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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Understanding why poly(acrylic acid) works: decarbonylation and cross-linking provide an ionically conductive passivation layer in silicon anodes

Poly(acrylic acid) (PAA) is commonly used as a binder for fabricating silicon (Si) anode active materials in lithium-ion batteries due to its useful properties including high polar solvent solubility, good rheology, and strong adhesive properties. However, the role and evolution of PAA during electrode fabrication, cycling, and calendar aging are not well understood. In this work, we reveal the evolution of PAA during electrode curing and relate its chemical change to the final electrode properties and performance. These studies are made possible using two types of in situ attenuated total reflectance-infrared Fourier transform (ATR-FTIR) spectroscopy: thermal ATR-FTIR to probe the cross-linking reaction, and ATR-FTIR spectroelectrochemistry of three-dimensional composite electrodes, a unique technique developed herein that probes the solvation dynamics of lithium ions at the silicon anode interface under electrochemical polarization. Specifically, we show that PAA undergoes a thermally-mediated, cross-linking decarbonylation reaction to form an ether-based network polymer. To show the importance of the polyether moieties, we synthesize partially esterified PAA analogues that do not undergo this cross-linking decarbonylation reaction and correlate the degree of cross-linking to half-cell performance metrics. Finally, we unveil the mechanism of the polyether binder performance through in situ ATR-FTIR spectroelectrochemistry and show that PAA acts as an interfacial material that conducts lithium-ions, limits solvent molecule access to the Si surface, and stabilizes the electrode against parasitic lithium inventory loss at high state of charge for an extended period of time.

25 ENERGY STORAGE↗
DOE OSTI2025

Role of perturbed parallel magnetic field effects in predicting turbulent transport in NSTX

This study presents analysis of gyrokinetic simulations on the National Spherical Torus Experiment (NSTX) to investigate the effects of electromagnetic fields on plasma turbulence and transport. The simulations, performed with varying levels of fidelity using the gyrokinetic CGYRO code, include electrostatic (ES), single-field electromagnetic (EM1), and two-field electromagnetic (EM2) models. A detailed comparison across the simulation database reveals that electromagnetic effects increase both predicted growth rates and quasilinear fluxes, with EM2 simulations producing stronger turbulence than ES and EM1 cases. Quasilinear modeling using QLGYRO demonstrates that while the perturbed parallel magnetic field (δB ∥ ) does not drastically affect the total flux at experimental gradients, it leads to a shift in the dominant instability, altering mode structures from microtearing to kinetic ballooning modes (KBMs). The proximity of the plasma profiles to the KBM threshold is explored, with the experimental conditions being near the onset of KBM-driven transport. The KBM, with its large growth rates, is identified as a potential driver of electron temperature flattening, as it can rapidly transport heat across flux surfaces. Performing stability analysis shows core-localized unstable a low- mode that could contribute to the flattening at the early times of the discharge. TGYRO predictive modeling, incorporating both TGLF and QLGYRO, indicates that the inclusion of δB ∥ significantly improves the accuracy of temperature profile predictions in NSTX high-beta plasmas, although challenges remain in modeling the sharp flux discontinuities caused by KBM-driven instabilities.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Holistic energy landscape management in 2D/3D heterojunction via molecular engineering for efficient perovskite solar cells

Constructing two-dimensional (2D) perovskite atop of 3D with energy landscape management is still a challenge in perovskite photovoltaics. Here, we report a strategy through designing a series of π-conjugated organic cations to construct stable 2D perovskites and to realize delicate energy level tunability at 2D/3D heterojunctions. As a result, the hole transfer energy barriers can be reduced both at heterojunctions and within 2D structures, and the preferable work function shift reduces charge accumulation at interface. Leveraging these insights and also benefitted from the superior interface contact between conjugated cations and poly(triarylamine) (PTAA) hole transporting layer, a solar cell with power conversion efficiency of 24.6% has been achieved, which is the highest among PTAA-based n-i-p devices to the best of our knowledge. The devices exhibit greatly enhanced stability and reproducibility. This approach is generic to several hole transporting materials, offering opportunities to realize high efficiency without using the unstable Spiro-OMeTAD.

14 SOLAR ENERGY↗
DOE OSTI2023

Rational Selection of Sodium Layered Oxides for High Performance Na-Ion Batteries: P2 vs O3 vs P2-O3 Intergrowths

Sodium ion batteries (NIBs) are gaining importance as an energy storage technology complementary to the Li-ion batteries. In this regard, sodium-based layered oxides are recognized as one of the most suitable positive electrode candidate for NIBs, but vast variety of their chemical compositions and crystal structures complicates the selection of the best material. To shed light on different figures of merit that control the selection of layered oxide material for NIB applications, we compare here a P2, P2-O3 intergrowth and two O3 sodium layered oxides composed of the same transition metals (Ni, Mn, Ti and Zn) but in differing stoichiometries. The results show that the new P2-type Na 0.67 Ni 0.3 Zn 0.03 Mn 0.52 Ti 0.15 O 2 phase reported here combines most of the advantages, such as stability towards moisture, reduced surface reactivity, better thermal stability and high rate capability, which are essential for commercialization, except for a limited capacity (∼125 mAh g −1 ) compared to the O3 NaNi 0.45 Zn 0.05 Mn 0.4 Ti 0.1 O 2 phase (∼180 mAh g −1 ), reported by our group previously. Altogether, this work enlarges the family of attractive Na-based positive electrodes and teaches us that we should not solely be obsessed with the capacity of a material to decide of its applicability.

Electrochemistry↗
NASA NTRS1972

Water landing characteristics of a model of a winged reentry vehicle

Proposed manned space shuttle vehicles are expected to land on airport runways. In an emergency situation, however, the vehicle may be required to land on water. A 1/10-scale dynamic model of a winged reentry vehicle was investigated to determine the water landing characteristics. Two configurations of the proposed vehicle were studied. Configuration 1 had a 30 deg negative dihedral of the stabilizer-elevon surface whereas configuration 2 had a 30 deg positive dihedral. Results indicate that the maximum normal accelerations for configurations 1 and 2 when landing in calm water were approximately 8g and 6g, respectively, and the maximum longitudinal accelerations were approximately 5g and 3g, respectively. A small hydroflap was needed to obtain satisfactory calm-water landings with configuration 2, whereas configuration 1 gave good landings without a hydroflap. All landings made in rough water resulted in unsatisfactory motions. For landings made in three different wave sizes, both configurations dived. The maximum normal accelerations for configurations 1 and 2 when landing in waves were -10.1g and -18.7g, respectively, and the maximum longitudinal accelerations for both configurations were approximately 13g.

Stubbs, S. M.↗
NASA NTRS1971

Dye penetrant indications caused by superficial surface defects in 2014 aluminum alloy welds.

Demonstration that dye penetrant indications on the heat-affected zone of 2014-T6 aluminum GMA weldments are frequently caused by superficial surface conditions and are less than 0.007 in. deep. The following methods are suggested for minimization of these surface defects: stabilization of the arc, application of dc ?GTA' welding procedures, reduction of the caustic etch time, and use of fine grain materials.

Hocker, R. G.↗
NASA NTRS1972

Decision surface estimate of nonlinear system stability domain by Lie series method.

The Lie series recursive algorithm for Zubov's partial differential equation is used to generate two sets of points, where one represents the exact asymptotic stability boundary of an equilibrium state of the nonlinear system under consideration and the other is interior to it. Based on these two sets of data as training samples of two classes, a decision hypersurface can be determined such that it is a close approximation of the asymptotic stability boundary.

Kormanik, J.↗
NASA NTRS1976

Experiments on the stability of FeOOH on the surface of the moon

A description is given of an investigation which had been conducted to determine whether the water-bearing phase of FeOOH composition found in the study of lunar rocks could be of lunar origin. The reported experiments demonstrate that FeOOH of any structure cannot exist for any length of time on the surface of the moon. The investigation substantiates, therefore, the original proposal of Taylor et al. (1973) that the FeOOH in the Apollo 16 rocks is due entirely to terrestrial water vapor contamination.

Taylor, L. A.↗
NASA NTRS1977

Structural design significance of tension-tension fatigue data on composites

Constant cycle tension-tension fatigue and related static tension data have been generated on six single composite material/orientation combinations and twenty-one hybrid composite material/orientation combinations. Anomalies are related to the temperature rise and stopped interval creep, whereas endurance limit stresses (runouts) are associated with static proportional limit values, when they occur, and internal damage. The significance of these room temperature-dry data on the design allowables and weight of aerodynamic structueres is discussed. Such structures are helicopter rotor blades and wing and horizontal stabilizer lower surfaces. Typical criteria for turning these data into preliminary allowables are shown, as are examples of such allowables developed from the data. These values are then compared to those that might be used if the structures were made of metal.

Grimes, G. C.↗
NASA NTRS1979

On the internal structure of the major satellites of the outer planets

The structures and thermal evolutions of the large icy-satellites of the outer solar system are considered. It is shown (for bodies comparable in size and mass to the Galilean satellites, having sizeable mass fraction of H2O, and with meteoritic abundances of radioactive materials contained within their silicate fractions) that the crust of solid ice over a liquid mantle predicted by conductive heat-transfer calculations is unstable to large-scale solid-state convection. For appropriate material parameters, convective heat-transfer rates are sufficient to freeze a large liquid mantle on a time scale that is short compared to the lifetime of the body. It is also concluded that the ice layer is convecting at the present time. A reevaluation of previous work, using improved values for material parameters and boundary conditions, reverses earlier conclusions and implies a rigid outer crust with resulting long-term stability of surface features to creep deformation. The combination of a rigid crust with active internal convection presents the additional possibility of surface features that are produced and maintained by dynamic internal processes.

Reynolds, R. T.↗
NASA NTRS1987

Modeling the interactions between the ocean and the environment for microwave radar sensing

An extensive set of X-band microwave backscatter measurements has been analyzed to determine its dependence on winds near the surface, atmospheric stability, and long-wave slopes. These radar measurements, made from a tower in the Gulf of Mexico, were performed in conjunction with an extensive set of simultaneous environmental measurements. The CW microwave system operated at an incidence angle of 45 deg, with antennas directed into winds and waves. Model functions for the radar cross section (RCS) and the modulation transfer function (MTF) are developed that depend on the geophysical variables, including wind stress. Statistical analysis shows that these models functions yield a significant smaller error when fit to the RCS data than a simple wind-speed function displays. A Taylor-series expansion of the returned power from a small area provides a unified function that demonstrates the complementary roles of wave slope and atmospheric fluctuations on both the RCS, the MTF, and the coherence. The issue of linearity of the MTF is addressed with this data set, yielding evidence that this is a valid assumption. These results have direct application to the remote sensing of the mean and fluctuating winds, and the wave spectrum with coherent and incoherent active radars.

Weissman, David E.↗
NASA NTRS1987

Components of the ice age circulation

The effects of ice age boundary conditions on atmospheric dynamics and regional climate patterns are investigated using four GCM simulations. Particular consideration is given to sea surface temperature-sea ice distribution, the appearance of land ice, and the increased elevation of land ice. It is observed that the ice-age sea surface temperature stabilizes the atmosphere over the oceans, increases the frequency of storm tracking through central North America, and amplifies transient eddy energy without increasing baroclinic generation. It is detected that low-elevation ice generates low pressure over eastern North America and southern Europe in winter, while increasing cloud cover and cooling the land in summer. Elevation of the ice sheets cools the land in winter, further intensifies storms off northeastern North America, induces subsidence warming downstream of the European ice sheets in summer, and increases the transient and stationary eddy energy through increased baroclinicity.

Rind, D.↗
NASA NTRS1987

An LDA investigation of three-dimensional normal shock-boundary layer interactions in a corner

Nonintrusive, three-dimensional, measurements have been made of a normal shock wave-turbulent boundary layer interaction. The measurements were made in the corner of the test section of a continuous supersonic wind tunnel in which a normal shock wave had been stabilized. LDA, surface pressure measurement and flow visualization techniques were employed for two freestream Mach number test cases: 1.6 and 1.3. The former contained separated flow regions and a system of shock waves. The latter was found to be far less complicated. The reported results are believed to accurately define the flow physics of each case and may be used as benchmark data to verify three-dimensional computer codes.

Chriss, R. M.↗
NASA NTRS1988

Ceramic Thermal Barriers For Dirty-Fuel Turbines

Report discusses performances of ceramic thermal-barrier coating materials for use in electric-utility gas-turbine engines. Variations of standard coating evaluated in search for coating resistant to dirty fuel. Variations included alterations of level of yttria, replacement of yttria by other stabilizers, controlling surface density (by plasma spray processing, infiltration, laser glazing, or sputtering), and interface treatments.

Miller, Robert A.↗