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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21

Signatures of chiral superconductivity in rhombohedral graphene

Chiral superconductors are unconventional superconducting states that break time-reversal symmetry spontaneously and typically feature Cooper pairing at non-zero angular momentum. Such states may host Majorana fermions and provide an important platform for topological physics research and fault-tolerant quantum computing. Despite intensive search and prolonged studies of several candidate systems, chiral superconductivity has remained elusive so far. Here we report the discovery of robust unconventional superconductivity in rhombohedral tetralayer and pentalayer graphene without moiré superlattice effects. We observed two superconducting states in the gate-induced flat conduction bands with T c up to 300 mK and charge density n e down to 2.4 ×10 11 cm −2 in five devices. Spontaneous time-reversal-symmetry breaking (TRSB) owing to orbital motion of the electron is found and several observations indicate the chiral nature of these superconducting states, including: (1) in the superconducting state, R xx shows magnetic hysteresis in varying out-of-plane magnetic field B ⊥ —absent from all other superconductors; (2) the superconducting states are robust against in-plane magnetic field and are developed within a spin-polarized and valley-polarized quarter-metal (QM) phase; (3) the normal states show anomalous Hall signals at zero magnetic field and magnetic hysteresis. Here, we also observed a critical B ⊥ of 1.4 T, higher than any graphene superconductivity, which indicates a strong-coupling superconductivity close to the Bardeen–Cooper–Schrieffer (BCS)–Bose–Einstein condensate (BEC) crossover. Our observations establish a pure carbon material for the study of topological superconductivity, with the promise to explore Majorana modes and topological quantum computing.

36 MATERIALS SCIENCE↗

Physical processes in an electron current layer causing intense plasma heating and formation of x-lines

We study the evolution of an electron current layer (ECL) through its several stages by means of three-dimensional particle-in-cell (PIC) simulations with ion to electron mass ratio M/m{sub e} = 400. An ECL evolves through the following stages: (i) Electrostatic (ES) current-driven instability (CDI) soon after its formation with half width w about 2 electron skin depth (d{sub e}), (ii) current disruption in the central part of the ECL by trapping of electrons and generation of anomalous resistivity, (iii) electron tearing instability (ETI) with significantly large growth rates in the lower end of the whistler frequency range, (iv) widening of the ECL and modulation of its width by the ETI, (v) gradual heating of electrons by the CDI-driven ES ion modes create the condition that the electrons become hotter than the ions, (vi) despite the reduced electron drift associated with the current disruption by the CDI, the enhanced electron temperature continues to favor a slow growth of the ion waves reaching nonlinear amplitudes, (vii) the nonlinear ion waves undergo modulation and collapse into localized density cavities containing spiky electric fields like in double layers (DLs), (viii) such spiky electric fields are very effective in further rapid heating of both electrons and ions. As predicted by the electron magnetohydrodynamic (EMHD) theories, the ETI growth rate maximizes at wave numbers in the range 0.4 < k{sub x}W < 0.8 where k{sub x} is the wave number parallel to the ECL magnetic field and w is the evolving half width of the ECL. The developing ETI generates in-plane currents that support out-of-plane magnetic fields around the emerging x-lines. The ETI and the spiky electrostatic structures are accompanied by fluctuations in the magnetic fields near and above the lower-hybrid (ion plasma) frequency, including the whistler frequency range. We compare our results with experimental results and satellite observation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Structural, electronic and optical properties of well-known primary explosive: Mercury fulminate

Mercury Fulminate (MF) is one of the well-known primary explosives since 17th century and it has rendered invaluable service over many years. However, the correct molecular and crystal structures are determined recently after 300 years of its discovery. In the present study, we report pressure dependent structural, elastic, electronic and optical properties of MF. Non-local correction methods have been employed to capture the weak van der Waals interactions in layered and molecular energetic MF. Among the non-local correction methods tested, optB88-vdW method works well for the investigated compound. The obtained equilibrium bulk modulus reveals that MF is softer than the well known primary explosives Silver Fulminate (SF), silver azide and lead azide. MF exhibits anisotropic compressibility (b > a > c) under pressure, consequently the corresponding elastic moduli decrease in the following order: C{sub 22} > C{sub 11} > C{sub 33}. The structural and mechanical properties suggest that MF is more sensitive to detonate along c-axis (similar to RDX) due to high compressibility of Hg⋯O non-bonded interactions along that axis. Electronic structure and optical properties were calculated including spin-orbit (SO) interactions using full potential linearized augmented plane wave method within recently developed Tran-Blaha modified Becke-Johnson (TB-mBJ) potential. The calculated TB-mBJ electronic structures of SF and MF show that these compounds are indirect bandgap insulators. Also, SO coupling is found to be more pronounced for 4d and 5d-states of Ag and Hg atoms of SF and MF, respectively. Partial density of states and electron charge density maps were used to describe the nature of chemical bonding. Ag—C bond is more directional than Hg—C bond which makes SF to be more unstable than MF. The effect of SO coupling on optical properties has also been studied and found to be significant for both (SF and MF) of the compounds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Evolution of charge density wave soft phonon modes in Pd 𝑥 ⁢ErTe 3

Here, we investigated the lattice dynamics of quasi-two-dimensional Pd-intercalated ErTe 3 in relation to its charge-density-wave (CDW) transitions by means of x-ray diffuse and meV-resolution inelastic x-ray scattering. In pristine ErTe 3 , CDW order develops at orthogonal in-plane wave vectors q$^𝑐_1$ =(0,0,0.29) (the 𝑐−CDW ) and q$^𝑎_2 $= (0.31,0,0) (the 𝑎−CDW ), with transition temperatures $𝑇^𝑐_1$ = 270K and $𝑇^𝑎_2$ = 160K, respectively. Remarkably, we observe diffuse x-ray scattering already near the higher transition temperature $𝑇^𝑐_1$ along 𝑎−CDW but at a slightly different wave vector q$^𝑎_1$ = (0.29,0,0). Inelastic x-ray scattering for Pd 0.01 ⁢ErTe 3 shows that a partial phonon softening at q$^𝑎_1$, underscoring the strong competition between ordering tendencies along the nearly equivalent in-plane axes of the orthorhombic lattice. For intercalation levels 𝑥 ≥ 0.02, the 𝑎−CDW state is suppressed. Nevertheless, a similar correlation between phonon softening and diffuse scattering persists along the [100] direction, again observed at q$^𝑎_1$ = (0.29,0,0) and $𝑇^𝑐_1$. These findings suggest that the 𝑎−CDW is fully suppressed for 𝑥 ≥ 0.02, and that the residual diffuse scattering at originates from the partial phonon softening associated with the 𝑐−CDW, reflected by the near equality of the absolute size of q$^𝑐_1$ and q$^𝑎_1$.

Maity, Avishek [Technische Univ. München, Garching↗

Ultrafast Enhancement of Ferromagnetic Spin Exchange Induced by Ligand-to-Metal Charge Transfer

Here, we theoretically predict and experimentally demonstrate a nonthermal pathway to optically enhance superexchange interaction energies in a material based on exciting ligand-to-metal charge-transfer transitions, which introduces lower-order virtual hopping contributions that are absent in the ground state. We demonstrate this effect in the layered ferromagnetic insulator CrSiTe 3 by exciting Te-to-Cr charge-transfer transitions using ultrashort laser pulses and detecting coherent phonon oscillations that are impulsively generated by superexchange enhancement via magneto-elastic coupling. This mechanism kicks in below the temperature scale where short-range in-plane spin correlations begin to develop and disappears when the excitation energy is tuned away from the charge-transfer resonance, consistent with our predictions.

36 MATERIALS SCIENCE↗

Synthesizing pseudo-Kossel lines from neutron transmission data. I. An analytical approach for recovering single-crystal orientation

The energy-dispersive neutron spectra transmitted through single crystals are characterized by sharp Bragg dips at specific wavelengths, where Bragg's law is being fulfilled for certain crystallographic planes. This phenomenon allows for developing methods for crystal-orientation determination techniques similar to electron backscatter diffraction and X-ray diffraction microscopy. This work presents a new procedure to recover the orientation matrix for single crystals using transmission spectra recorded during rotation of a crystal about an axis perpendicular to a polychromatic neutron beam. The proposed method consists of an initial transformation of the as-collected wavelength–rotation maps to a wavevector $\textit{K}$ space, resulting in linear pseudo-Kossel lines that are suitable for analysis and indexing using image-processing procedures. Further, simulated neutron transmission spectra through a copper crystal with known orientations were used to set and prove the numerical approach. This technique may be expanded for cases where the neutron beam intersects multiple single-crystal grains with different orientations.

36 MATERIALS SCIENCE↗

Effect of Pulsed IR Laser Radiation on the Dynamics and Morphology of Deformation Bands in an Aluminum–Magnesium Alloy

The dynamics and morphology of deformation bands under the simultaneous effect of mechanical loading and pulsed IR laser radiation on the surface of in aluminum–magnesium alloy AlMg6 were studied by high-speed video recording. The conditions, under which a laser pulse pierces a through hole with a diameter of an order of magnitude smaller than the thickness of a plane specimen, thus inducing the development of a complicated spatiotemporal structure of deformation bands and a macroscopic jump in the tension diagram, were determined. The morphological transitions associated with the transformation of the type, shape, and spatiostatistical distribution of bands with a change in the laser pulse energy density were revealed. The probable mechanism of this phenomenon was discussed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Nonlinear Curvature Expressions for Combined Flapwise Bending, Chordwise Bending, Torsion and Extension of Twisted Rotor Blades

The nonlinear curvature expressions for a twisted rotor blade or a beam undergoing transverse bending in two planes, torsion, and extension were developed. The curvature expressions were obtained using simple geometric considerations. The expressions were first developed in a general manner using the geometrical nonlinear theory of elasticity. These general nonlinear expressions were then systematically reduced to four levels of approximation by imposing various simplifying assumptions, and in each of these levels the second degree nonlinear expressions were given. The assumptions were carefully stated and their implications with respect to the nonlinear theory of elasticity as applied to beams were pointed out. The transformation matrices between the deformed and undeformed blade-fixed coordinates, which were needed in the development of the curvature expressions, were also given for three of the levels of approximation. The present curvature expressions and transformation matrices were compared with corresponding expressions existing in the literature.

Kvaternik, R. G.↗

Biaxial fatigue loading of notched composites

Thin walled, 2.54-cm (1-in.) diameter tubular specimens of T300/934 graphite/epoxy were fabricated and fatigue cycled in combinations of axial, torsional, and internal pressure loading. Two different four-ply layup configurations were tested: (0/90)S and (+ or - 45)S; all tubes contained a 0.48-cm (3/16-in.) diameter circular hole penetrating one wall midway along the tube length. S-N curves were developed to characterize fatigue behavior under pure axial, torsional, or internal pressure loading, as well as combined loading fatigue. A theory was developed based on the Hill plane stress model which enabled the S-N curve for combined stress states to be predicted from the S-N data for the uniaxial loading modes. Correlation of the theory with the experimental data proved to be remarkably good.

Francis, P. H.↗

Mixer nozzle aeroacoustic characteristics for the energy efficient engine

Aeroacoustic tests are conducted on scale model mixer nozzle configurations, a separate flow nozzle, and a baseline conical nozzle in an anechoic chamber free-jet facility to investigate exhaust system designs. Far-field acoustic data and exhaust jet plume aerodynamic data are obtained for various combinations of exhaust jet velocity and simulated flight speed, with corrected microphone data at a constant 12.2 m arc distance, and scaled acoustic data at a sideline distance of 457 m. It is found that jet plume aerodynamic and acoustic characteristics of lobed mixer exhaust systems are similar to those of a conical nozzle operating at the same specific thrust, although differences occur at high frequencies, where the sound pressure level of the mixer nozzle is 1-5 dB higher than that of a conical nozzle. In addition, no direct correlation is found between exit plane turbulence levels and plume development or acoustic characteristics for mixer exhaust configurations.

Gliebe, P. R.↗

Lightning mapper and the future

A trade-off analysis was completed that reveals how the lightning mapper detection efficiency will change as a function of interference filter bandwidth, pixel field of view, and telescope aperture. It is shown that the critical parameter on which we have minimum flexibility is filter band-width. The problem is that too narrow a filter bandwidth is incompatible with wide areal coverage. The trade-off analysis demonstrates that an 80 percent lightning detection efficiency will technically be relatively straight-forward, while a 90 percent detection efficiency will apparently be difficult to achieve. Three focal plane designs are currently under consideration. One would use a single large, solid state silicon integrating array with multiple output channels and off-the-focal-plane analog, time domain, background removing fibers. A second design would use the same technology, but the sensor would consist of up to four virtually independent focal plane arrays. This design reduces the areal coverage of each detector. Thus narrower interference filters could be utilized. Superior performance would be realized at a probable increase in cost. The final design would use a three-dimensional focal plane in order to perform background removal at the focal plane. Superior performance would be achieved along with reduced weight and power requirements. Unfortunately, this focal plane technology is still under development.

Christian, H. J.↗

Stresses and deformations in angle-ply composite tubes

The stress and deformations in angle-ply composite tubes subjected to axisymmetric thermal loading were investigated both experimentally and analytically. For the theoretical portion a generalized plane strain elasticity analysis was developed. The analysis included mechanical and thermal loading, and temperature-dependent material properties. The elasticity analysis was also used to study the effect of including a thin metallic coating on a graphite-epoxy tube. The stresses in the coatings were found to be quite high, exceeding the yield stress of aluminum. An important finding in the analytical studies was the fact that even tubes with a balanced-symmetric lamination sequence exhibit shear deformation, or twist. For the experimental portion an apparatus was developed to measure torsional and axial response in the temperature range of 140 to 360 K. Eighteen specimens were tested, combining three material systems, eight lamination sequences, and three off-axis ply orientation angles. For the twist response, agreement between analysis and experiment was found to be good. The axial response of the tubes tested was found to be greater than predicted by a factor of three. As a result, it is recommended that the thermally induced axial deformations be investigated, both experimentally and analytically.

Rousseau, Carl Q.↗

Mercury cadmium telluride short- and medium-wavelength infrared staring focal plane arrays

Short and medium IR wavelength 64 x 64 hybrid focal plane arrays (FPAs) have been developed using sapphire-grown HgCdTe. The short wavelength arrays were developed for a prototype airborne imaging spectrometer, while those of medium wavelength are suitable for tactical missile seekers and strategic surveillance systems. Attention is presently given to results obtained for these FPAs' current-voltage characteristics, as well as for their characterization at different temperatures. The detector arrays were also mated to a multiplexer and characterized under different operating conditions. The unit cell size used is 52 x 52 microns.

Vural, Kadri↗

HgCdTe 256x256 NWIR FPA

Researchers developed a HgCdTe 256x256 focal plane array (FPA) which operates in the 1 to 5 micron band. This is presently the largest demonstrated HgCdTe FPA. The detector material is HgCdTe on sapphire (PACE-1 technology) which has a low thermal expansion mismatch with silicon. The multiplexer is a CMOS FET-switch device processed through a commercial silicon foundry. The multiplexer input is direct injection and the charge capacity is about 2 times 10 to the 7th power electrons. The kTC limited read noise is 400 electrons. Researchers demonstrated high background imaging using the device. The broadband quantum efficiency is measured to be 59 percent. Dark currents less than 0.1 pA were measured at 77 K for detectors processed on PACE-1 material with 4.9 microns cutoff. The dark currents decrease as the temperature is lowered, and researchers are presently studying the T less than 77 K characteristics. The interconnect yield is greater than 95 percent. The devices are available for astronomical applications.

Vural, Kadri↗

Analytical solutions to constrained hypersonic flight trajectories

The flight trajectory of aerospace vehicles subject to a class of path constraints is considered. The constrained dynamics is shown to be a natural two-time-scale system. Asymptotic analytical solutions are obtained. Problems of trajectory optimization and guidance can be dramatically simplified with these solutions. Applications in trajectory design for an aerospace plane strongly support the theoretical development.

Lu, Ping↗

A combined experimental and finite element study to predict the failure mechanisms in SiC coated carbon/carbon composites at room and elevated temperatures under flexural loading

Response of quasi-isotropic laminates of SiC coated Carbon/Carbon (C/C) composites have been investigated under flexural loading at various temperatures. Variation of load-deflection behavior with temperatures are studied. Increase in flexural strength and stiffness are observed with the rise in temperature. Extensive analyses through Optical Microscope (OM) and Non-Destructive Evaluation (NDE) have been performed to understand the failure mechanisms. Damage zone is found only within the neighborhood of the loading plane. Isoparametric layered shell elements developed on the basis of the first order shear deformation theory have been used to model the thin laminates of C/C under flexural loading. Large deformation behavior has been considered in the finite element analysis to account for the non-linearities encountered during the actual test. Data generated using finite element analysis are presented to corroborate the experimental findings, and a comparison in respect of displacement and stress-strain behavior are given to check the accuracy of the finite element analysis. Reasonable correlation between the experimental and finite element results have been established.

Mahfuz, Hassan↗

Analytical solutions to constrained hypersonic flight trajectories

The flight trajectory of aerospace vehicles subject to a class of path constraints is considered. The constrained dynamics is shown to be a natural two-time-scale system. Asymptotic analytical solutions are obtained. Problems of trajectory optimization and guidance can be dramatically simplified with these solutions. Applications in trajectory design for an aerospace plane strongly support the theoretical development.

Lu, Ping↗