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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
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NASA NTRS1976

The photochemistry of ammonia in the Jovian atmosphere

A reinvestigation of the ammonia photochemistry in the Jovian lower atmosphere above the cloud tops is conducted in connection with certain questions concerning the model proposed by Strobel (1973). Chemical reactions and their rate coefficients are considered along with the model atmosphere, solar fluxes, the continuity equations, and numerical details. Differences between the newmodel and Strobel's model are related to more moderate ammonia depletion relations. The height profiles of H, NH2, N2H3, N2H4, and NH3 concentrations are presented in a graph.

Prasad, S. S.↗
NASA NTRS1977

Atomic and molecular fluorescence as a stratospheric species monitor

The results of an investigation are presented evaluating the potential of atomic and molecular fluorescence as a stratospheric monitor of the concentrations of any one of 18 minor species: Cl, Cl2, ClO, ClO2, CO, H2, HCHO, HCl, HNO2, HNO3, H2S, NH3, NO, NO2, N2O, O, OH, and SO2. All spectral regions from the vacuum ultraviolet through the infrared were included. It was found that suitable systems can be constructed for the stratospheric monitoring of CO (5 ppb), NO2 (less than 1 ppb), OH (0.2 ppt), and O (50-200 ppt). The fluorescence sensitivities for Cl (0.5-1.0 ppt), H2 (0.2 ppm at 10 torr) and SO2 (1-10 ppb) are marginally insufficient with current technology.

Schofield, K.↗
NASA NTRS1976

Gas interaction effects on lunar bonded particles and their implications

Results are reported for an experimental investigation of gas-interaction effects on different Apollo 11 and Apollo 12 lunar-soil samples containing bonded particles. In the experiments, lunar fines were exposed to pure O2, pure water vapor, HCl, NH3, N2, HCOOH, and CH3NH2, in order to observe whether bonded particles would separate. In addition, repeated gas adsorption/desorption measurements were performed to determine the nature and reactive properties of the particle surfaces, and surface areas were measured for comparison with analogous terrestrial samples to determine whether the surface areas of highly radiation-damaged particles were larger or smaller. It is found that N2 is apparently ineffective in separating bonded particles and that the ratio of Apollo 11 to Apollo 12 bonded particles separated by a particular gas exposure ranges from 2.5 to 3.0. Possible reasons for differences in material surface properties at the two Apollo sites are considered, and it is concluded that material from a certain depth at some other site was transported to the Apollo 12 site and mixed with the original material in recent years (considerably less than 2000 years ago).

Mukherjee, N. R.↗
NASA NTRS1976

The atmosphere of Io

Observations of Io suggest that it may have an atmosphere in which sodium vapor, ammonia, and nitrogen are important constituents. Several atmospheric models consisting of these gases are tested as a function of total content against the Pioneer 10 observations and for stability against escape. The results suggest that the atmosphere is very tenuous and that the interpretation of the ionosphere detected by Pioneer 10 by a static model may be inconsistent with the sodium-cloud observations. It is postulated that ionization may also be escaping and that sodium may be comparable in content in the atmosphere with some molecular constituent such as NH3 or N2. Sodium and this molecular component then dominate the atmosphere. It is also suggested that particle precipitation contributes to heating of the atmosphere and to the production of ionization; the difference between day- and nighttime ionospheres and possible trailing and leading side effects may relate to the nature of the particle energy distributions. These distributions may result from the peculiar interaction of Io with the Jovian magnetosphere.

Gross, S. H.↗
NASA NTRS1977

Observations of Jupiter and Saturn at 5-8 micron

Moderate-resolution spectrophotometry (about 0.015) has shown the effects of known atmospheric constituents (NH3, CH4, C2H6) on the 5-8 micron spectrum of Jupiter. Broadband observations of Saturn at 6.5 micron are also reported.

Russell, R. W.↗
NASA NTRS1977

The molecular composition of dense interstellar clouds

Presented in this paper is an ab initio chemical model for dense interstellar clouds that incorporates 598 grain surface reactions, with small grains providing the reaction area. Gas-phase molecules are depleted through collisions with grains. The abundances of 372 chemical species are calculated as a function of time and are found to be of sufficient magnitude to explain most observations. Peak abundances are achieved on time scales of the order of 100,000 to 1 million years, depending on cloud density and kinetic temperature. The reaction rates for ion-molecule chemistry are approximately the same, indicating that surface and gas-phase chemistry may be coupled in certain regions. The composition of grain mantles is shown to be a function of grain radius. In certain grain-size ranges, large molecules containing two or more heavy atoms are more predominant than lighter 'ices' - H2O, NH3, and CH4. It is possible that absorption due to these large molecules in the mantle may contribute to the observed 3-micron band in astronomical spectra.

Allen, M.↗
NASA NTRS1976

Chemical abundances in the atmospheres of the giant planets and their satellites

Recent results on the composition and structure of the atmospheres of Jupiter, Saturn, Uranus, Neptune, Pluto, and their satellites are summarized with an orientation toward topics of particular interest to the subject of exobiology. The need for an accurate Jovian temperature profile is noted, and current values are given for the known H2, NH3, and CH4 abundances of each planet as well as Titan and Triton. Trace constituents and chromophores in the Jovian atmosphere are discussed, the role of comets as a link between chemical evolution in the solar system and the chemistry of the interstellar medium is examined, and some features in the IR spectrum of Titan are interpreted. The hope is expressed that Titan will remain a useful proving ground for theories of low-temperature abiogenic organic-compound production

Owen, T.↗
NASA NTRS1976

Origin of organic compounds on the primitive earth and in meteorites

The paper examines the role and relative contributions of different forms of energy to the synthesis of amino acids and other organic compounds on the primitive earth and in the solar nebula. Attention is directed mainly to the activation steps and formation of reactive intermediate compounds. Electric discharges appear to be not only the most efficient energy for amino acid synthesis but also yield a mixture of amino acids that is qualitatively and quantitatively the same as that found in the Murchison carbonaceous chondrite. Ultraviolet light is likely to have played a major role in prebiotic synthesis. The reaction of CO plus H2 plus NH3 on the surface of a Fischer-Tropsch catalyst produces reactive intermediates which lead to amino acids and other organic compounds in a much less efficient way than electric discharges.

Miller, S. L.↗
NASA NTRS1976

Angular distribution of photoelectrons at 584 A using polarized radiation

Photoelectron angular distributions for Ar, Xe, N2, O2, CO, CO2, and NH3 have been obtained at 584 A by observing the photoelectrons at a fixed angle and simply rotating the plane of polarization of a highly polarized photon source. The radiation from a helium dc glow discharge source was polarized (84%) using a reflection type polarizer

Hancock, W. H.↗
NASA NTRS1977

Isothermal degradation of poly-2,2'-/m-phenylene/-5,5'-bibenzimidazole

The isothermal degradation of poly-2,2'-(m-phenylene)-5,5'-bibenzimidazole in vacuo has been studied. Measurement of the increase in pressure with time, coupled with infrared analysis, was used to determine the distribution of the degradation products. Processes A and B with different second-order rate laws were determined to be significant in the temperature range of 550-700 C. Process A leads to the formation of equimolar quantities of hydrogen and ammonia and has an activation energy of 68 kcal/mole. Process B leads to the production of HCN, NH3, and H2 in the ratio of 1:1:2.5 and has an activation energy of 77 kcal/mole. The activation energies and the rate laws are consistent with a mechanism in which the initial degradation step is the bimolecular reaction of two aromatic rings.

Lerner, N. R.↗
NASA NTRS1977

The sodium and hydrogen gas clouds of Io

Models are developed to describe the spatial distribution of gases emitted by Io and are applied to recent observations which indicate extensive gas clouds of hydrogen and sodium in orbit around Jupiter. Hydrogen and sodium atoms are emitted from Io with velocities in the range from 2 to 3 km/sec, with fluxes of about 10 billion and 100 million per sq cm/sec for hydrogen and sodium, respectively. Hydrogen atoms may be formed by photodecomposition of gases such as NH3 or H2S released from the satellite surface and may escape thermally from an exosphere whose temperature is about 500 K. Sodium may be ejected from the surface by energetic particles or by ultraviolet radiation, and it appears that a nonthermal mechanism drawing energy from Jupiter's magnetic field is required in order to account for its release to space.

Smyth, W. H.↗
NASA NTRS1977

Far-infrared and submillimeter observations of the planets

Broadband observations in several passbands between 30 and 500 microns of Mercury, Venus, Mars, Jupiter, Saturn, and Uranus are presented. The best agreement between the data and various thermal models of Mars, Jupiter, and Uranus is obtained with a slightly cooler absolute temperature scale than that previously adopted by Armstrong et al. (1972). The effective temperature of Uranus is 58 + or - 2 K, which is in agreement with its solar equilibrium temperature. The existence of an internal energy source for Saturn has been reconfirmed; its output must lie within the range of 0.9 to 3.2 times the absorbed solar flux. A depression exists in the spectra of Jupiter, Saturn, and Uranus between 80 and 300 microns, which may be a result of NH3 opacity.

Loewenstein, R. F.↗
NASA NTRS1977

Saturn - Long-term variation of H2 and CH4 absorptions

Results are presented for observations of various H2 quadrupole lines and CH4 absorption bands in spectra of Saturn obtained with a coude scanner at each apparition since 1969. The data are found to indicate a long-term variation in Saturn's H2 equivalent widths, a seasonal dependence of H2 line strength, and a fairly steady increase in CH4 absorption during the period from 1973 to 1976. A possible correlation between planetary shading and the strength of H2 absorption features is discussed along with seasonal variations in Saturn's NH3 cloud deck and atmospheric models that correspond to the observed H2 equivalent widths. It is suggested that: (1) significant shadowing by the rings may cause dynamical atmospheric activity due to the occurrence of a temperature gradient in the penumbral boundaries of the ring shadow in the planet's upper atmosphere; (2) cooling in the shadow may be a source of a high-altitude CH4 mist; and (3) spreading of this mist over the globe by advective winds would reduce the H2 and CH4 absorptions, as observed.

Trafton, L.↗
NASA NTRS1977

Reducing greenhouses and the temperature history of earth and Mars

It has been suggested that NH3 and other reducing gases were present in the earth's primitive atmosphere, enhancing the global greenhouse effect; data obtained through isotopic archeothermometry support this hypothesis. Computations have been applied to the evolution of surface temperatures on Mars, considering various bolometric albedos and compositions. The results are of interest in the study of Martian sinuous channels which may have been created by aqueous fluvial errosion, and imply that clement conditions may have previously occurred on Mars, and may occur in the future.

Sagan, C.↗
NASA NTRS1977

Atlas of Infrared Absorption Lines

This atlas of infrared absorption line contains absorption line parameters (line strength vs. wavenumber) from 500 to 7000 cm(exp-1) for 15 gases: H2O, CO2, O3, N2O, CO, CH4, O2, SO2, NO, NO2, NH3, HCl, HF, HNO3 and CH3Cl.

Park, J. H.↗
NASA NTRS1977

Infrared laboratory studies of synthetic planetary atmospheres

Topics covered include: the broadening of individual lines in the CO fundamental by various gases; total band absorptance as a function of absorber thickness and total effect pressure at various temperatures for bands of CO and N2O; nitric acid vapor content in the region of the ozone layer; optical properties of solid NH3; HSO4 concentration in Venus clouds; Burch's law of multiplicative transmittance for mixing absorbing gases when their lines are broadened by helium and hydrogen; ling strength and self-broadening parameters in the v3 fundamental of CO2 and N2O; optical constants of liquid ammonia, liquid methane, saturated hydrocarbons, ammonium hydride and ammonium salts.

Williams, D.↗
NASA NTRS1977

Development and evaluation of die materials for use in the growth of silicon ribbons by the inverted ribbon growth process, task 2, LSSA project

Silicon sessile drop experiments were performed on a variety of commercially available refractory carbides, nitrides, oxides, and borides to examine the potential of these materials for applications involving either direct contact with molten silicon or as substrates for CVD coatings in the fabrication of dies and crucibles for containing molten silicon. Simultaneous experiments were also conducted with CVD layers of SiC, Si3N4, and SiOxNy. Silicon nitride layers, deposited with NH3:SiH4 ratios ranging from 100:1 down to 5:1, were examined in sessile drop experiments to determine if the layers are degraded as a result of using lower reagent ratios. Preliminary experiments were undertaken on the stability of CVD Si3N4 near the melting point of silicon. Silicon ribbon segments were grown from vitreous carbon dies which had been coated with CVD Si3N4. Depending upon the purity of the die materials, ribbon resistivity values up to 40 Omega cm were obtained.

Duffy, M. T.↗
NASA NTRS1977

Ultraviolet observations of Mars and Saturn by the TD1A and OAO-2 satellites

Ultraviolet photometric and spectrophotometric observations of Mars and Saturn, obtained from two earth-orbiting satellites, are discussed. High-resolution data reveal no definite absorption features in the spectra of either planet. In order to reconcile the absence of a prominent absorption in the Mars data near 2150 A with preliminary Viking measurements of NO, this gas must be preferentially concentrated at high Martian altitudes. Broadband photometry from OAO-2 shows that atmospheric dust from the great dust storm of 1971-1972 on Mars reduced the ultraviolet geometric albedo by a factor of 3 at the height of the storm. Atmospheric energy deposition appears to be an important mechanism of the storm dynamics. The combined Saturn data indicate that NH3 is not the absorber that influences the UV spectrum of Saturn. The possibility that H2S is the absorber is investigated.

Caldwell, J.↗