamma titanium aluminide and beryllium was found to be relatively weak, in the sense that adsorption leads to a low surface concentration of dissociated hydrogen, i.e., the chemisorption process is reversible at room temperature (300 K) for gamma titanium aluminide and the sticking coefficient for chemisorption is extremely small for beryllium. Hydrogen was found to interact readily with alpha-2 titanium aluminide to form a stable surface hydride at 300 K. These results correlate well with other recent studies which show that the mechanical properties for alpha-2 titanium aluminide are readily degraded in hydrogen while gamma titanium aluminide exhibits less degradation and beryllium essentially no degradation. The interaction of oxygen with the surface of these materials has been studied, also, in the present program.
Methanogenesis and Acetogenesis in Hydrogenotrophy with Carbonate Minerals: Dependence on Mineral Surface Area, Biofilm Growth, and Microbial Community
The production, storage, and use of hydrogen are anticipated to grow substantially to achieve energy and climate goals. Consequently, microbial communities in many terrestrial and subsurface Earth environments could be exposed to elevated hydrogen concentrations. Hydrogen stimulates metabolic processes that reduce aqueous chemical species, such as bicarbonate or sulfate, that can exchange with solid mineral phases, but the controls on microbial hydrogenotrophy with mineral sources of electron acceptors are not fully understood. Herein, we applied laboratory experiments and biogeochemical modeling to study the response of a natural microbial community to an elevated partial pressure of hydrogen in the presence of carbonate minerals of varying composition, solubility, and size. Experimental incubations and simulation results showed that hydrogen consumption by microbial communities was initially dominated by sulfate reduction and, subsequently, transitioned to acetogenesis and methanogenesis. The rates of acetogenesis and methanogenesis were not correlated with the solubility of carbonate minerals. Instead, we observed strong linear correlations between the rates and surface area of carbonate minerals. Methane and acetate production slowed down in all incubations after about 2 weeks of incubation, although biogeochemical modeling predicted that the metabolic processes were not thermodynamically limited. Electron microscopy and infrared spectroscopy showed that biofilms with diverse microorganisms grew on the carbonates during this period. The methane δ13C value significantly increased, consistent with slower growth at elevated pH. This work highlights that microbial communities form biofilm on carbonate mineral surfaces as a response to hydrogen and that biofilm formation could pose a strong kinetic limitation to hydrogenotrophic metabolism utilizing carbonate minerals.
Modular Biomass Gasification for Co-Production of Hydrogen and Power
The overall goal of this project was to demonstrate a novel process-intensified and modular Combined Hydrogen, Heat and Power (CH 2 P) production technology, targeting commercial scales of 5-to-10-megawatt electric (MWe) equivalent of hydrogen (H 2 ). The process technology integrates a novel adaptation of the steam-iron process to produce high purity H 2 from gasification of biomass and biomass blends with a compression-ready carbon dioxide (CO 2 ) stream, enabling significant progress towards achieving $1 per kilogram (kg) cost for clean H 2 .
High specific energy, high capacity nickel-hydrogen cell design
A 3.5 inch rabbit-ear-terminal nickel-hydrogen cell was designed and tested to deliver high capacity at steady discharge rates up to and including a C rate. Its specific energy yield of 60.6 wh/kg is believed to be the highest yet achieved in a slurry-process nickel-hydrogen cell, and its 10 C capacity of 113.9 AH the highest capacity yet of any type in a 3.5 inch diameter size. The cell also demonstrated a pulse capability of 180 amps for 20 seconds. Specific cell parameters and performance are described. Also covered is an episode of capacity fading due to electrode swelling and its successful recovery by means of additional activation procedures.
Development of Liquid Hydrogen Leak Frequencies Using a Bayesian Update Process.
Abstract not provided.
Modeling and optimization of a regenerative fuel cell system using the ASPEN process simulator
The Hydrogen-Oxygen Regenerative Fuel Cell System was identified as a key component for energy storage in support of future lunar missions. Since the H2-O2 regenerative electrochemical conversion technology has not yet been tested in space applications, it is necessary to implement predictive techniques to develop initial feasible system designs. The ASPEN simulation software furnishes a constructive medium for analyzing and for optimizing such systems. A rudimentary regenerative fuel cell system design was examined using the ASPEN simulator and this modular approach allows for easy addition of supplementary ancillary components and easy integration with life support systems. The modules included in the preliminary analyses may serve as the fundamental structure for more complicated energy storage systems.
Modeling and optimization of a regenerative fuel cell system using the ASPEN process simulator
The Hydrogen-Oxygen Regenerative Fuel Cell System was identified as a key component for energy storage in support of future lunar missions. Since the H2-O2 regenerative electrochemical conversion technology has not yet been tested in space applications, it is necessary to implement predictive techniques to develop initial feasible system designs. The ASPEN simulation software furnishes a constructive medium for analyzing and optimizing such systems. A rudimentary regenerative fuel cell system design was examined using the ASPEN simulator and this modular approach allows for easy addition of supplementary ancillary components and easy integration with life support systems. The modules included in the preliminary analyses may serve as the fundamental structure for more complicated energy storage systems.
Further studies of the mechanism by which hydrogen enters metals during chemical and electrochemical processing
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A Fundamental Study of the Mechanism by which Hydrogen Enters Metals During Chemical and Electrochemical Processing
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Development of Liquid Hydrogen Leak Frequencies Using a Bayesian Update Process.
Abstract not provided.
ZeroCAL: Eliminating Carbon Dioxide Emissions from Limestone’s Decomposition to Decarbonize Cement Production
Limestone (calcite, CaCO 3 ) is an abundant and cost-effective source of calcium oxide (CaO) for cement and lime production. However, the thermochemical decomposition of limestone (~800 °C, 1 bar) to produce lime (CaO) results in substantial carbon dioxide (CO 2(g) ) emissions and energy use, i.e., ~1 tonne [t] of CO 2 and ~1.4 MWh per t of CaO produced. Here, we describe a new pathway to use CaCO 3 as a Ca source to make hydrated lime (portlandite, Ca(OH) 2 ) at ambient conditions (p, T) while nearly eliminating process CO 2(g) emissions (as low as 1.5 mol. % of the CO 2 in the precursor CaCO 3 , equivalent to 9 kg of CO 2(g) per t of Ca(OH) 2 ) within an aqueous flowelectrolysis/ pH-swing process that coproduces hydrogen (H 2(g) ) and oxygen (O 2(g) ). Because Ca(OH) 2 is a zero-carbon precursor for cement and lime production, this approach represents a significant advancement in the production of zero-carbon cement. The Zero CArbon Lime (ZeroCAL) process includes dissolution, separation/recovery, and electrolysis stages according to the following steps: (Step 1) chelator (e.g., ethylenediaminetetraacetic acid, EDTA)-promoted dissolution of CaCO 3 and complexation of Ca 2+ under basic (>pH 9) conditions, (Step 2a) Ca enrichment and separation using nanofiltration (NF), which allows separation of the Ca-EDTA complex from the accompanying bicarbonate (HCO 3 – ) species, (Step 2b) acidity-promoted decomplexation of Ca from EDTA, which allows near-complete chelator recovery and the formation of a Ca-enriched stream, and (Step 3) rapid precipitation of Ca(OH) 2 from the Ca-enriched stream using electrolytically produced alkalinity. These reactions can be conducted in a seawater matrix yielding coproducts including hydrochloric acid (HCl) and sodium bicarbonate (NaHCO 3 ), resulting from electrolysis and limestone dissolution, respectively. Careful analysis of the reaction stoichiometries and energy balances indicates that approximately 1.35 t of CaCO 3 , 1.09 t of water, 0.79 t of sodium chloride (NaCl), and ~2 MWh of electrical energy are required to produce 1 t of Ca(OH) 2 , with significant opportunity for process intensification. This approach has major implications for decarbonizing cement production within a paradigm that emphasizes the use of existing cement plants and electrification of industrial operations, while also creating approaches for alkalinity production that enable cost-effective and scalable CO 2 mineralization via Ca(OH) 2 carbonation.
Sustainable valorization of waste tires: Selective hydrotreating for renewable p-cymene production
The escalating global concern over waste tire management driven by the surge in automobiles necessitates sustainable and innovative solutions. Here, this study posits a novel approach by introducing a selective catalytic hydrogenation and dehydrogenation process using a tandem two-stage pressurized fixed-bed reactor, aiming to convert waste tires into valuable sulfur-free p-cymene. The experimental results indicate that among the studied catalysts including Pt/C, Pd/C, Ru/C, and Ni/Al 2 O 3 -SiO 2 , the Pd/C exhibits concomitant hydrogenation and dehydrogenation functionalities, achieving full conversion and displaying 100 % selectivity towards p-cymene from limonene model compound. Furthermore, the Pd/C catalyst demonstrates remarkable efficiency in converting real-world waste tires into p-cymene, yielding up to 134.8 mg/g at optimal conditions. Importantly, this catalyst also facilitates complete hydrodesulfurization activity, addressing environmental concerns by producing sulfur-free liquid products. This innovative method not only optimizes p-cymene synthesis from waste tires but also contributes to environmental sustainability, showcasing both economic and ecological viability.
Nuclear Integrated Hydrogen Production Analysis Tool
This is an Excel-based time-independent discount cash flow calculator for LWR-HTSE systems. The tool incorporates (1) discounted cash flow and levelized cost of hydrogen (LCOH) analysis, (2) sensitivity analysis with respect to select financial performance metrics with output ‘tornado’ charts, (3) profitability analysis represented by heat maps using the two most sensitive parameters, (4) electricity versus hydrogen production preference analysis by comparing change in net present value (?NPV) between NPP-HTSE and business-as-usual electricity production for the grid, and (5) competitiveness analysis by comparing the calculated LCOH for NPP-HTSE with that of steam methane reforming, which is the conventional process to produce hydrogen.
A Gas Management System for an Ultra Long Duration Titan Blimp
This paper presents analyses, designs and experimental results for the gas management system of a hydrogen-filled blimp capable of flying in the lower atmosphere of Titan for a period of one year or more. The engineering strategy has two basic elements: first, to minimize leakage rates from the blimp envelope and ballonets; and second, to provide auxiliary subsystems to mitigate the life-limiting effects resulting from those leaks. Leak minimization is achieved through use of cryogenically compatible balloon materials and adhesives, and selection of ballonet geometries that minimize pinhole generation via folding and material fatigue. Hydrogen loss to the environment through leaks in the blimp envelope is compensated for by producing new hydrogen through chemical processing of atmospheric methane. Nitrogen leaked into the blimp from the ballonets is removed by a carbon absorption system and periodically vented to the atmosphere. Data is presented on the measured leak rate from a full scale (13 m long) prototype blimp envelope and on the performance of a low mass, low power prototype device that generates hydrogen from methane. These results are factored in to an overall system design that quantifies the mass and power requirements for a minimum one year operational lifetime.
System design and analysis of thermal power dispatch systems for boiling water reactors
Nuclear power plants are crucial to meeting net zero emission goals and achieving energy sustainability. Integrating these plants with clean energy technologies such as high-temperature steam electrolysis (HTSE) may improve the efficiency and economic competitiveness of these plants. Here, the current study investigates the design and operation of a thermal power dispatch (TPD) system for coupling boiling water reactors (BWRs) to HTSE plants. The TPD system extracts a portion of the steam from the reactor’s main steam line and transfers its thermal energy to an HTSE plant through a power transport loop. A TPD system for 5 % steam extraction has been designed and the system performance during steady and transient operations has been analyzed. The TPD system dispatched a total of 197 MW thermal energy to the HTSE plant under nominal design conditions. Saturated steam at 7.17 MPa from the BWR plant was condensed and subcooled to a temperature of 168 °C, while a mass flow rate of 91.1 kg/s of superheated steam was dispatched to the HTSE plant. Furthermore, the system performance during transient operation showed a continuous transition from the initial hot standby mode to the nominal power dispatch level. The transient simulation results emphasized the importance of investigating component level performance for the TPD system design. The current results will guide future works on the development of integrated energy systems for hydrogen production or process heat applications.
On the existence of molecular hydrogen along lines of sight with low reddening
The existence of molecular hydrogen along lines of sight with low reddening (B-V color excesses not exceeding 0.03) is discussed for the stars HD 28497, Mu Col, Alpha Vir, Beta Cen, and Lambda Sco. The main observations are of the R(1) features, which for effective rotational temperatures above 200 K are the dominant source of H2 transitions. If the formation process for molecular hydrogen is similar to that for regions of greater reddening, the observations indicate that the neutral gas outside standard clouds may be partially in small clouds, though a more diffuse component seems to exist in some cases. Extremely high rotational temperatures are inferred for the H2 toward HD 28497. The possibility of formation of H2 through the reaction H(-) + H yields H2 + e(-) is briefly discussed. In any case, only small regions seem to contribute to the observed H2 column density.