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At least 379 records · Page 21

The impact of chromium coatings on Zircaloy cladding deformation behavior under reactivity-initiated accident-like mechanical loading conditions

A reactivity-initiated accident (RIA) occurs when a control rod ejection or control blade drop causes an increase in the fission rate. The injection of energy results in an increase in fuel temperature which in turn causes rapid thermal expansion of the fuel pellet. This thermal expansion may result in pellet-cladding mechanical interaction (PCMI) in which the fuel imparts a mechanical strain to the cladding. PCMI may cause the cladding to fail, and thus, the mechanical response of cladding due to PCMI must be investigated when characterizing new cladding materials. Chromium-coated Zircaloy-4 is a near-term accident-tolerant fuel cladding that exhibits improved high-temperature oxidation resistance. Modified burst testing was utilized to experimentally simulate the effects of PCMI on both uncoated and chromium-coated Zircaloy cladding samples at hot zero power conditions. Samples were coated using either cold spraying or physical vapor deposition to understand the differences in behavior that the coating application method may cause. Digital image correlation was used to analyze images of the deforming specimens to extract the in-situ strain behavior of the cladding. The uncoated specimens burst at hoop strains ranging from 8.8 % to 17.2 %. The cold-spray chromium-coated Zircaloy specimens burst at hoop strains of 7.0 % to 11.0 %. The physical vapor deposition coated tubes burst at hoop strains of 9.1 % to 11.5 %. These results indicate that the chromium coating causes a loss in the ductility of the cladding. Furthermore, the higher burst hoop strains of the physical vapor deposition-coated samples relative to the cold-spray samples indicate that the cold-spraying technique causes more of a loss in ductility than physical vapor deposition. All samples burst at higher hoop strains than those expected to occur in an RIA for fresh cladding.

Accident-tolerant fuel↗

Hierarchical low Pt-loading “core-shell” electrocatalysts for the oxygen reduction reaction in fuel cells

The sluggish kinetics of the oxygen reduction reaction (ORR) hinder cost-effective polymer electrolyte fuel cells (PEFCs), which rely on scarce, expensive platinum-based electrocatalysts (ECs). Here, we present a novel synthesis method for ORR ECs achieving exceptional platinum utilization. The design features a hierarchical “multi-carbon” support comprising carbon nanoparticles interacting with graphene nanoplatelets as the “core”, encapsulated by a porous carbon nitride (CN) “shell”. This configuration promotes strong core/shell interactions and a bimodal active site distribution, consisting of chemically dispersed Pt and Ni single-atom complexes and PtNix alloy nanoclusters embedded in the CN shell. These advantages enable high activity and durability, achieving an ORR activity of 1.6 A mgPt−1 at 0.9 V vs. RHE-an order of magnitude higher than Pt/C (0.17 A mgPt−1). A proof-of-concept PEFC demonstrates a specific power of 12.0 kW gPt−1 at 0.60 V. This approach offers a significant step toward more efficient and sustainable PEFC technologies.

Pagot, Gioele [University of Padova, Italy]↗

Shock compression of additively manufactured high solids loaded polymer composites with aligned porosity

The effects of aligned porosity on the shock-compression response of additively manufactured (AM) composite structures with collinear and log-cabin geometries are investigated. The composites contain two inorganic and two organic particle populations and a UV-curable polymer binder. X-ray phase contrast imaging (X-PCI) is used as an in-material diagnostic in plate-impact experiments performed at the Dynamic Compression Sector of the Advanced Photon Source at the Argonne National Laboratory. Macroscale shock and particle velocities and microscale pore collapse velocities are measured from X-PCI images obtained from samples impacted in various orientations relative to the AM build directions. The linear shock and particle velocity relation for the structures with collinear build geometry shows directional differences, with the build direction exhibiting the highest slope and the filament print direction having the shallowest slope. Composites with log-cabin geometry, due to their slightly lower porosity and smaller sized pores, show higher shock velocities than the collinear structures at the same particle velocity. Microscale directionality effects are also observed, with the pore collapse velocity dependent on the pore configuration. Specifically, the pore collapse velocity is highest for pores elongated along the impact direction which is the case for the colinear structures impacted in the filament print direction, which is consistent with the directionality trend observed in the data for the shock and particle velocity equation of state. The pore collapse velocity approaches ∼80 % of the shock velocity and is several times the average bulk particle velocity, suggesting a highly hydrodynamic mechanism of pore collapse. Overall, both the macroscale response as measured by the shock and particle velocity relationship, and the microscale response as measured by the pore collapse velocity, are found to be anisotropic and dependent on the AM composite structure.

Wagner, K. B. [Georgia Institute of Technology, At↗

Flexible operation of nuclear hybrid energy systems for load following and water desalination

Nuclear hybrid energy systems (NHES) have the potential to provide dependable and emission-free electricity to the grid while also increasing the flexibility and reliability of the electrical grid. Molten salt reactor (MSR) technology can provide consistent, carbon-free electricity while also increasing efficiency, security, and sustainability and reducing nuclear waste. This study investigates the integration of Molten Salt Reactors (MSR) and conventional Pressurized Water Reactors (PWR) with desalination technologies: Direct Contact Membrane Distillation (DCMD), Multi-Stage Flash Distillation (MSFD), and Reverse Osmosis (RO). Dynamic first-principles models were developed and tested using real grid data from the New York Independent System Operator. The results demonstrate that nuclear power is capable of flexibly responding to changing grid demand while simultaneously producing clean water, particularly during periods of low electricity demand. The MSR-RO system was found to be the most efficient in electricity generation and water production, and all hybrid systems reduced CO2 emissions by 356,000 to 682,000 tons annually. Economic analysis reveals that nuclear desalination technologies are cost-competitive with conventional systems, especially when paired with RO. Finally, these findings confirm the technical feasibility and environmental benefits of nuclear hybrid systems for sustainable electricity and water production.

24 POWER TRANSMISSION AND DISTRIBUTION↗