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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21

Induction Heating Model of Cermet Fuel Element Environmental Test (CFEET)

Deep space missions with large payloads require high specific impulse and relatively high thrust to achieve mission goals in reasonable time frames. Nuclear Thermal Rockets (NTR) are capable of producing a high specific impulse by employing heat produced by a fission reactor to heat and therefore accelerate hydrogen through a rocket nozzle providing thrust. Fuel element temperatures are very high (up to 3000 K) and hydrogen is highly reactive with most materials at high temperatures. Data covering the effects of high‐temperature hydrogen exposure on fuel elements are limited. The primary concern is the mechanical failure of fuel elements due to large thermal gradients; therefore, high‐melting‐point ceramics‐metallic matrix composites (cermets) are one of the fuels under consideration as part of the Nuclear Cryogenic Propulsion Stage (NCPS) Advance Exploration System (AES) technology project at the Marshall Space Flight Center. The purpose of testing and analytical modeling is to determine their ability to survive and maintain thermal performance in a prototypical NTR reactor environment of exposure to hydrogen at very high temperatures and obtain data to assess the properties of the non‐nuclear support materials. The fission process and the resulting heating performance are well known and do not require that active fissile material to be integrated in this testing. A small‐scale test bed; Compact Fuel Element Environmental Tester (CFEET), designed to heat fuel element samples via induction heating and expose samples to hydrogen is being developed at MSFC to assist in optimal material and manufacturing process selection without utilizing fissile material. This paper details the analytical approach to help design and optimize the test bed using COMSOL Multiphysics for predicting thermal gradients induced by electromagnetic heating (Induction heating) and Thermal Desktop for radiation calculations.

Gomez, C. F.↗

Induction Heating Model of Cermet Fuel Element Environmental Test (CFEET)

Deep space missions with large payloads require high specific impulse and relatively high thrust to achieve mission goals in reasonable time frames. Nuclear Thermal Rockets (NTR) are capable of producing a high specific impulse by employing heat produced by a fission reactor to heat and therefore accelerate hydrogen through a rocket nozzle providing thrust. Fuel element temperatures are very high (up to 3000 K) and hydrogen is highly reactive with most materials at high temperatures. Data covering the effects of high‐temperature hydrogen exposure on fuel elements are limited. The primary concern is the mechanical failure of fuel elements due to large thermal gradients; therefore, high‐melting‐point ceramics‐metallic matrix composites (cermets) are one of the fuels under consideration as part of the Nuclear Cryogenic Propulsion Stage (NCPS) Advance Exploration System (AES) technology project at the Marshall Space Flight Center. The purpose of testing and analytical modeling is to determine their ability to survive and maintain thermal performance in a prototypical NTR reactor environment of exposure to hydrogen at very high temperatures and obtain data to assess the properties of the non‐nuclear support materials. The fission process and the resulting heating performance are well known and do not require that active fissile material to be integrated in this testing. A small‐scale test bed; Compact Fuel Element Environmental Tester (CFEET), designed to heat fuel element samples via induction heating and expose samples to hydrogen is being developed at MSFC to assist in optimal material and manufacturing process selection without utilizing fissile material. This paper details the analytical approach to help design and optimize the test bed using COMSOL Multiphysics for predicting thermal gradients induced by electromagnetic heating (Induction heating) and Thermal Desktop for radiation calculations.

Gomez, Carlos F.↗

On the relationship of interstellar N2H/+/, HCO/+/, HCN, and CN

A survey of 73 sources has been made in the emission lines of N2H(+) and HCO(+), including detailed maps of four sources (Ori A, OMC-2, DR 21 OH, and NGC 6334). These data are combined with equally extensive data for HCN and CN to make a detailed study of the spatial relationship of these four species. Actual abundance ratios are shown to vary, often sharply, over small scale lengths (of the order of 1 arcmin) within the mapped sources. Excitation temperatures also vary. All four species appear to be subthermally excited. The abundance ratios and their spatial variations are interpreted in terms of ion-molecular formation and destruction processes. It is concluded that the relative abundances of CO may be considerably lower in some regions than previously believed. No evidence is found for variations in the C/O ratio over small scale lengths in Ori A. The degree of ionization of the Ori A molecular cloud may be significantly different from that of other molecular clouds.

Turner, B. E.↗

Synthesis and processing of lithium-loaded plastic scintillators on the kilogram scale

Plastic scintillators that can discriminate between gamma rays, fast neutrons, and thermal neutrons were synthesized and characterized while considering the performance at the kilogram scale. The synthesis and processing of these plastic scintillators on the kilogram scale required examination of several factors. The examination of these factors was necessitated by the inclusion of 0.1 wt.% lithium-6 to enable detection of thermal neutrons. First, methacrylic acid was used as an additive to solubilize salts of lithium-6, which allow for a thermal-neutron capture reaction that produces scintillation light following energy transfer. Second, a trade-off between scintillation performance and processability was considered because the increasing content of the methacrylic acid that aided processability resulted in a sharp decrease in the light output. The use of small amounts of methacrylic acid (≤3 wt.%) resulted in better performance but required high processing temperatures. At large scales, these high temperatures could initiate exothermic polymerization that results in premature curing and/or defects. Additionally, the deleterious effects of the methacrylic acid may be mitigated by using m-terphenyl as a primary dye rather than 2,5-diphenyloxazole (PPO), which has been traditionally used in organic scintillators. Finally, the curing environment was controlled to avoid defects like cracking and discolouration​ while maintaining solubility of dopants during curing. For scintillators that were produced from kilogram-scale batches of precursors, the effective attenuation of scintillation light was characterized.

36 MATERIALS SCIENCE↗

A visco-plastic constitutive model for accurate densification and shape predictions in powder metallurgy hot isostatic pressing

Powder metallurgy hot isostatic pressing (PM-HIP) is an advanced manufacturing process that produces near net shape parts with high material utilization and uniform microstructures. Despite being used frequently to produce small-scale components, the application of PM-HIP to large-scale components is limited due to inadequate understanding of its complex mechanisms that cause unpredictable post-HIP shape distortions. A computational model can provide necessary information about the intermediate and final stages of the HIP process that can help understand it better and make accurate predictions. Generally, two types of computational models are employed for PM-HIP of metal powders, namely, plastic and visco-plastic models. Between these, the plastic model is preferred due to its cheaper calibration approach requiring less experimental data. However, the plastic model sometimes produces incorrect predictions when slight variations of the HIP conditions are encountered in practical situations. Therefore, this work presents a visco-plastic model that addresses these limitations of the plastic model. A novel modified calibration approach is employed for the visco-plastic model that utilizes less experimental data than existing approaches. With the new approach, the data requirement is same for both plastic and visco-plastic models. This also enables a quantitative comparison of plastic and visco-plastic models, which have been only qualitatively compared in the past. When calibrated with the same experimental data, both the models are found to produce similar results. In conclusion, the calibrated visco-plastic model is applied to several complex geometries, and the predictions are found to be in good agreement with experimental observations.

Hot isostatic pressing↗

Thermal coupling of ions and electrons by collective effects in two-temperature accretion flows

A plasma instability which may lead to the thermal coupling of ions and electrons in two-temperature accretion flows on a time scale shorter than the Coulomb coupling time has been found. The processes involved with the instability are described. It is shown that the instability has time to grow only in regions of large-amplitude, small-scale MHD turbulence.

Begelman, Mitchell C.↗

AsterAnts: A Concept for Large-Scale Meteoroid Return and Processing using the International Space Station

AsterAnts is a concept calling for a fleet of solar sail powered spacecraft to retrieve large numbers of small (1/2-1 meter diameter) Near Earth Objects (NEOs) for orbital processing. AsterAnts could use the International Space Station (ISS) for NEO processing, solar sail construction, and to test NEO capture hardware. Solar sails constructed on orbit are expected to have substantially better performance than their ground built counterparts [Wright 1992]. Furthermore, solar sails may be used to hold geosynchronous communication satellites out-of-plane [Forward 1981] increasing the total number of slots by at least a factor of three. potentially generating $2 billion worth of orbital real estate over North America alone. NEOs are believed to contain large quantities of water, carbon, other life-support materials and metals. Thus. with proper processing, NEO materials could in principle be used to resupply the ISS, produce rocket propellant, manufacture tools, and build additional ISS working space. Unlike proposals requiring massive facilities, such as lunar bases, before returning any extraterrestrial larger than a typical inter-planetary mission. Furthermore, AsterAnts could be scaled up to deliver large amounts of material by building many copies of the same spacecraft, thereby achieving manufacturing economies of scale. Because AsterAnts would capture NEOs whole, NEO composition details, which are generally poorly characterized, are relatively unimportant and no complex extraction equipment is necessary. In combination with a materials processing facility at the ISS, AsterAnts might inaugurate an era of large-scale orbital construction using extraterrestrial materials.

Globus, Al↗

Metals production

Existing procedures for design of electrochemical plants can be used for design of lunar processes taking into consideration the differences in environmental conditions. These differences include: 1/6 Earth gravity, high vacuum, solar electrical and heat source, space radiation heat sink, long days and nights, and different availability and economics of materials, energy, and labor. Techniques have already been developed for operation of relatively small scale hydrogen-oxygen fuel cell systems used in the U.S. lunar landing program. Design and operation of lunar aqueous electrolytic process plants appears to be within the state-of-the-art. Finding or developing compatible materials for construction and designing of fused-magma metal winning cells will present a real engineering challenge.

Beck, Theodore S.↗

Scaling Impact-Melt and Crater Dimensions: Implications for the Lunar Cratering Record

The consequences of impact on the solid bodies of the solar system are manifest and legion. Although the visible effects on planetary surfaces, such as the Moon's, are the most obvious testimony to the spatial and temporal importance of impacts, less dramatic chemical and petrographic characteristics of materials affected by shock abound. Both the morphologic and petrologic aspects of impact cratering are important in deciphering lunar history, and, ideally, each should complement the other. In practice, however, a gap has persisted in relating large-scale cratering processes to petrologic and geochemical data obtained from lunar samples. While this is due in no small part to the fact that no Apollo mission unambiguously sampled deposits of a large crater, it can also be attributed to the general state of our knowledge of cratering phenomena, particularly those accompanying large events. The most common shock-metamorphosed lunar samples are breccias, but a substantial number are impact-melt rocks. Indeed, numerous workers have called attention to the importance of impact-melt rocks spanning a wide range of ages in the lunar sample collection. Photogeologic studies also have demonstrated the widespread occurrence of impact-melt lithologies in and around lunar craters. Thus, it is clear that impact melting has been a fundamental process operating throughout lunar history, at scales ranging from pits formed on individual regolith grains to the largest impact basins. This contribution examines the potential relationship between impact melting on the Moon and the interior morphologies of large craters and peaking basins. It then examines some of the implications of impact melting at such large scales for lunar-sample provenance and evolution of the lunar crust.

Cintala , Mark J.↗

Patterning of magneto-optical nanomaterials

Patterning of colloidal particles in precisely organized architectures has attracted intense research interest for decades. This is due to their potential applications in flexible electronics, magnetic and optical devices, sensors, biotechnology, communications, etc. However, creation of mesoscale assemblies at commercial scale received less attention. The mesoscale systems reside between the micro- and macroscopic scales, with length dimensions from ≈ 100 um to 5mm. One way to create mesoscale materials is to leverage decades of experimental and theoretical research in nanomaterials field that allows us to precisely create and control the placement of nanoscale materials. We developed a versatile and automatic mesoscale patterning technology that provide precise and consistent control and special arrangement of functional nanomaterials. The versatility of the strategy is demonstrated by patterning nanoparticles with different dimensions, shapes and compositions, tethered with various functionalities and subjected to different external stimuli. Nanomaterials were created via the paten t pending automated flow-throughput domain process (AFTDP), aka nano-additive manufacturing approach, recently developed by us, based on a unique small-scale fluidics concept, that enables a uniform reaction environment for production of high-quality materials in large quantities.

36 MATERIALS SCIENCE↗

Determining the biogeochemical transformations of organic matter composition in rivers using molecular signatures

Inland waters are hotspots for biogeochemical activity, but the environmental and biological factors that govern the transformation of organic matter (OM) flowing through them are still poorly constrained. Here we evaluate data from a crowdsourced sampling campaign led by the Worldwide Hydrobiogeochemistry Observation Network for Dynamic River Systems (WHONDRS) consortium to investigate broad continental-scale trends in OM composition compared to localized events that influence biogeochemical transformations. Samples from two different OM compartments, sediments and surface water, were collected from 97 streams throughout the Northern Hemisphere and analyzed to identify differences in biogeochemical processes involved in OM transformations. By using dimensional reduction techniques, we identified that putative biogeochemical transformations and microbial respiration rates vary across sediment and surface water along river continua independent of latitude (18°N–68°N). In contrast, we reveal small- and large-scale patterns in OM composition related to local (sediment vs. water column) and reach (stream order, latitude) characteristics. These patterns lay the foundation to modeling the linkage between ecological processes and biogeochemical signals. We further showed how spatial, physical, and biogeochemical factors influence the reactivity of the two OM pools in local reaches yet find emergent broad-scale patterns between OM concentrations and stream order. OM processing will likely change as hydrologic flow regimes shift and vertical mixing occurs on different spatial and temporal scales. As our planet continues to warm and the timing and magnitude of surface and subsurface flows shift, understanding changes in OM cycling across hydrologic systems is critical, given the unknown broad-scale responses and consequences for riverine OM.

rivers↗

Efficient electrosynthesis of hydrogen peroxide in neutral media using boron and nitrogen doped carbon catalysts

The two-electron electrocatalytic oxygen reduction reaction (2e - ORR) is a promising, sustainable, and efficient route for on-site and small-scale production of hydrogen peroxide (H 2 O 2 ) compared to the conventional anthraquinone oxidation process. Although heteroatom doped carbon materials are widely studied for the 2e - ORR, few studies have been conducted on the synergistic relationship between multiple doping elements on H 2 O 2 performance. Moreover, there is a lack of efficient and stable catalysts for H 2 O 2 electrosynthesis in neutral media. In this work, a series of boron and nitrogen co-doped carbon (BNC) catalysts are synthesized and assessed for the 2e - ORR in neutral pH electrolyte. Through X-ray photoelectron and absorption spectroscopy analyses, we characterize B–N–C moieties and correlate them with H 2 O 2 production performance. In rotating ring disk electrode measurements, BNC catalysts pyrolyzed at 900 °C exhibit H 2 O 2 Faradaic efficiency of ~70% and demonstrate excellent long-term stability over 10 hours of continuous operation. In a three-electrode flow cell, this catalyst achieves ~78% H 2 O 2 Faradaic efficiency and 0.9 mmol cm -2 h -1 productivity at 0.20 V vs. RHE, surpassing most previously reported carbon-based catalysts in neutral media. This work contributes fundamental insights into the role of boron and nitrogen heteroatom dopants toward 2e - ORR and highlights the practical viability of these catalysts for real world applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Case Studies and Parametric Analysis of Heliostat Performance With a Tradeoff-Informed Technoeconomic Analysis Metric

The Heliostat Consortium (HelioCon) was launched in 2021 to advance heliostat technology. Here this work presents a collection of baseline case studies for the technoeconomic analysis (TEA) of candidate heliostat improvements for concentrating solar power (CSP) and concentrated solar thermal (CST) systems that employ central receivers. The case studies we develop include a large-scale CSP plant, a smaller, modular CSP plant, and a small CST plant used for industrial process heat. In this work, we also propose a novel metric for TEA of a plant component technology that recasts relative changes in levelized system costs into component-specific capital cost budgets. This measure, which we refer to as the equivalent breakeven installed cost, is the maximum budget for the technology component that leads to improved levelized costs. Finally, we perform a parametric analysis to show the impact of candidate technologies on the levelized cost of heat and, by extension, equivalent breakeven installed cost.

14 SOLAR ENERGY↗

Boundary Layer Controls on the Shallow-to-Deep Cumulus Transition (Final Technical Report)

This project advanced our understanding of the processes governing cumulus cloud formation and provides an improved observational basis for validating earth system models. To be specific, the project used laser- and radar-remote sensors to examine the physical properties of updrafts that rise from earth’s surface and initiate clouds deeper in the atmosphere. These updrafts comprise “thermals” and “plumes” and occur at small spatial and temporal scales (e.g., 10s of minutes, 100s of meters). These small scales preclude explicit representation in most earth system and climate models, and thus necessitate “sub-grid-scale” parameterization of updraft processes. The innovation of this project was to directly measure the size, shape, strength and water vapor content of these updrafts with Doppler and Raman lidars, respectively, and to link these updraft properties to cloud processes using vertically pointed weather radars. The resulting data sets comprise 100s of thousands of updrafts and thousands of clouds, which far exceeds previous efforts, and thereby provides a robust statistical and physical representation of these processes. From these large datasets the project produced a sequence of scientific analyses that: (1) Elucidate how variations in the turbulent structure of the convective boundary layer control shallow cumulus convection, (2) Quantify the upward transport of water vapor to cloud base via thermals and plumes, (3) Validate large-eddy simulations of updrafts and shallow convective clouds, (4) Demonstrate a size-to-strength relationship between updraft width and updraft speed, and (5) Demonstrate how updrafts interact with the stability at the top of the convective boundary layer to modulate the depth and vigor of convective clouds. These results have been disseminated via several published journal articles, academic theses, and conference presentations. Collectively these results contribute to the Atmospheric System Research (ASR) program’s goal to “improve understanding of the key cloud, aerosol, precipitation, and radiation processes that affect the Earth’s radiative balance and hydrological cycle, particularly processes that limit the predictive ability of regional and global earth system models”.

54 ENVIRONMENTAL SCIENCES↗

Lava flow surface textures - SIR-B radar image texture, field observations, and terrain measurements

SIR-B images, field observations, and small-scale (cm) terrain measurements are used to study lave flow surface textures related to emplacement processes of a single Hawaiian lava flow. Although smooth pahoehoe textures are poorly characterized on the SIR-B data, rougher pahoehoe types and the a'a flow portion show image textures attributed to spatial variations in surface roughness. Field observations of six distinct lava flow textural units are described and used to interpret modes of emplacement. The radar smooth/rough boundary between pahoehoe and a'a occurs at a vertical relief of about 10 cm on this lava flow. While direct observation and measurement most readily yield information related to lava eruption and emplacement processes, analyses of remote sensing data such as those acquired by imaging radars and altimeters can provide a means of quantifying surface texture, identifying the size and distribution of flow components, and delineating textural unit boundaries.

Gaddis, Lisa R.↗

Model of brittle matrix composite toughening based on discrete fiber reinforcement

An analytical approach for the analysis of the effectiveness of fiber reinforcement in brittle matrix composites is presented. The analytical method allows consideration of discrete fiber distribution and examination of the development of crack growth parameters on microscale. The problem associated with the bridging zone development is addressed here; therefore, the bridging zone is considered to be smaller than the main preexisting crack, and the small scale approach is used. The mechanics of the reinforcement is accurately accounted for in the process zone of a growing crack. Closed form solutions characterizing the initial failure process are presented for linear and nonlinear force - fiber pullout displacement relationships. The implicit exact solution for the extended bridging zone is presented as well.

Rubinstein, Asher A.↗

Physical Mechanisms Controlling Upper Tropospheric Water Vapor as Revealed by MLS Data from UARS

The seasonal changes of the upper tropospheric humidity are studied with the water vapor data from the Microwave Limb Sounder on the NASA Upper Atmosphere Research Satellite, and the winds and vertical velocity data obtained from the European Centre for Medium-Range Weather Forecasts. Using the same algorithm for vertical transport as that used for horizontal transport (Zhu and Newell, 1998), we find that the moisture in the tropical upper troposphere may be increased mainly by intensified local convection in a small portion, less than 10%, of the whole area between 40 deg S to 40 deg N. The contribution of large scale background circulations and divergence of horizontal transport is relatively small in these regions. These dynamic processes cannot be revealed by the traditional analyses of moisture fluxes. The negative feedback suggested by Lindzen (1990) also exists, if enhanced convection is concentrated in the tropics, but is apparently not the dominant process in the moisture budget.

Newell, Reginald E.↗

Factors Controlling Upper-Troposphere Water Vapor

The seasonal changes of the upper-tropospheric humidity are studied with the water vapor data from the Microwave Limb Sounder on the National Aeronautics and Space Administration's Upper Atmosphere Research Satellite and the winds and vertical velocity data obtained from the European Centre for Medium-Range Weather Forecasts. Using the same algorithm for vertical transport as that used for horizontal transport (by Zhu and Newell), the authors find that the moisture in the tropical upper troposphere may be increased mainly by intensified local convection in a small portion, less than 10%, of the whole area between 40 degrees S and 40 degrees N. The contribution of large-scale background circulations and divergence of horizontal transport is relatively small in these regions. These dynamic processes cannot be revealed by the traditional analyses of moisture fluxes. The negative response suggested by Lindzen, with enhanced convection in the Tropics being accompanied by subsidence drying in the subtropics, also exists, but the latter does not apparently dominate in the moisture budget.

Zhu, Yong↗