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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Empirical relation between interstellar X-ray absorption and optical extinction

An empirical relation between interstellar X-ray absorption and optical extinction is derived from the correlation of measurements made on objects of large intrinsic diameter. The result is Av = 4.5 times 10 to the -22nd power N(H) mag, with the principal error being largely systematic in origin, where N(H) represents the column density of interstellar matter in the Brown and Gould model for the X-ray absorption coefficient. Applying this ratio to optically identified compact sources, it is concluded that sources in binary systems showing pronounced X-ray occultations have an intrinsic absorption equivalent to about 10 to the 22-nd power atoms per sq cm of interstellar matter and that there are a few compact sources where the absorption seems to be primarily interstellar in origin. The interstellar absorption expected in Cyg X-1 from the extinction of its optical counterpart is much greater than that suggested by X-ray spectra, which may be due to a soft X-ray component greater than that predicted by the power law fitted to higher energy data.

Gorenstein, P.↗
NASA NTRS1976

Sulfidation of 310 stainless steel at sulfur potentials encountered in coal conversion systems

The sulfidation of SAE 310 stainless steel was carried out in gas mixtures of hydrogen and hydrogen sulfide over a range of sulfur potentials anticipated in advanced coal gasification processes. The kinetics, composition, and morphology of sulfide scale formation were studied at a fixed temperature of 1,065 K over a range of sulfur potentials from .00015 Nm to the -2nd power to 900 Nm to the -2nd power. At all sulfur potentials investigated, the sulfide scales were found to be multilayered. The relative thickness of the individual layers as well as the composition was found to depend on the sulfur potential. The reaction was found to obey the parabolic rate law after an initial transient period. Considerably longer transient periods were found to be due to unsteady state conditions resulting from compositional variations in the spinel layer. The sulfur pressure dependence on the parabolic rate constant was found to best fit the equation K sub p equals const. (P sub S2) to the 1/nth power, where n equals 3.7. The growth of the outer layers was found to be primarily due to the diffusion of metal ions, iron being the predominant species. The inner layer growth was due to the dissociation of the primary product at the alloy scale interface and depended on the activity of chromium.

Rao, D. B.↗
NASA NTRS1978

Barium and neodymium isotopic anomalies in the Allende meteorite

The discovery of Ba and Nd isotopic anomalies in two inclusions from the Allende meteorite is reported. The inclusions are Ca-Al-rich objects typical of the type considered as high-temperature condensation products in the solar nebula and contain distinctive Mg and O isotopic anomalies of the FUN (mass Fractionation, Unknown Nuclear processes) type. Mass-spectrometry results are discussed which show that inclusion C1 has anomalies in Ba at masses 134 and 136, while inclusion EK1-4-1 exhibits large marked negative anomalies at 130, 132, 134, and 136, as well as a positive anomaly at 137. It is also found that inclusion EK1-4-1 shows marked negative anomalies in Nd at masses 142, 146, 148, and 150, in addition to a positive anomaly at 145. These isotopic shifts are attributed to addition of r-process nuclei rather than mass fractionation. It is suggested that an onion-shell supernova explosion followed by injection into the solar nebula is the most likely generic model that may explain the observations.

Mcculloch, M. T.↗
NASA NTRS1978

An interpretation of special and general isotopic anomalies in r-process nuclei

My analysis of new discoveries by McCulloch and Wasserburg of Ba and Nd isotopic anomalies in inclusions of the Allende meteorite argues that (1) these anomalies contain special extinct radioactivities resulting from radioactive decay within grains formed in and ejected from the supernova interior, (2) the inclusions studied are fused assemblies of interstellar grains that were never totally vaporized, and (3) theoretical separation into r and s abundances suggests that fluctuations between r and s components has occurred during the accumulation processes. These points lend support to a new chemical picture of the early solar system that I have developed, although many interpretations remain possible. Measurements of the neutron-capture cross sections of Nd isotopes are urgently needed to experimentally validate these conclusions.

Clayton, D. D.↗
NASA NTRS1978

Petrology, chemistry, age and irradiation history of Luna 24 samples

The results of petrological, chemical, isotopic age determination and irradiation studies of sample 24170 from the 170 cm depth of the regolith core returned from Mare Crisium by Luna 24 are presented. The sample is found to be comprised of fragments from a single igneous rock, with mineralogical evidence indicating it to be a mare basalt. The crystallization age is determined by Sm-Nd and Ar(40)-Ar(39) ages to be 3.30 AE, establishing the presence of relatively young flows. All soil samples show low trace element compositions with minimum contamination by KREEPUTh-rich materials. Rb-Sr and Sm-Nd relations reflect the absence of significant fractionation at ages younger than 4.5 AE. One soil sample shows extremely large neutron capture effects, imposing a new lower limit to the neutron production rate in the regolith and requiring the addition of irradiated materials from depth.

Wasserburg, G. J.↗
NASA NTRS1981

Crustal influence in the generation of continental flood basalts

The suggestion that primordial undifferentiated material may exist in the earth's mantle has recently been revived on the strength of Nd isotope data for two types of young continental rocks - flood basalts and kimberlites. The limited published data show a clustering of Nd isotopic compositions close to those for meteorites with chondritic relative rare-earth (REE) abundance. In contrast, data are presented for samples from the Columbia flood basalt province of the northwestern United States which show large isotopic variability suggestive of mixing processes acting after the separation of the primary magmas from their mantle source.

Carlson, R. W.↗
NASA NTRS1981

Time and duration of lunar highlands crust formation

Due to remaining uncertainties in model parameters and assumptions in the calculation of model ages, it is not yet possible to resolve the precise dating and duration of lunar crust-mantle differentiation phenomena. Norites 78236 and 73255,27,45 were examined utilizing the Sm-Nd radiometric system. The systematics of 78236 show post-crystallization disturbance but indicate a crystallization date 4.34 AE ago. An isochron is defined by the 73255,27,45 data, with a crystallization date of 4.23 AE. The initial Nd isotopic composition of both norites is within uncertainty limits for a 'chondritic' reference reservoir at the time of their respective crystallizations. The implications for lunar crustal formation persisting over a time span of nearly 350 million years are discussed.

Carlson, R. W.↗
NASA NTRS1981

Simulated directional radiances of vegetation from satellite platforms

A computer modeling and simulation investigated the effects of off-nadir viewing, canopy geometry and density, solar zenith angle, and atmospheric conditions on the radiance of several vegetated targets. Effects on the normalized difference (ND) index were also investigated, and two wavelengths of 0.68 and 0.80 micron were simulated at nine sensor zenith angles, five sensor azimuths, and nine solar zenith angles. Seven canopies of low, medium, and high densities were observed, and bidirectional reflectance functions of other canopies were discussed. A modified Turner's (1974) atmospheric radiative transfer model was used for 2300 simulation runs. Off-nadir viewing effects were more pronounced in the red than the infrared, and the variability was found to be a function of canopy geometry. The ND index eliminated much of the variability seen in the individual bands, while the overall variability decreased with increasing biomass, and increased with increasing solar zenith angles.

Kirchner, J. A.↗
NASA NTRS1981

Isotopic and REE studies of lunar basalt 12038 - Implications for petrogenesis of aluminous mare basalts

Sr, Nd, and Sm isotopic studies of lunar basalt 12038, one of the so-called aluminous mare basalts, are reported. The evolution of the Sr and Nd isotopic compositions and the rare earth element (REE) abundances is successfully modeled within the framework of the model developed by Nyquist et al. (1977, 1979) for Apollo 12 olivine-pigeonite and ilmenite basalts. It is pointed out that the isotopic and trace element features of 12038 can by modeled as produced by partial melting of a cumulate mantle source which crystallized from a lunar magma ocean with a chondrite-normalized REE pattern of constant negative slope. Chondrite-normalized La/Yb is equal to 2.2 for this hypothetical magma ocean pattern.

Nyquist, L. E.↗
NASA NTRS1983

Airborne dual laser excitation and mapping of phytoplankton photopigments in a Gulf Stream Warm Core Ring

Utilization of a two-color airborne lidar system in the systematic study of a major oceanographic feature is reported here for the first time. An excimer pumped dye laser was optically and electronically integrated into the NASA Airborne Oceanographic Lidar for simultaneous use with a frequency doubled Nd:YAG laser. The output beams exit the laser system along parallel paths after being produced on an alternating pulse basis at a combined rate of 12.5 pps. Results are presented for missions flown over a Gulf Stream Warm Core Ring (WCR) as well as over shelf, slope, Gulf Stream, and Sargasso Sea waters. From the airborne data a high coherence is shown between the two-color chlorophyll a data and between the Nd:YAG chlorophyll a and phycoerythrin responses within each of these water masses. However, distinct differences in the response patterns of these photopigments are shown to exist between the differing water masses. At certain of the boundaries separating the water masses a sharp transition is seen to occur, while at others a wider transition zone was observed in which the correlation between the photopigments appears to degrade.

Hoge, F. E.↗
NASA NTRS1984

Partition coefficients of Hf, Zr, and REE between phenocrysts and groundmasses

Partition coefficients of Hf, Zr, and REE between olivine, orthopyroxene, clinopyroxene, plagioclase, garnet, amphibole, ilmenite, phlogopite, and liquid are presented. Samples consist of megacrysts in kimberlite, phenocrysts in alkaline basalts, tholeiitic basalts and andesitic to dacitic rocks, and synthetic garnet and clinopyroxene in Hawaiian tholeiites. The Hf-Lu and Zr-Lu elemental fractionations are as large as the Lu-Sm or Lu-Nd fractionation. The Hf and Zr partition coefficients between mafic phenocrysts and liquids are smaller than the Lu partition coefficients, but are similar to the Nd or Sm partition coefficients. The Hf and Zr partition coefficients between ilmenite, phlogopite, and liquid are larger than the Lu partition coefficients for these minerals and their corresponding liquids. The Hf-Zr elemental fractionation does not occur except for extreme fractionation involving Zr-minerals and extremely low fO2. These data have an important bearing on chronological and petrogenetic tracer studies involving the Lu-Hf isotopic system.

Fujimaki, H.↗
NASA NTRS1984

Potential for coherent Doppler wind velocity lidar using neodymium lasers

Existing techniques for the frequency stabilization of Nd:YAG lasers operating at 1.06 micron, and the high-gain amplification of radiation at that wavelength, make possible the construction of a coherent Doppler wind velocity lidar using Nd:YAG. Velocity accuracy and range resolution are better at 1.06 micron than at 10.6 microns at the same level of the SNR. Backscatter from the atmosphere at 1.06 micron is greater than that at 10.6 microns by about 2 orders of magnitude, but the quantum-limited noise is higher by 100 also. Near-field attenuation and turbulent effects are more severe at 1.06 micron. In some configurations and environments, the 1.06-micron wavelength may be the better choice, and there may be technological advantages favoring the use of solid-state lasers in satellite systems.

Kane, T. J.↗
NASA NTRS1986

Hybrid Laser Would Combine Power With Efficiency

Efficient laser system constructed by using two semiconductor lasers to pump neodymium yttrium aluminum garnet (Nd:YAG) device. Hybrid concept allows digital transmission at data rates of several megabits per second with reasonably sized optical aperture of 20 cm. Beams from two GaAs lasers efficiently coupled for pumping Nd:YAG crystal. Combination of lasers exploits best features of each.

Sipes, Donald L., Jr↗
NASA NTRS1985

Conducting a wind sensing study

Signal-to-noise requirements, and how signal-to-noise determines wind velocity measurement accuracy were studied. A Nd:YAG-based system was found to be competitive with a CO2-based system. Hardware was developed for a coherent Nd:YAG LIDAR system, and is being integrated into a functioning system. A diode-pumped monolithic rod laser to be used as a reference oscillator, a high-power, single-mode ring laser, for use as a master oscillator, and a high-gain, multipass amplifier were constructed.

Byer, R. L.↗
NASA NTRS1985

Constraints on the development of the early continental crust from isotopic data

Aspects of the origin and development of the early (AE) continential crust are addressed by radiogenic isotope and trace element studies. The most important ones are: (1) at what time did the earliest continental crust form; (2) what was its composition; (3) by what processes did it grow and by what processes was it destroyed; (4) what were the rates of production and destruction as a function of time during this time period? Nd is isotopic data on the oldest terrestrial rocks indicate that the mantle at this time had already suffered substantial depletion in incompatible elements due to earlier continent forming events. Isotopic data on young volcanic rocks derived from the depleted mantle show no evidence of this early history. The observed isotopic patterns of Nd, Sr, Hf and Pb through time together with the presently observed age spectrum of crustal rocks are considered. These patterns can be modelled by a transport model in which the continental growth and destruction rates are allowed to vary as a function of time. It is suggest that the mass of the continents at 3.8 AE ago was about 25% of the current continental mass. However, due to the very high recycling rates obtained in the early Archean only a few percent of this crust has been preserved up to the present.

Jacobson, S. B.↗
NASA NTRS1985

Anorthositic oceanic crust in the Archean Earth

Ultrapure minerals separated from eclogite inclusions in kimberlites were analyzed for Sm, Nd, Sr, and oxygen isotopes and for major and trace elements. Clinopyroxene (cpx) and garnet (gnt) are the only primary mineral phases in these rocks, and mineral phases and their alteration products. The WR sub calc. is the reconstructed bulk composition excluding all the contamination influences. Two groups of eclogites: are distinguished: (1) type A Noritic-anorthositic eclogites; and (2) type B Ti-ferrogabbroic eclogites. The oxygen isotopes are primary mantle-derived features of these rocks and are not caused by posteruption processes, as they were measured on unaltered, clean mineral separates and show a correlation with REE pattern and Sr and Nd isotopes. It is suggested that the variation of the oxygen isotopes are caused by crustal-level fluid-rock interaction at relatively low temperature. It is shown that oxygen isotopes variation in MORB basalts caused by the hydrothermal system are in the same range as the observed oxygen isotope variation in eclogites. A model to explain the new set of data is proposed. It is thought that some of these eclogites might be emplaced into the upper lithosphere or lower crust at the time corresponding to their internal isochron age. The calculated WR composition was used to estimate model ages for these rocks.

Jagoutz, E.↗
NASA NTRS1984

Growth of InSb and InAs(1-x)Sb(x) by OM-CVD

Organometallic chemical vapor deposition (OM-CVD) growth of InSb and InAs(1-x)Sb(x) has been obtained using triethylindium (TEI), trimethylantimony (TMS), and arsine (AsH3) on (100) GaAs, (100) InSb, and (111)-B InSb substrates. InSb with excellent morphology was achieved on both (100) InSb and (111)-B InSb substrates. The measured electron mobility at 300 K of undoped InSb grown on (100) GaAs semi-insulating substrates was 40,000 sq cm/V-s at a carrier concentration of ND-NA = 2.0 x 10 to the 16th per cu cm. Carrier concentration of ND-NA = 1.2 x 10 to the 15th per cu cm has been measured at 77 K. InAs(1-x)Sb(x) (x = 0.07-0.75) with mirror-like surfaces have been grown on (100) InSb and InAs substrates. This composition range of x between 0.55 and 0.75 (Eg = 0.1 eV) has been successfully achieved for the first time. Solid composition variations as a function of growth temperature and InSb substrate orientations are also discussed.

Chiang, P. K.↗
NASA NTRS1984

Intermediate phases in some rare earth-ruthenium systems

The phase equilibria and crystal structures of intermediate phases were investigated in eight representative RE-Ru systems using powder X-ray diffraction and metallographic techniques. The Fe3C, Mn5C2 and Er5Ru3 structures occur in all but the Ce-Ru systems. Phases analogous to Er5Ru3 possess an unknown crystal structure similar to Er5Rh3(I). MgCu2 and MgZn2 type Laves phases are encountered in the light rare earth and heavy rare earth systems, respectively, and RERu2 phases, where RE = Nd and Sm, possess both the Laves phase structures. An intermediate phase, NdRu, with an unknown structure, occurs only in the Nd-Ru system. A bcc structure with 40 atoms per unit cell is encountered in the phases Er3Ru2 and Y3Ru2. The behavior of cerium in Ce-Ru alloys is unique in that four unidentified structures, not encountered in other RE-Ru systems, have been encountered. Also a phase designated as Ce3Ru is found with the Th7Fe3 type structure.

Sharifrazi, P.↗