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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

An Experimental Study of Characteristic Combustion-Driven Flow for CFD Validation

A series of uni-element rocket injector studies were completed to provide benchmark quality data needed to validate computational fluid dynamic models. A shear coaxial injector geometry was selected as the primary injector for study using gaseous hydrogen/oxygen and gaseous hydrogen/liquid oxygen propellants. Emphasis was placed on the use of nonintrusive diagnostic techniques to characterize the flowfields inside an optically-accessible rocket chamber. Measurements of the velocity and species fields were obtained using laser velocimetry and Raman spectroscopy, respectively. Qualitative flame shape information was also obtained using laser-induced fluorescence excited from OH radicals and laser light scattering studies of aluminum oxide particle seeded combusting flows. The gaseous hydrogen/liquid oxygen propellant studies for the shear coaxial injector focused on breakup mechanisms associated with the liquid oxygen jet under subcritical pressure conditions. Laser sheet illumination techniques were used to visualize the core region of the jet and a Phase Doppler Particle Analyzer was utilized for drop velocity, size and size distribution characterization. The results of these studies indicated that the shear coaxial geometry configuration was a relatively poor injector in terms of mixing. The oxygen core was observed to extend well downstream of the injector and a significant fraction of the mixing occurred in the near nozzle region where measurements were not possible to obtain. Detailed velocity and species measurements were obtained to allow CFD model validation and this set of benchmark data represents the most comprehensive data set available to date. As an extension of the investigation, a series of gas/gas injector studies were conducted in support of the X-33 Reusable Launch Vehicle program. A Gas/Gas Injector Technology team was formed consisting of the Marshall Space Flight Center, the NASA Lewis Research Center, Rocketdyne and Penn State. Injector geometries studied under this task included shear and swirl coaxial configurations as well as an impinging jet injector.

Santoro, Robert J.↗
NASA NTRS1997

An Experimental Study of Characteristic Combustion-Driven Flow for CFD Validation

A series of uni-element rocket injector studies were completed to provide benchmark quality data needed to validate computational fluid dynamic models. A shear coaxial injector geometry was selected as the primary injector for study using gaseous hydrogen/oxygen and gaseous hydrogen/liquid oxygen propellants. Emphasis was placed on the use of non-intrusive diagnostic techniques to characterize the flowfields inside an optically-accessible rocket chamber. Measurements of the velocity and species fields were obtained using laser velocimetry and Raman spectroscopy, respectively Qualitative flame shape information was also obtained using laser-induced fluorescence excited from OH radicals and laser light scattering studies of aluminum oxide particle seeded combusting flows. The gaseous hydrogen/liquid oxygen propellant studies for the shear coaxial injector focused on breakup mechanisms associated with the liquid oxygen jet under sub-critical pressure conditions. Laser sheet illumination techniques were used to visualize the core region of the jet and a Phase Doppler Particle Analyzer was utilized for drop velocity, size and size distribution characterization. The results of these studies indicated that the shear coaxial geometry configuration was a relatively poor injector in terms of mixing. The oxygen core was observed to extend well downstream of the injector and a significant fraction of the mixing occurred in the near nozzle region where measurements were not possible to obtain Detailed velocity and species measurements were obtained to allow CFD model validation and this set of benchmark data represents the most comprehensive data set available to date As an extension of the investigation, a series of gas/gas injector studies were conducted in support of the X-33 Reusable Launch Vehicle program. A Gas/Gas Injector Technology team was formed consisting of the Marshall Space Flight Center, the NASA Lewis Research Center, Rocketdyne and Penn State. Injector geometries studied under this task included shear and swirl coaxial configurations as well as an impinging jet injector.

Santoro, Robert J.↗
NASA NTRS2014

Relationship between LIBS Ablation and Pit Volume for Geologic Samples: Applications for in situ Absolute Geochronology

In planetary sciences, in situ absolute geochronology is a scientific and engineering challenge. Currently, the age of the Martian surface can only be determined by crater density counting. However this method has significant uncertainties and needs to be calibrated with absolute ages. We are developing an instrument to acquire in situ absolute geochronology based on the K‐Ar method. The protocol is based on the laser ablation of a rock by hundreds of laser pulses. Laser Induced Breakdown Spectroscopy (LIBS) gives the potassium content of the ablated material and a mass spectrometer (quadrupole or ion trap) measures the quantity of 40Ar released. In order to accurately measure the quantity of released 40Ar in cases where Ar is an atmospheric constituent (e.g., Mars), the sample is first put into a chamber under high vacuum. The 40Arquantity, the concentration of K and the estimation of the ablated mass are the parameters needed to give the age of the rocks. The main uncertainties with this method are directly linked to the measures of the mass (typically some μg) and of the concentration of K by LIBS (up to 10%). Because the ablated mass is small compared to the mass of the sample, and because material is redeposited onto the sample after ablation, it is not possible to directly measure the ablated mass. Our current protocol measures the ablated volume and estimates the sample density to calculate ablated mass. The precision and accuracy of this method may be improved by using knowledge of the sample's geologic properties to predict its response to laser ablation, i.e., understanding whether natural samples have a predictable relationship between laser energy deposited and resultant ablation volume. In contrast to most previous studies of laser ablation, theoretical equations are not highly applicable. The reasons are numerous, but the most important are: a) geologic rocks are complex, polymineralic materials; b) the conditions of ablation are unusual (for example, variable vacuum pressure), and c) the ablation is made with hundreds of successive laser pulses. In this work, we aim to understand the effects that occur on LIBS spectra when a homogeneous rock or a mineral is ablated under high vacuum. Understanding these effects is important to define best practices for LIBS measurements and may lead to improved measurement (or possibly prediction) of the ablated volume. We will describe our laboratory approach and first results, and discuss its utility for situ absolute geochronology campaigns.

Devismes, D.↗
NASA NTRS2014

Updates of the KArLE Experiment: New Libs Calibration Under High Vacuum for the Quantification of Potassium in Basalt for In Situ Geochronology

In planetary exploration, in situ absolute geochronology is one of the main important measurements that needs to be accomplished. Until now, on Mars, the age of the surface is only determined by crater density counting, which gives relative ages. These ages can have a lot of uncertainty as they depend on many parameters. More than that, the curves must be ties to absolute ages. Thus far, only the lost lander Beagle 2 was designed to conduct absolute geochronology measurements, though some recent attempts using MSL Curiosity show that this investigation is feasible and should be strongly encouraged for future flight. Experimental: The Potassium (K)-Argon Laser Experiment (KArLE) is being developed at MSFC through the NASA Planetary Instrument Definition and Development Program (PIDDP). The goal of this experiment is to provide in situ geochronology based on the K-Ar method. A laser ablates a rock under high vacuum, creating a plasma which is sensed by an optical spectrometer to do Laser Induced Breakdown Spectroscopy (LIBS). The ablated material frees gases, including radiogenic 40Ar,which is measured by a mass spectrometer (MS). As the potassium is a content and the 40Ar is a quantity, the ablated mass needed in order to relate them. The mass is given by the product of the ablated volume by the density of this material. So we determine the mineralogy of the ablated material with the LIBS spectra and images and calculate its density. The volume of the pit is measured by using microscopy. LIBS measurement of K under high vacuum: Three independant projects [1, 2, 3] including KArLE, are developing geochronological instruments based on this LA-LIBS-MS method. Despite several differences in their setup, all of them have validated the methods with analyses and ages. However, they all described difficulties with the LIBS measurements of K [3,4]. At ambient pressure, the quantification of K by LIBS on geological materials can be accurate [5]. However the protocol of the LA-LIBS-MS experiment required hundreds of shots under high vacuum in order to free enough 40Ar* to be measured by the QMS. This long duration of ablation may induces significant changes in the LIBS spectra. The pressure may increases by orders of magnitudewithin the chamber and the laser pit geometry can change the effectiveness of ablation and intensity of plasma light received. These effects introduce variation between the first and last spectra and so the quantification of K is more complex. The ablation of one crater can give, depending on the protocol of acquisition, from tens to hundreds of spectra. Protocol and results: We are in the process of further characterizing the variation introduced into LIBS spectra by the use of hundreds of laser shots, and definining a protocol that can be used to ensure accuracy and reporoducibility in the results.We are using natural rock powder standards fused in a furnace, as well as mars analog samples with known K content. We will show the result of the calibration and some new statistical approaches in order to apprehend the effects of the long time ablation on rocks under high vacuum.

Devismes, D.↗
NASA NTRS1987

Spectral line shapes. Volume 4 - Proceedings of the Eighth International Conference, College of William and Mary, Williamsburg, VA, June 9-13, 1986

The present conference discusses topics in line broadening and shift phenomena in low-to-moderately dense plasmas, resonances in the continuum, hot and dense laser-produced plasmas, collisional broadening and intermolecular potentials, molecular broadening and collision-induced spectroscopy, collisional redistribution and laser-assisted collision processes, coherent and nonlinear spectroscopy, astrophysical line-shapes, and short-wavelength lasers. Attention is given to the widths and shifts of Be ion lines, the Stark broadening of Xe II and Fe I lines, perturbed and unperturbed series in the line-shapes of autoionizing Rydberg series, the line-broadening of hydrogenic ions in dense plasmas, Doppler-free line-shapes, the Franck-Condon principle, the dynamics of laser-assisted reactive collisions, the gas-kinetic effects of light, collision-induced processes in nonlinear optics, and line-shaping phenomena in cool stars.

Exton, Reginald J.↗
NASA NTRS1979

Infrared heterodyne spectroscopy for astrophysical applications

The paper reviews principles of laser heterodyne detection for sub-doppler spectroscopy of individual infrared spectral lines. State of the art capabilities are discussed and emphasis is placed on systems using semi-conductor diode lasers or CO2 lasers as local oscillators. Finally, the benefits of sub-doppler spectroscopy are illustrated by heterodyne spectroscopy of the atmospheres of Jupiter and Venus.

Mumma, M. J.↗
NASA NTRS1976

Laser induced fluorescence applied to turbulent reacting flows

The saturated fluorescence method makes use of the great simplifications which occur when under conditions of intense radiation the excitation process becomes saturated. A description is presented of the saturated fluorescence method, taking into account rate equations and saturation, radiative transfer, the two-level system, a multilevel system, and measurements under saturation conditions. The detectability limits of the method are investigated. Fluorescence trapping is found to place an upper limit on the number density of the fluorescing species that can be measured without signal loss. Turbulence places time and spatial constraints on the measurements, but otherwise poses no difficulties. Saturated laser induced fluorescence spectroscopy appears to be a most promising method for measuring species concentrations in flames.

Daily, J. W.↗
NASA NTRS1984

Far-infrared laser magnetic resonance of vibrationally excited CD2

The detection of 13 rotational transitions in the first excited bending state (010) of CD2 using the technique of far-infrared laser magnetic resonance spectroscopy is reported. Molecular parameters for this state are determined from these new data together with existing infrared observations of the v(2) band. Additional information on the ground vibrational state (000) is also provided by the observation of a new rotational transition, and this is combined with existing data to provide a refined set of molecular parameters for the CD2 ground state. One spectrum has been observed that is assigned as a rotational transition within the first excited symmetric stretching state (100) of CD2. These data will be of use in refining the structure and the potential function of the methylene radical.

Evenson, K. M.↗
NASA NTRS1986

Development of high-efficiency solar cells on silicon web

Achievement of higher efficiency cells by directing efforts toward identifying carrier loss mechanisms; design of cell structures; and development of processing techniques are described. Use of techniques such as deep-level transient spectroscopy (DLTS), laser-beam-induced current (LBIC), and transmission electron microscopy (TEM) indicated that dislocations in web material rather than twin planes were primarily responsible for limiting diffusion lengths in the web. Lifetimes and cell efficiencies can be improved from 19 to 120 microns, and 8 to 10.3% (no AR), respectively, by implanting hydrogen at 1500 eV and a beam current density of 2.0 mA/sq cm. Some of the processing improvements included use of a double-layer AR coating (ZnS and MgF2) and an addition of an aluminum back surface reflectors. Cells of more than 16% efficiency were achieved.

Meier, D. L.↗
NASA NTRS1988

Laser Diagnostics for combustion temperature and species measurements

Laser optical diagnostic techniques for the measurement of combustion gaseous-phase temperatures and, or species concentrations are discussed. The techniques fall into two classes: incoherent (Rayleigh scattering, spontaneous Raman scattering, laser induced fluorescence spectroscopy) and coherent (coherent anti-Stokes Raman spectroscopy). The advantages, disadvantages and applicability of each method are outlined.

Eckbreth, Alan C.↗
NASA NTRS1990

Absorption coefficients for the 6190-A CH4 band between 290 and 100 K with application to Uranus' atmosphere

A novel laser intracavity photoacoustic spectroscopy method allowing high sample control accuracy due to the small sample volume required has been used to obtain absorption coefficients for the CH4 6190 A band as a function of temperature, from 290 to 100 K. The peak absorption coefficient is found to increase from 0.6 to 1.0/cm, and to be accompanied by significant band shape changes. When used to further constrain the Baines and Bergstrahl (1986) standard model of the Uranus atmosphere, the low-temperature data yield an excellent fit to the bandshape near the 6190 A band's minimum.

Smith, Wm. Hayden↗
NASA NTRS1990

The C9 cluster - Structure and infrared frequencies

A structural characterization is presented for C9, the largest cluster predicted to have a linear ground state. IR laser diode absorption spectroscopy of a supersonic carbon jet is used to measure 51 lines of the nu6 (sigma u) antisymmetric stretch fundamental transition within the linear 1Sigma(g)+ ground electronic state of C9. The measured ground state rotational constant suggests an effective C-C bond length which is in good agreement with ab initio theory and consistent with cumulenic bonding in this cluster.

Heath, J. R.↗
NASA NTRS1991

MPD thruster research issues, activities, strategies

The following activities and plans in the MPD thruster development are summarized: (1) experimental and theoretical research (magnetic nozzles at present and high power levels, MPD thrusters with applied fields extending into the thrust chamber, and improved electrode performance); and (2) tools (MACH2 code for MPD and nozzle flow calculation, laser diagnostics and spectroscopy for non-intrusive measurements of flow conditions, and extension to higher power). National strategies are also outlined.

Source record↗
NASA NTRS1991

Chemical nature of the barrier in Pb/YBa2Cu3O(7-x) tunneling structures

Several reports of reproducible tunneling measurements on YBa2Cu3O(7-x) thin films or single crystals with a Pb counterelectrode have recently appeared. The nature of the tunnel barrier, formed by air exposure, in these structures has been unknown. In the present work, the chemical nature of the tunnel barrier is studied with X-ray photoelectron spectroscopy (XPS). Laser-ablated films grown on LaAlO3 which have been chemically etched and heated in air are found to form nonsuperconducting surface Ba species, evident in an increase of the high binding energy Ba 3d and O 1s signals. A deposited Pb film about 10 A thick is found to be oxidized, and Cu(+2) is partially reduced to Cu(+1). The tunneling barrier thus appears to consist of species resulting from a combination of the air exposure and a reaction between the superconductor and the deposited Pb counterelectrode.

Vasquez, R. P.↗
NASA NTRS1993

MSFC orbital spacecraft development emphases for this decade

Historically, the Marshall Space Flight Center (MSFC) has been responsible for significant accomplishments in the area of developing both manned and unmanned spacecraft. MSFC is presently involved in many of NASA's largest and most prominent programs, with some operational, others being readied for flight, and still others in various stages of design and development. Examples of MSFC programs being designed or developed are Space Station Freedom (S.S. Freedom), the Advanced X-Ray Astrophysics Facility (AXAF) which includes imaging and spectroscopy facilities, the Laser Atmospheric Wind Sounder (LAWS), and the Lunar Ultraviolet Telescope Experiment (LUTE), with Spacelab and Tethered Satellite System (TSS) as examples of current operational MSFC spacecraft. The information obtained from the Long Duration Exposure Facility (LDEF) will aid the design process and life predictions for these and all future spacecraft. A second LDEF is presently being considered. All of these projects will be briefly described in this paper.

Schwinghamer, Robert J.↗
NASA NTRS1995

High-Temperature Optical Window Design

A high-temperature optical window is essential to the optical diagnostics of high-temperature combustion rigs. Laser Doppler velocimetry, schlieren photography, light sheet visualization, and laser-induced fluorescence spectroscopy are a few of the tests that require optically clear access to the combustor flow stream. A design was developed for a high-temperature window that could withstand the severe environment of the NASA Lewis 3200 F Lean Premixed Prevaporized (LPP) Flame Tube Test Rig. The development of this design was both time consuming and costly. This report documents the design process and the lessons learned, in an effort to reduce the cost of developing future designs for high-temperature optical windows.

Roeloffs, Norman↗
NASA NTRS1996

Trace Element Zoning and Incipient Metamictization in a Lunar Zircon: Application of Three Microprobe Techniques

We have determined major (Si, Zr, Hf), minor (Al, Y, Fe, P), and trace element (Ca, Sc, Ti, Ba, REE, Th, U) concentrations and Raman spectra of a zoned, 200 microns zircon grain in lunar sample 14161,7069, a quartz monzodiorite breccia collected at the Apollo 14 site. Analyses were obtained on a thin section in situ with an ion microprobe, an electron microprobe, and a laser Raman microprobe. The zircon grain is optically zoned in birefringence, a reflection of variable (incomplete) metamictization resulting from zo- nation in U and Th concentrations. Variations in the concentrations of U and Th correlate strongly with those of other high-field-strength trace elements and with changes in Raman spectral parameters. Concentrations of U and Th range from 21 to 55 ppm and 6 to 31 ppm, respectively, and correlate with lower Raman peak intensities, wider Raman peaks, and shifted Si-O peak positions. Concentrations of heavy rare earth elements range over a factor of three to four and correlate with intensities of fluorescence peaks. Correlated variations in trace element concentrations reflect the original magmatic differentiation of the parental melt approx. 4 b.y. ago. Degradation of the zircon structure, as reflected by the observed Raman spectral parameters, has occurred in this sample over a range of alpha-decay event dose from approx. 5.2 x 10(exp 14) to 1.4 x 10(exp 15) decay events per milligram of zircon, as calculated from the U and Th concentrations. This dose is well below the approx. 10(exp 16) events per milligram cumulative dose that causes complete metamictization and indicates that laser Raman microprobe spectroscopy is an analytical technique that is very sensitive to the radiation-induced damage in zircon.

Wopenka, Brigitte↗