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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
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NASA NTRS1987

Ozone over McMurdo Station, Antarctica, austral spring 1986 - Altitude profiles for the middle and upper stratosphere

In the austral spring of 1986, a program of measurements of the ozone altitude profile (for the z values between 25 and 55 km), relevant to an understanding of the ozone hole, was conducted at McMurdo Station, Antarctica. The measurements were performed using ground-based millimeter-wave spectrometry. It was found that the ozone mixing ratio peaked at altitudes ranging from 28 to 34 km, with peak values between 5 and 9 ppm by volume. During the period between September 12 and October 29, the ozone mixing ratio decreased, with great variability, by about 15 percent at 25 km, with no significant decrease at higher altitudes. The observation of the depletion occurring only below 25 km is consistent with ozone-sonde observations during previous years.

Connor, Brian J.↗
NASA NTRS1992

Hydrocarbons and eddy mixing in Neptune's atmosphere

The most recent analysis of the Voyager ultraviolet solar occultation observations at Neptune indicates a methane mixing ratio 1-10 times above saturation in the lower stratosphere, unlike the value of 500-1000 times saturation which was suggested just before the encounter of Voyager with Neptune. The acetylene mixing ratio in the 0.1 mb region is found to be (6-8) x 10 exp -8, which is approximately a factor of 3 lower than the value reported in our Voyager/Science paper. The eddy diffusion coefficient at the homopause (1-3) x 10 exp 7 sq cm/s, is found to be more like that of Saturn than Uranus. The new results on CH4, C2H2 and K have strong implications for the stratospheric temperatures, now warmer, and the source of heating. Furthermore, the pre-Voyager models of the hydrocarbon hazes need to be revised in view of the new model atmosphere.

Atreya, S. K.↗
NASA NTRS2011

Temporal and Spatial Aspects of Gas Release During the 2010 Apparition of Comet 103P/Hartley-2

We report measurements of eight primary volatiles (H2O, HCN, CH4, C2H6, CH3OH, C2H2, H2CO, and NH3) and two product species (OH and NH2) in comet 103P/Hartley-2 using high dispersion infrared spectroscopy. We present production rates for individual volatiles species, their mixing ratios relative to water, and their spatial distributions in the coma on multiple dates that span the interval Sept. - Dec. 2010. The production rates vary strongly with nucleus rotation, but the mixing ratios remain constant throughout the campaign. The released primary volatiles exhibit diverse spatial properties which favor the presence of separate polar and apolar ice phases in the nucleus, establish dust and gas release from icy clumps (and also, directly from the nucleus), and provide insights into the driver for the cyanogen (CN) polar jet.

Bonev, B. P.↗
NASA NTRS2017

Retrieval of Water Vapor Column Abundance and Aerosol Properties from ChemCam Passive Sky Spectroscopy

We derive water vapor column abundances and aerosol properties from Mars Science Laboratory (MSL) ChemCam passive mode observations of scattered sky light. This paper covers the methodology and initial results for water vapor and also provides preliminary results for aerosols. The data set presented here includes the results of 113 observations spanning from Mars Year 31 L(s) = 291 deg (March 30, 2013) to Mars Year 33 L(s) = 127 deg (March 24, 2016). Each ChemCam passive sky observation acquires spectra at two different elevation angles. We fit these spectra with a discrete-ordinates multiple scattering radiative transfer model, using the correlated-k approximation for gas absorption bands. The retrieval proceeds by first fitting the continuum of the ratio of the two elevation angles to solve for aerosol properties, and then fitting the continuum-removed ratio to solve for gas abundances. The final step of the retrieval makes use of the observed CO 2 absorptions and the known CO 2 abundance to correct the retrieved water vapor abundance for the effects of the vertical distribution of scattering aerosols and to derive an aerosol scale height parameter. Our water vapor results give water vapor column abundance with a precision of +/-0.6 precipitable microns and systematic errors no larger than +/-0.3 precipitable microns, assuming uniform vertical mixing. The ChemCam-retrieved water abundances show, with only a few exceptions, the same seasonal behavior and the same timing of seasonal minima and maxima as the TES, CRISM, and REMS-H data sets that we compare them to. However ChemCam-retrieved water abundances are generally lower than zonal and regional scale from-orbit water vapor data, while at the same time being significantly larger than pre-dawn REMS-H abundances. Pending further analysis of REMS-H volume mixing ratio uncertainties, the differences between ChemCam and REMS-H pre-dawn mixing ratios appear to be much too large to be explained by large scale circulations and thus they tend to support the hypothesis of substantial diurnal interactions of water vapor with the surface. Our preliminary aerosol results, meanwhile, show the expected seasonal pattern in dust particle size but also indicate a surprising interannual increase in water-ice cloud opacities.

Mcconnochie, Timothy H.↗
NASA NTRS1979

Sulfur dioxide in the Venus atmosphere - Distribution and implications

The Pioneer Venus Orbiter ultraviolet spectrometer sees variable disk brightness features similar to the well-known 'UV markings' seen at longer wavelengths. The bright features are consistent with a homogeneous cloud of H2SO4 aerosols. The darker features show the presence of a broad-band absorber, which is at some depth in the cloud layer. Additional contrast arises from SO2 absorption. The observed strength of the SO2 absorption as a function of wavelength rules out a uniform mixing ratio for the SO2. The data are well fitted by an inhomogeneous light scattering model in which the SO2 scale height is one-fifth of the CO2 scale height, and the mixing ratio of SO2 at 40 mb is 10 to the -7th. A model of the oxidation of sulfur dioxide in the upper cloud reproduces the observed vertical distribution of SO2 and indicates that SO2 alone is sufficient to produce the observed amount of H2SO4 in this region.

Esposito, L. W.↗
NASA NTRS1984

Ultraviolet observations of Uranus and Neptune below 3000 A

From 2000 A to 3000 A, both Uranus and Neptune have albedos that are about two times higher than Jupiter or Saturn's, implying that the outer giants have stratospheres that are relatively free of aerosol absorption. Uncertainties in the absolute calibration procedure allow discrepancies of order 15% between conservative models and the observations. A small amount of aerosol absorption is therefore possible. Below 2000 A, the derived albedo is highly dependent on the solar spectrum source used in the data reduction. The most recent result for Uranus is consistent with a secular change in C2H2 mixing ratio from approximately 3 x (10 to the -8 power) in 1980 to or = 10 to the -9 power in 1983. These values are approximately 2 orders of magnitude less than the mixing ratios of this gas on Saturn, and comparable to the amount on Jupiter.

Caldwell, J.↗
NASA NTRS1993

AASE-2 observations of trace carbon species distributions in the mid to upper troposphere

We report tropospheric (altitudes greater than 5 km) observations of CO2, CO, CH4, and light hydrocarbons (C2-C4) over the latitude range from 90 deg N to 23 deg S recorded onboard the NASA DC-8 aircraft during the winter 1992 Second Airborne Arctic Stratospheric Expedition (AASE-2). Mixing ratios for these species exhibited significant north-south gradients with maximum values in subpolar and arctic regions and minima over the southern tropics. At latitudes greater than 40 deg N, the mixing ratios of most species increased significantly over the course of the 3-month measurement period. Also at high northern latitudes, the variations of all relatively long-lived reactive carbon species were linearly correlated with fluctuations of CO2 with CO, CH4, C2H6, C2H2, C3H8, and n-C4H10 exhibiting average enhancement ratios in terms of ppbv(X)/ppmb(CO2) of 13.8, 8.4, 0.21, 0.075, 0.085, and 0.037, respectively.

Anderson, B. E.↗
NASA NTRS1993

AASE-2 Observations of Trace Carbon Species Distributions in the Mid to Upper Troposphere

We report tropospheric (altitudes greater than 5 km) observations of CO2, CO, CH4, and light hydrocarbons (C2-C4) over the latitude range from 90 deg N to 23 deg S recorded onboard the NASA DC-8 aircraft during the winter 1992 Second Airborne Arctic Stratospheric Expedition (AASE-II). Mixing ratios for these species exhibited significant north-south gradients with maximum values in subpolar and arctic regions and minima over the southern tropics. At latitudes greater than 40 deg N, the mixing ratios of most species increased significantly over the course of the 3-month measurement period. Also at high northern latitudes, the variations of all relatively long-lived reactive carbon species were linearly correlated with fluctuations of CO2 with CO, CH4, C2H6, C2H2, C3H8, and n-C4H10 exhibiting average enhancement ratios in terms of ppbv(X)/ppmv(CO2) of 13.8, 8.4, 0.21, 0.075, 0.085, and 0.037, respectively.

Anderson, B. E.↗
NASA NTRS2019

Decomposition of Electron Ionization Mass Spectra for Space Application Using a Monte-Carlo approach

Rationale: Quadrupole mass spectrometers equipped with an electron ionization (EI) sources have been widely used in space exploration to investigate the composition of planetary surfaces and atmospheres. However, the complexity of the samples and the minimal calibration for the fragmentation of molecules in the ionization chambers have prevented the deconvolution of the majority of the mass spectra obtained at different targets, thus limiting the determination of the exact composition of the samples analyzed. We propose a Monte‐Carlo approach to solve this issue mathematically. Methods: We decomposed simulated mass spectra of mixtures acquired with unit resolving power mass spectrometers and EI sources into the sum of the single components fragmentation patterns weighted by their relative concentration using interior‐point least‐square fitting. To fit compounds with poorly known fragmentation patterns, we used a Monte‐Carlo method to vary the intensity of individual fragment ions. We then decomposed the spectrum thousands of times to obtain a statistical distribution. Results: By performing the deconvolution on a mixture of seven different molecules with interfering fragmentation patterns (H2O, O2, CH4, Ar, N2, C2H4, and C2H6) we show that this approach retrieves the mixing ratio of the individual components more accurately than regular mass spectra decomposition methods that rely on fragmentation patterns from general databases. It also provides the probability density function for each species's mixing ratio. Conclusions: By removing the solution degeneracy in the decomposition of mass spectra, the method described herein could significantly increase the scientific retrieval from archived space flight mass spectrometry data, where calibration of the ionization source is no longer an option.

Thomas Gautier↗
NASA NTRS1995

Estimates of total organic and inorganic chlorine in the lower stratosphere from in situ and flask measurements during AASE 2

Aircraft sampling has provided extensive in situ and flask measurements of organic chlorine species in the lower stratosphere. The recent Airborne Arctic Stratospheric Expedition 2 (AASE 2) included two independent measurements of organic chlorine species using whole air sample and real-time techniques. From the whole air sample measurements we derive directly the burden of total organic chlorine (CCl(y)) in the lower stratosphere. From the more limited real-time measurements we estimate the CCl(y) burden using mixing ratios and growth rates of the principal CCl(y) species in the troposphere in conjunction with results from a two-dimensional photochemical model. Since stratospheric chlorine is tropospheric in origin and tropospheric mixing ratios are increasing, it is necessary to establish the average age of a stratospheric air parcel to assess its total chlorine (Cl(sub Total)) abundance. Total inorganic chlorine (Cl(y)) in the parcel is then estimated by the simple difference, Cl(y) = Cl(sub Total) - CCl(y). The consistency of the results from these two quite different techniques suggests that we can determine the CCl(y) and Cl(y) in the lower stratosphere with confidence. Such estimates of organic and inorganic chlorine are crucial in evaluating the photochemistry controlling chlorine partitioning and hence ozone loss processes in the lower stratosphere.

Woodbridge, E. L.↗
NASA NTRS1994

An examination of the total hydrogen budget of the lower stratosphere

We analyze the hydrogen budget of the lower stratosphere using simultaneous in situ measurements of northern hemispheric water vapor (H2O) and methane (CH4) obtained during the spring Stratospheric Photochemistry, Aerosols, and Dynamics Expedition (SPADE), as well as previously published in situ H2 data. Based on this data, we conclude that approximately two H2O molecules are produced for each CH4 molecule destroyed. This implies that H2 production from CH4 oxidation is balanced by H2 oxidation. The uncertainty in this analysis is greatly reduced by the use of multiple data sets. Additionally, we infer that, on an annual and global average, H2O enters the stratosphere with a mixing ratio of 4.2 +/- 0.5 ppmv, and that the quasi-conserved quantity 2 x CH4 + H2O has a value of 7.6 +/- 0.6 ppmv in these northern hemishere air parcels (where xi denotes the mixing ratio of the constituent xi).

Dessler, A. E.↗
NASA NTRS1993

An intercomparison of aircraft instrumentation for tropospheric measurements of sulfur dioxide

As part of the NASA Tropospheric Chemistry Program, a series of field intercomparisons have been conducted to evaluate the state-of-the art for measuring key tropospheric species. One of the objectives of the third intercomparison campaign in this series, Chemical Instrumentation Test and Evaluation 3 (CITE 3), was to evaluate instrumentation for making reliable tropospheric aircraft measurements of sulfur dioxide, dimethyl sulfide, hydrogen sulfide, carbon disulfide, and carbonyl sulfide. This paper reports the results of the intercomparisons of five sulfur dioxide measurement methods ranging from filter techniques, in which samples collected in flight are returned to the laboratory for analyses (chemiluminescent or ion chromatographic), to near real-time, in-flight measurements via gas chromatographic, mass spectrometric, and chemiluminescent techniques. All techniques showed some tendency to track sizeable changes in ambient SO2 such as those associated with altitude changes. For SO2 mixing ratios in the range of 200 pptv to a few ppbv, agreement among the techniques varies from about 30% to several orders of magnitude, depending upon the pair of measurements intercompared. For SO2 mixing ratios less than 200 pptv, measurements from the techniques are uncorrelated. In general, observed differences in the measurement of standards do not account for the flight results. The CITE 3 results do not unambiguously identify one or more of the measurement techniques as providing valid or invalid SO2 measurements, but identify the range of 'potential' uncertainty in SO2 measurements reported by currently available instrumentation and as measured under realistic aircraft environments.

Gregory, Gerald L.↗
NASA NTRS1990

Redistribution of reactive odd nitrogen in the lower arctic stratosphere

In-situ measurements of total reactive odd nitrogen NO(y), were made from the NASA DC-8 aircraft in the lower arctic stratosphere during the 1989 Airborne Arctic Stratospheric Expedition. Throughout January and February, NO(y) mixing ratios were typically between 0.5 and 3 parts per billion by volume (ppbv) at altitudes between 10 and 12.5 km. During several flights late in the mission, events of unusually light NO(y) occurred with mixing ratios up to 12 ppbv at these altitudes. Simultaneous measurements of N2O, O3, and H2O during these events suggest that large changes in NO(y) are not expected. The elevated NO(y) values are interpreted as a vertical redistribution of NO(y) in the lower stratosphere resulting from gravitational sedimentation of aerosol particles containing HNO3. No evidence of the redistribution of H2O is noted, consistent with observations of denitrification without dehydration higher in the stratosphere.

Huebler, G.↗
NASA NTRS1996

ATMOS/ATLAS-3 Measurements of Stratospheric Chlorine and Reactive Nitrogen Partitioning Inside and Outside the November 1994 Antarctic Vortex

Partitioning between HCl and ClONO2 and among the main components of the reactive nitrogen family (NO, NO2, HNO3, ClONO2, N2O5, and HO2NO2) has been studied inside and outside the Antarctic stratospheric vortex based on ATMOS profiles measured at sunrise during the 3-12 November 1994 ATLAS-3 Shuttle mission. Elevated mixing ratios of HCl in the lower stratosphere with a peak of approximately 2.9 ppbv (10(exp -9) parts per volume) were measured inside the vortex near 500 K potential temperature (approximately 19 km). Maximum ClONO2 mixing ratios of approximately 1.2, approximately 1.4, and approximately 0.9 ppbv near 700 K (approximately 25 km) were measured inside, at the edge, and outside the vortex, respectively. Model calculations reproduce the higher levels of HCl and NO(x) (NO + NO2) inside the lower stratospheric vortex both driven by photochemical processes initiated by low O3. The high HCl at low O3 results from chemical production of HC1 via the reaction of enhanced Cl with CH4, limited production of ClONO2, and the descent of inorganic chlorine from higher altitudes.

Rinsland, C. P.↗
NASA NTRS2011

Temporal and Spatial Aspects of Gas Release During the 2010 Apparition of Comet 103P/Hartley-2

We report measurements of eight primary volatiles (H2O, HCN, CH4, C2H6, CH3OH, C2H2, H2CO, and NH3) and two product species (OH and NH2) in comet lO3P/Hartley-2 using high dispersion infrared spectroscopy. We quantified the long- and short-term behavior of volatile release over a three-month interval that encompassed the comet's close approach to Earth, its perihelion passage, and flyby of the comet by the Deep Impact spacecraft during the EPOXI mission. We present production rates for individual species, their mixing ratios relative to water, and their spatial distributions in the coma on multiple dates. The production rates for water, ethane, HCN, and methanol vary in a manner consistent with independent measures of nucleus rotation, but mixing ratios for HCN, C2H6, & CH3OH are independent of rotational phase. Our results demonstrate that the ensemble average composition of gas released from the nucleus is well defined, and relatively constant over the three-month interval (September 18 through December 1,7). If individual vents vary in composition, enough diverse vents must be active simultaneously to approximate (in sum) the bulk composition of the nucleus. The released primary volatiles exhibit diverse spatial properties which favor the presence of separate polar and apolar ice phases in the nucleus, establish dust and gas release from icy clumps, and from the nucleus, and provide insights into the driver for the cyanogen (CN) polar jet. The spatial distributions of C2H6 & HCN along the near-polar jet (UT 19.5 October) and nearly orthogonal to it (UT 22.5 October) are discussed relative to the origin of CN. The ortho-para ratio (OPR) of water was 2.85 +/- 0.20; the lower bound (2.65) defines T(sub spin) > 32 K. These values are consistent with results returned from ISO in 1997 .

Mumma, M. J.↗
NASA NTRS2003

New Examination of the Traditional Raman Lidar Technique II: Evaluating the Ratios for Water Vapor and Aerosols

In a companion paper, the temperature dependence of Raman scattering and its influence on the Raman and Rayleigh-Mie lidar equations was examined. New forms of the lidar equation were developed to account for this temperature sensitivity. Here those results are used to derive the temperature dependent forms of the equations for the water vapor mixing ratio, aerosol scattering ratio, aerosol backscatter coefficient, and extinction to backscatter ratio (Sa). The error equations are developed, the influence of differential transmission is studied and different laser sources are considered in the analysis. The results indicate that the temperature functions become significant when using narrowband detection. Errors of 5% and more can be introduced in the water vapor mixing ratio calculation at high altitudes and errors larger than 10% are possible for calculations of aerosol scattering ratio and thus aerosol backscatter coefficient and extinction to backscatter ratio.

Whiteman, David N.↗
NASA NTRS1992

Large-scale variability of ozone and aerosols in the summertime Arctic and sub-Arctic troposphere

The results of mesoscale and large-scale studies of the distribution of aerosols and O3 using primarily an airborne DIAL system are reported. The tropospheric composition at high latitudes is found to be strongly influenced by stratospheric intrusions. Regions of low-aerosol scattering and enhanced O3 mixing ratios are correlated with descending air from the lower stratosphere. Over 37 percent of the troposphere along the flight track at latitudes higher than 57 deg N had significantly enhanced O3 levels due to stratospheric intrusions, and in the 4-6 km latitude range the tropospheric extent of the enhanced O3 exceeded 56 percent. Ozone mixing ratios of 80 ppbv at 6 km are common, with vertical O3 gradients of over 11 ppbv/km observed across the base of strong intrusions. In the mixed layer over the tundra, O3 was in the 25-35 ppbv range with a gradient of 5.5 ppbv/km, while in the continental polar air masses, the average gradient in the lower troposphere is 7.4 ppbv/km, indicating more downward transport of O3 at higher latitudes.

Browell, E. V.↗
NASA NTRS1983

The distribution and annual cycle of ozone in the upper stratosphere

Study of the global distribution of upper stratospheric ozone derived from backscatter ultraviolet (BUV/SBUV) instruments on the Nimbus 4 and 7 satellites reveals the following characteristics for the period June 1970 May 1972 plus portions of 1978 and 1979. At pressures less than 5 mbar a local midlatitude maximum in the ozone mixing ratio develops in autumn and persists through the winter season in both hemispheres. However, by a pressure of 10 mbar the seasonal trend has reversed, with midlatitude summer values exceeding those in winter. The largest ozone mixing ratios in a global sense occur at tropical latitudes between pressures of 7 and 9 mbar. The general character of this pattern repeats from year to year, although differences in detail exist, especially in winter. This interannual variability in ozone increases the difficulty in extracting small long-term trends from the available data base. The overall seasonal pattern revealed by the measurements is in accord with photochemical model predictions which include the annual variation in temperature and solar illumination.

Frederick, J. E.↗