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At least 379 records · Page 21

The thermoremanence hypothesis and the origin of magnetization in iron meteorites

The intensity, relative stability and directional behavior in alternating field demagnetization of natural, saturation, thermal and spontaneous magnetization were studied for a variety of iron meteorites. Results show that remanence and relative stability increase from the coarser to the finer-grained samples. In addition, natural remanent magnetization coercivity spectra are found to soften with coarsening of the grain size. The link between fine structure and magnetization direction in octahedrites is also discussed. The combined effect of magnetocrystalline- and shape-anisotropy of the crystallographically ordered ferromagnetic kamacite alpha-phase renders the iron meteorites of little use for the study of ancient solar system fields.

Brecher, A.↗

A core origin for group IVA iron meteorites - A reply to Moren and Goldstein

Because uncertainties in experimental data are large, one has considerable latitude in choosing the input parameters needed to calculate iron meteorite cooling rates. The best way to test input parameters is by examining their ability to yield the observed properties of the meteorites. Our phase diagram yields fits to kamacite profiles that are superior to those based on the Moren-Goldstein phase diagram. Our method of allowing for the effect of P on the Ni diffusion coefficient takes into account the enhancement in this effect with decreasing temperature; Moren and Goldstein use a relationship derived for a temperature of 1100 C, well outside the 700-350 C range where kamacite growth occurs. Use of our input parameters yields cooling rates in IVA irons that are independent of composition, consistent with a core origin. Since the fractionation of siderophiles in group IVA also indicates a core origin, we conclude that this is the correct model for this group.

Willis, J.↗

Fretting wear of iron, nickel, and titanium under varied environmental conditions

Fretting wear experiments were conducted on high purity iron, nickel and titanium in air under conditions of varied humidity and temperature, and in nitrogen. For iron and titanium, maximum fretting occurred at 10 and 30 percent relative humidity respectively. Nickel showed a minimum in fretting wear at about 10 percent relative humidity. With increasing temperature, all three metals initially showed reduced fretting wear, with increasing wear observed as temperatures increased beyond 200-300 C. For titanium, dramatically reduced fretting wear was observed at temperatures above 500 C, relatable to a change in oxidation kinetics. All three metals showed much less fretting wear in N2 with the presence of moisture in N2 having a proportionally stronger effect than in air.

Bill, R. C.↗

Protoplanetary core formation by rain-out of iron drops

Using the stochastic collection equation we find that the time scale for rain out of liquid iron in a Saturn mass protoplanet is rapid compared with other evolutionary time scales and hence iron protoplanetary core formation is inevitable. The survival of this core during subsequent protoplanetary evolution and the consequences of the rain-out on the evolution are also discussed.

Slattery, W. L.↗

The depletion of interstellar gaseous iron

The Copernicus UV telescope was used to measure equivalent widths of interstellar Fe II resonance lines toward 55 early-type stars; the measurements permit the determination of Fe II column densities. The depletion of interstellar gaseous iron was obtained by combining these measurements with the results from a previous atomic and molecular hydrogen survey program; the derived depletions refer mostly to matter in H I regions. As an example, the nearly normal gaseous iron abundance in the distant high-latitude intermediate-velocity cloud toward HD 93521 is consistent with the idea that these clouds are produced by galactic supernova explosions.

Savage, B. D.↗

Fretting wear of iron, nickel, and titanium under varied environmental conditions

Fretting wear experiments were conducted on high-purity iron, nickel and titanium in air under conditions of varied humidity and temperature, and in nitrogen. For iron and titanium, maximum fretting occurred at 10 and 30 percent relative humidity respectively. Nickel showed a minimum in fretting wear at about 10% relative humidity. With increasing temperature, all three metals initially showed reduced fretting wear, with increasing wear observed as temperatures increased beyond 200-300 C. For titanium, dramatically reduced fretting wear was observed at temperatures above 500 C, relatable to a change in oxidation kinetics. All three metals showed much less fretting wear in N2 with the presence of moisture in N2 having a proportionally stronger effect than in air.

Bill, R. C.↗

High energy cosmic ray iron spectrum experiment

An instrument containing a gas Cerenkov counter and an iron ionization spectrometer was constructed in order to measure the cosmic-ray iron spectrum to 300 GeV/nucleon. Trajectories of particles were determined by entopistic or position-determining scintillator systems. The geometric factors with and without the gas Cerenkov counter were 0.3 and 0.6 sq m-ster, respectively. The instrument was successfully flown in June 1976 without the spectrometer and in October 1976 with the spectrometer from Palestine, Texas. The June flight yielded 14.5 h of data; the October flight, 25 h.

Arens, J. F.↗

Experimental investigations of trace element fractionation in iron meteorites. I - Early results

Experimental procedures for measuring trace element partitioning among metal and sulfide and silicate phases are described, and solid metal/liquid metal partition coefficients for minor and trace elements in the Fe-Ni system at 5 to 14% Ni are reported. The bulk compositions desired are homogenized at superliquidus temperature for 15-24 hours, held at a temperature in the solid/liquid two phase region for about 24 hours, and quenched to freeze in the equilibrium compositions. Run products are analyzed by electron microprobe. With the exception of Cr, all preliminary partition coefficients obtained are in the same sense as values derived from iron meteorites. The partition coefficients for Cr in solid metal/liquid metal and metal/troilite systems suggest that IIIAB and main group pallasites equilibrated with 9-22% troilite. A second method which makes it possible to place upper and lower limits on the partition coefficient by holding part of the sample at subliquidus and part at superliquidus temperatures, yielded significantly different results for the two metals tested (Au and Pt) from those obtained by the first method, demonstrating the importance of a close approach to equilibrium before using experimentally-determined partition coefficients to test empirical differentiation models for iron meteorites.

Bild, R. W.↗

Fractional crystallization of iron meteorites, an experimental study

Measurements of the distribution coefficients of various elements (Ni, Co, P, Pt, Ir, Ge, Cr, and Au) between solid and liquid phases were made for FeNi alloys. A high thermal gradient crystal growing furnace was employed in order to promote plane front solidification, rapid mixing in the liquid and a minimum of diffusion in the solid. Eight measurements of the nickel distribution coefficient gave an average value of 0.91 plus or minus 0.03 and this value was independent of the Ni concentration in the range 5.5 to 8.75 wt. % Ni. Equilibrium distribution coefficients were also calculated by correcting for the diffusion boundary layer present in the liquid. These values are within 20% of the measured distribution coefficient values. Except for Co and Ni, all the measured distribution coefficient values are closer to 1.0 than those calculated by Scott (1972) for the IIIAB irons. Using the experimental values and the calculated equilibrium values for ternary additions to FeNi melts, it appears that fractional crystallization processes will not explain the observed chemical variations in the major iron meteorite groups. Alternative explanations are suggested which also recognize the fact that cooling rates vary widely in several chemical groups.

Goldstein, J. I.↗

X-ray iron-line emission from the SN 185 remnant

Radio and optical research was carried out in order to show that the supernova remnant RCW86 is a remnant of the earliest supernova event ever recorded in history (185 AD). The results are as follows: (1) an iron-line emission was found at 6.7 keV; (2) the temperature measured from HEAO-1 was approximately 6 keV; and (3) the equivalent width was consistent within the uncertainties with a cosmic iron abundance. These results support the identification of the supernova remnant RCW86 (it's X-ray source) with the historic supernova event.

Winkler, P. F.↗

Content of total iron, copper and manganese in liver of animals during hypokinesia, muscle activity and process of recovery

It is shown that the content of total iron, copper and manganese in the liver of animals is altered depending on the intensity and duration of their swimming. Hypodynamia for 7 days does not alter the concentration of iron, but sufficiently increases the content of copper and manganese. The barometric factor effectively influences the maintenance of constancy in the content of microelements accumulated in the liver after intensive muscle activity.

Potapovich, G. M.↗

Nebular condensation of Ga, Ge and Sb and the chemical classification of iron meteorites

The quantization of the Ga and Ge contents in iron meteorites, which is used as a key parameter in the chemical classification of iron meteorites, is discussed in terms of nebular condensation. The calculation of nebular equilibrium condensation is examined, taking into account the dependence of the activity coefficient on temperature and composition, and recent calculations of the condensation temperatures of Ga, Ge, Sb, Au, As and Cu are presented, noting that Ge is the most volatile siderophile, followed by Ga and Sb. The narrow intragroup ranges of Ga and Ge are interpreted in terms of minimal fractionation during core crystallization, while the larger ranges of Sb are attributed to its significantly smaller solid/liquid distribution coefficient in IIIAB meteorites.

Wai, C. M.↗

Origin of iron meteorite groups IAB and IIICD

Several low Ni-iron meteorites previously classified with group IAB are reclassified with group IIICD because of lower Ge, Ga, W, and Ir concentrations and higher As concentrations. The low Ni extreme of IIICD is now 62 mg/g, and that of IAB is 64 mg/g. It is proposed that the meteorites of both groups formed as individual shock melts on a chondritic parent body. The differences in log element-log Ni slopes of the daughter irons demonstrate that there were detailed differences in the composition and size of phases in the parental material (e.g., more Ni in the sulfides or metal of IAB, or more Ge and Ir in the oxides of IIICD).

Wasson, J. T.↗

Abundances of energy spectra of individual iron-secondary elements

Relative abundances of individual Iron-secondary elements have been measured using a balloon-borne 6.6 m ster ionization/Cerenkov detector system. The unusually large geometry factor and single-charge resolution yield empirical atmospheric attenuation curves for individual elements which combine with high statistics at float altitude to yield individual element abundances, extrapolated to the top of the atmosphere, with high precision. Results are presented for top-of-the-atmosphere abundances (relative to iron) of individual elements in the Z range 13-30.

Israel, M. H.↗

The elements just beyond iron - Formation during explosive carbon burning

It is pointed out that the details of the synthesis of the elements just beyond iron are unclear. Thus, a reexamination of the role played by neutron-capture reactions during explosive carbon burning is indicated. A description is given of calculations of explosive carbon-burning nucleosynthesis using a complete neutron capture (n-process) computer code with a network extending from Cr through Zr and including not only (n,gamma), (gamma,n) reactions and beta-decay but also (p,n), (n,p), (p,gamma), and (p,alpha) reactions. Initial conditions indicative of the composition of a massive star following core helium burning were selected, and a comparison is made with conditions similar to those used by Howard et al. (1972). It is found that neutron reactions during explosive carbon burning are an important source for the elements just beyond iron.

Wefel, J. P.↗

Influence of hydrogen chemisorption kinetics on the interpretation of hydrogen transport through iron membranes

The influence of a specific surface reaction on the transport of gas-phase hydrogen through iron membranes has been investigated on the basis of model calculations. The surface reaction involves an adsorbed molecular hydrogen precursor between the gas phase and the dissociated chemisorbed state. The calculations demonstrate that the surface reaction for the H2/Fe system makes significant contributions to the time delay associated with the transient hydrogen transport through iron membranes, even under conditions where the steady-state hydrogen transport is independent of the surface reaction. These contributions to the time delay are interpreted in terms of an effective diffusivity, which is a function of the pressure on the entrance side and the thickness of the membrane.

Shanabarger, M. R.↗

An investigation of the kinetics for hydrogen chemisorption on iron metal surfaces

A quasi-isothermal approach was used to study the kinetics of hydrogen and hydrogen sulfide chemisorption onto iron film in an effort to understand the environmental degradation of steels. The coverage of chemisorbed hydrogen or chemisorbed sulfur was observed as a function of time for fixed conditions of substrate temperature. Auger electron spectroscopy was used to observe the sulfur and chemisorption-induced resistance change was employed to monitor hydrogen coverage. To compare the results obtained from studying the kinetics by two different techniques, the kinetics of oxygen chemisorption onto iron films was also studied. A reaction model utilized to interpret the H2/Fe2 chemisorption kinetics was applied to data from an earlier study on the desorption kinetics for H2 chemisorbed onto nicket films in the vicinity of the Curie temperature of the film. This analysis permitted a separation of the gross desorption process into individual components so that the influence of the magnetic phase transition on the rate constants could be determined.

Shanabarger, M. R.↗