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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21

Dynamic Implications of Noncovalent Interactions in Amphiphilic Single-Chain Polymer Nanoparticles

Single-chain polymer nanoparticles (SCNPs) combine the chemical diversity of synthetic polymers with the intricate structure of biopolymers, generating versatile biomimetic materials. The mobility of polymer chain segments at length scales similar to secondary structural elements in proteins is critical to SCNP structure and thus function. However, the influence of noncovalent interactions used to form SCNPs (e.g., hydrogen-bonding and biomimetic secondary-like structure) on these conformational dynamics is challenging to quantitatively assess. To isolate the effects of noncovalent interactions on SCNP structure and conformational dynamics, we synthesized a series of amphiphilic copolymers containing dimethylacrylamide and monomers capable of forming these different interactions: (1) di(phenylalanine) acrylamide that forms intramolecular β-sheet-like cross-links, (2) phenylalanine acrylamide that forms hydrogen-bonds but lacks a defined local structure, and (3) benzyl acrylamide that has the lowest propensity for hydrogen-bonding. Each SCNP formed folded structures comparable to those of intrinsically disordered proteins, as observed by size exclusion chromatography and small angle neutron scattering. The dynamics of these polymers, as characterized by a combination of dynamic light scattering and neutron spin echo spectroscopy, was well described using the Zimm with internal friction (ZIF) model, highlighting the role of each noncovalent interaction to additively restrict the internal relaxations of SCNPs. These results demonstrate the utility of local scale interactions to control SCNP polymer dynamics, guiding the design of functional biomimetic materials with refined binding sites and tunable kinetics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NGEE Arctic Tram: Periodic Soil CO2 and CH4 Flux Chamber Measurements across Polygonal Tundra, Utqiagvik (Barrow), Alaska, 2014-2017

Soil chamber flux measurements made from a 2014-2017 adjacent to the TRAM system, with measurements referenced to TRAM stop numbers. Dataset includes measurements using transparent and opaque chambers (CO2 and CH4 fluxes in light and dark). The Tram location was selected to be in the footprint of the NGEE Arctic AmeriFlux tower (US-NGB). Measurement stop positions are at 0.5 m intervals (1-137) over the 68 m Tram track. Dataset includes one CSV data file and one user guide in PDF. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Concept definition study for an extremely large aerophysics range facility

The development of a large aerophysical ballistic range facility is considered to study large-scale hypersonic flows at high Reynolds numbers for complex shapes. A two-stage light gas gun is considered for the hypervelocity launcher, and the extensive range tankage is discussed with respect to blast suppression, model disposition, and the sabot impact tank. A layout is given for the large aerophysics facility, and illustrations are provided for key elements such as the guide rail. The paper shows that such a facility could be used to launch models with diameters approaching 250 mm at velocities of 6.5 km/s with peak achievable accelerations of not more than 85.0 kgs. The envisioned range would provide gas-flow facilities capable of controlling the modeled quiescent atmospheric conditions. The facility is argued to be a feasible and important step in the investigation and experiment of such hypersonic vehicles as the National Aerospace Plane.

Swift, H.↗

Experimental and theoretical investigations of rotating algae biofilm reactors (RABRs): Areal productivity, nutrient recovery, and energy efficiency

Microalgae biofilms have been demonstrated to recover nutrients from wastewater and serve as biomass feedstock for bioproducts. However, there is a need to develop a platform to quantitatively describe microalgae biofilm production, which can provide guidance and insights for improving biomass areal productivity and nutrient uptake efficiency. Here, this paper proposes a unified experimental and theoretical framework to investigate algae biofilm growth on a rotating algae biofilm reactor (RABR). Experimental laboratory setups are used to conduct controlled experiments on testing environmental and operational factors for RABRs. We propose a differential–integral equation‐based mathematical model for microalgae biofilm cultivation guided by laboratory experimental findings. The predictive mathematical model development is coordinated with laboratory experiments of biofilm areal productivity associated with ammonia and inorganic phosphorus uptake by RABRs. The unified experimental and theoretical tool is used to investigate the effects of RABR rotating velocity, duty cycle (DC), and light intensity on algae biofilm growth, areal productivity, nutrient uptake efficiency, and energy efficiency in wastewater treatment. Our framework indicates that maintaining a reasonable light intensity range improves biomass areal productivity and nutrient uptake efficiency. Our framework also indicates that faster RABR rotation benefits biomass areal productivity. However, maximizing the nutrient uptake efficiency requires a reasonably low RABR rotating speed. Energy efficiency is strongly correlated with RABR rotating speed and DC.

09 BIOMASS FUELS↗

Large Deployable Shroud

Preliminary design proposed for large, lightweight telescope shroud or light shield carried to orbit in single Space Shuttle cargo load. Shroud concept applied on Earth in portable, compactly storable displays or projection screens. Large telescope shroud includes four deployable masts erecting eight walls of hinged panels of polyimide film. Panels stored fanfolded before deployment and threaded on guide wires unwinding from spools and remain taut during deployment.

Jacquemin, G. G.↗

Cross Section Sensitivity and Propagated Errors in HZE Exposures

It has long been recognized that galactic cosmic rays are of such high energy that they tend to pass through available shielding materials resulting in exposure of astronauts and equipment within space vehicles and habitats. Any protection provided by shielding materials result not so much from stopping such particles but by changing their physical character in interaction with shielding material nuclei forming, hopefully, less dangerous species. Clearly, the fidelity of the nuclear cross-sections is essential to correct specification of shield design and sensitivity to cross-section error is important in guiding experimental validation of cross-section models and database. We examine the Boltzmann transport equation which is used to calculate dose equivalent during solar minimum, with units (cSv/yr), associated with various depths of shielding materials. The dose equivalent is a weighted sum of contributions from neutrons, protons, light ions, medium ions and heavy ions. We investigate the sensitivity of dose equivalent calculations due to errors in nuclear fragmentation cross-sections. We do this error analysis for all possible projectile-fragment combinations (14,365 such combinations) to estimate the sensitivity of the shielding calculations to errors in the nuclear fragmentation cross-sections. Numerical differentiation with respect to the cross-sections will be evaluated in a broad class of materials including polyethylene, aluminum and copper. We will identify the most important cross-sections for further experimental study and evaluate their impact on propagated errors in shielding estimates.

Heinbockel, John H.↗

Preparing Lamellae from Vitreous Biological Samples using a Dual-Beam Scanning Electron Microscope for Cryo-Electron Tomography

Presented here is a protocol for preparing cryo-lamellae from plunge-frozen grids of Plasmodium falciparum-infected human erythrocytes, which could easily be adapted for other biological samples. The basic principles for preparing samples, milling, and viewing lamellae are common to all instruments and the protocol can be followed as a general guide to on-grid cryo-lamella preparation for cryo-electron microscopy (cryoEM) and cryo-electron tomography (cryoET). Electron microscopy grids supporting the cells are plunge-frozen into liquid nitrogen-cooled liquid ethane using a manual or automated plunge freezer, then screened on a light microscope equipped with a cryo-stage. Frozen grids are transferred into a cryo-scanning electron microscope equipped with a focused ion beam (cryoFIB-SEM). Grids are routinely sputter coated prior to milling, which aids dispersal of charge build-up during milling. Alternatively, an e-beam rotary coater can be used to apply a layer of carbon-platinum to the grids, the exact thickness of which can be more precisely controlled. Once inside the cryoFIB-SEM an additional coating of an organoplatinum compound is applied to the surface of the grid via a gas injection system (GIS). This layer protects the front edge of the lamella as it is milled, the integrity of which is critical for achieving uniformly thin lamellae. Regions of interest are identified via SEM and milling is carried out in a step-wise fashion, reducing the current of the ion beam as the lamella reaches electron transparency, in order to avoid excessive heat generation. A grid with multiple lamellae is then transferred to a transmission electron microscope (TEM) under cryogenic conditions for tilt-series acquisition. A robust and contamination-free workflow for lamella preparation is an essential step for downstream techniques, including cellular cryoEM, cryoET, and sub-tomogram averaging. Development of these techniques, especially for lift-out and milling of high-pressure frozen samples, is of high-priority in the field.

59 BASIC BIOLOGICAL SCIENCES↗

Progress in the Fabrication and Testing of Telescope Mirrors for the James Webb Space Telescope

The telescope of the James Webb Space Telescope (JWST) is an f/20, three mirror anastigmat design, passively cooled (40K) in an L2 orbit. The design provides diffraction limited performance (Strehl > or = 0.8) at .=2 m. To fit within the launch vehicle envelope (Arianne V), the 6.6 meter primary mirror and the secondary mirror support structure are folded for launch, then deployed and aligned in space. The primary mirror is composed of 18 individual, 1.3 meter (flat flat) hexagonal segments, each adjustable in seven degrees of freedom (six rigid body + radius of curvature) provided by a set of high precision actuators. The actuated secondary mirror (approx.0.74m) is similarly positioned in six degrees of rigid body motion. The approx..70x.51m, fixed tertiary and approx. 0.17m, flat fine steering mirror complete the telescope mirror complement. The telescope is supported by a composite structure optimized for performance at cryogenic temperatures. All telescope mirrors are made of Be with substantial light-weighting (21 kg for each 1.3M primary segment). Additional Be mounting and supporting structure for the high precision (approx.10nm steps) actuators are attached to the primary segments and secondary mirror. All mirrors undergo a process of thermal stabilization to reduce stress. An extensive series of interferometric measurements guide each step of the polishing process. Final polishing must account for any deformation between the ambient temperature of polishing and the cryogenic, operational temperature. This is accomplished by producing highly precise, cryo deformation target maps of each surface which are incorporated into the final polishing cycle. All flight mirrors have now completed polishing, coating with protected Au and final cryo testing, and the telescope is on track to meet all system requirements. We here review the measured performance of the component mirrors and the predicted performance of the flight telescope.

Bowers, Charles↗

NGST/XRCF Design and Build Wavescope System Pallet

Based on the successful Wavescope demonstration at MSFC at the end of March, the decision was made by the optical testing team to purchase an upgraded Wavescope from AOA. The MSFC version would include: a higher resolution camera (1000 x 1000 pixels); a higher density lenslet array (150 x 150); updated software; and longer cables (to accommodate the remote operation of the Wavescope optical head which was resident in the Beam Guide Tube). The AOA proposal for the new instrument was received in mid-April, and delivered to MSFC in mid-July. A considerable amount of effort was expended to provide the infrastructure needed for Wavescope operation, and to incorporate it into the overall test system. This was provided by the Wavescope System Pallet (WSP) built by UAH. The WSP is illustrated. Several instruments are incorporated on this pallet. These include the: Wavescope optical head; a PDI wavefront sensor; a point spread function sensor; a Leica light-based distance measuring sensor. In addition there is a single mode fiber point source (fed from a separate source pallet) which serves both as a reference for the Wavescope and as a source point for the test mirror. There is a dual function lens which both collimates the beam from the test image point, and images the test mirror onto the lenslet array. There is a high quality Collimator which can provide a flat input wavefront directly into the Wavescope. There are also various aids such as an alignment laser, an alignment telescope, alignment sticks and apertures. The WSP was delivered to MSFC on 7/28/99. An picture shows the WSP installed in the Guide Tube at the X-Ray Calibration Facility (XRCF).

Geary, Joe↗

Quantification of heterogeneity in human CD8 + T cell responses to vaccine antigens: an HLA-guided perspective

Vaccines have historically played a pivotal role in controlling epidemics. Effective vaccines for viruses causing significant human disease, e.g., Ebola, Lassa fever, or Crimean Congo hemorrhagic fever virus, would be invaluable to public health strategies and counter-measure development missions. Here, we propose coverage metrics to quantify vaccine-induced CD8 + T cell-mediated immune protection, as well as metrics to characterize immuno-dominant epitopes, in light of human genetic heterogeneity and viral evolution. Proof-of-principle of our approach and methods are demonstrated for Ebola virus, SARS-CoV-2, and Burkholderia pseudomallei (vaccine) proteins.

60 APPLIED LIFE SCIENCES↗

On-line installation of the Superallowed Transition Beta-Neutrino Decay Ion Coincidence Trap

The Cabibbo-Kobayashi-Maskawa quark mixing matrix currently does not satisfy unitarity at the 2σ-level. This could be the result of an inaccurate value of one or both of its largest matrix elements V us and V ud . In the case of V ud , the most precise measurement is obtained from the f t -value measurements of superallowed beta-transitions between 0 + states. The accuracy of this determination can, in turn, be tested by extracting V ud in other transitions including superallowed transitions between mirror nuclei. The Superallowed Transition Beta-Neutrino Decay Ion Coincidence Trap (St. Benedict) is currently under construction at the Nuclear Science Laboratory of the University of Notre Dame to perform such a determination, with the goal of shedding more light on this tension with unitarity. St. Benedict will take a radioactive ion beam produced by TwinSol , thermalize it in a large volume gas catcher, then transport it in two separate differentially-pumped volumes using a radio-frequency (RF) carpet and a radio-frequency quadrupole (RFQ) ion guide before injecting it in an RFQ trap to create cool ion bunches for injection in the measurement Paul trap. In this paper, we detail the installation of the beam preparation components of St. Benedict, and present the results of the first RIBs successfully stopped and extracted from its gas catcher.

Brodeur, M.↗

Angular distribution of interstellar Al-26

The angular distribution and local concentration of interstellar Al-26 are calculated for five theoretical models of its origin, as a guide for future observations. The models considered relate Al-26 to current star formation (with surface CO density as its indicator), treat Al-26 as a secondary-nucleosynthesis product on seed nuclei with the same metallicity gradient as O, assume the Al-26 ejection rate is proportional to present light output, make Al-26 synthesis depend on total H I + H2 gas density, or assume that Al-26 is formed mainly in novae. The local decay and production rates for the five models are found to lie within a factor of 2 of surface density 0.0003/sq cm s, corresponding to a present (Al-26)/(Al-27) ratio of 5 x 10 to the -6th averaged over H I and H2 phases.

Leising, M. D.↗

Distributed Optoelectronic Proximity Sensor

Optoelectronic proximity sensor comprises seven identical units functioning together to provide partially redundant data on spatial relationship between sensor and nearby diffusely reflecting surface. Provides data on distance, relative orientation, and curvature of surface. Sensor called "Hexeye" because its units exhibit hexagonal symmetry when viewed along optical axes and mounted together in hexagonal close packing. Because all six arrays of photodetectors in unit measure essentially identical distributions of light in operating mode, each provides redundant information averaged to increase accuracy or used to verify operation of others. Malfunctioning photodector identified, and output ignored or replaced by interpolated value. Developed for use in such robotic applications as noncontact probing or scanning of surfaces, localization and recognition of objects, and guiding "smart" robot hands in grasping objects.

Lee, Sukhan↗

An Efficient End-To-End Model for the Kepler Photometer

The Kepler Mission is designed to characterize the frequency of Earth-sized planets in the habitable zones of solar-like stars in the solar galactic neighborhood by observing >100,000 main-sequence stars in a >100 square degree field of view (FOV) and seeking evidence of transiting planets. As part of the system engineering effort, we have developed an End-To-End Model (ETEM) of the photometer to better characterize the expected performance of the instrument and to guide us in making design trades. This model incorporates engineering information such as the point spread function, time histories of pointing offsets, operating temperature, quantization noise, the effects of shutterless readout, and read noise. Astrophysical parameters, such as a realistic distribution of stars vs. magnitude for the chosen FOV, zodiacal light, and cosmic ray events are also included. For a given set of design and operating parameters, ETEM generates pixel time series for all pixels of interest for a single CCD channel of the photometer. These time series are then processed to form light curves for the target stars and the impact of various noise sources on the combined differential photometric precision can be determined. This model is of particular value when investigating the effects of noise sources that cannot be easily subjected to direct analysis, such as residual pointing offsets, thermal drift or cosmic ray effects. This version of ETEM features extremely efficient computation times relative to the previous version while maintaining a high degree of fidelity with respect to the realism of the relevant phenomena.

performance modeling↗

Advanced Fuels Campaign Execution Plan

The Advanced Fuels Campaign (AFC) Execution Plan details the strategy, mission, scope, and goals—both near-term and long-term—along with the structure and organization of nuclear fuels and materials research, development, and demonstration (RD&D) activities within the Fuel Cycle Technologies (FCT) program. The FCT program, tasked by the U.S. Department of Energy (DOE), employs a science-based approach to advance fuel technologies. This approach integrates theory, experiments, and multi-scale modeling and simulation (M&S) to develop a predictive understanding of fuel fabrication processes and fuel/cladding performance under irradiation, moving beyond traditional empirical methods. The long-term goals of the AFC are guided by the AFC Strategic Plan and align with the DOE Office of Nuclear Energy (NE) Roadmap [1], which outlines a multi-decade vision for demonstrating and qualifying advanced fuel forms to support diverse fuel cycle options. Near-term goals focus on enhancing accident tolerant fuels (ATF) for Light Water Reactors (LWR), a significant challenge that demands balancing immediate objectives with ongoing progress toward advanced reactor missions. Accelerating the traditional fuel qualification process to meet ATF objectives is another critical challenge. A detailed set of 5-year goals, summarized below, has been developed in line with the overarching science-based fuel development approach: • Advanced LWR Fuel Technologies: By 2027, support the development of advanced LWR fuel technologies with improved performance and enhanced accident tolerance. This includes high burnup (HBu), low enriched uranium (LEU)+, coated cladding, and doped fuel, aimed at complementing industry-led significant LWR uprates and plant refurbishments. • Tristructural Isotropic (TRISO) Fuel: Achieve qualification by 2028 and develop improved designs for emerging markets. • Metal Fuel: Achieve qualification by 2028 and develop improved designs for emerging markets. • Molten Salt Fuel: By 2027, deploy a robust program that enables fuel salt qualification technologies needed to support fuel salt research and development (R&D), focusing on emergent needs to derisk fuel salt production and utilization in advanced reactors. • Long-Term ATF: Develop fuel technologies that enable significant power uprates (~50%) in refurbished or new LWRs while optimizing fissile material utilization and waste disposal. The 5-year milestones in the AFC Execution Plan are contingent on an assumed budget. This Execution Plan will be updated annually to reflect actual funding profiles as budget guidance becomes available, ensuring milestones are adjusted accordingly. In summary, the AFC Execution Plan presents a comprehensive strategy to advance nuclear fuel technologies through a science-based approach, addressing both near-term and long-term goals while adapting to funding realities.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Performance Assurance Planning Guide for Utility Energy Service Contracts: 2025 Edition

Administered by the U.S. Department of Energy's (DOE) Federal Energy Management Program (FEMP), the Utility Program has fostered collaboration among federal agencies and their serving utilities for more than 25 years. The Utility Program supports agencies using Utility Energy Service Contracts (UESCs), a well-developed, effective contracting vehicle that enable the latest approaches to cost-effective energy management at federal sites. Federal agencies have successfully used UESCs to award over 2,000 energy and water efficiency and renewable energy projects, investing approximately $\$$2.8 billion in furthering the Federal Government's efforts to reduce energy intensity. Authorized by 42 U.S. Code section 8256 (10 U.S. Code section 2913 for the Department of Defense), a UESC is a limited-source acquisition between a federal agency and an eligible serving utility for energy management services that generate savings from the implementation of energy- and water -conservation measures (collectively referred to as ECMs), with 42 U.S. Code section 8287 (Defense Federal Acquisition Regulation Supplement, Part 241), providing the term of a UESC, which may extend up to 25 years. Through a UESC, the utility partner assesses designs, and implements the desired ECMs - which can range from lighting retrofits and renewable energy systems, to combined heat and power plants or other technologies and strategies, and may provide financing for the project. The agency may use any combination of appropriations and third-party financing to pay for the project, providing useful flexibility. There is no limit to the project size, big or small, that can be implemented using a UESC. To assist agencies implementing a UESC, FEMP has developed a Utility Energy Service Contract Guide and this companion guidance document to help agencies and their utility partners better understand the best practices for to ensure UESCs continue to perform and generate savings throughout their performance period. These best practices utilize a combination of effective project management, communication, documentation, and a detailed Performance Assurance Plan. This plan is a project specific set of actionable protocols that define important tasks and responsibilities throughout the contract term and reflects the site conditions, complexities, agency capabilities, and operating and maintaining planned ECMs.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Rethinking agrivoltaic incentive programs: A science-based approach to encourage practical design solutions

Agrivoltaic systems are promising solutions to address global food and energy challenges by combining agriculture and solar photovoltaics. However, the lack of appropriate regulations to define and guide their implementation constrains the growth of agrivoltaic systems in the U.S. This study uses a shading and radiation tool to evaluate an existing agrivoltaic incentive program that defines agrivoltaic designs based on shading reduction limits and panel height requirements. Our analysis indicates that structuring policy requirements around shading, and not light availability, may lead to an underestimation of crop suitability by neglecting diffuse radiation. Furthermore, we show that agrivoltaic systems can avoid increasing panel height if policy acknowledges use-case scenarios where farming only occurs between rows. In light of these insights, this study proposes two key policy recommendations: (1) benchmark crop suitability based on daily light integral (DLI) requirements for a shade-intolerant crop selected to represent a prevalent crop in the region, and (2) include an incentive scenario where agriculture is only required between rows. Furthermore, these two recommendations can potentially incentivize designs that are practical and closer in cost to conventional solar farms, thereby accelerating the adoption of cost-effective agrivoltaic systems.

14 SOLAR ENERGY↗

The Cosmology Large Angular Scale Surveyor (CLASS): 40 GHz Optical Design

The Cosmology Large Angular Scale Surveyor (CLASS) instrument will measure the polarization of the cosmic microwave background at 40, 90, and 150 GHz from Cerro Toco in the Atacama desert of northern Chile. In this paper, we describe the optical design of the 40 GHz telescope system. The telescope is a diffraction limited catadioptric design consisting of a front-end Variable-delay Polarization Modulator (VPM), two ambient temperature mirrors, two cryogenic dielectric lenses, thermal blocking filters, and an array of 36 smooth-wall scalar feedhorn antennas. The feed horns guide the signal to antenna-coupled transition-edge sensor (TES) bolometers. Polarization diplexing and bandpass definition are handled on the same microchip as the TES. The feed horn beams are truncated with 10 dB edge taper by a 4 K Lyot-stop to limit detector loading from stray light and control the edge illumination of the front-end VPM. The field-of-view is 19 deg x 14 deg with a resolution for each beam on the sky of 1.5 deg. FWHM.

Eimer, Joseph R.↗