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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

High-Order Hybrid RANS-LES Study of NACA0012 Wing Sections

We develop hybrid RANS-LES strategies within Nek5000 for application to airfoil sections at small flight configurations. We present a validation and verification study of $k \space – \space \tau$ SST applied to a NACA 0012 wing section in a pure RANS and in a hybrid RANS-LES setup. The study shows good corroboration with existing experimental and numerical datasets. We also analyze some of the observed discrepancies with the experiments by evaluating the side wall “blocking” effect. We demonstrate that for the hybrid turbulence modeling approach a high-order spectral- element discretization converges faster (i.e., with less resolution) than a representative low-order finite-volume-based approach.

42 ENGINEERING↗
DOE OSTI2020

Imaging broadband soft X-ray transmission-grating spectrograph for a wavelength range λ > 111 Å

A family of aperiodic Mo/Be multilayer mirrors was designed for maximum uniform reflectivity in the ranges 111 – 138, 111 – 150, 111 – 200 and 111 – 222 Å at normal radiation incidence. The simulations took into account the existence of Mo-on-Be and Be-on-Mo transition layers. It was shown that the reflectivity may be as high as 10% in an octave wavelength range of 111 – 222 Å. We demonstrate the operation of an imaging transmission-grating spectrograph with a broadband Mo/Be multilayer mirror with a uniform reflectivity in the wavelength range 111 – 138 Å synthesised at the Institute for the Physics of Microstructures, RAS. The spectrograph was used to record the line spectra of multiply charged fluorine and magnesium ions from a laser-produced plasma. The role of the grating support structure in the formation of spectral source images is discussed. The spatial resolution of 50 μm is demonstrated. (laser applications and other topics in quantum electronics)

36 MATERIALS SCIENCE↗
DOE OSTI2022

Cluster environment quenches the star formation of low-mass satellite galaxies from the inside-out

ABSTRACT Environment plays a critical role in the star formation history of galaxies. Tidal and hydrodynamical stripping, prominent in cluster environment, can remove the peripheral gas of galaxies and star formation may thus be environmentally suppressed from the outside-in. We revisit the environmental dependence of the radial gradient of specific star formation rate (sSFR) profile. We probe the radial gradient by using the archival spectral indices D4000n and HδA measured from SDSS fibre spectra, to indicate central sSFR and the total sSFR from fitting the spectral energy distribution. Despite the low spatial resolution, the wealth of SDSS data allows to disentangle the dependences on stellar mass, sSFR, and environment. We find that low-mass satellite galaxies in the mass range $9\lt \mathrm{log}\, \mathcal {M}_{\star }/\mathcal {M}_{\odot }\lt 9.8$ on average quench in more inside-out pattern compared to isolated galaxies matched in mass, sSFR, and fibre coverage. This environmental effect is particularly strong for galaxies below the star formation main sequence, and peaks for those in the core of massive clusters where the phase-space diagram reveals clear links between the inside-out quenching and orbital properties. Our results suggest that both tidal and hydrodynamical interactions in cluster environment suppress the star formation of satellites mainly from the inside-out. As accreted gas of low angular momentum from hot gas haloes is an important source for replenishing central gas reservoir, we discuss how gas stripping in clusters may lead to starvation and cause inside-out quenching when the outer star-forming discs are not significantly affected.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Spectroscopy of QUBRICS quasar candidates: 1672 new redshifts and a golden sample for the Sandage test of the redshift drift

ABSTRACT The QUBRICS (QUasars as BRIght beacons for Cosmology in the Southern hemisphere) survey aims at constructing a sample of the brightest quasars with $z \lower.5ex\hbox{$\,\, \buildrel\gt \over \sim \,\,$}2.5$, observable with facilities in the Southern Hemisphere. QUBRICS makes use of the available optical and IR wide-field surveys in the South and of Machine Learning techniques to produce thousands of bright quasar candidates of which only a few hundred have been confirmed with follow-up spectroscopy. Taking advantage of the recent Gaia Data Release 3, which contains 220 million low-resolution spectra, and of a newly developed spectral energy distribution fitting technique, designed to combine the photometric information with the Gaia spectroscopy, it has been possible to measure 1672 new secure redshifts of QUBRICS candidates, with a typical uncertainty of σz = 0.02. This significant progress of QUBRICS brings it closer to (one of) its primary goals: providing a sample of bright quasars at redshift 2.5 < z < 5 to perform the Sandage test of the cosmological redshift drift. A Golden Sample of seven quasars is presented that makes it possible to carry out this experiment in about 1500 h of observation in 25 yr, using the ANDES spectrograph at the 39m ELT, a significant improvement with respect to previous estimates.

Cristiani, Stefano (ORCID:0000000221155234)↗
DOE OSTI2020

Emission-line Data Cubes of the HH 32 Stellar Jet

We analyze data cubes of over 60 emission lines in the HH 32 stellar jet acquired with the Keck Cosmic Web Imager (KCWI). The data cover the less explored blue portion of the spectrum between 3586 and 6351 Å and have both high spectral (R ∼ 10,000) and spatial (≲1″) resolution. The study includes all three major ionization states of oxygen, three Balmer lines, multiple lines of Fe ii and Fe iii, and the first data cubes ever acquired for important unblended diagnostic lines such as He ii λ4686, Ca i λ3933, and Mg i] λ4571. The data cubes generally sort according to excitation and have a relatively continuous progression from the highest-excitation ions (He ii, O iii) through the intermediate-excitation ions (O i and H i) to the lowest-excitation ions (Ca ii and Mg i). Merging the KCWI cubes with Hubble Space Telescope images leads to several new insights about the flow, including evidence for bow shocks, partial bow shocks, spur shocks, Mach disks, jet deflection shocks, a wiggling jet, and potential shock precursors. The most surprising result is that one of the velocity components of Fe ii in the Mach disk suddenly increases in flux relative to other lines by a factor of two, implying that the Mach disk vaporizes dust in the jet. Hence, jets must accelerate or entrain dust to speeds of over 300 km s{sup −1} without destroying the grains.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

High-resolution X-ray spectroscopy of the stellar wind in Vela X-1 during a flare

In this work, we present a ~130 ks observation of the prototypical wind-accreting, high-mass X-ray binary Vela X-1 collected with XMM-Newton at orbital phases between 0.12 and 0.28. A strong flare took place during the observation that allows us to investigate the reaction of the clumpy stellar wind to the increased X-ray irradiation. To examine the wind’s reaction to the flare, we performed both time-averaged and time-resolved analyses of the RGS spectrum and examined potential spectral changes. We focused on the high-resolution XMM-Newton RGS spectra and divided the observation into pre-flare, flare, and post-flare phases. We modeled the time-averaged and time-resolved spectra with phenomenological components and with the self-consistent photoionization models calculated via CLOUDY and XSTAR in the pre-flare phase, where strong emission lines due to resonant transitions of highly ionized ions are seen. In the spectra, we find emission lines corresponding to K-shell transitions in highly charged ions of oxygen, neon, magnesium, and silicon as well as radiative recombination continua (RRC) of oxygen. Additionally, we observe potential absorption lines of magnesium at a lower ionization stage and features identified as iron L lines. The, CLOUDY and XSTAR photoionization models provide contradictory results, either pointing towards uncertainties in theory or possibly a more complex multi-phase plasma, or both. We are able to demonstrate the existence of a plethora of variable narrow features, including the firm detection of oxygen lines and RRC that RGS enables to observe in this source for the first time. We show that Vela X-1 is an ideal source for future high-resolution missions, such as XRISM and Athena.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Electro-optic sampling of classical and quantum light

Full characterization of electric-field waveforms in amplitude and phase is achieved across the terahertz to visible spectral range through interaction with an optical pulse shorter than a half-cycle period via the Pockels (linear electro-optic) effect. This technique of electro-optic sampling has become an indispensable tool in various areas, including ultrafast pump-probe, time-domain and frequency-comb spectroscopies, quantum optics, high-harmonic generation, and attosecond science, and holds great promise for further advances. Not only does it enable spectroscopic measurements with record dynamic range and temporal resolution, along with massively parallel real-time spectral data acquisition, but its remarkable sensitivity also allows the detection of vacuum fluctuations, i.e., “zero-point motion” of electric fields, profoundly impacting our understanding of the fundamental laws of nature.

Benea-Chelmus, Ileana-Cristina (ORCID:000000024814↗
DOE OSTI2020

Chirped-grating spectrometer-on-a-chip

We demonstrate an on-chip spectrometer readily integrable with CMOS electronics. The structure is comprised of a SiO 2 /Si 3 N 4 /SiO 2 waveguide atop a silicon substrate. A transversely chirped grating is fabricated, in a single-step optical lithography process, on a portion of the waveguide to provide angle and wavelength dependent coupling to the guided mode. The spectral and angular information is encoded in the spatial dependence of the grating period. A uniform pitch grating area, separated from the collection area by an unpatterned propagation region, provides the out-coupling to a CMOS detector array. A resolution of 0.3 nm at 633 nm with a spectral coverage tunable across the visible and NIR (to ∼ 1 µm limited by the Si photodetector) by changing the angle of incidence, is demonstrated without the need for any signal processing deconvolution. This on-chip spectrometer concept will cost effectively enable a broad range of applications that are beyond the reach of current integrated spectroscopic technologies.

Nezhadbadeh, Shima↗
DOE OSTI2024

Studying microbially induced corrosion on glass using ToF-SIMS

Microbially induced corrosion (MIC) is an emerging topic that has huge environmental impacts, such as long-term evaluation of microbial interactions with radioactive waste glass, environmental cleanup and disposal of radioactive material, and weathering effects of microbes. Time-of-flight secondary ion mass spectrometry (ToF-SIMS), a powerful mass spectral imaging technique with high surface sensitivity, mass resolution, and mass accuracy, can be used to study biofilm effects on different substrates. Understanding how to prepare biofilms on MIC susceptible substrates is critical for proper analysis via ToF-SIMS. We present here a step-by-step protocol for preparing bacterial biofilms for ToF-SIMS analysis, comparing three biofilm preparation techniques: no desalination, centrifugal spinning (CS), and water submersion (WS). Comparisons of two desalinating methods, CS and WS, show a decrease in the media peaks up to 99% using CS and 55% using WS, respectively. Proper desalination methods also can increase biological signals by over four times for fatty acids using WS, for example. ToF-SIMS spectral results show chemical compositional changes of the glass exposed in a Paenibacillus polymyxa SCE2 biofilm, indicating its capability to probe microbiologically induced corrosion of solid surfaces. This represents the proper desalination technique to use without significantly altering biofilm structure and substrate for ToF-SIMS analysis. ToF-SIMS spectral results showed chemical compositional changes of the glass exposed by a Paenibacillus bacterial biofilm over 3-month inoculation. Finally, possible MIC products include various phosphate phase molecules not observed in any control samples with the highest percent increases when experimental samples were compared with biofilm control samples.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Distributed Acoustic Sensing to Estimate the Permeability

Optical fiber in a borehole can be interrogated with distributed acoustic sensors (DAS) to capture fracture displacements with the potential to map surrounding fracture networks. We designed a laboratory experiment to test the capability of DAS to determine borehole flow characteristics, and we show that for the first time DAS can be used to remotely estimate permeability. Optical fiber was wrapped around a bead filled pipe and the pressure drop and flow velocity were measured to directly calculate permeability. A machine learning model using statistical features from continuous DAS estimated the bulk permeability. Fluid interactions with the permeable material demonstrate insufficient resolution using DAS amplitude-based measurements for estimating pressure drop to infer permeability. Variations in the spectral domain relate DAS measurements to the pressure drop and provide consistent permeability estimates. Resolution with DAS is sufficient to estimate permeability and provides a reliable method to monitor at depth in borehole conditions.

58 GEOSCIENCES↗
DOE OSTI2023

Quantifying neptunium oxidation states in nitric acid through spectroelectrochemistry and chemometrics

Controlled-potential in situ thin-layer spectropotentiometry was leveraged to generate visible/near-infrared (VIS/NIR) absorption spectral data sets for the development of chemometric models to quantify Np(III/IV/V/VI) oxidation states in HNO 3 . This technology would be valuable in laboratory studies and when monitoring process solutions to guide feed adjustments for radiochemical separations—the performance of which depends on oxidation state. This approach successfully isolated and stabilized Np species in pure (~99%) oxidation states without compromising solution optical properties. Multivariate curve resolution–alternating least squares models were evaluated to resolve spectral and component concentrations from a scan that sequentially produced Np(VI), Np(V), Np(IV), and Np(III) spectra with mixtures of two valences at a time. Although it provided a useful approximation, the method was not able to quantitively resolve each component likely because of rotational ambiguity. Additionally, partial least squares regression models were built from artificial and electrochemically generated VIS/NIR spectral training sets to study the effect of interionic interactions on spectral characteristics. Models built with true Bi-chemical mixtures of coexisting Np oxidation states and spectra generated from additive combinations of pure end points had similar prediction performance. This methodology can be used to directly quantify Np concentration and the ratio of Np oxidation states and other actinides in remote settings such as hot cells.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2026

Transient Pulse-Response Time-of-Flight Mass Spectrometry for Complex, Deactivating Heterogeneous Catalytic Systems: Application to Ethane Dehydroaromatization

The study of complex, multistep bond-forming and -breaking reactions in heterogeneous catalytic systems often encounters challenges associated with the involvement of large numbers of intermediates among branching pathways. Kinetic information obtained from traditional steady-state measurements can be complemented with that from time-resolved methods to uncover details of the underlying chemistry. Herein, we describe an approach for tracking the complete time-resolved chemical composition (ca. 4–200 u) of a reactor effluent in response to a reactant pulse. We use a six-port rotary valve with a metered sampling loop to pulse reactants at ambient pressure into a flow reactor packed with a catalyst bed within the isothermal region of a heated furnace. The temporal evolution of effluent species is tracked using time-resolved molecular-beam time-of-flight mass spectrometry. We highlight the possibilities that this method has to offer by studying the complex bifunctional mechanism of ethane dehydroaromatization over an HZSM-5-supported platinum catalyst. We demonstrate that energy-tunable ionization sources, which facilitate isomer resolution, enable the measurement of the full mass spectral time-dependent system response. This includes the evolution of major products and mechanistically relevant reactive intermediates such as 1,3-butadiene and cyclopentadiene; these species have not previously been observed from this reaction. In additional studies, we also assess the role of platinum in the catalyst by examining temporal responses to ethane and ethylene feeds. Results show that two temporally distinct formation pathways exist for methane and benzene, and that their importance depends on both catalyst composition and reactant identity. Additionally, characteristics of catalyst deactivation are uniquely observable in the time-resolved mass spectral response, including the selective deactivation of a benzene formation pathway. The combination of time-of-flight mass spectrometry with tunable ionization enables the simultaneous observation of all effluents in a complex mixture of intermediates with isomer/isobar differentiation capabilities that can be applied to any complex reaction system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Stratus and Stratocumulus Cloud Microphysics and Drizzle Relationships With CCN Modality

High resolution extended-range cloud condensation nuclei (CCN) spectral comparisons with cloud microphysics and drizzle of the Physics of Stratocumulus Tops (POST) field experiment confirmed results in the Marine Stratus/Stratocumulus Experiment (MASE). Both of these stratus cloud projects demonstrated that bimodal CCN spectra typically caused by cloud processing were associated with clouds that exhibited higher concentrations of smaller droplets with narrower distributions and less drizzle than clouds associated with unimodal CCN spectra. Resulting brighter clouds and increased cloudiness could enhance both indirect aerosol effects (IAE). These stratus findings are opposite of analogous measurements in two cumulus cloud projects, which showed bimodal CCN associated with fewer larger droplets more broadly distributed and with more drizzle than clouds associated with unimodal CCN. Resulting reduced cumulus brightness and cloudiness could reduce both IAE. Physics of Stratocumulus Tops (POST) flights in air masses with higher CCN concentrations, N CCN , showed more extremes of the stratus characteristics. However, POST flights with lower N CCN showed opposite droplet characteristics similar to the cumulus clouds, yet still showed less drizzle in clouds associated with bimodal CCN, but not as much less as the flights with higher N CCN . Since all MASE clouds were in polluted air masses, while the two cumulus projects were in clean air masses we deduce from these four projects that both the dynamic stratus/cumulus differences (vertical wind) and N CCN are responsible for the microphysics and drizzle differences among these projects. This is because the clean POST characteristics are a hybrid between MASE/POST high N CCN and the two cumulus projects.

bimodality↗
DOE OSTI2021

Absolute throughput calibration of multiple spherical crystals for the Orion High-REsolution X-ray spectrometer (OHREX)

We present absolute throughput analysis of several crystals for the Orion High-REsolution X-ray (OHREX) imaging crystal spectrometer using ray tracing and experimental measurements. The OHREX spectrometer is a high-resolution x-ray spectrometer designed to measure spectral line shapes at the Orion laser facility. The spectrometer is fielded with up to two spherical crystals simultaneously covering two independent spectral ranges. Each crystal has a nominal radius of curvature of R = 67.2 cm and is fielded at a nominal Bragg angle of 51.3°. To cover different bands of interest, several different crystals are available, including Ge (111), KAP, and several cuts of quartz, whose resolving power λ/Δλ exceeds 10 000. The calibrated response of the available crystals has previously been reported from measurements at the EBIT-I electron beam ion trap at Lawrence Livermore National Laboratory. Here, we model the absolute throughput of each crystal using ray tracing and verify the results using experimental data for the quartz $(10\bar{1}1)$ crystal.

47 OTHER INSTRUMENTATION↗
DOE OSTI2024

Gravitational waves from binary neutron star mergers with a spectral equation of state

In numerical simulations of binary neutron star systems, the equation of state of the dense neutron star matter is an important factor in determining both the physical realism and the numerical accuracy of the simulations. Some equations of state used in simulations are C 2 or smoother in the pressure/density relationship function, such as a polytropic equation of state, but may not have the flexibility to model stars or remnants of different masses while keeping their radii within known astrophysical constraints. Other equations of state, such as tabular or piece-wise polytropic, may be flexible enough to model additional physics and multiple stars' masses and radii within known constraints, but are not as smooth, resulting in additional numerical error. We will study in this paper a recently developed family of equation of state, using a spectral expansion with sufficient free parameters to allow for a larger flexibility than current polytropic equations of state, and with sufficient smoothness to reduce numerical errors compared to tabulated or piece-wise polytropic equations of state. We perform simulations at three mass ratios with a common chirp mass, using two distinct spectral equations of state, and at multiple numerical resolutions. We evaluate the gravitational waves produced from these simulations, comparing the phase error between resolutions and equations of state, as well as with respect to analytical models. From our simulations we estimate that the phase difference at merger for binaries with a dimensionless weighted tidal deformability difference greater than Δ$\tilde{Λ}$=55 can be captured by the SpEC code for these equations of state.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Impacts of long-range-transported mineral dust on summertime convective cloud and precipitation: a case study over the Taiwan region

As one of the most abundant atmospheric aerosols and effective ice nuclei, mineral dust affects clouds and precipitation in the Earth system. Here numerical experiments are carried out to investigate the impacts of dust aerosols on summertime convective clouds and precipitation over the mountainous region of Taiwan by acting as ice-nucleating particles. We run the Weather Research and Forecasting model (WRF) with the Morrison two-moment and spectral-bin microphysics (SBM) schemes at 3 km resolution, using dust number concentrations from a global chemical transport model (GEOS-Chem-APM). The case study indicates that the long-range-transported mineral dust, with relatively low number concentrations, can notably affect the properties of convective clouds (ice and liquid water contents, cloud top height, and cloud coverage) and precipitation (spatial pattern and intensity). The effects of dust are evident during strong convective periods, with significantly increased ice water contents in the mixed-phase regime via the enhanced heterogeneous freezing. With both the Morrison and SBM schemes, we see the invigoration effects of dust aerosols on the convective intensity through enhanced condensation and deposition latent heating. The low-altitude dust particles are uplifted to the freezing level by updrafts, which, in turn, enhance the convective cloud development through immersion freezing and convective invigoration. Compared to the Morrison scheme, the SBM scheme predicts more realistic precipitation and different invigoration effects of dust. The differences are partially attributed to the saturation adjustment approach utilized in the bulk scheme, which leads to a stronger enhancement of condensation at midlatitudes to low altitudes and a weaker deposition increase at the upper level.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Learning Spectral Templates for Photometric Redshift Estimation from Broadband Photometry

Estimating redshifts from broadband photometry is often limited by how accurately we can map the colors of galaxies to an underlying spectral template. Current techniques utilize spectrophotometric samples of galaxies or spectra derived from spectral synthesis models. Both of these approaches have their limitations: either the sample sizes are small and often not representative of the diversity of galaxy colors, or the model colors can be biased (often as a function of wavelength), which introduces systematics in the derived redshifts. In this paper, we learn the underlying spectral energy distributions from an ensemble of ∼100 K galaxies with measured redshifts and colors. We show that we are able to reconstruct emission and absorption lines at a significantly higher resolution than the broadband filters used to measure the photometry for a sample of 20 spectral templates. We find that our training algorithm reduces the fraction of outliers in the derived photometric redshifts by up to 28%, bias up to 91%, and scatter up to 25%, when compared to estimates using a standard set of spectral templates. We discuss the current limitations of this approach and its applicability for recovering the underlying properties of galaxies. Our derived templates and the code used to produce these results are publicly available in a dedicated Github repository: https://github.com/dirac-institute/photoz-template-learning.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

LANL-UW Collaboration on LC-QTOF Datasets (Annual Report)

Prior to the application of non-targeted chemometric techniques (i.e., Fisher ratio analysis), pre-processing steps must be carried out on the data collected using liquid chromatography-quadrupole time of flight (LC-QTOF) mass spectrometry. Data compression is the most important pre-processing step due to the vast number of high-resolution mass channels (m/z; 0.0001 Da) collected. Our first approach was to bin the mass spectral dimension to 0.01 Da; however, this approach was computationally expensive and did not preserve the high-resolution data.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗