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Rejection of low-molecular weight neutral organics is highly sensitive to reverse osmosis system design and operation

A computational model was developed to investigate the significance of system design and operating conditions on the rejection of neutral, low-MW organics by reverse osmosis for potable reuse. Here, the model demonstrated that the decrease in local rejection as net driving pressure decreases is substantially greater for moderately rejected compounds than for highly rejected compounds. At recovery values less than 70%, the local permeate concentration can exceed the pressure vessel feed concentration for moderately rejected compounds. System-level rejection of moderately rejected compounds is likewise substantially more sensitive to operating conditions than highly rejected compounds. The findings highlight a drawback of relying on rejection results from bench-scale testing that operates at low recovery, which invariably has higher rejection than full-scale systems operating at similar pressure. The analysis demonstrates a trade-off in which the low-pressure, high-recovery operation desired for potable reuse systems can be detrimental to the removal of low-MW neutral organics. The removal of low-MW neutral organics can be improved if organics rejection is explicitly evaluated during the design process.

42 ENGINEERING↗

Spatial orientation and balance control changes induced by altered gravitoinertial force vectors

To better understand the mechanisms of human adaptation to rotating environments, we exposed 19 healthy subjects and 8 vestibular-deficient subjects ("abnormal"; four bilateral and four unilateral lesions) to an interaural centripetal acceleration of 1 g (resultant 45 degrees roll-tilt of 1.4 g) on a 0.8-m-radius centrifuge for periods of 90 min. The subjects sat upright (body z-axis parallel to centrifuge rotation axis) in the dark with head stationary, except during 4 min of every 10 min, when they performed head saccades toward visual targets switched on at 3- to 5-s intervals at random locations (within +/- 30 degrees) in the earth-horizontal plane. Eight of the normal subjects also performed the head saccade protocol in a stationary chair adjusted to a static roll-tilt angle of 45 degrees for 90 min (reproducing the change in orientation but not the magnitude of the gravitoinertial force on the centrifuge). Eye movements, including voluntary saccades directed along perceived earth- and head-referenced planes, were recorded before, during, and immediately after centrifugation. Postural center of pressure (COP) and multisegment body kinematics were also gathered before and within 10 min after centrifugation. Normal subjects overestimated roll-tilt during centrifugation and revealed errors in perception of head-vertical provided by directed saccades. Errors in this perceptual response tended to increase with time and became significant after approximately 30 min. Motion-sickness symptoms caused approximately 25% of normal subjects to limit their head movements during centrifugation and led three normal subjects to stop the test early. Immediately after centrifugation, subjects reported feeling tilted 10 degrees in the opposite direction, which was in agreement with the direction of their earth-referenced directed saccades. Postural COP, segmental body motion amplitude, and hip-sway frequency increased significantly after centrifugation. These postural effects were short-lived, however, with a recovery time of several postural test trials (minutes). There were also asymmetries in the direction of postcentrifugation COP and head tilt which depended on the subject's orientation during the centrifugation adaptation period (left ear or right ear out). The amount of total head movements during centrifugation correlated poorly or inversely with postcentrifugation postural stability, and the most unstable subject made no head movements. There was no decrease in postural stability after static tilt, although these subjects also reported a perceived tilt briefly after return to upright, and they also had COP asymmetries. Abnormal subjects underestimated roll-tilt during centrifugation, and their directed saccades revealed permanent spatial distortions. Bilateral abnormal subjects started out with poor postural control, but showed no postural decrements after centrifugation, while unilateral abnormal subjects had varying degrees of postural decrement, both in their everyday function and as a result of experiencing the centrifugation. In addition, three unilateral, abnormal subjects, who rode twice in opposite orientations, revealed a consistent orthogonal pattern of COP offsets after centrifugation. These results suggest that both orientation and magnitude of the gravitoinertial vector are used by the central nervous system for calibration of multiple orientation systems. A change in the background gravitoinertial force (otolith input) can rapidly initiate postural and perceptual adaptation in several sensorimotor systems, independent of a structured visual surround.

Clinical Trial↗

Testing of an Iodine and Tritium Capture System for an NO₂-Based Tritium Pretreatment Process

The reprocessing of used nuclear fuel would release volatile radionuclides into the off-gas streams of a processing plant, including ³H, ¹⁴C, ⁸⁵Kr, and ¹²⁹I. One potential simplification to the management of the off-gas streams could be achieved through an efficient tritium pretreatment (TPT) step in which the UO₂ fuel is oxidized by either air or NO₂ before dissolution. The oxidation of the UO₂ fuel matrix will result in the release of tritium from the fuel. Upfront release of tritium from the fuel in a pretreatment step with subsequent tritium abatement can minimize or eliminate the distribution of tritium throughout a plant. This can decrease or eliminate the need for tritium capture on multiple off-gas streams and prevent distribution to the aqueous inventory. The use of NO₂ as the oxidant in an advanced tritium pretreatment (ATPT) allows for the oxidation to be performed at lower temperatures and may also result in the quantitative release of iodine from the fuel. The ATPT off-gas will contain up to 75 vol% NO₂ gas. Spencer et al. identified the most promising iodine sorbent as silver nitrate-impregnated alumina (AgA) and the most promising tritium sorbents as 3Å molecular sieve (3Å MS) and silica gel for radionuclide capture from ATPT off-gas streams. An initial series of tests were conducted in fiscal years 2017–2018 with the intent of demonstrating the recovery of iodine and tritium using these sorbents from a recirculating gas stream that simulated the NO₂ recycle loop envisioned for the ATPT system. These initial tests showed low tritium recoveries and significant variations in the iodine recovery on the AgA. Ultimately it was concluded, following disassembly of the system, that corrosion within the system was partially the cause of the poor recovery of both species. All components of that system were disposed of at the end of the analysis. One of the conclusions drawn from the initial tests pointed to the reconsideration of the materials of construction. Based on that recommendation a new test bed for the advanced TPT off-gas system, that addresses the issues identified in the fiscal years 2017 and 2018 scoping tests, was designed and constructed. The test bed used high nickel alloys wherever possible to address the previously observed corrosion issues, a redesigned surge tank to permit ease of purging, an improved feed injection system and a more modular system design that allowed testing of incremental increases in system complexity to allow the isolation of any element that results in changes to recovery of target species. Accompanying that design, a multifaceted test plan was completed. The overarching goals of this test series were two-fold. The first goal was to demonstrate the ability to recover both the iodine and tritium that would be released during TPT in a manner that the releases from the fuel can be quantified. The second goal was to demonstrate that the combined recovery system could operate in any of the three proposed TPT modes (once-through air or O₂, recirculating air or O₂, or recirculating NO x ). A total of 22 tests were completed. Ten tests examined tritium behavior under varying operating parameters, 8 tests examined iodine behavior under varying operating parameters, and 4 tests examined both tritium and iodine behavior. Silica gel was used for the tritium sorbent, and AgA or Ag-mordenite (AgZ) was used as the iodine sorbent. The following conclusions were drawn: Full recovery is achieved for both sorbates when no sorbent is in place indicating no accumulation within the test system. In even the simplest of the configurations (i.e., no sorbents in the columns), iodine is more difficult to transport and recover from the system than tritium. Analysis of the AgA iodine sorbent beds from the integrated tritium and iodine tests indicate quantitative iodine recovery can be achieved (within anticipated experimental errors). This system may provide a means for the quantification of the iodine released by the ATPT process within the experimental uncertainties. This would support 0.33 to 1.00 kg demonstrations of the ATPT process with actual used nuclear fuel. Iodine penetrated further into AgZ than into AgA when operated in gas recirculation mode. Tritium adsorbs to and cannot be fully recovered from the 10-cm column of silica gel at regeneration temperatures up to 140 °C.; Tritium adsorbs to and cannot be recovered from the 10-cm column of AgA at desorption temperatures up to 200 °C. Co-adsorbed tritium was recovered to a greater extent from AgZ than from AgA, but recovery was not complete. No visible corrosion was observed in the test system.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Power System Recovery Coordinated with (Non-)Black-Start Generators

Power restoration is an urgent task after a black-out, and recovery efficiency is critical when quantifying system resilience. Multiple elements should be considered to restore the power system quickly and safely. This paper proposes a recovery model to solve a direct-current optimal power flow (DCOPF) based on mixed-integer linear programming (MILP). Since most of the generators cannot start independently, the interaction between black-start (BS) and non-black-start (NBS) generators must be modeled appropriately. The energization status of the NBS is coordinated with the recovery status of transmission lines, and both of them are modeled as binary variables. Also, only after an NBS unit receives the cranking power through connected transmission lines, will it be allowed to participate in the following system dispatch. The amount of cranking power is estimated as a fixed proportion to the maximum generation capacity. The proposed model is validated on several test systems, as well as a 1393-bus representation system of the Puerto Rican electric power grid. Test results demonstrate how the recovery of NBS units and damaged transmission lines can be optimized, resulting in an efficient and well-coordinated recovery procedure.

Zhao, Meng↗

Performance Efficient Launch Vehicle Recovery and Reuse

For decades, economic reuse of launch vehicles has been an elusive goal. Recent attempts at demonstrating elements of launch vehicle recovery for reuse have invigorated a debate over the merits of different approaches. The parameter most often used to assess the cost of access to space is dollars-per-kilogram to orbit. When comparing reusable vs. expendable launch vehicles, that ratio has been shown to be most sensitive to the performance lost as a result of enabling the reusability. This paper will briefly review the historical background and results of recent attempts to recover launch vehicle assets for reuse. The business case for reuse will be reviewed, with emphasis on the performance expended to recover those assets, and the practicality of the most ambitious reuse concept, namely propulsive return to the launch site. In 2015, United Launch Alliance (ULA) announced its Sensible, Modular, Autonomous Return Technology (SMART) reuse plan for recovery of the booster module for its new Vulcan launch vehicle. That plan employs a non-propulsive approach where atmospheric entry, descent and landing (EDL) technologies are utilized. Elements of such a system have a wide variety of applications, from recovery of launch vehicle elements in suborbital trajectories all the way to human space exploration. This paper will include an update on ULA's booster module recovery approach, which relies on Hypersonic Inflatable Aerodynamic Decelerator (HIAD) and Mid-Air Retrieval (MAR) technologies, including its concept of operations (ConOps). The HIAD design, as well as parafoil staging and MAR concepts, will be discussed. Recent HIAD development activities and near term plans including scalability, next generation materials for the inflatable structure and heat shield, and gas generator inflation systems will be provided. MAR topics will include the ConOps for recovery, helicopter selection and staging, and the state of the art of parachute recovery systems using large parafoils for space asset recovery and high altitude deployment. The next proposed HIAD flight demonstration is called HULA (for HIAD on ULA), and will feature a 6m diameter HIAD. An update for the HULA concept will be provided in this paper. As proposed, this demonstration will fly as a secondary payload on an Atlas mission. The Centaur upper stage provides the reentry pointing, deorbit burn, and entry vehicle spin up. The flight test will culminate with a recovery of the HIAD using MAR. HULA will provide data from a Low Earth Orbit (LEO) return aeroheating environment that enables predictive model correlation and refinement. The resultant reduction in performance uncertainties should lead to design efficiencies that are increasingly significant at larger scales. Relevance to human scale Mars EDL using a HIAD will also be presented, and the applicability of the data generated from both HULA and SMART Vulcan flights, and its value for NASA's human exploration efforts will be discussed. A summary and conclusion will follow.

Reed, John G.↗

Spin flight research summary

An extensive general aviation stall/spin research program is underway at the NASA Langley Research Center. Flight tests have examined the effects of tail design, wing leading edge design, mass distribution, and minor airframe modifications on spin and recovery characteristics. Results and observations on test techniques are presented for the first airplane in the program. Configuration changes produced spins varying from easily recoverable slow, steep spins to unrecoverable, fast flat spins.

Patton, J. M., Jr.↗

Balloon materials degradation (S1006)

The objective of this experiment is to assess the effects of long-term exposure of candidate balloon films, tapes, and lines to the hostile environment above the Earth's atmosphere. Degradation of mechanical and radiometric properties will be observed by a series of tests on exposed materials. The experiment is passive and will test candidate balloon films, tapes, and lines. The experiment will occupy one-third of a 3-in.-deep peripheral tray. Two additional identical sets of material will be prepared. The first set will be tested immediately and the second will be held in a controlled environment until the recovery of the samples placed on orbit. Tests will then be performed on this second set to determine any effects of aging. The specimens that are recovered from the Long Duration Exposure Facility will also be tested and the effects of long-duration exposure noted. In addition to these specimens, another set of specimens will be exposed at an accelerated exposure facility and the results will be compared with those of specimens exposed in situ.

Allen, D. H.↗

Preliminary fatigue tests on short-crack specimens

The objective of the preliminary fatigue tests was to determine the stress levels to be used by the participants in the Cooperative Test Program. As previously mentioned, the United States Air Force Wright-Patterson Aeronautical Laboratory machined about 700 single-edge-notched tension (SENT) specimens from material supplied by the NASA Langley Research Center. In addition, NASA Langley machined about 50 SENT specimens from the same material. Comparison of fatigue tests conducted on the two sets of specimens indicated a large difference in fatigue behavior under constant-amplitude loading. A recovery program was initiated to resolve this difference before the specimens were distributed to participants. The following sections describe the recovery program and the preliminary fatigue tests and analyses conducted to determine stress levels for constant-amplitude, FALSTAFF, and Gaussian loading.

Newman, J. C., Jr.↗

Sasquatch Footprint Tool

The Crew Exploration Vehicle Parachute Assembly System (CPAS) is the parachute system for NASA s Orion spacecraft. The test program consists of numerous drop tests, wherein a test article rigged with parachutes is extracted or released from an aircraft. During such tests, range safety is paramount, as is the recoverability of the parachutes and test article. It is crucial to establish an aircraft release point that will ensure that the article and all items released from it will land in safe locations. A new footprint predictor tool, called Sasquatch, was created in MATLAB. This tool takes in a simulated trajectory for the test article, information about all released objects, and atmospheric wind data (simulated or actual) to calculate the trajectories of the released objects. Dispersions are applied to the landing locations of those objects, taking into account the variability of winds, aircraft release point, and object descent rate. Sasquatch establishes a payload release point (e.g., where the payload will be extracted from the carrier aircraft) that will ensure that the payload and all objects released from it will land in a specified cleared area. The landing locations (the final points in the trajectories) are plotted on a map of the test range. Sasquatch was originally designed for CPAS drop tests and includes extensive information about both the CPAS hardware and the primary test range used for CPAS testing. However, it can easily be adapted for more complex CPAS drop tests, other NASA projects, and commercial partners. CPAS has developed the Sasquatch footprint tool to ensure range safety during parachute drop tests. Sasquatch is well correlated to test data and continues to ensure the safety of test personnel as well as the safe recovery of all equipment. The tool will continue to be modified based on new test data, improving predictions and providing added capability to meet the requirements of more complex testing.

Bledsoe, Kristin↗

Aircraft ship operations

Worldwide interest in the use of shipborne aircraft as a major weapons system is very broad. Many NATO countries operate fixed wing aircraft from ships. Additionally, the use of ships as helicopter platforms is extensive in the NATO community and brings another import dimension to the aircraft/ship interface issue. Thus, it seemed that both fixed and rotary wing aviation deserved equal billing in the Aircraft/Ship Interface Symposium which is the subject of this Technical Evaluation Report. This Symposium was held in Seville, Spain, from 20th to 23rd May 1991 and was the first Symposium sponsored by the AGARD Flight Mechanics Panel devoted to this topic. The Symposium contained twenty-five presentations grouped under the following topics: Keynote Addresses; Ship Environment; Guidance, Controls, and Displays; Flight Test and Simulation Techniques; Launch, Recovery, and Handling Systems Development; and Operational Views and Future Developments. The full texts of the papers presented at this Symposium are published in AGARD-CP-509.

Aircraft carriers↗

The Combined Influence of Molecular Weight and Temperature on the Aging and Viscoelastic Response of a Glassy Thermoplastic Polyimide

The effect of molecular weight on the viscoelastic performance of an advanced polymer (LaRC-SI) was investigated through the use of creep compliance tests. Testing consisted of short-term isothermal creep and recovery with the creep segments performed under constant load. The tests were conducted at three temperatures below the glass transition temperature of five materials of different molecular weight. Through the use of time-aging-time superposition procedures, the material constants, material master curves and aging-related parameters were evaluated at each temperature for a given molecular weight. The time-temperature superposition technique helped to describe the effect of temperature on the timescale of the viscoelastic response of each molecular weight. It was shown that the low molecular weight materials have higher creep compliance and creep rate, and are more sensitive to temperature than the high molecular weight materials. Furthermore, a critical molecular weight transition was observed to occur at a weight-average molecular weight of M (bar) (sub w) 25000 g/mol below which, the temperature sensitivity of the time-temperature superposition shift factor increases rapidly. The short-term creep compliance data were used in association with Struik's effective time theory to predict the long-term creep compliance behavior for the different molecular weights. At long timescales, physical aging serves to significantly decrease the creep compliance and creep rate of all the materials tested.

Nicholson, Lee M.↗

Molecular Weight Effects on the Viscoelastic Response of a Polyimide

The effect of molecular weight on the viscoelastic performance of an advanced polymer (LaRC -SI) was investigated through the use of creep compliance tests. Testing consisted of short-term isothermal creep and recovery with the creep segments performed under constant load. The tests were conducted at three temperatures below the glass transition temperature of each material with different molecular weight. Through the use of time-aging-time superposition procedures, the material constants, material master curves and aging-related parameters were evaluated at each temperature for a given molecular weight. The time-temperature superposition technique helped to describe the effect of temperature on the timescale of the viscoelastic response of each molecular weight. It was shown that the low molecular weight materials have increased creep compliance and creep compliance rate, and are more sensitive to temperature than the high molecular weight materials. Furthermore, a critical molecular weight transition was observed to occur at a weight-average molecular weight of approximately 25000 g/mol below which, the temperature sensitivity of the time-temperature superposition shift factor increases rapidly.

Nicholson, Lee M.↗

Spatial Orientation and Balance Control Changes Induced by Altered Gravito-Inertial Force Vectors

Seventeen healthy and eight vestibular deficient subjects were exposed to an interaural centripetal acceleration of 1 G (resultant 45 deg roll tilt of 1.4 G) on a 0.8 meter radius centrifuge for a period of 90 minutes in the dark. The subjects sat with head fixed upright, except every 4 of 10 minutes when instructed to rotate their head so that their nose and eyes pointed towards a visual point switched on every 3 to 5 seconds at random places (within +/- 30 deg) in the Earth horizontal plane. Motion sickness caused some subjects to limit their head movements during significant portions of the 90 minute period, and led three normal subjects to stop the test earlier. Eye movements, including directed saccades for subjective Earth- and head-referenced planes, were recorded before, during, and immediately after centrifugation using electro-oculography. Postural stability measurements were made before and within ten minutes after centrifugation. In normal subjects, postural sway and multisegment body kinematics were gathered during an eyes-closed head movement cadence (sway-referenced support platform), and in response to translational/rotational platform perturbations. A significant increase in postural sway, segmental motion amplitude and hip frequency was observed after centrifugation. This effect was short-lived, with a recovery time of several postural test trials. There were also asymmetries in the direction of post-centrifugation center of sway and head tilt which depended on the subject's orientation during the centrifugation adaptation period (left ear or right ear out). To delineate the effect of the magnitude of the gravito-inertial vector versus its direction during the adaptive centrifugation period, we tilted eight normal subjects in the roll axis at a 45 deg angle in the dark for 90 minutes without rotational motion. Their postural responses did not change following the period of tilt. Based on verbal reports, normal subjects overestimated roll-tilt during 90 minutes of both tilt and centrifugation stimuli. Subjective estimates of head-horizontal, provided by directed saccades, revealed significant errors after approximately 30 minutes that tended to increase only in the group who underwent centrifugation. Immediately after centrifugation, subjects reported feeling tilted on average 10 degrees in the opposite direction, which was in agreement with the direction of their earth-directed saccades. In vestibular deficient (VD) subjects, postural sway was measured using a sway-referenced or earth-fixed support surface, and with or without a head movement sequence. 'Me protocol was selected for each patient during baseline testing, and corresponded to the most challenging condition in which the patient was able to maintain balance with eyes closed. Bilaterally VD subjects showed no postural decrement after centrifugation, while unilateral VD subjects had varying degrees of decrement. Unilateral VD subjects were tested twice; they underwent centrifugation both with right ear out and left ear out. Their post-centrifuation center of sway shifted at right angles depending on the centrifuge GIF orientation. Bilateral VD subjects bad shifts as well, but no consistent directional trend. VD subjects underestimated roll-tilt during centrifugation, These results suggest that orientation of the gravito-inertial vector and its magnitude arc both used by the central nervous system for calibration of multiple orientation systems. A change in the background gravito-inertial force (otolith input) can rapidly initiate postural and perceptual adaptation in several sensorimotor systems, independent of a structured visual surround.

Kaufman, Galen D.↗

Comprehensive Evaluation of Electrochemical Hydrogen Separator as Hydrogen Recovery Solution for Plasma Pyrolysis Assembly

The previously tested State-of-the-Art (SOA) air revitalization architecture onboard the International Space Station recovers approximately 50% of the oxygen (O 2 ) from metabolic carbon dioxide (CO 2 ) via the Sabatier process. Maximum O 2 recovery is required to reduce resupply mass for long-duration manned missions. O 2 recovery is constrained by the limited availability of reactant hydrogen (H 2 ) from water (H 2 O) electrolysis, and Sabatier-produced methane (CH 4 ) is vented as a waste product resulting in a continuous loss of reactant H 2 . The Plasma Pyrolysis Assembly (PPA) has the potential to substantially increase O 2 recovery by post-processing the Sabatier-produced methane to recover H 2 . The PPA decomposes CH 4 into predominately H 2 and acetylene (C 2 H 2 ). A separation system is needed to purify the H 2 from the PPA stream before it is recycled back to the Sabatier reactor. Two sub-scale electrochemical H 2 separation systems, developed by Skyre, Incorporated, were delivered to NASA for evaluation. Complimentary of the previous submittal, ICES-2023-260, this paper reports a summation of Phase I and Phase II testing and evaluation of the C 2 H 2 removal systems as well as lessons learned.

Plasma Pyrolysis Assembly↗

Free-Spinning and Recovery Characteristics of a 1/19-Scale Model of the North American T-28C Airplane, TED No. NACA AD 3127

An investigation has been conducted in the Langley 20-foot free-spinning tunnel on a l/19-scale model of the North American T-28C airplane to determine the spin and recovery characteristics. The T-28C airplane is similar to the T-28B airplane except for slight modifications for the arresting hook. The lower rear section of the fuselage was cut out and, consequently, the lower part of the rudder was removed to make a smooth fairing with the fuselage. The T-28B airplane had good recovery characteristics; but these modifications, along with the addition of gun packages on the wings, led to poor and unsatisfactory spin-recovery characteristics during demonstration spins of the T-28C airplane. Model test results indicated that without the gun packages installed, satisfactory recoveries could be obtained if the elevators were held full back while the rudder was fully reversed and the ailerons were held neutral. However, with the addition of gun packages to the wings and the corresponding change in loading, recoveries were considered unsatisfactory. Recoveries attempted by using a larger chord or larger span rudder were improved very slightly, but were still considered marginal or unsatisfactory. Strakes placed on the nose of the model were effective in slowing the spin rotation slightly and, in most instances, decreased the turns for recovery slightly. Recovery characteristics were slightly marginal for the full fuel loading when strakes and the extended-chord rudder were installed; but with the wing fuel partly used, recovery characteristics were again considered unsatisfactory or, at least, definitely on the marginal side. The optimum control technique for recovery is movement of the rudder to full against the spin with the stick held full back (elevators full up) and the ailerons held neutral, followed by forward movement of the stick only after the spin rotation ceases. Inverted-spin test results indicate that the airplane will spin steep and fast and that recovery by full rudder reversal will be satisfactory if the ailerons are held neutral.

Bowman, James S., Jr.↗

Probing the Damage Recovery Mechanism in Irradiated Stainless Steels Using In-Situ Microcantilever Bending Test

Single crystalline microcantilevers are fabricated from the base metal and heat-affected zone (HAZ) of a laser welded, neutron irradiated austenitic stainless steel, for scanning electron microscope (SEM) in-situ bending. In the HAZ, cantilevers exhibit higher yield point and lower crack tip blunting displacement than in the base metal and unirradiated archive specimen. These results suggest that radiation-induced defects harden the base metal, whereas the HAZ exhibits annealing of defects leading to mechanical softening. Dislocation nucleation ahead of the crack tip is responsible for ductile blunting behavior and provides a pathway to mitigating helium-induced cracking during weld repairs of irradiated materials.

36 MATERIALS SCIENCE↗

Development of software fault-tolerance techniques

As computers become more widely used, and in particular as they become used in more safety critical applications, the reliability of the computer system and its software becomes more important. There is also an increasing need for high levels of reliability in applications involving very large numbers of inexpensive units where recall of the units would be disproportionately expensive. The nature of faults and the assumptions made by different approaches to correct operation are considered. The recovery block approach is described and a probabilistic analysis of its effectiveness, with and without correlated design errors is provided. Mechanisms for generating acceptance tests from specifications, and for providing recovery in the presence of asynchrony, are described. An analysis of, and design for, the provision of recovery blocks in the microprogram of the Bendix BDX930 processor is provided. An example of the use of recovery blocks in a simple operating system is also provided.

Melliar-Smith, P. M.↗

Continuous hydrodeoxygenation of lignin to jet-range aromatic hydrocarbons

Sustainable aviation fuel (SAF) is essential to decrease the carbon footprint of the aviation industry. Although many strategies have been developed to provide the branched, aliphatic components of SAF, few viable strategies have been demonstrated to supply the aromatic and cycloalkane fraction of SAF at the necessary scale from bio-based feedstocks. Lignin is the largest natural source of renewable aromatic compounds, yet major challenges in deoxygenation have prevented its use as a feedstock for SAF. Here we report a continuous, two-stage catalytic process using molybdenum carbide to deoxygenate lignin from poplar into aromatic hydrocarbons with 87.5% selectivity towards aromatic hydrocarbons at 86% of the theoretical carbon recovery. This work demonstrates an effective approach to convert lignin into aromatic SAF blendstocks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗