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NASA NTRS2020

Mineralogy of Vera Rubin Ridge in Gale Crater from the Mars Science Laboratory CheMin instrument

Gale crater was selected as the landing site for the Mars Science Laboratory Curiosity rover because of orbital evidence for a variety of secondary minerals in the lower slopes of Aeolis Mons (aka Mount Sharp) that indicate changes in aqueous conditions over time. Distinct units demonstrate orbital spectral signatures of hematite, phyllosilicate (smectite), and sulfate minerals, which suggest that ancient aqueous environments in Gale crater varied in oxidation potential, pH, and water activity. Vera Rubin ridge (VRR) is the first of these units identified from orbit to have been studied by Curiosity. Orbital near-infrared data from VRR show a strong band at 860 nm indicative of hematite. Before Curiosity arrived at VRR, the hypotheses to explain the formation of hematite included (1) precipitation at a redox interface where aqueous Fe2+ was oxidized to Fe3+, and (2) acidic alteration of olivine in oxic fluids. Studying the composition and sedimentology of the rocks on VRR allow us to test and refine these hypotheses and flesh out the depositional and diagenetic history of the ridge. Here, we focus on the mineralogical results of four rock powders drilled from and immediately below VRR as determined by CheMin.

Rampe, E. B.↗
NASA NTRS2020

Saponite Dissolution Experiments and Implications for Mars

Phyllosilicates detected throughout the Noachian terrains of Mars provide ample evidence of water-rock interactions in its geologic past, and characterizing their formation would elucidate past environmental conditions on the martian surface. Previous work suggests that ferric smectite may have been deposited in the Noachian as ferroan (Fe2+) smectite and then subsequently oxidized after formation. This is further supported by the detection of trioctahedral saponite at the base of the stratigraphic section in Gale crater by CheMin and the gradual transition to dioctahedral ferric smectite up section. A better understanding of the dissolution behavior of saponites would therefore help us better interpret past water-rock interactions at Gale crater. However, smectite structures and compositions are variable and complex, and very few saponite dissolution rates exist in the literature. To further understand past water-rock interactions at Gale crater, we are reporting our results to date from dissolution experiments of Fe- and Mg- saponites under a range of conditions.

Luu, N. C.↗
NASA NTRS2020

Automated Identification and Differentiation of Spectrally Similar Hydrothermal Minerals on Mars

Early telescopic observations corroborated hydration related absorptions on Mars in the infrared. Images from the Viking missions led to speculation of hydrothermal alteration and were followed by two missions which mapped the spatial variability of the ~ 3 μm hydration feature. Since then, the Compact Reconnaissance Imager for Mars (CRISM) has provided high spatial resolution (up to 18m) spectral identification of a suite of hydrothermal and diagenetic minerals which have illuminated a range of formation mechanisms. Presence/absence and spatial segregation or mixing of minerals like prehnite, epidote, chlorite amphiboles, and mixed-layer Fe/Mg smectite-chlorite provide valuable evidence for the geologic setting of deposits on Earth, and these phases are often used as temperature and aqueous chemistry indicators in terrestrial systems. Mapping the distribution of these phases will help to answer whether Mars had widespread conditions favorable for low-grade metamorphism and diagenesis, or only focused hydrothermal systems in areas of high heat flow. Further characterizing the chemistry and structure of these phases will then help to answer how most of the widespread Fe/Mg phyllosilicates formed, further defining early geochemical cycling and climate. A fully automated approach for accurate mapping of important hydrothermal mineral phases on Mars has been a challenge. Due to overlapping features in the M-OH region (~2.2-2.4 μm), the strongest absorption features of chlorite, prehnite, and epidote in the short-wave infrared are difficult to distinguish from one another and from the most commonly occurring hydrated silicates on Mars, Fe/Mg smectites. Weaker absorptions are present in both prehnite and epidote which help to distinguish them from chlorite and smectites, but their relative strength in the presence of noise and spatial mixing is often too low to confidently identify them without the noise suppression and feature enhancement methods described here. The spectral signatures of mixed-layer Fe/Mg smectite-chlorite and partially chloritized Fe/Mg smectites have not yet been adequately assessed. Here we evaluate the effectiveness of two empirical and statistical methods for identifying and differentiating these phases using CRISM data.

Rasmussen, B. P.↗
NASA NTRSDate not supplied

Constraints on the surface materials of Ryugu from spectral and water analysis of experimentally-heated CI carbonaceous chondrite

We performed heating experiments of the Orgueil CI chondrite in vacuum conditions at fO2 around I/W to evaluate systematic changes in mineralogy, water contents, and visible to infrared spectral features. Our goal is to interpret the spectra of Ryugu, the target C asteroid of the Hayabusa2 mission, because Ryugu shows spectral features similar to partially dehydrated carbonaceous chondrites. However heated carbonaceous chondrites can be easily contaminated by terrestrial water, which makes it almost impossible for laboratory data to be compared with spectra of asteroids directly. Therefore, our heated samples were analyzed without exposure to the air after experimental heating to minimize the effects of terrestrial water. The depth of the 2.7-µm absorption band and the water content of the heated Orgueil form a positive correlation trend which follows the results of experimental heating of CM and Tagish Lake meteorites using our experimental procedures. It is found that 500-°C heated Orgueil sample shows the best spectral match with Ryugu in terms of the low reflectance (~2%) at visible wavelengths and a weak absorption (~10%) at around 2.72 µm owing to survival of Mg-rich phyllosilicates. We suggest that Ryugu might have experienced heating and dehydration at a temperature around 500 °C, after aqueous alteration, and presently contains a small quantity of hydrated minerals equivalent to 1-2 wt.% of water at the surface.

K. Amano↗
NASA NTRS2020

Widespread carbon-bearing materials on near-Earth asteroid (101955) Bennu

(101955) Bennu is a dark, Earth orbit-crossing, asteroid thought to be assembled from the fragments of an ancient collision. Spatially-resolved visible and near-infrared spectra of Bennu provide details about its surface properties and composition. In addition to a hydrated phyllosilicate band, we detect a ubiquitous 3.4-micron absorption feature, which we attribute to a mix of organic and carbonate materials. The shape and depth of this absorption feature vary across Bennu’s surface, spanning the range seen among similar main-belt asteroids. Its distribution does not correlate with the temperature, reflectance, spectral slope, or hydrated minerals although those characteristics correlate with each other in some cases. The deepest 3.4-micron absorptions occur on individual boulders. The variations may be due to differences in abundance, recent exposure, or space weathering.

Amy A. Simon↗
NASA NTRS2020

Volatile-rich Asteroids in the Inner Solar System

Bennu (101195), target of the Origins, Spectral Interpretation, Resource Identification, Security, Regolith Explorer (OSIRIS-REx) mission, is a type-B asteroid with abundant spectral evidence for hydrated silicates, low thermal inertia “boulders” and frequent bursts of particle emission. We suggest that Bennu’s parent body formed in the outer solar system before it was perturbed into the asteroid belt and then evolved into a near-Earth object. We show that this is consistent with models of planetesimal evolution. Bennu has many characteristics expected for a dormant comet, and could potentially contain a minimum of 1 wt.% adsorbed water if its gross mineralogy is consistent with the Orgueil meteorite. This is in addition to any ice or water contained within the hydrous minerals themselves. Based on this hypothesis, we predict the properties of the samples that will be returned to Earth by the OSIRIS-REx mission, including abundant phyllosilicate minerals, amorphous hydrated silicates and low-density, very high-porosity aggregates, already observed by the OSIRIS-REx instrument suite. We predict enrichments in D/H and 15N/14N, high C/Mg ratios (>∼7 wt%), and a greater range of organic compositions than found in meteorites, including an organic component poor in aromatics, and a more labile organic fraction. Ammonium salts, ranging from NH4Cl to ammonium–organic acid salts could carry much of the nitrogen in comets, yet only NH4CH3COO and heavier salts are sufficiently stable to be found in these returned samples. Water adsorbed onto highly porous grains should also be detected provided that the sample return capsule remains below 300 K during Earth return, and this water should be isotopically heavy.

Joseph A. Nuth, III↗
NASA NTRSDate not supplied

Coordinated analyses of hydrated Kuiper Belt dust

We report on coordinated mineralogical, chemical, and isotopic analyses of hydrated carbon-rich interplanetary dust particles (IDPs). We focus on hydrated IDPs that contain high solar flare track densities consistent with an origin in outer Solar System bodies such as Edgeworth-Kuiper belt objects (EKBOs) [1]. We are searching for evidence of the heavy water reservoir predicted by self-shielding models [2]. The IDPs were embedded in sulfur and microtome thin sections were obtained for Fourier-transform infrared (FTIR), transmission electron microscopy (TEM), and nanoSIMS analyses. The IDPs were only partly microtomed and the remainder was extracted from the sulfur and pressed into In or Au for high precision O isotopic analyses. The hydrated IDPs in this study are compact low-porosity objects with a mineralogy dominated by fine-grained saponite and lesser serpentine, Fe-Ni sulfides, Mg-Fe carbonates, rare crystaline silicates, and abundant organic matter. The C in the IDPs is abundant (typically >4X CI) and occurs as isolated nanoglobules and finely disseminated within the phyllosilicate matrix of the IDPs. TEM analyses of the nanoglobules show O-rich, S-depleted rims with higher carbonyl functionality than their cores. FTIR spectra show strong aliphatic C-H stretches consistent with the presence of short-chain aliphatic hydrocarbons in these IDPs. The oxygen isotopic compositions measured in 6 IDPs all plot within error of the CCAM line [3]. For several of the IDPs we were able to obtain multiple analyses. The ∆^(17)O values range from -23‰ up to +3.4‰ with most analyses clustering above the terrestrial fractionation line. The O isotopic compositions and the high C contents of these IDPs are distinct from known hydrated carbonaceous chondrites. The track-rich hydrated IDPs record parent body aqueous alteration effects through interactions with 16O-poor H2O on a EKBO parent body. The aqueous alteration activity likely resulted from the heat generated by collisional processes among EKBOs given that these objects are believed to have accreted late after the decay of 26Al [4].

Lindsay P. Keller↗
NASA NTRS2021

The Role of Hydrated Minerals and Space Weathering Products in the Bluing of Carbonaceous Asteroids

The surfaces of airless bodies such as lunar and S-type asteroids typically become spectrally redder in visible to near-infrared reflectance with longer exposures to space weathering. However, some carbonaceous asteroids instead become spectrally bluer. Space weathering experiments on carbonaceous meteorites have provided some clues as to the space weathering products that could produce spectral bluing. We applied these experimental results to our Hapke radiative transfer model, with which we modeled spectral data from the OSIRIS-REx mission in order to determine whether these space weathering products—specifically, nanophase and microphase metallic iron, troilite, and magnetite—could explain the globally blue spectrum of the carbonaceous asteroid (101955) Bennu. The model suggests that the surface of Bennu has microphase iron, nanophase magnetite, and nanophase and microphase troilite. Considering previous space weathering experiments together with our spectral modeling of Bennu, we posit that the presence of nanophase magnetite is what causes a carbonaceous asteroid to become spectrally bluer with exposure time. Nanophase magnetite can form on asteroids that have Fe-bearing hydrated minerals (phyllosilicates). On anhydrous carbonaceous asteroids, nanophase iron forms instead of magnetite, leading to spectral reddening. We therefore predict that samples returned by the OSIRIS-REx mission from Bennu will have more nanophase magnetite than nanophase iron with nanophase and microphase sulfides, whereas samples returned by the Hayabusa2 mission from the carbonaceous asteroid (162173) Ryugu, which is spectrally red, will contain nanophase and microphase sulfides as well as more nanophase iron than nanophase magnetite.

David Trang↗
NASA NTRS2021

Hydrothermal History of (162173) Ryugu’s Parent Body Inferred from Remote-Sensing Data

Small rubble pile asteroids record the thermal evolution of their much larger parent bodies. However, recent space weathering and/or solar heating create ambiguities between the uppermost layer observable by remote-sensing and the pristine material from the parent body. Hayabusa2 remote-sensing observations find that on the asteroid (162173) Ryugu both north and south pole regions preserve the least space-weathered material, which is spectrally blue carbonaceous chondritic material with a 0 – 3% deep 0.7-μm band absorption, indicative of Fe-bearing phyllosilicates . We report that spectrally blue Ryugu’s parent body experienced intensive aqueous alteration and subsequent thermal metamorphism at 570 – 670 K (300 – 400 ˚C), suggesting that Ryugu’s parent body was heated by radioactive decay of short-lived radionuclides possibly because of its early formation 2-2.5 Ma. The samples being brought to Earth by Hayabusa2 will give us our first insights into this epoch in solar system history. Moreover, we found the NUV-VIS spectral similarity between Ryugu and Polana–Eulalia family members, suggesting plausible origin from inner main belt predicted by the dynamical simulation.

Eri Tatsumi↗
NASA NTRS2021

Spectrally Blue Parent Body of Asteroid (162173) Ryugu and its Hydrothermal History

Small rubble pile asteroids record the thermal evolution of their much larger parent bodies. However, recent ‘space weathering’ and/or ‘solar heating’ create ambiguities between the uppermost layer observable by remote-sensing and the pristine material from the parent body. Hayabusa2 remote-sensing observations found that on the asteroid (162173) Ryugu both north and south pole regions preserve the material least processed by space weathering: spectrally blue carbonaceous chondritic material with a 0.7-μm band absorption, indicative of Fe-bearing phyllosilicates. This discovery suggests that Ryugu’s parent body experienced intensive aqueous alteration and subsequent thermal metamorphism at 670 – 970 K. Ryugu’s parent body was heated by radioactive decay of short-lived radionuclides possibly because of its early formation 2-2.5 Ma. Ryugu’s parent body which is spectrally blue represents some of the most ancient of carbonaceous chondritic compositions from the solar system. The samples being brought to Earth by Hayabusa2 will give us our first insights into this epoch in solar system history.

Eri Tatsumi↗
NASA NTRSDate not supplied

Progress of chemical characterization of asteroid Ryugu samples

It is believed that meteorites come from asteroids. Samples of asteroid (25143) Itokawa returned by the JAXA Hayabusa mission revealed that S-type asteroids are composed of materials consistent with the ordinary chondrite class[1,2]. The JAXA Hayabusa 2 [3]spacecraft launched on December 3rd, 2014 towards an asteroid (162173) Ryuguto clarify relationships between C-type asteroids and the carbonaceous chondrite class. Remote sensing observations from Hayabusa 2 show that (1) the albedo of Ryugu is darker than those of every known meteorite class[4, 5], (2) an absorption band at 2.72 μm indicates that phyllosilicates are ubiquitous on Ryugu [5],(3) the strength and shape of the absorption band feature suggests that Ryugu materials experienced heating above 300 °C[6], and (4) thermal inertia suggests that Ryugu materials are more porous than every known carbonaceous chondrite[7]. These results suggest that carbonaceous chondrite class materials are plausible for Ryugu materials, but no known carbonaceous chondrite completely matches the results obtained from Ryugu. *Complete abstract available in attached document

Lan Anh Ngoc Nguyen↗
NASA NTRSDate not supplied

Aqueous Alteration on the Ryugu Parent Body Constrained by Chemical Equilibrium Models

The composition of solid samples returned from the asteroid 162173 Ryugu byHayabusa2 indicates aqueous alteration of rocks that formed a parent body of Ryugu [1, 2]. As on parent bodies of carbonaceous chondrites [3-5], Ryugu materials could have went through (1) accretion of anhydrous and reduced rocky grains together with water-rich ices, (2) melting of ices in the body’s interior through release of radiogenic heat [6], and (3)aqueous alteration of rocky and organic materials that produced secondary minerals, salt- and organic-bearing water solutions, gases, and altered organic matter. Although the bulk chemical composition and major mineralogy (phyllosilicates, magnetite, pyrrhotite, carbonates, phosphates, etc.) of Ryugu [1,2]are similar to those of CI carbonaceous chondrites [3-5, 7], the lack of sulfates and a deficiency of oxygen in the returned samples suggest a distinct alteration pathway. Chondritic materials [3-5] do not indicate complete chemical equilibration though low-temperature parent body processes. However, calculations of chemical equilibria in modeling rock-water-gas type systems[e.g., 8, 9], could assess deviations of chondritic materials from equilibrium conditions and constrain partitioning of chemical elements between solid, aqueous, and gas phase for different stages of alteration. Here we constrained speciation of solid, aqueous, and gaseous phases during aqueous alteration on the Ryugu parent body through chemical equilibrium calculations.

M Yu Zolotov↗
NASA NTRSDate not supplied

Olivine Dissolution and Formation of Secondary phases in Ultramafic Soils

Introduction: Olivine has been proposed as an indicator for the duration of water-rock interaction within Martian rocks and sediments [1-3]. The use of olivine as a mineralogical indicator for past aqueous alteration on Mars requires interpretation of a complex combination of factors including pH, temperature, and composition [5,6]. Here, we examine the persistence of natural olivine within terrestrial ultramafic soils (Fe/Mg-rich, Al-poor) developing under different climatic conditions and the incipient dissolution of emplaced forsterite (Fo) and fayalite (Fa) surfaces to investigate environmental effects on incipient olivine dissolution, olivine persistence in soils, and formation of secondary phases. Methods: Field Sites. We examined olivine weathering and secondary material formation in ultramafic soils at 6 sites in the Klamath Mountains (KM) of northern California with a mean annual temperature of ~12.8℃ and precipitation of ~55.7-95.4 cm/year [7], and soil pH of ~6.5-7.3; 4 sites in the Tablelands (TB) of Newfoundland, Canada with a mean annual temperature of <3.9℃ and precipitation of ~120.0 cm/year [8], and soil pH of ~7.7; and at 3 sites at Pickhandle Gulch (PG), Nevada with a mean annual temperature of ~14.4℃ and precipitation of ~14.1 cm/year [7], and soil pH of ~8.5. Sampling sites span an age range of ~12.1-50+ kya in the Klamath Mountains [9,10] and ~13-30 kya in the Tablelands [11]. Pickhandle Gulch sites are undated. Parent Material and Soil Analyses. Polished thin sections of bulk soil prepared by Wagner Petrographic, Inc were carbon-coated and analyzed on a JEOL 2100 SEM in back-scattered electron mode in the EMIL lab at UNLV and at the 13-ID-E synchrotron beamline at Argonne National Laboratory using µXRF, µXRD, and XAS. Soil and parent material samples were powdered in a Fritsch pulverisette and analyzed by XRD and soil by VNIR. Soil preparation is further described in [12]. Disk Preparation, Burial, and Collection. Fo disks were cut from a column prepared via hot-pressing and Fa disks by sintering synthetic fayalite powder, see [13] for detail. Disks were polished to a 0.25-micron level with diamond grit. Disks were buried in 3 KM soils, 4 TB soils, and 3 PG soils, collected after exactly 365 days, and washed gently with 100% reagent grade ethanol to remove potential adhered soil material. Weathered disks and soil samples were stored in a -20℃ freezer until analysis. Unaltered control disks prepared identically to the buried disks were stored at -20℃ for the duration of the experiment. Disk Analyses. One Fo and Fa disk from each climate zone was analyzed on a variable pressure Zeiss Supra 40VP SEM at Northern Arizona University. A separate Fo and Fa disk from each climate zone was analyzed by XPS using a Physical Electronics VersaProbe II at the Penn State Univ. Materials Characterization Lab after a Na-dodecyl sulfate wash and ozonation to remove carbon contamination as in [14]. VNIR measurements were conducted at Johnson Space Center using an ASD FieldSpec3 under ambient lab conditions on a separate Fo and Fa disk from each climate zone. One separate Fo and Fa control sample was analyzed for each technique for comparison with weathered samples. XPS uncertainty was determined from 5 repeat measurements on controls. Results: Bedrock and Soil Results Olivine is present in the parent material in the KM and TB. Olivine is found in ~12.1 ka KM soils but is absent from all older soils, while persisting into the oldest (>20 ka) TB soil (Figure 1). In both locations, olivine is found as cores surrounded by a serpentine rind (Figure 2). VNIR spectra from the analyzed soils possess strong OH-associated spectral features at ~2.33 µm indicating the presence of Mg-rich phyllosilicates as well as ferric-oxide features at ~0.92 µm in the KM (Figure 3). Primary crystalline silicate grains mostly incorporate Fe2+, while poorly crystalline weathering rinds are best fit by ferric oxide XAS standards (Figure 4). µXRF also shows that Fe and Ni concentrate in weathering rinds and Cr remains within interior silicate grains (Figure 4). Buried Sample Results All Fo surfaces exhibited formation of dissolution features including shallow pitting not observed on controls. Dissolution features were most visually widespread on the KM disk (Figure 5). Leaching of Mg from KM and TB Fo disks was evident from <1.6 Mg/Si ratios measured by XPS (Figure 6). Fe-rich precipitates in SEM (Figure 5) and Fe presence in XPS scans (Figure 6) indicate Fe deposition onto KM and TB Fo disk surfaces. The appearance of a spectral feature at 0.55 µm in the VNIR spectra from the TB Fo suggests this Fe is ferric (Figure 7). The PG Fo appears least altered, with minimal formation of dissolution features in SEM (Figure 5), a Mg/Si ratio inconsistent with leaching (~2) (Figure 6), and VNIR spectra almost identical to the control sample. Analysis of Fa surfaces is ongoing. The higher temperatures and more acidic pH in the KM soils likely drive the faster dissolution of the Fo disks described above. While the TB soils experience greater precipitation than in the KM, the cooler temperatures and more basic soil pH facilitate observable but more limited alteration. The dry climate and basic soil pH at PG lead to minimal dissolution of the PG disk surfaces.

A D Feldman↗
NASA NTRSDate not supplied

Formation of Fe(III) (hydr)oxides from Fe(II) sulfides: Implications for akaganeite detection on Mars

Akaganeite (β-FeO(OH,Cl)) is a Fe(III) (hydr)oxide with a tunnel structure typically occupied by chloride. This mineral was first proposed to be present in Meridiani Planum and Gusev crater on Mars and akaganeite was subsequently detected by X-ray diffraction in Yellowknife Bay and Vera Rubin Ridge locations in Gale crater. Akaganeite in Gale crater has been proposed to form from Fe(II) sulfides but formation conditions remain unconstrained. We investigated akageneite formation by oxidative alteration of natural Fe(II) sulfide pyrrhotite exposed to HCl and oxidation-hydrolysis of Fe(II) HCl-leached from pyrrhotite at initial pH0 1.5, 2, 3, and 4. X-ray diffraction and Mössbauer analyses revealed formation of poorly-crystallized akageneite in oxidative alteration experiments. Air-exposure of the HCl-reacted dry pyrrhotite led to an increase in akageneite formation and precipitation of Fe(II) hydrated sulfates, goethite, and hydronium jarosite. Iron(II) oxidation-hydrolysis was sensitive to Si dissolved from phyllosilicates in one pyrrhotite sample. Akaganeite and goethite formed at pH0 1.5 and 2 with akageneite more abundant at dissolved Si/Fe ratio of 0.08 and goethite more abundant at Si/Fe of 0.01. Akaganeite formed together with hematite, ferrihydrite, and goethite at pH0 3, and formation was suppressed at pH0 4. Well-crystallized akageneite precipitated at pH0 1.5 while akaganeite of poorer crystallinity formed at pH0 2 and 3. Akageneite in Gale crater could form from sulfides by both mechanisms: oxidative alteration of sulfide minerals and oxidation-hydrolysis of leached Fe(II). The processes likely occurred during late diagenetic events triggered by interactions of acidic Cl-bearing groundwater with Fe(II) sulfides. Akaganeite in Yellowknife Bay, Gale crater could have formed by Fe(II) oxidation-hydrolysis either as a sole Fe(III) (hydr)oxide at pH<2 or along with ferrihydrite and hematite at 2<pH<4 in Si-enriched conditions. Akaganeite formation at Vera Rubin Ridge, Gale crater could have occurred through oxidative alteration of sulfides in Cl-bearing pH 1.2-1.5 solutions. The presence of well-crystalline akageneite in Vera Rubin Ridge indicates that Fe(II) oxidation-hydrolysis contributed to akageneite formation.

Mars gale crater akaganeite↗
NASA NTRSDate not supplied

Olivine Mineralogy of Asteroid Ryugu Samples and CI Chondrites: Further Evidence for their Common Origin

Initial analysis of asteroid Ryugu samples has revealed that they were mm-mm scale brecciamostly composed of aqueously altered phases (e.g., Mg-Fe phyllosilicates, carbonates) and showed remarkablesimilarities to CI chondrites in mineralogy and chemistry [e.g., 1,2]. Our detailed analysis of Ryugu samples hasdetected small amounts (<<1 vol.%) of unaltered silicates that would escape severe aqueous alteration [3]. Olivine isthe most abundant (>90 vol%) phase among such unaltered silicates. Although most Ryugu olivine grains aresmaller than 5 mm, they bear important information about the precursors of the parent Ryugu asteroid. In thisabstract we report additional results of olivine mineralogical study of Ryugu samples, and especially compare witholivine grains in CI chondrites (Ivuna and Orgueil) to further discuss their relationship and possible common origin.

T. Mikouchi↗
NASA NTRS2021

Mineralogy, Petrology, and Oxygen-isotope Compositions of Magnetite ± Fayalite Assemblages in CO3, CV3, and LL3 Chondrites

We report on the mineralogy, petrology, and O-isotope compositions of magnetite and fayalite (Fa90−100) from several metasomatically altered and weakly metamorphosed carbonaceous (Y-81020 [CO3.05], EET 90043 [CO3.1], MAC 88107 [CO3.1-like], and Kaba [oxidized Bali-like CV3.1]) and unequilibrated ordinary chondrites (UOCs; Semarkona [LL3.00], MET 00452 [LL3.05], MET 96503 [LL3.05], EET 910161 [LL3.05], Ngawi [LL3.0−3.6 breccia], and Vicencia [LL3.2]). In MAC 88107, EET 90043, and Kaba, nearly pure fayalite (Fa98−100) associates with phyllosilicates, magnetite, Fe, Ni-sulfides, and hedenbergite (Fs~50Wo~50), and occurs in all chondritic components—chondrules, matrices,and refractory inclusions. In UOCs, nearly pure fayalite (Fa95−98) associates withphyllosilicates and magnetite, and occurs mainly in matrices and fine-grained chondrulerims. Oxygen-isotope compositions of fayalite and magnetite in UOCs, COs, CVs, and MAC 88107 are in disequilibrium with those of chondrule olivine and low-Ca pyroxene phenocrysts, and plot along mass-dependent fractionation lines with slope of~0.5, butdifferent 17O (~+4.3 1.4‰,−0.2 0.6‰,−1.5 1‰, and−1.8 0.8‰, respectively). Based on the mineralogical observations, thermodynamic analysis, O-isotope compositions, and recently reported experimental data, we infer that (1) fayalite and magnetite in COs,CVs, MAC 88107, and UOCs resulted from aqueous fluid–rock interaction on the chondrite parent asteroids that occurred at low local water-to-rock mass ratios (0.1−0.4) and elevated temperatures (~100−300°C), and (2) 17O of fayalite and magnetite reflects O-isotope compositions of aqueous fluids on the host meteorite parent bodies. The observed differences in 17O of fayalite–magnetite assemblages in UOCs, CVs, COs, and MAC 88107suggest that water ices that accreted into the ordinary chondrite and carbonaceous chondrite parent asteroids had different 17O, implying spatial and/or temporal variations in O-isotope compositions of water in the protoplanetary disk.

Alexander N Krot↗
NASA NTRS2024

Chemical and Physical Properties of Cometary Dust

Cometary dust particles are best preserved remnants of the matter present at the onset of the formation of the Solar System. In Space missions, telescopic observations and laboratory analyses advanced the knowledge on the properties of cometary dust. the only samples certified with a cometary origin were returned by the Stardust space mission from comet 81P/Wild2. The “chondritic porous” (here called “chondritic anhydrous”) interplanetary dust particles (CA-IDPs) and micrometeorites (CP-MMs), and the ultracarbonaceous Antarctic MMs (UCAMMs) also show strong evidence for a cometary origin. The elemental composition of cometary dust is generally consistent with the chondritic (CI) composition, with the notable exception of elevated contents in carbon and nitrogen compared with CI. The organic matter of cometary dust is mixed with minor amounts of crystalline (at least 25% of the minerals) and amorphous mineral phases. The most abundant crystalline minerals are ferromagnesian silicates (olivine and low-Ca pyroxenes), but High-Ca pyroxenes, refractory minerals and Low Ni Fe sulfides are also present. The crystalline olivine and low-Ca pyroxene compositions can vary from their Mg-rich end-member (forsterite and enstatite) to relatively Fe-rich compositions. Refractory minerals as well as secondary minerals likeLIME (low-iron, Mn-enriched) olivines, unusual Fe sulfides or mineral aggregates of specific compositions like Kosmochloric high-Ca pyroxene and FeO-rich olivine - KOOL grains) are also found. The presence of carbonates in cometary dust is still debated, but a phyllosilicate-like phase was observed in a UCAMM. The abundance of pyroxene to olivine (in numbers) is larger than in primitive meteorites (e.g. the Px/Ol ratio is usually larger than 1). GEMS phases (glass with embedded metals and sulfides) are abundant in cometary dust, although not systematically found. Some of the organic matter present in cometary dust particle resembles the insoluble organic matter (IOM) present in primitive meteorites, but amorphous carbon and exotic (e.g. N-rich) organic phases are also present. The hydrogen isotopic composition of cometary dust particles (in the organic matter) is usually rich in deuterium, tracing a formation at very low temperatures, either in the protosolar cloud or in the outer regions of the protoplanetary disk. The presolar dust concentration in cometary dust can reach about 1%, which is the most elevated value observed in extraterrestrial samples. The size distribution of cometary dust in comet trails is well represented by a power-law distribution (differential size distribution) with a mean power index N typically ranging from -3 to -4. Polarimetric and light scattering studies of cometary dust suggest mixtures of porous agglomerates of sub-micrometer minerals with organic matter, which is compatible with the in situ analyses of 67P/Churyumov-Gerasimenko by MIDAS (Rosetta) and with the studies of it Stardust samples, CA-IDPs, CP-MMs and UCAMMs. Cometary dust particles have low tensile strength, and low density.

C. Engrand↗
NASA NTRS2022

The First Returned Samples From A C-Type Asteroid Show Kinship to the Chemically Most Primitive Meteorites

Bulk chemical and isotopic compositions, and mineralogy in the asteroid (162173) Ryugu samples show that Ryugu is mainly composed of materials related to the CI (Ivuna-like) carbonaceous chondrite group. The samples consist predominantly of minerals produced by aqueous alteration in a parent planetesimal from which Ryugu was derived. The 53Mn-53Cr systematics of dolomite suggest that this alteration occurred 5.2 (+0.7/–0.8) million years after formation of Ca-Al-rich inclusions, the first solids formed in the Solar System. The aqueous alteration temperature at the time dolomite and magnetite coprecipitated was 37±10°C. Unlike in CI chondrites, phyllosilicates in Ryugu have lost most of their interlayer water, but retained structural water. This indicates that following aqueous alteration the Ryugu samples avoided heating above ~90°C.

Tetsuya Yokoyama↗