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At least 379 records · Page 21

Theoretical study of the spectroscopy of Al2

The present study of the singlet and triplet states of Al2 below about 30,000/cm at the multireference configuration-interaction level attempts to identify and characterize the band systems in both the singlet and triplet manifolds. The spectroscopy of Al2 can be understood in terms of an X 3Pi(u) ground state. Calculations suggest that the assignments of the E and F systems recently noted in a jet-cooled beam are correct, although remaining differences between theoretical and experimental spectroscopic constants and radiative lifetimes preclude a definitive assignment.

Langhoff, Stephen R.↗

Complete the development and construction of a spaceborne hydrogen maser clock

The objective, to complete the development of an engineering model of a spaceborne hydrogen maser, was successfully achieved. A layout of the maser and detail drawings of the physics package was completed during the first 7 months of the contract. A computer model was made for the maser's thermal design. Using numerical computations, heater resistances were established for 7 temperature controlled zones. The physics package includes: a vacuum manifold that houses four sorption pumps capable of scavenging hydrogen for 4 years, a titanium vacuum tank housing the cavity, metallic seals for all vacuum joints, an RF dissociator within the vacuum envelope, a two-layer printed circuit solenoid and four layers of moly-permalloy magnetic shields. Problems were encountered and overcome in the procurements of the PC solenoid and the magnetic shields. After completion of the fabrication of the maser's components, the maser was assembled using these parts and other components made available by SAO, NRL, and NASA from earlier development work. In March, 1990, the vacuum system was assembled, and by May the maser assembly was completed. The magnetic shielding was poor and the shields were removed, reannealed by a local vendor, and the maser was reassembled. The maser began tests in early June and has been oscillating since that time. The test results of the maser are very good and a life test of the maser is being conducted. It is anticipated that the development and construction of a maser to be tested in space under a new contract from NASA's Marshall Space Flight Center will continue.

Vessot, Robert F. C.↗

New method of making advanced tube-bundle rocket thrust chambers

An improved method of fabrication rocket chambers for future space applications is described. Included are fabrication demonstrator and test chambers produced by this method. This concept offers the promise of improved cyclic life, reusability, and performance. The performance is improved because of the enhanced enthalpy extraction. The improved cyclic life, reusability, and reliability is improved because of the structural compliance inherent in the construction. The method of construction involves the forming of the combustion chamber by a tube-bundle of high conductivity copper or copper alloy tubes and the bonding of these tubes by a unique electroforming operation. Furthermore, the method of fabrication reduces chamber complexity by incorporating manifolds, and structural stiffeners while having the potential for thrust chamber cost and weight reduction.

Kazaroff, John M.↗

Spiral vane bioreactor

A spiral vane bioreactor of a perfusion type is described in which a vertical chamber, intended for use in a microgravity condition, has a central rotating filter assembly and has flexible membranes disposed to rotate annularly about the filter assembly. The flexible members have end portions disposed angularly with respect to one another. A fluid replenishment medium is input from a closed loop liquid system to a completely liquid filled chamber containing microcarrier beads, cells and a fluid medium. Output of spent medium is to the closed loop. In the closed loop, the output and input parameters are sensed by sensors. A manifold permits recharging of the nutrients and pH adjustment. Oxygen is supplied and carbon dioxide and bubbles are removed and the system is monitored and controlled by a microprocessor.

Morrison, Dennis R.↗

Engine throat/nozzle optics for plume spectroscopy

The Task 2.0 Engine Throat/Nozzle Optics for Plume Spectroscopy, effort was performed under the NASA LeRC Development of Life Prediction Capabilities for Liquid Propellant Rocket Engines program. This Task produced the engineering design of an optical probe to enable spectroscopic measurements within the SSME main chamber. The probe mounts on the SSME nozzle aft manifold and collects light emitted from the throat plane and chamber. Light collected by the probe is transferred to a spectrometer through a fiber optic cable. The design analyses indicate that the probe will function throughout the engine operating cycle and is suitable for both test stand and flight operations. By detecting metallic emissions that are indicative of component degradation or incipient failure, engine shutdown can be initiated before catastrophic failure. This capability will protect valuable test stand hardware and provide enhanced mission safety.

Bickford, R. L.↗

Cometary implications of the internal energy distributions of the C2 and C3 radicals produced in the photolysis of the C2H and C3H2

The C2 and C3 radicals are prominent emission in the visible region of cometary spectra. Observational evidence exists that suggests these radicals are formed as granddaughter fragments in the photolysis of more stable molecules. Likely candidates for these parent molecules ar C2H2, C3H4 (allene), and CH3C2H (propyne). Recent laboratory studies were performed on all of these parent molecules and they indicate that they can indeed produce the observed cometary radicals. In the case of C2H2, the laboratory evidence suggest that C2 is formed via the following mechanisms: (1) C2H2 + photon(193 nm) yields C2H + H; and (2) C2H + photon(193 nm) yields C2 + H. Evidence is presented to show that the C2 radical produced in the second reaction occurs in a variety of electronic, vibrational, and rotational states. It is argued that this is a result of conical intersections in the potential energy curves and the density of states associated with these curves. Since this is a property of the C2H radical similar initial product state distributions are expected to occur in comets. This means that any models of the C2 emission may have to start off with rotationally excited C2 radicals in both the singlet and the triplet manifolds. When C3H4 (allene) and CH3C2H (propyne) were photolyzed, the C3 radical is formed. In the allene case, laboratory evidence shows that the C3 radical is formed via the following mechanism: (1) C3H4 + photon(193 nm) yields C3H2 + H2; and (2) C3H2 + photon(193 nm) yields C3 + H2. More C3 is formed in the case of allene than in the propyne case, even though the absorption cross section for propyne is a factor of 2 larger. This suggests that competing dissociation pathways are present during the photolysis of propyne that are not available to allene. The observed quantum state distributions of the C3 product were the same for both parent molecules, indicating that the same intermediate state is involved. These observations can be understood if the excited propyne formed in the initial absorption step isomerizes to excited allene before it dissociates to the same daughter compound. This postulate was tested by comparing RRKM calculations of the isomerization rate of excited propyne versus the decomposition rate to other products.

Jackson, William M.↗

Robust and real-time control of magnetic bearings for space engines

Currently, NASA Lewis Research Center is developing magnetic bearings for Space Shuttle Main Engine (SSME) turbopumps. The control algorithms which have been used are based on either the proportional-intergral-derivative control (PID) approach or the linear quadratic (LQ) state space approach. These approaches lead to an acceptable performance only when the system model is accurately known, which is seldom true in practice. For example, the rotor eccentricity, which is a major source of vibration at high speeds, cannot be predicted accurately. Furthermore, the dynamics of a rotor shaft, which must be treated as a flexible system to model the elastic rotor shaft, is infinite dimensional in theory and the controller can only be developed on the basis of a finite number of modes. Therefore, the development of the control system is further complicated by the possibility of closed loop system instability because of residual or uncontrolled modes, the so called spillover problem. Consequently, novel control algorithms for magnetic bearings are being developed to be robust to inevitable parametric uncertainties, external disturbances, spillover phenomenon and noise. Also, as pointed out earlier, magnetic bearings must exhibit good performance at a speed over 30,000 rpm. This implies that the sampling period available for the design of a digital control system has to be of the order of 0.5 milli-seconds. Therefore, feedback coefficients and other required controller parameters have to be computed off-line so that the on-line computational burden is extremely small. The development of the robust and real-time control algorithms is based on the sliding mode control theory. In this method, a dynamic system is made to move along a manifold of sliding hyperplanes to the origin of the state space. The number of sliding hyperplanes equals that of actuators. The sliding mode controller has two parts; linear state feedback and nonlinear terms. The nonlinear terms guarantee that the systems would reach the intersection of all sliding hyperplanes and remain on it when bounds on the errors in the system parameters and external disturbances are known. The linear part of the control drives the system to the origin of state space. Another important feature is that the controller parameter can be computed off-line. Consequently, on-line computational burden is small.

Sinha, Alok↗

Three-dimensional kinematic reconnection of plasmoids

The kinematic reconnection model of Lau and Finn (1990) is applied in a theoretical investigation of three-dimensional plasmoid morphology, as seen in the solar corona and earth magnetotail. The derivation of the governing equations is outlined; long, short, and periodic plasmoid models are developed; and the evolution of the stable and unstable manifolds in these models is presented graphically. It is inferred that sheet currents and tangential discontinuities can form on surfaces topologically identical to those where Delta(phi) about equal to Delta(z) singularities occur in the kinematic reconnection model, and can be broadened in a similar way by nonideal effects. Two such surfaces exist in long plasmoids, and also in short plasmoids in the presence of finite resistivity; the intertwined surfaces characteristic of the periodic plasmoid form a fractal set but merge in the presence of finite resistivity, producing structures similar to those proposed by the sheet-current theory of Parker (1983).

Lau, Yun-Tung↗

A search for vibrationally excited H2O at 68 GHz

Water vapor may be one of the most abundant constituents of shocked molecular clouds. The nonequilibrium distribution of population among its rotational energy states requires the observation of a multiplicity of transitions to constrain its abundance and excitation state. Flux limits are presented for emission due to the (010) 4(14) - 3(21) rotational transition of ortho-H2O at 67.804 GHz in several nebular and stellar sources. Upper limits for a beam-averaged column density of H2O in its nu2 vibrational manifold are derived for Orion BN-KL. Constraints placed by these observations on an internal source of infrared radiation in the Orion shock are discussed.

Petuchowski, Sam J.↗

Room temperature Dy:YLF laser operation at 4.34 micron

A Dy:YLF laser operating on the 6H11/2 to 6H13/2 transition at 4.34 micron and using a laser pumping scheme is reported. This pumping scheme is necessitated by the short upper-laser-level lifetime and the small effective stimulated-emission cross section. A suitable laser for this application is the Er:YLF laser operating at 1.73 micron. A simple model that approximates Dy:YLF laser performance well is presented. Results on laser performance, including a determination of the slope efficiency and threshold as a function of the output mirror reflectivity and a correlation of the pulse length with the laser output energy, are reported. Overall laser efficiency is found to be limited primarily by the ratio of the pump wavelength to laser output wavelength and the terminated four-level laser operation. Spectroscopic results, including the measurement of the absorption spectra and the lifetimes of both the upper- and lower-laser manifolds, are given.

Barnes, Norman P.↗

Low temperature hydrogen broadened linewidths of ammonia in the (0,1,0,0)-(0,0,0,0) band at 200 K

Results are reported of extensive and systematic measurements of hydrogen broadening of the ammonia (0,1,0,0)-(0,0,0,0) band at 200 K. The measured linewidths for each of the observed branches in this band were determined with an average rms of 5 percent or less. Plots of the K manifolds for four of the five branches that were measured are presented. It is suggested that these width data can be used for analyzing atmospheric spectra of the outer planets and for validating theories of foreign-gas broadening of ammonia.

Margolis, Jack S.↗

Theoretical branching ratios for the 5I7 to 5I7 levels of Ho(3+) in the garnets A3B2C3O12 (A = Y,La,Lu,Gd; B = Al,Lu,Sc,Ga; C = Al,Ga)

Results are reported from an experimental study investigating triply ionized holmium in 10 garnets using the point-change model to predict theoretical energy levels and temperature-dependent branching ratios for the 5I7 to 5I8 manifolds for temperatures between 50 and 400 K. Plots were made for the largest lines at 300 K. YScAG was plotted twice, once for each set of X-ray data available. Energy levels are predicted based on theoretical crystal-field parameters, and good agreement to experiment is found. It is suggested that the present set of theoretical crystal-field parameters provides good estimates of the energy levels for the other hosts on which there are no experimental optical data. X-ray and index-of-refraction data are used to evaluate the performance of 10 lasers via a quantum mechanical model to predict the position of the energy levels and the temperature-dependent branching rations of the 5I7 to 5I8 levels of holmium. The fractional population inversion required for threshold is also evaluated.

Filer, Elizabeth D.↗

Explosive Transient Camera (ETC) Program

Since the inception of the ETC program, a wide range of new technologies was developed to support this astronomical instrument. The prototype unit was installed at ETC Site 1. The first partially automated observations were made and some major renovations were later added to the ETC hardware. The ETC was outfitted with new thermoelectrically-cooled CCD cameras and a sophisticated vacuum manifold, which, together, made the ETC a much more reliable unit than the prototype. The ETC instrumentation and building were placed under full computer control, allowing the ETC to operate as an automated, autonomous instrument with virtually no human intervention necessary. The first fully-automated operation of the ETC was performed, during which the ETC monitored the error region of the repeating soft gamma-ray burster SGR 1806-21.

Ricker, George↗

Some methods of encoding simple visual images for use with a sparse distributed memory, with applications to character recognition

To study the problems of encoding visual images for use with a Sparse Distributed Memory (SDM), I consider a specific class of images- those that consist of several pieces, each of which is a line segment or an arc of a circle. This class includes line drawings of characters such as letters of the alphabet. I give a method of representing a segment of an arc by five numbers in a continuous way; that is, similar arcs have similar representations. I also give methods for encoding these numbers as bit strings in an approximately continuous way. The set of possible segments and arcs may be viewed as a five-dimensional manifold M, whose structure is like a Mobious strip. An image, considered to be an unordered set of segments and arcs, is therefore represented by a set of points in M - one for each piece. I then discuss the problem of constructing a preprocessor to find the segments and arcs in these images, although a preprocessor has not been developed. I also describe a possible extension of the representation.

Jaeckel, Louis A.↗

Domain wall formation in late-time phase transitions

We examine domain wall formulation in late time phase transitions. We find that in the invisible axion domain wall phenomenon, thermal effects alone are insufficient to drive different parts of the disconnected vacuum manifold. This suggests that domain walls do not form unless either there is some supplemental (but perhaps not unreasonable) dynamics to localize the scalar field responsible for the phase transition to the low temperature maximum (to an extraordinary precision) before the onset of the phase transition, or there is some non-thermal mechanism to produce large fluctuations in the scalar field. The fact that domain wall production is not a robust prediction of late time transitions may suggest future directions in model building.

Kolb, Edward W.↗

Observation of the visible absorption spectrum of H2O(+)

The water cation, H2O(+), has been studied, using laser absorption spectroscopy in a velocity-modulated discharge. It is shown that it is possible to observe the absorption spectrum of an ion that is not a terminal ion, despite the weak absorption oscillator strength, and despite the use of a relatively noisy dye laser. The relative intensities of the absorption lines have been measured to an accuracy of 13 percent. It is concluded that if the absorption cross section of a single transition can be measured absolutely, then the entire manifold will be known absolutely.

Das, Biman↗

Motion and force control of multiple robotic manipulators

This paper addresses the motion and force control problem of multiple robot arms manipulating a cooperatively held object. A general control paradigm is introduced which decouples the motion and force control problems. For motion control, different control strategies are constructed based on the variables used as the control input in the controller design. There are three natural choices; acceleration of a generalized coordinate, arm tip force vectors, and the joint torques. The first two choices require full model information but produce simple models for the control design problem. The last choice results in a class of relatively model independent control laws by exploiting the Hamiltonian structure of the open loop system. The motion control only determines the joint torque to within a manifold, due to the multiple-arm kinematic constraint. To resolve the nonuniqueness of the joint torques, two methods are introduced. If the arm and object models are available, an optimization can be performed to best allocate the desired and effector control force to the joint actuators. The other possibility is to control the internal force about some set point. It is shown that effective force regulation can be achieved even if little model information is available.

Wen, John T.↗

One vs two primary LOX feedline configuration study for the National Launch System

Six single LOX feedline designs were evaluated for use on the National Launch Vehicle. A single feedline design, designated the 'Spider', was chosen and compared to the baseline system. The baseline configuration employs two 20-inch I.D. lines, each supplying LOX to three 650,000 lbf thrust Space Transportation Main Engines. Five single feedline diameters were examined for the spider configuration; 22, 24, 26, 28, and 30-inch I.D. System dry weights and LOX residuals were estimated. These parameters, along with calculated staged mass for the different single line and baseline configurations, were used to calculate the payload mass to orbit. For the cases where LOX is drained to minimum NPSP conditions, none of the single lines performed as well as the dual line system, although the 22-inch diameter single line compared well. However, for the cases where LOX is drained to operating levels (LOX level at the booster and spider manifolds for the dual and single line configurations, respectively), the 22 - 26-inch I.D. single line systems show a greater payload capability.

Dill, K.↗