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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
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NASA NTRS1986

Photolysis products of CO, NH3 aND H2O and their significance to reactions on interstellar grains

With the increase in evidence that interstellar grains are the basic building blocks of comets and with the realization that comet collisions with the earth have probably occured at a much higher frequency than earlier assumed it may be presumed that interstellar dust chemistry played an important role in the early chemistry of the earth. As a part of the study of the photochemical processes taking place on interstellar grains the photolysis of mixtures of CO, NH3 and H2O was performed at 10 K, 77K and 298K. The reaction products were determined by GC/MS and HPLC analysis to be lactic acid, glycolic acid, hydroxyacetamide, urea, biuret, oxamic acid, oxamide, glyceric acid and glyceramide. Ethylene glycol and glycerol were also detected but is is not clear at present whether these are true photoproducts or contaminants. The mechanism of formation of these molecules are discussed as well as their possible significance to the origins of life.

Ferris, J. P.↗
NASA NTRS1986

Photoabsorption and photodissociation of molecules important in the interstellar medium

In the period from May 15, 1985 to May 14, 1986, the photoabsorption and photodissociation cross sections of the interstellar radical of SO and the interstellar molecules of HCl, H2CO, and CH3CN were measured and the results were reported in scientific papers. In the meantime, a windowless apparatus is used to measure the photoabsorption and photodissociation cross sections of CO in the 90-105 nm region. The optical data obtained in this research program are needed for the determination of the formation and destruction rates of molecules and radicals in the interstellar medium. Accomplishments in this research period are summarized below.

Lee, L. C.↗
NASA NTRS1986

Interplanetary dust: The interstellar connection

Although not proven, there is the widespread belief that comets consist, at least in part, of interstellar material that was originally present in the solar nebula. Furthermore, there are strong arguments in favor of the view that much of the interplanetary dust complex is derived from comets. The main arguments supporting this view are based on mass balance, analysis of the orbital parameters of meteors, and the long known association between meteor showers and specific comets. Laboratory measurements on interplanetary dust particles (IDPs) collected in the stratosphere have confirmed the view that many of the dust particles are primitive in the sense that they show striking enrichments of D/H relative to average solar system materials. It has also been demonstrated that the mid-infrared absorption spectra of one infrared red class of particles show strong similarities to IR sources such as the protostar W-33A. However, the laboratory studies of IDPs have shown that they represent a diverse set of objects and the measurement of the orbital parameters of specific dust particles is essential to answering the question of sources. The observation of the IRAS dust bands reopens the question of the role of asteroids in supplying a significant fraction of the dust and part of the diversity observed may be due to the fact that some of the dust is asteroidal and some cometary. In addition, some fraction of interplanetary dust must consist of an interstellar component intercepted by the solar system in its motion through the local interstellar medium. It has been shown that dust derived from nearby stars will have 75% of their orbits with eccentricities or equal to 1.1 and might be difficult to distinguish from interplanetary dust based on orbital measurements alone.

Carey, W. C.↗
NASA NTRS1985

A catalog of ultraviolet interstellar extinction excesses for 1415 stars

Ultraviolet interstellar extinction excesses are presented for 1415 stars with spectral types B7 and earlier. The excesses with respect to V are derived from Astronomical Netherlands Satellite (ANS) 5-channel UV photometry at central wavelengths of approximately 1550, 1800, 2500, and 3300 A. A measure of the excess extinction in the 2200-A extinction bump is also given. The data are valuable for investigating the systematics of peculiar interstellar extinction and for studying the character of UV interstellar extinction in the general direction of stars for which the extinction-curve shape is unknown.

Savage, B. D.↗
NASA NTRS1985

On interstellar Fe X forbidden line absorption. III - The lambda 6367 feature

Echelle spectra of Zeta Oph and HD 190603 are reported which show a weak interstellar absorption feature near 6367 A. The feature had been previously detected only toward two members of the Cepheus OB2 association in an extensive search for interstellar Fe X forbidden line absorption (lambda 6375). On the basis of the resulting radial velocities, the two new detections exclude the preliminary identification of the lambda 6367 feature with high-velocity Fe X ions in the hot, X-ray-emitting gas and demonstrate that the feature arises instead in the ordinary diffuse clouds. This unidentified feature may be either a molecular transition or a very weak diffuse interstellar band.

Hobbs, L. M.↗
NASA NTRS1985

Probing the local interstellar medium

A sophisticated model of solar wind expansion is applied to deduce a range of parameters for the local interstellar medium that predicts a location for the heliospheric shock of about 30 AU. It is found that either the interstellar magnetic field is more than double the presently accepted value of 0.3 nT, or the pressure due to galactic cosmic rays with energies near 0.1 MeV is that obtained by simple extrapolation of the observed flux at higher energies inside the heliosphere. Alternatively, some combination of these two external effects yields an effective interstellar pressure approximately quadruple present estimates.

Suess, S. T.↗
NASA NTRS1985

Collisional excitation of molecules in dense interstellar clouds

State transitions which permit the identification of the molecular species in dense interstellar clouds are reviewed, along with the techniques used to calculate the transition energies, the database on known molecular transitions and the accuracy of the values. The transition energies cannot be measured directly and therefore must be modeled analytically. Scattering theory is used to determine the intermolecular forces on the basis of quantum mechanics. The nuclear motions can also be modeled with classical mechanics. Sample rate constants are provided for molecular systems known to inhabit dense interstellar clouds. The values serve as a database for interpreting microwave and RF astrophysical data on the transitions undergone by interstellar molecules.

Green, S.↗
NASA NTRS1985

Photochemical reactions in interstellar grains photolysis of CO, NH3, and H2O

The interstellar grains are currently considered to be the basic building blocks of comets and, possibly, meteorites. To test this theory, a simulation of the organic layer accreted onto interstellar dust particles was prepared by slow deposition of a CO:NH3:H2O gas mixture on an Al block at 10 K, with concomitant irradiation with vacuum UV. The results of the HPLC and IR analyses of the nonvolatile residue formed by photolysis at 10 K are compared with those observed at 77 K and 298 K. Some of the compounds that may be present on the surfaces of interstellar dust particles have been identified, and some specific predictions concerning the types of molecular species present in comets could be drawn. The results also suggest that photochemical reactions may have been important for the formation of meteorite components. The implication of the findings to the questions of the source of organic matter on earth and the origin of life are discussed.

Agarwal, V. K.↗
NASA NTRS1986

A reanalysis of the HCO(+)/HOC(+) abundance ratio in dense interstellar clouds

New theoretical and experimental results have prompted a reinvestigation of the HCO(+)/HOC(+) abundance ratio in dense interstellar clouds. These results pertain principally but not exclusively to the reaction between HOC(+) and H2, which was previously calculated by DeFrees et al. (1984) to possess a large activation energy barrier. New calculations, reported here, indicate that this activation energy barrier is quite small and may well be zero. In addition, experimental results at higher energy and temperature indicate strongly that the reaction proceeds efficiently at interstellar temperatures. If HOC(+) does indeed react efficiently with H2 in interstellar clouds, the calculated HCO(+)/HOC(+) abundance ratio rises to a substantially greater value under standard dense cloud conditions than is deduced via the tentative observation of HOC(+) in Sgr B2.

Jarrold, M. F.↗
NASA NTRS1985

Recent observations of organic molecules in nearby cold, dark interstellar clouds

Recent investigations of the organic chemistry of relatively nearby cold, dark interstellar clouds are reported. Specifically, the presence of interstellar tricarbon monoxide (C3O) in Taurus Molecular Cloud 1 (TMC-1) is confirmed. The first detection in such regions of acetaldehyde (CH3CHO), the most complex oxygen-containing organic molecule yet found in dark clouds is reported, as well as the first astronomical detection of several molecular rotational transitions, including the J = 18-17 and 14-13 transitions of cyanodiacetylene (HC5N), the 1(01)-0(00) transition of acetaldehyde, and the J = 5-4 transition of C3O. A significant upper limit is set on the abundance of cyanocarbene (HCCN) as a result of the first reported interstellar search for this molecule.

Suzuki, H.↗
NASA NTRS1985

On the question of interstellar travel

Arguments are presented which show that motives for interstellar travel by advanced technological civilizations based on an extrapolation of earth's history may be quite invalid. In addition, it is proposed that interstellar travel is so enormously expensive and perhaps so hazardous, that advanced civilizations do not engage in such practices because of the ease of information transfer via interstellar communication.

Wolfe, J. H.↗
NASA NTRS1986

Detection of scattering in the 2175 A interstellar band

Spectrophotometric observations of two reflection nebulae and their illuminating stars obtained with the International Ultraviolet Explorer Satellite have provided the first evidence for the presence of a scattering contribution to the 2175 A interstellar extinction band. Lower than normal far-UV extinction for the stars embedded in the nebulae indicates that the nebulae have a dust particle size distribution that is dominated by larger particles. The strength of the 2175 A band is larger than normal in both cases. The scattering is found to dominate the long-wavelength wing of the band, without shifting the central wavelength of the band by more than 20 A toward longer wavelengths. These observations are taken to indicate that the solid particles responsible for the 2175 A band can be considerably larger than the Rayleigh limit in some interstellar locations. The absence of a notable shift in the central wavelength of the band in such large particles presents a new severe constraint for models of interstellar grains.

Witt, A. N.↗
NASA NTRS1986

Diatoms on earth, comets, Europa and in interstellar space

There exists a close correspondence between the measured infrared properties of diatoms and the infrared spectrum of interstellar dust as observed in the Trapezium nebula and toward the galactic center source GC-IRS 7. Diatoms and bacteria also exhibit an absorbance peak near 2200 A, which is found to agree with the observed ultraviolet absorbance properties of interstellar grains. The observational data are reviewed, and the known properties of diatoms and bacteria are considered. It is suggested that these characteristics are consistent with the concept of a cosmic microbiological system in which these or similar microorganisms might exist on comets, Europa and in interstellar space.

Hoover, R. B.↗
NASA NTRS1986

The interstellar medium

Observations and models of interstellar matter in the Milky Way are reviewed. The general structure of the gas layer, high velocity gas, and heavy element depletion patterns are outlined. The IUE survey of Fe and Si abundances, and the correlation of Fe and Si depletions with infrared cirrus are described. Studies of neutral hydrogen may disagree with three-phase models of the interstellar medium, dominated by supernova remnants. The effects of shock waves on interstellar medium structure, the grain population, and refractory element abundances are considered. It appears that the frequency, distribution, energy, and dynamical effects of supernovae in the galaxy may be overestimated.

Shull, J. Michael↗
NASA NTRS1986

Interstellar abundances in dense, moderately reddened lines of sight. I - Observational evidence for density-dependent depletion

The nature of dust-gas interactions, which are capable of modifying the size distribution of interstellar grains and thus causing changes in the selective extinction curve, are investigated through depletion studies. The gaseous abundances of 15 elements have been determined for several lines of sight toward moderately reddened stars, each having an anomalous extinction curve and a large abundance of cyanogen (CN). The basic result of this study is that certain elements appear to deplete preferentially in interstellar clouds having a large abundance of CN. Since CN is a sensitive indicator of the interstellar spatial density, the data might suggest that the unique pattern of enhanced depletion observed here represents the best observational evidence of accretion.

Joseph, Charles L.↗
NASA NTRS1986

The isotopes of hydrogen and helium in the Galactic cosmic radiation - Their source abundances and interstellar propagation

A self-consistent model describing the interstellar propagation of Galactic cosmic radiation is developed using low-energy measurements and calculations of the effects of interstellar propagation and solar modulation. The source ratio H-1/He-4 at constant energy per nucleon is determined to be 12.2 + or - 1.5, and the mean path length for an exponential path length weighting function required to account for the data is 7.2 + or - 1.0 g/sq cm. The measured H-2/He-4 and He-3/He-4 ratios do not vary by more than about 30 percent over the solar cycle. The behavior of the ratios during the solar cycle reflects the energy dependence of the local interstellar ratios, and leads to an energy dependence of the mean path length below 1 GeV per nucleon weaker than that inferred from boron/carbon. The source ratio H-1/He-4 inferred from the low-energy data is consistent both with the value inferred from high-energy cosmic ray data using a model of rigidity-dependent confinement and with the solar system abundance ratio.

Beatty, James J.↗
NASA NTRS1987

Interstellar problems and matrix solutions

The application of the matrix isolation technique to interstellar problems is described. Following a brief discussion of the interstellar medium (ISM), three areas are reviewed in which matrix experiments are particularly well suited to contribute the information which is sorely needed to further understanding of the ISM. The first involves the measurement of the spectroscopic properties of reactive species. The second is the determination of reaction rates and the elucidation of reaction pathways involving atoms, radicals, and ions which are likely to interact on grain surfaces and in grain mantles. The third entails the determiantion of the spectroscopic, photochemical, and photophysical properties of interstellar and cometary ice analogs. Significant, but limited, progress has been made in these three areas, and a tremendous amount of work is required to fully address the variety of unique chemical and spectroscopic questions posed by the astronomical observations.

Allamandola, Louis J.↗
NASA NTRS1987

Element abundances in the interstellar atomic material

In the interstellar medium, a significant fraction of the free atoms for elements heavier than helium must have condensed into solids, in the form of small, interstellar dust grains. Observations of optical and ultraviolet absorption lines in the spectra of hot stars indicate that the depletions below the cosmic abundances of various elements range from almost none at all to a factor of 0.0001 and seem to be enhanced along lines of sight with higher mean density. Other methods of measuring abundances confirm the absorption line results. The available evidence supports the notion that the grains form in both the atmospheres of cool stars and in dense interstellar clouds, and they are destroyed by shocks which frequently pass through the low density gas.

Jenkins, Edward B.↗