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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Observation of the Gamma-Ray Binary HESS J0632+057 with the H.E.S.S., MAGIC, and VERITAS Telescopes

The results of gamma-ray observations of the binary system HESS J0632 + 057 collected during 450 hr over 15 yr, between 2004 and 2019, are presented. Data taken with the atmospheric Cherenkov telescopes H.E.S.S., MAGIC, and VERITAS at energies above 350 GeV were used together with observations at X-ray energies obtained with Swift-XRT, Chandra, XMM-Newton, NuSTAR, and Suzaku. Some of these observations were accompanied by measurements of the Hα emission line. A significant detection of the modulation of the very high-energy gamma-ray fluxes with a period of 316.7 ± 4.4 days is reported, consistent with the period of 317.3 ± 0.7 days obtained with a refined analysis of X-ray data. The analysis of data from four orbital cycles with dense observational coverage reveals short-timescale variability, with flux-decay timescales of less than 20 days at very high energies. Flux variations observed over a timescale of several years indicate orbit-to-orbit variability. The analysis confirms the previously reported correlation of X-ray and gamma-ray emission from the system at very high significance but cannot find any correlation of optical H$α$ parameters with fluxes at X-ray or gamma-ray energies in simultaneous observations. The key finding is that the emission of HESS J0632 + 057 in the X-ray and gamma-ray energy bands is highly variable on different timescales. The ratio of gamma-ray to X-ray flux shows the equality or even dominance of the gamma-ray energy range. This wealth of new data is interpreted taking into account the insufficient knowledge of the ephemeris of the system and discussed in the context of results reported on other gamma-ray binary systems.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1990

Photometric and spectroscopic modeling of starspots on the RS Canum Venaticorum binary HD 26337

Results are presented on photometric and spectroscopic observations made in 1987-1988 on the rapidly rotating G5 subgiant in the single-lined RS CVn binary HD 26337. Results show the existence of a cool polar spot on HD 26337, which is rather long lived, persisting at least the nine years of the photometry observations. The polar spot contributes only insignificantly to the light curve amplitude, but is crucial for the overall brightness of the system. Evidence is also found for extremely rapid light curve shape variations on a time scale of only one or two rotation cycles. These changes could be modeled by rapidly decreasing a spot area.

Strassmeier, Klaus G.↗
DOE OSTI2018

Pyroelectric and electrocaloric effects in ferroelectric silicon-doped hafnium oxide thin films

The emergent ferroelectricity in HfO 2 -based systems has attracted significant attention as this simple binary high- k dielectric now offers the possibility of nonvolatile function. Here we employ zero-field and field-dependent pyroelectricity to show that thin films of silicon-doped HfO 2 do exhibit a broken-inversion symmetry and are indeed ferroelectric. In addition, the pyroelectric response is found to exhibit a wake-up behavior akin to the wake-up phenomenon observed in the ferroelectric polarization with electric-field cycling. Using polarization-electric field hysteresis measurements, this wake-up phenomenon is attributed to the presence of defect dipoles which explains the measured pyroelectric response. Finally, direct electrocaloric measurements are performed on these silicon-doped HfO 2 thin films, revealing an electrocaloric coefficient ~ 4 times larger in magnitude than that expected for the measured pyroelectric coefficient. This enhancement is explained using the plausible role played by defect dipoles that contribute to additional configurational or dipolar entropy.

36 MATERIALS SCIENCE↗
NASA NTRS1985

The 1982-1984 Eclipse of Epsilon Aurigae

A workshop proceedings concerned with the new data collected during the 1982-1984 eclipse period of the 27-year system Epsilon Aurigae is presented. This binary star has been a classic problem in astrophysics because the opaque eclipsing object is nonstellar, and probably disk shaped. Invited papers concerning the history of the system, optical, infrared and ultraviolet photometry, optical polarimetry and ultraviolet spectroscopy are included. An invited paper concerning comprehensive theoretical interpretation in the context of stellar evolution also is included. The information collected herein is unparalleled in scope and will remain a standard reference until the next eclipse cycle in the year 2009 A.D., in all probability.

Stencel, R. E.↗
DOE OSTI2025

MXene/graphitic carbon nitride-supported metal selenide for all-solid-state flexible supercapacitor and oxygen evolution reaction

We report a new type of combination of rare earth metal selenides (Ce 2 Se 3 and Er 2 Se 3 ) with a Ti 3 C 2 T x /S-doped graphitic carbon nitride heterostructure for bifunctional application in flexible supercapacitors and oxygen evolution reactions. The incorporation of S-doped graphitic carbon nitride in MXenes reduced the layer stacking tendency of both two-dimensional sheets and eliminated volume expansion by forming a heterostructure. Cerium and erbium rare earth metal centers induce reactive surface sites, whereas binary layers of Ti 3 C 2 T x /S-doped graphitic carbon nitride provide a conducting matrix for the homogeneous growth of the metal selenides. The assembled all-solid-state flexible asymmetric supercapacitor exhibited a high specific capacitance of 60 F g –1 , an energy density of 10.1 W h kg –1 (volumetric energy density: 0.9 mW h cm –3 ) at 2 A g –1 , and 100% capacitance retention after 10 000 charge–discharge cycles with good flexibility for real-time applications. Furthermore, the optimum nanohybrid showed a low overpotential of 280 mV and a Tafel slope of 99 mV dec –1 with durable electrocatalytic performance. Furthermore, this work is the first to investigate the bifunctional energy efficiency of rare earth metal selenides grown over MXene materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Polymer ligand–induced autonomous sorting and reversible phase separation in binary particle blends

The tethering of ligands to nanoparticles has emerged as an important strategy to control interactions and organization in particle assembly structures. Here, we demonstrate that ligand interactions in mixtures of polymer-tethered nanoparticles (which are modified with distinct types of polymer chains) can impart upper or lower critical solution temperature (UCST/LCST)–type phase behavior on binary particle mixtures in analogy to the phase behavior of the corresponding linear polymer blends. Therefore, cooling (or heating) of polymer-tethered particle blends with appropriate architecture to temperatures below (or above) the UCST (or LCST) results in the organization of the individual particle constituents into monotype microdomain structures. The shape (bicontinuous or island-type) and lengthscale of particle microdomains can be tuned by variation of the composition and thermal process conditions. Thermal cycling of LCST particle brush blends through the critical temperature enables the reversible growth and dissolution of monoparticle domain structures. The ability to autonomously and reversibly organize multicomponent particle mixtures into monotype microdomain structures could enable transformative advances in the high-throughput fabrication of solid films with tailored and mutable structures and properties that play an important role in a range of nanoparticle-based material technologies.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Racoons ( Procyon Lotor ) Show Higher Trypanosoma Cruzi Detection Rates than Virginia Opossums ( Didelphis Virginiana ) in South Carolina, USA

Chagas disease, a significant public health concern in the Americas, is caused by a protozoan parasite, Trypanosoma cruzi. The life cycle of T. cruzi involves kissing bugs (Triatoma spp.) functioning as vectors and mammalian species serving as hosts. Raccoons (Procyon lotor) and opossums (Didelphis virginiana) have been identified as important reservoir species in the life cycle of T. cruzi, but prevalence in both species in the southeastern US is currently understudied. We quantified T. cruzi prevalence in these two key reservoir species across our study area in South Carolina, US, and identified factors that may influence parasite detection. We collected whole blood from 183 raccoons and 126 opossums and used PCR to detect the presence of T. cruzi. We then used generalized linear models with parasite detection status as a binary response variable and predictor variables of land cover, distance to water, sex, season, and species. Our analysis indicated that raccoons experienced significantly higher parasite detection rates than Virginia opossums, with T. cruzi prevalence found to be 26.5% (95% confidence interval [CI], 20.0–33.8) in raccoons and 10.5% (95% CI, 5.51–17.5) in opossums. Altogether, our results concur with previous studies, in that T. cruzi is established in reservoir host populations in natural areas of the southeastern US.

60 APPLIED LIFE SCIENCES↗
NASA NTRS1981

The impact of pulsed RFI on the coded BER performance of the nonlinear satellite communication channel

An examination is conducted of the coded bit error rate (BER) performance of a satellite communication system in which binary phase-shift-keyed (BPSK) modulation is employed, pulsed CW or pulsed noise RFI is present, and the transponder contains a nonlinearity characterized by arbitrary AM/AM and AM/PM characteristics; the RFI pulse duration is further assumed to exceed that of the information symbol. Computed performance curves consider several hypothetical RFI scenarios in which either a hard limiter or an 8 dB clipper represent the transponder amplitude nonlinearity. Results demonstrate the potential seriousness of RFI duty cycles as low as 2 percent, and the fact that CW represents the most severe form of interference.

Weinberg, A.↗
NASA NTRS2022

Determination of X-ray Pulsar Geometry with IXPE Polarimetry

Using observations of X-ray pulsar Hercules X-1 by the Imaging X-ray Polarimetry Explorer we report a highly significant (>17σ) detection of the polarization signal from an accreting neutron star. The observed degree of linear polarization of ~10% is far below theoretical expectations for this object, and stays low throughout the spin cycle of the pulsar. Both the degree and angle of polarization exhibit variability with the pulse phase, allowing us to measure the pulsar spin position angle 57(2) deg and the magnetic obliquity 12(4) deg, which is an essential step towards detailed modelling of the intrinsic emission of X-ray pulsars. Combining our results with the optical polarimetric data, we find that the spin axis of the neutron star and the angular momentum of the binary orbit are misaligned by at least ~20 deg, which is a strong argument in support of the models explaining the stability of the observed superorbital variability with the precession of the neutron star.

x-ray polarimetry↗
DOE OSTI2024

Binary Cation Matrix Electrolyte and Its Effect on Solid Electrolyte Interphase Suppression and Evolution of Si Anode

An unstable solid electrolyte interphase (SEI) has been recognized as one of the biggest challenges to commercializing silicon (Si) anodes for high-energy-density batteries. This work thoroughly investigates a binary cation matrix of Mg 2+ +Li + electrolyte and its role in SEI development, suppression, and evolution of a Si anode. Findings demonstrate that introducing Mg ions dramatically reduces the SEI growth before lithiation occurs, primarily due to the suppression of solvent reduction, particularly ethylene carbonate (EC) reduction. The Mg 2+ alters the Li + cation solvation environment as EC preferably participates in the oxophyllic Mg 2+ solvation sheath, thereby altering the solvent reduction process, resulting in a distinct SEI formation mechanism. The initial SEI formation before lithiation is reduced by 70% in the electrolyte with the presence of Mg 2+ cations. While the SEI continues to develop in the postlithiation, the inclusion of Mg ions results in an approximately 80% reduction in the postlithiation SEI growth. Continuous electrochemical cycling reveals that Mg 2+ plays a crucial role in stabilizing the deep-lithiated Si phases, which effectively mitigates side reactions, resulting in controlled SEI growth and stable interphase while eliminating complex Li x Si y formation. Mg ions promote the development of a notably more rigid and homogeneous SEI, characterized by a reduced dissipation (ΔD) in the Mg 2+ +Li + ion matrix compared to the solely Li + system. In conclusion, this report reveals how the Mg 2+ +Li + ion matrix affects the SEI evolution, viscoelastic properties, and electrochemical behavior at the Si interface in real time, laying the groundwork for devising strategies to enhance the performance and longevity of Si-based next-generation battery systems.

25 ENERGY STORAGE↗
DOE OSTI2016

High-speed bullet ejections during the AGB-to-planetary nebula transition: HST observations of the carbon star, v hydrae

The well-studied carbon star, V Hya, showing evidence for high-speed, collimated outflows and dense equatorial structures, is a key object in the study of the poorly understood transition of AGB stars into aspherical planetary nebulae. Using the Space Telescope Imaging Spectrograph instrument on board the Hubble Space Telescope, we have obtained high spatial-resolution long-slit optical spectra of V Hya that show high-velocity emission in [S ii] and [Fe ii] lines. Our data set, spanning three epochs spaced apart by a year during each of two periods (in 2002–2004 and 2011–2013), shows that V Hya ejects high-speed (∼200–250 km s{sup −1}) bullets once every ∼8.5 years. The ejection axis flip–flops around a roughly eastern direction, both in and perpendicular to the sky-plane, and the radial velocities of the ejecta also vary in concert between low and high values. We propose a model in which the bullet ejection is associated with the periastron passage of a binary companion in an eccentric orbit around V Hya with an orbital period of ∼8.5 years. The flip–flop phenomenon is likely the result of collimated ejection from an accretion disk (produced by gravitational capture of material from the primary) that is warped and precessing, and/or that has a magnetic field that is misaligned with that of the companion or the primary star. We show how a previously observed 17 year period in V Hya’s light-cycle can also be explained in our model. Additionally, we describe how the model proposed here can be extended to account for multipolar nebulae.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1978

Development of a Direct Contact Heat Exchanger, Phase 1 Study Report

Electric power generation from geothermal brine requires, first, bringing the hot brine to the surface and then converting the heat to electric power. Binary conversion schemes were proposed, with the heat transfer between the brine and the working organic fluid taking place in a conventional tube and shell heat exchanger. If the brine is heavily laden with dissolved solids, however, solids buildup on the heat exchanger surfaces leads to a considerable degree of fouling and an accompanying drop in performance is experienced. A possible solution to this problem is the use of a direct contact exchanger with the secondary fluid power cycle. The proposed concept involves the formation of fluid sheets and bells as heat angles. Results of a study concerning the fluid mechanics of such surfaces are given.

Manvi, R.↗
DOE OSTI2019

Autogenous healing of Engineered Cementitious Composites (ECC) based on MgO-fly ash binary system activated by carbonation curing

Developing self-healing of concrete cracks represents a critical approach for extending material longevity. If demonstrated on concretes with CO 2 stored through carbonation curing, self-healing can further mitigate infrastructure lifecycle emissions. In this study, the self-healing process is investigated on novel Engineered Cementitious Composites (ECC) based on binary blends of reactive MgO cement and siliceous fly ash activated by carbonation. The self-healing was observed under cyclic wetting and drying exposures and was characterized by measurements of resonance frequency, optical microscopy and X-ray computed microtomography (XCT). Thermogravimetric analysis, X-ray powder diffraction and scanning electron microscopy were employed to assist in identifying healing products and mechanisms. It was found that micro-cracks could be autogenously filled in 7 wet-dry cycles, as evidenced by over 95% recovery of resonance frequency and healed crack appearance under optical microscopic observation. Nevertheless, the composite mechanical performance, particularly tensile strength and ductility, did not fully recover with respect to the uncracked specimens. The inadequate post-healing mechanical properties were consistent with XCT observations that indicated low material densities in the cracked area. Based on the chemical and microstructural characterizations, it was determined that nesquehonite crystallites were responsible for the crack filling. Although the nesquehonite filled cracks will be less permeable to invasion of reactive fluids, novel strategies are needed to establish more robust healing capability to completely restore the crack bridging and composite tensile performance.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Phase Behavior of the Ternary NaCl-PuCl 3 -Pu Molten Salt

There is a gap in our understanding of the behavior of fused and molten fuel salts containing unavoidable contamination, such as those due to fabrication, handling, or storage. Therefore, this work used calorimetry to investigate the change in liquidus temperature of PuCl 3 , having an unknown purity and that had been in storage for several decades. Further research was performed by additions of NaCl, making several compositions within the binary system, and summarizing the resulting changes, if any, to the phase diagram. The melting temperature of the PuCl 3 was determined to be 746.5°C, approximately 20°C lower than literature reported values, most likely due to an excess of Pu metal in the PuCl 3 either due to the presence of metallic plutonium remaining from incomplete chlorination or due to the solubility of Pu in PuCl 3 . From the melting temperature, it was determined that the PuCl 3 contained between 5.9 to 6.2mol% Pu metal. Analysis of the NaCl-PuCl 3 samples showed that using the Pu rich PuCl 3 resulted in significant changes to the NaCl-PuCl 3 phase diagram. Most notably an unreported phase transition occurring at approximately 406°C and a new eutectic composition of 52.7mol% NaCl–38.7mol% PuCl 3 –2.5mol% Pu which melted at 449.3°C. Additionally, an increase in the liquidus temperatures was seen for NaCl rich compositions while lower liquidus temperatures were seen for PuCl 3 rich compositions. It can therefore be concluded that changes will occur in the NaCl-PuCl 3 binary system when using PuCl 3 with excess Pu metal. However, melting temperature analysis can provide valuable insight into the composition of the PuCl 3 and therefore the NaCl-PuCl 3 system.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRSDate not supplied

Benefits of using Electronic Data Sheets (EDS) with coreFlight Systems (cFS) - A Project Example

Recently there has been interest in the incorporation of core Flight Systems (cFS) with Spacecraft Onboard Interface Services (SOIS) Electronic Data Sheets (EDS) in the spaceflight software community. The Regenerative Fuel Cell project at the Glenn Research Center is using cFS architecture with EDS support for its monitoring and control software. The presentation will outline the benefits to using cFS with EDS support: First, EDS establishes a single source of truth for the definitions of data structures used throughout an entire mission that may otherwise be programmed in different languages and designed with different processor architectures. Not only does this help with inter-application communication via the software bus, but it also greatly simplifies communication between systems. An EDS Application Programming Interface (API) library allows the conversion of EDS data structures to and from native data structures. Second, bindings for other programming languages (e.g. Lua, Python, JSON) have been written to allow the creation and manipulation of EDS data objects within those languages. The RFC project uses Lua scripts to automatically generate binary configuration files at build time to be loaded into our cFS programs. We also use Python bindings in a graphical user interface (GUI) to allow an operator to send commands and view telemetry messages sent from cFS instances. Finally, using Lua scripts we can set up specific simulation scenarios to perform automatic functional testing. During the development of the RFC software, the software team put together a generic python GUI called “cFS-EDS-GroundStation” that provides a basic interface to an instance of cFS with EDS support. The GUI includes a basic telecommand and telemetry system that reads directly from the generated EDS databases. In the telecommand system, dropdown menus are populated with all user commands that are defined in EDS. In the telemetry system, telemetry messages are automatically decoded, written to the screen, and saved to a binary file. Additional Python scripts have been written to convert the binary data files into a comma separated value (CSV) format for further processing. We will demonstrate the basic use of the cFS-EDS-GroundStation software including adding additional commands and telemetry payload values in EDS and see them appear automatically in the cFS-EDS-Groundstation software. About the RFC project: The Regenerative Fuel Cell project is tasked with developing and demonstrating a power system consisting of a fuel cell and electrolyzer to provide power during a lunar day/night cycle. During the night, the fuel cell takes Hydrogen and Oxygen gasses and converts them into electricity, water, and heat. During the day, the electrolyzer takes input power (e.g. from a photovoltaic array) and converts water back into Hydrogen and Oxygen gasses.

Mathew Mccaskey↗
DOE OSTI2014

Non-Ideality in Solvent Extraction Systems: PNNL FY 2014 Status Report

The overall objective of this project is to develop predictive modeling capabilities for advanced fuel cycle separation processes by gaining a fundamental quantitative understanding of non-ideality effects and speciation in relevant aqueous and organic solutions. Aqueous solutions containing actinides and lanthanides encountered during nuclear fuel reprocessing have high ionic strength and do not behave as ideal solutions. Activity coefficients must be calculated to take into account the deviation from ideality and predict their behavior. In FY 2012-2013, a convenient method for determining activity effects in aqueous electrolyte solutions was developed. Our initial experiments demonstrated that water activity and osmotic coefficients of the electrolyte solutions can be accurately measured by the combination of two techniques, a Water Activity Meter and Vapor Pressure Osmometry (VPO). The water activity measurements have been conducted for binary lanthanide solutions in wide concentration range for all lanthanides (La-Lu with the exception of Pm). The osmotic coefficients and Pitzer parameters for each binary system were obtained by the least squares fitting of the water activity data. However, application of Pitzer model for the quantitative evaluation of the activity effects in the multicomponent mixtures is difficult due to the large number of the required interaction parameters. In FY 2014, the applicability of the Bromley model for the determination of the Ln(NO 3 ) 3 activity coefficients was evaluated. The new Bromley parameters for the binary Ln(NO 3 ) 3 electrolytes were obtained based on the available literature and our experimental data. This allowed for the accurate prediction of the Ln(NO 3 ) 3 activity coefficients for the binary Ln(NO 3 ) 3 electrolytes. This model was then successfully implemented for the determination of the Ln(NO 3 ) 3 activity coefficients in the ternary Nd(NO 3 ) 3 /HNO 3 /H2O, Eu(NO 3 ) 3 /HNO 3 /H 2 O, and Eu(NO 3 ) 3 /NaNO 3 /H 2 O systems. The main achievement of this work is the verified pathway for the estimation of the activity coefficients in the multicomponent aqueous electrolyte systems. The accurate Bromley electrolytes contributions obtained in this work for the entire series of lanthanide(III) nitrates (except Pm) can be applied for predicting activity coefficients and non-ideality effects for multi-component systems containing these species. This work also provides the proof-of-principle of extending the model to more complex multicomponent systems. Moreover, this approach can also be applied to actinide-containing electrolyte systems, for determination of the activity coefficients in concentrated radioactive solutions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2019

Electronic Structure Calculations for improving Catalyst Design for Use in the Hybrid Sulfur Cycle

The hybrid sulfur cycle is a promising means for efficient production of large quantities of hydrogen with a small carbon footprint. Furthermore, there is a demonstrated need to design catalysts that are sulfur tolerant and have stability at high temperatures and reduced activation energies. Theoretical calculations can serve as a blueprint for fulfilling these needs by providing fundamental mechanistic insights to guide future experimental studies. Density functional theory was used to calculate the energetics of Pt-Au systems. Adsorption energetics for the unary and binary structures were investigated to provide mechanistic insights for improved catalyst design. Results conclude that adsorption of the SO 2 molecule is further stabilized on the Pt surface with a Pt-0 dative bond compared to Au. Energetics suggest that the adsorbates are more stabilized in the Pt surface due to a stabilization of the S p bands in the electronic structure. Examination of the density of states support the postulation that SO 2 is more weakly bound to Au, thereby leading to better catalytic performance compared to Pt. These results are encouraging and we expect there to be a weakening effect of ligand adsorption on the Pt/Au surfaces when an electric field is applied.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2000

The X-ray Spectral Evolution of eta Carinae as Seen by ASCA

Using data from the ASCA X-ray observatory, we examine the variations in the X-ray spectrum of the supermassive star nu Carinae with an unprecedented combination of spatial and spectral resolution. We include data taken during the recent X-ray eclipse in 1997-1998, after recovery from the eclipse, and during and after an X-ray flare. We show that the eclipse variation in the X-ray spectrum is apparently confined to a decrease in the emission measure of the source. We compare our results with a simple colliding wind binary model and find that the observed spectral variations are only consistent, with the binary model if there is significant high-temperature emission far from the star and/or a substantial change in the temperature distribution of the hot plasma. If contamination in the 2-10 keV band is important, the observed eclipse spectrum requires an absorbing column in excess of 10(exp 24)/sq cm for consistency with the binary model, which may indicate an increase in the first derivative of M from nu Carinae near the time of periastron passage. The flare spectra are consistent with the variability seen in nearly simultaneous RXTE observations and thus confirm that nu Carinae itself is the source of the flare emission. The variation in the spectrum during the flare seems confined to a change in the source emission measure. By comparing 2 observations obtained at the same phase in different X-ray cycles, we find that the current, X-ray brightness of the source is slightly higher than the brightness of the source during the last cycle perhaps indicative of a long-term increase in the first derivative of M, not associated with the X-ray cycle.

Corcoran, M. F.↗