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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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The Human Exploration and Development of Space Roadmap calls for Human Missions to Mars and other planets in the 2010 to 2023 timeframe.
The Galileo Near Infrared Mapping Spectrometer (NIMS) was used to investigate the distribution and relative particle size variations of sulfur dioxide over one hemisphere of Io, centered at 210(deg)W.
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Here we present work which shows that superoxide radicals form on mineral grain surfaces upon exposure to a simulated martian environment and suggest that these species actively decompose organic structures.
As part of a larger CO2 removal architecture study, a model was developed in Aspen Custom Modeler of the Thermal Amine Scrubber (TAS), an ISS flight experiment intended to scrub CO2 from the cabin air. In order to minimize mass losses, it was determined the TAS should work in conjunction with the Air Cooled-Temperature Swing Adsorption Compressor (AC-TSAC) to reduce the CO2 for O2 production. First the TAS removes CO2 from the cabin atmosphere, then the AC-TSAC compresses the CO2 and feeds it in a steady steam to a Sabatier or Bosch process. This document details an effort to add a model of the AC-TSAC to the existing TAS model to determine if the two hardware systems will have deleterious effects on each other’s performance. It was found the AC-TSAC provided sufficient vacuum for the TAS’s desorption to occur, but not the same level of vacuum as space vacuum. This lower quality vacuum led to a reduction in the total cyclical uptake capacity of the TAS and thus a lower CO2 removal under the same conditions. The TAS did not remove enough CO2 to fill the AC-TSAC bed to capacity during the production phase which caused the AC-TSAC to run out of CO2 during production. This renders the addition of the AC-TSAC pointless. It is believed these effects can be overcome with a redesign of one or both systems.
Among future space missions, national aeronautics and space administration (NASA) selected two of them to analyze the diversity in organic content within Martian and Titan soil samples using a gas chromatograph – mass spectrometer (GC–MS) instrument. The Dragonfly space mission is planned to be launched in 2027 to Titan's surface and explore the Shangri-La surface region for years. One of the main goals of this mission is to understand the past and actual abundant prebiotic chemistry on Titan, which is not well characterized yet. The ExoMars space mission is planned to be launched in 2028 to Mars’ surface and explore the Oxia Planum and Mawrth Vallis region for years. The main objectives focus on the exploration of the subsurface soil samples, potentially richer in organics, that might be relevant for the search of past life traces on Mars where irradiation does not impact the matrices and organics. One recently used sample pre-treatment for gas chromatography – mass spectrometry analysis is planned on both space missions to detect refractory organic molecules of interest for astrobiology. This pre-treatment is called derivatization and uses a chemical reagent – called dimethylformamide dimethyl acetal (DMF-DMA) – to sublimate organic compounds keeping them safe from thermal degradation and conserving the chirality of the molecules extracted from Titan or Mars’ matrices. Indeed, the detection of building blocks of life or enantiomeric excess of some organics (e.g. amino acids) after DMF-DMA pre-treatment and GC–MS analyses would be both bioindicators. The main results highlighted by our work on DMF-DMA and Tenax®TA interaction and efficiency to detect organic compounds at ppb levels in a fast and single preparation are first that Tenax®TA did not show the onset of degradation until after 150 experiments – a 120 h at 300 °C experiment – which greatly exceeds the experimental lifetimes for the DraMS and GC-space in situ investigations. Tenax®TA polymer and DMF-DMA produce many by-products (about 70 and 46, respectively, depending on the activation temperature). Further, the interaction between the two leads to the production of 22 additional by-products from DMF-DMA degradation, but these listed by-products do not prevent the detection of trace-level organic molecules after their efficient derivatization and volatilization by DMF-DMA in the oven ahead the GC–MS trap and column.
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A fiber comprising a carbon chain backbone and amidoxime, carboxylate, and nitrile pendant groups. The fiber may be used for removing uranium from seawater and toxic metals from drinking water.
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American Chemical Society (ACS) presentation.
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A resin includes a functionalized aminopolymer having amine sites for capturing carbon dioxide molecules, where each aminopolymer molecule has at least one functional group amenable to crosslinking, a porogen, and a crosslinking initiator. A product includes an aminopolymer material formed into a self-supporting structure, the aminopolymer material including crosslinked aminopolymers having amine sites for the capture of carbon dioxide molecules.